THIN-FILM RESISTOR (TFR) WITH DISPLACEMENT-PLATED TFR HEADS
20220157927 · 2022-05-19
Assignee
Inventors
Cpc classification
H01L23/5226
ELECTRICITY
H01L21/76849
ELECTRICITY
H01L23/5228
ELECTRICITY
H01L21/76805
ELECTRICITY
H01L21/76834
ELECTRICITY
H01L23/53238
ELECTRICITY
H01L28/24
ELECTRICITY
International classification
H01C7/00
ELECTRICITY
Abstract
A thin film resistor (TFR) module may be formed in copper interconnect in an integrated circuit device. A pair of displacement-plated TFR heads may be formed by forming a pair of copper TFR head elements (e.g., damascene trench elements) spaced apart from each other in a dielectric region, and displacement plating a barrier region on each TFR head element to form a displacement-plated TFR head. A TFR element may be formed on the pair of displacement-plated TFR heads to define a conductive path between the pair of TFR head elements through the TFR element and through the displacement-plated barrier region on each metal TFR head. Conductive contacts may be formed connected to the pair of displacement-plated TFR heads. The displacement-plated barrier regions may protect the copper TFR heads from copper corrosion and/or diffusion, and may comprise CoWP, CoWB, Pd, CoP, Ni, Co, Ni—Co alloy, or other suitable material.
Claims
1. A method of manufacturing a thin film resistor (TFR) module in an integrated circuit (IC) structure, the method comprising: forming a pair of displacement-plated TFR heads by: forming a pair of TFR head elements spaced apart from each other in a dielectric region; and displacement plating a barrier region on each TFR head element; forming a TFR element on the pair of displacement-plated TFR heads to define a conductive path connecting the pair of TFR head elements through the TFR element and through the displacement-plated barrier region on each metal TFR head; and forming conductive contacts, each conductively coupled to a respective one of the pair of displacement-plated TFR heads.
2. The method of claim 1, wherein the TFR element comprises SiCr or SiCCr.
3. The method of claim 1, comprising forming the pair of TFR head elements using a damascene process.
4. The method of claim 1, wherein the TFR head elements comprise Cu damascene structures.
5. The method of claim 1, wherein the barrier region formed on each TFR head element comprises cobalt tungsten phosphide (CoWP).
6. The method of claim 1, wherein the TFR element fully covers a top area of each displacement-plated TFR head.
7. The method of claim 1, wherein the TFR film includes (a) a pair of head regions, each covering a top area of one of the displacement-plated TFR heads and (b) a connecting region connecting the pair of head regions, the connecting region having a smaller width than the head regions.
8. An integrated circuit (IC) structure, comprising: a thin film resistor (TFR) module, comprising: a pair of spaced-apart displacement-plated TFR heads, each comprising: a pair of TFR head elements spaced apart from each other in a dielectric region; and a displacement-plated barrier region at a top of each TFR head element; a TFR element formed on the pair of spaced-apart displacement-plated TFR heads to define a conductive path between the pair of TFR head elements through the TFR element and through the displacement-plated barrier region at the top of each metal TFR head; and conductive contacts coupled to the pair of displacement-plated TFR heads.
9. The IC structure of claim 8, wherein the TFR element comprises SiCr or SiCCr.
10. The IC structure of claim 8, wherein the pair of TFR head elements comprise copper damascene structures.
11. The IC structure of claim 8, wherein the displacement-plated barrier region at the top of each TFR head element comprises cobalt tungsten phosphide (CoWP).
12. The IC structure of claim 8 wherein the TFR element fully covers a top area of each displacement-plated TFR head.
13. The IC structure of claim 8, wherein the TFR film includes (a) a pair of head regions, each covering a top area of one of the displacement-plated TFR heads and (b) a connecting region connecting the pair of head regions, the connecting region having a smaller width than the head regions.
14. An integrated circuit (IC) structure, comprising: a thin film resistor (TFR) module comprising: a pair of spaced-apart displacement-plated TFR heads, comprising: a pair of TFR head elements formed in a first metal layer; and a displacement-plated barrier region formed on each TFR head element; and a TFR element formed on the pair of spaced-apart displacement-plated TFR heads to define a conductive path connecting the pair of TFR head elements through the TFR element and through the displacement-plated barrier region formed on each TFR head element; and a first interconnect structure comprising: an interconnect trench element formed in the first metal layer; and a displacement-plated barrier region formed on the interconnect trench element.
15. The IC structure of claim 14, further comprising a TFR film region formed on the displacement-plated barrier region formed on the interconnect trench element and spaced apart from the TFR element, wherein the TFR film region and the TFR element are formed from a common TFR film.
16. The IC structure of claim 14, wherein the TFR element comprises SiCr or SiCCr.
17. The IC structure of claim 14, wherein the pair of TFR head elements and the interconnect trench element comprise copper damascene structures.
18. The IC structure of claim 14, wherein the displacement-plated barrier region formed on each TFR head element and the displacement-plated barrier region formed on the interconnect trench element each comprise cobalt tungsten phosphide (CoWP).
19. The IC structure of claim 14, wherein the TFR film includes (a) a pair of head regions, each covering a top area of one of the displacement-plated TFR heads and (b) a connecting region connecting the pair of head regions, the connecting region having a smaller width than the head regions.
20. The IC structure of claim 14, further comprising a second metal layer comprising: a respective TFR contact connected to each displacement-plated TFR head by a respective TFR contact via; and an upper interconnect structure connected to the first interconnect structure by an interconnect via.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0031] Example aspects of the present disclosure are described below in conjunction with the figures, in which:
[0032]
[0033]
[0034]
[0035]
[0036] It should be understood that the reference number for any illustrated element that appears in multiple different figures has the same meaning across the multiple figures, and the mention or discussion herein of any illustrated element in the context of any particular figure also applies to each other figure, if any, in which that same illustrated element is shown.
DETAILED DESCRIPTION
[0037] Embodiments of the present disclosure provide TFR modules including a TFR element formed on a pair of displacement-plated TFR heads. Each displacement-plated TFR head may include a displacement-plated barrier region formed on a copper TFR head element, e.g., a Cu damascene trench structure formed in a Cu interconnect layer. The TFR element formed on the displacement-plated TFR heads provides a conductive path connecting the pair of Cu TFR head elements through the TFR element and through the displacement-plated barrier regions. The displacement-plated barrier regions may both (a) provide a reliable conductive contact between the TFR element and Cu TFR heads and (b) protect upper surfaces of the Cu TFR head elements during the manufacture of the TFR module. In some embodiments the displacement-plating may comprise CoWP, CoWB, Pd, CoP, Ni, Co, Ni—Co alloy, or any other suitable material. Although the present disclosure focuses on embodiments formed in Cu interconnect, in other embodiments the TFR module may be formed in damascene interconnect of other metals, for example iridium (Ir), rhodium (Rh), ruthenium (Ru), or cobalt (Co).
[0038]
[0039] Each TFR head 206 and lower interconnect structure 208 may comprise a Cu trench element 210 having a displacement-plated barrier region 216 formed at the top of the Cu trench element 210 by a displacement plating process on an exposed top surface of each Cu trench element 210. In particular, each TFR head 206 may comprise a Cu TFR head element 211 having a displacement-plated barrier region 216 formed thereon, and lower interconnect structure 208 may comprise a Cu interconnect element 212 having a displacement-plated barrier region 216 formed thereon. Thus, TFR heads 206 and lower interconnect structure 208 may be referred to as “displacement-plated TFR heads 206” and “displacement-plated lower interconnect structure 208.” As discussed below, the displacement-plated barrier regions 216 may protect each Cu trench element 210 from corrosion during manufacturing of the IC structure 200.
[0040] In some embodiments, each Cu trench element 210 may comprise a Cu damascene trench element formed over a barrier layer 214 (e.g., a Ta/TaN bilayer) deposited in a respective trench. The displacement-plated barrier regions 216 formed over each Cu trench element 210 (including Cu TFR head elements 211 and Cu interconnect element 212) may comprise metal, to thereby define a conductive path between the TFR element 222 and Cu TFR head elements 211, as indicated by the double-headed arrow CP in
[0041] In addition, the displacement-plated barrier regions 216 may protect a top surface of each Cu trench element 210 during subsequent construction of the TFR module 202 and interconnect structure 204, e.g., to prevent or reduce copper corrosion, which may be important for the resulting reliability of the TFR module 202 and interconnect structure 204. Thus, the displacement-plated barrier regions 216 may be formed from material(s) suitable for both (a) providing an effective electrical contact between the TFR element 222 and Cu TFR head elements 211 and (b) protecting Cu trench elements 210 (including Cu TFR head elements 211 and Cu interconnect element 212) from corrosion or other degradation, e.g., during construction of the TFR module 202 and interconnect structure 204. In some embodiments, the displacement-plated barrier regions 216 may comprise CoWP, found to be particularly suitable for the properties discussed above. In other embodiments, the displacement-plated barrier regions 216 may comprise CoWB, Pd, CoP, Ni, Co, Ni—Co alloy, or any other suitable material.
[0042] As discussed in more detail below, the TFR element 222 may be formed by (a) depositing a TFR film 220, e.g., comprising SiCCR or SiCr, over the displacement-plated TFR heads 206 and displacement-plated lower interconnect structure 208, and (b) patterning the TFR film 220 to define (i) the TFR element 222 bridging the displacement-plated TFR heads 206 and (ii) a TFR film region 224 over the displacement-plated lower interconnect structure 208. A TFR cap 230 (e.g., comprising a silicon nitride or silicon oxide) may be formed over the TFR film 220, and an optional dielectric barrier layer 234 may be formed over the TFR cap. The dielectric barrier layer 234 may be optional, e.g., depending on the suitability of underlying layers (including the displacement-plated barrier regions 216) to act as a copper diffusion barrier. For example, the optional dielectric barrier layer 234 may be omitted where the displacement plated layer 216 itself provides an effective copper diffusion barrier for the underlying Cu damascene trench element 210. For example, in some embodiments TFR cap 230 is formed from SiN and provides an additional copper diffusion barrier, such that the dielectric barrier layer 234 may be omitted.
[0043] Each displacement-plated TFR head 206 and displacement-plated lower interconnect structure 208 may be contacted by circuitry in other metal layer(s). For example, as mentioned above, each displacement-plated TFR head 206 may be connected to a TFR contact 242 formed in a metal layer M.sub.x+1 by a respective TFR contact via 240a, and the displacement-plated lower interconnect structure 208 may be connected to an upper interconnect structure 244 formed in a metal layer M.sub.x+1 by a respective interconnect via 240b. In the illustrated embodiment, metal layer M.sub.x+1 structures 242, 244 and vias 240a, 240b are formed as Cu dual damascene structures. A dielectric barrier layer 246 may be formed over metal layer M.sub.x+1.
[0044] In some embodiments, TFR element 222 may comprise SiCCR, SiCr, or NiCr with a thickness in the range of 50 Å-1000 Å, which may provide a sheet resistance R.sub.s in the range of 100 Ω/square to 10 kΩ/square, or about 1 kΩ/square, and a temperature coefficient of resistance (TCR) close to 0, for example in the range of −100 ppm/° C. to +100 ppm/° C.
[0045] Although metal layers M.sub.x and M.sub.x+1 may comprise copper as discussed above, in other embodiments metal layer M.sub.x and/or M.sub.x+1 (and thus Cu trench elements 210, 242, 244) may be formed from other metal(s), for example Iridium (Ir), Rhodium (Rh), Ruthenium (Ru), or Cobalt (Co). The various barrier layers, e.g., displacement-plated barrier regions 216, the optional dielectric barrier layer 234, and/or dielectric barrier layer 246 may be adjusted accordingly, i.e. the constituent elements thereof, based on the selected interconnect metal.
[0046]
[0047] First, as shown in
[0048] After the CMP process, the exposed top surface 325 of each Cu trench element 310 is typically susceptible to oxidation, for example from the oxygen in the air, moisture in the air, or water residue left from a post CMP clean. Such corrosion can result in yield loss and reliability failure of the resulting IC device. Exposure to light may further accelerate such oxidation or corrosion process. Thus, it may be beneficial to protect the upper surface of each Cu trench element 310 soon after the CMP to reduce this corrosion risk.
[0049] Thus, as shown in
[0050] Using a displacement plating process to form displacement-plated barrier regions 324 on each Cu trench element 310 allows for selective formation of a metal diffusion barrier on each Cu trench element 310, but not on the areas of dielectrics region 312 between the Cu trench element 310s. This may be advantageous over other techniques for forming a separate barrier region over Cu trench element 310, for example by depositing a barrier layer (e.g., Ta/TaN layer) over the full wafer and etching selected areas (e.g., between the various Cu trench elements) to avoid shorting the circuit, which may be significantly more costly than the displacement plating process.
[0051] Next, as shown in
[0052] Next, as shown in
[0053] In this embodiment, the patterned photomask 340 fully covers the patterned copper layer M.sub.x, or in other words, the patterned photomask 340 covers the full area (from the top view shown in
[0054] In addition, patterning the larger percentage of the wafer area may substantially reduce the subsequent plasma etch burden (by reducing the area to etch). In addition, the risk of plasma etch penetrating through the displacement-plated barrier regions 324 at the top of each Cu trench may be reduced or eliminated. Moreover, by pattering the full copper layer M.sub.x, the photomask may be generated in a straightforward manner, e.g., by first reverse tuning the mask used to form the Cu trench layer M.sub.x, then performing a logic “OR” of the reverse tuned mask with the TFR module pattern (e.g., to form the dog-bone or bowtie shape).
[0055] Next, as shown in
[0056] TFR element 330a formed on the pair of displacement-plated TFR heads 322 as disclosed above thereby defines a conductive path, indicated by double-headed arrow CP, between the two Cu TFR head elements 314 through the TFR element 330a and through the displacement-plated barrier regions 324.
[0057] Next, as shown in the cross-sectional side view of
[0058] In the illustrated embodiment, Cu trench elements 366a, 366b and interconnect vias 364a, 364b comprise dual damascene Cu structures, e.g., formed by depositing a barrier layer 368 (e.g., a Ta/TaN bilayer), copper seed, and followed by copper plating, in respective dual damascene trenches and vias. Finally, a dielectric barrier layer 370, e.g., comprising silicon nitride (SiN) or silicon carbide (SiC), without limitation, may be formed over metal layer M.sub.x+1.
[0059] In some embodiments, each interconnect via 364a, 364b (including barrier layer 368), which as indicated may be formed of Cu, may extend down to the displacement-plated barrier region 324 on each respective Cu trench element 310, such that the displacement-plated barrier region 324 on each Cu trench element 310 provides a conductive coupling between the respective Cu via 364a, 364b and Cu trench element 310. In other embodiments, each Cu via 364 extends further down, into the respective Cu trench element 310, to provide a direct conductive coupling between the Cu via 364 and Cu trench element 310.
[0060] In some embodiments, TFR element 330a may comprise SiCCR, SiCr, or NiCr with a thickness in the range of 50 Å-1000 Å, which may provide a sheet resistance R.sub.s in the range of 100 Ω/square to 10 kΩ/square, or about 1 kΩ/square, and a temperature coefficient of resistance (TCR) close to 0, for example in the range of −100 ppm/° C. to +100 ppm/° C.
[0061]
[0062] Thus, the state of IC structure 900 shown in
[0063]