Method for fabricating CU interconnection using graphene
11328994 · 2022-05-10
Assignee
- Semiconductor Manufacturing International (Shanghai) Corporation (Shanghai, CN)
- Semiconductor Manufacturing International (Beijing) Corporation (Beijing, CN)
Inventors
Cpc classification
H01L21/76885
ELECTRICITY
H01L21/32055
ELECTRICITY
H01L21/76852
ELECTRICITY
H01L21/76805
ELECTRICITY
H01L21/76837
ELECTRICITY
International classification
H01L23/48
ELECTRICITY
H01L21/3205
ELECTRICITY
Abstract
A method for manufacturing an interconnect structure includes providing a substrate structure comprising a substrate, a first dielectric layer on the substrate, and a metal interconnect line formed in the first dielectric layer and extending through to a surface of the substrate; removing a portion of the first dielectric layer on opposite sides of the metal interconnect line to expose a surface of the metal interconnect line and to form a recess; forming a graphene layer on the exposed surface of the metal interconnect line; and forming a second dielectric layer filling the recess and covering the graphene layer. The interconnect structure can prevent metal atoms of the metal interconnect line from diffusion into the first and second dielectric layers.
Claims
1. An interconnect structure, comprising: a substrate; a metal interconnect line including an upper surface and a side surface on the substrate; a graphene layer conformally covering the upper surface and the side surface of the metal interconnect line; a first barrier layer in contact with a surface portion of the substrate; a first dielectric layer on the first barrier layer and in contact with a portion of the graphene layer on the side surface of the metal interconnect line, the dielectric layer being made of a material different from a material of the first barrier layer and having an upper surface flush with an upper surface of the graphene layer, wherein the first dielectric layer has a first portion directly under the metal interconnect line; and a second barrier layer having a first portion directly between the metal interconnect line and the first portion of the first dielectric layer and a second portion directly between the metal interconnect line and the first barrier layer, wherein the first portion of the first dielectric layer is completely surrounded by the first portion of the second barrier layer and the first barrier layer.
2. The interconnect structure of claim 1, wherein the dielectric layer does not cover a portion of the graphene layer on the upper surface of the metal interconnect line.
3. The interconnect structure of claim 1, further comprising: a second dielectric layer on the graphene layer for forming a second interconnect structure.
4. The interconnect structure of claim 2, further comprising: a third barrier layer on the upper surface of the metal interconnect line and on the dielectric layer; and a third dielectric layer on the third barrier layer for forming a new interconnect structure.
5. The interconnect structure of claim 1, wherein the dielectric layer further covers a portion of the graphene layer on the upper surface of the metal interconnect line.
6. The interconnect structure of claim 5, further comprising: a second dielectric layer on the first dielectric layer for forming a second interconnect structure.
7. The interconnect structure of claim 6, further comprising: a third barrier layer between the first dielectric layer and the second dielectric layer.
8. The interconnect structure of claim 1, further comprising an amorphous carbon layer between the first barrier layer and the dielectric layer.
9. The interconnect structure of claim 1, wherein the first barrier layer comprises SiCN, and the second barrier layer comprises Ta, TaN, or stacked layers of Ta and TaN.
10. The interconnect structure of claim 1, wherein the graphene layer comprises a layer of fluorinated graphene.
11. The interconnect structure of claim 1, wherein the metal interconnect line comprises a damascene structure.
12. The interconnect structure of claim 1, wherein the metal interconnect line comprises copper, and the dielectric layer comprises silicon oxide or a low-k dielectric material.
13. The interconnect structure of claim 1, wherein the graphene layer comprises 1 to 30 layers of monoatomic graphene layers.
14. The interconnect structure of claim 1, wherein the metal interconnect line extends through the dielectric layer and the first barrier layer.
15. The interconnect structure of claim 1, wherein the metal interconnect line comprises a lower portion surrounding a structure comprising a portion of the first barrier layer and a portion of the dielectric layer on the portion of the first barrier layer.
16. The interconnect structure of claim 15, wherein the metal interconnect line further comprises an upper portion on the lower portion, the upper portion having a lateral surface greater than a lateral surface of the lower portion.
17. The interconnect structure of claim 16, wherein the first portion of the dielectric layer on the portion of the first barrier layer has a slanted surface toward the upper portion of the metal interconnect line.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
(17)
(18)
(19)
(20)
(21)
(22)
DETAILED DESCRIPTION OF THE INVENTION
(23) Embodiments of the present invention now will be described more fully hereinafter with reference to the accompanying drawings. The invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. The features may not be drawn to scale, some details may be exaggerated relative to other elements for clarity. Like numbers refer to like elements throughout.
(24) It will be understood that when an element such as a layer, region or substrate is referred to as being “on” or extending “onto” another element, it can be directly on or extend directly onto the other element or intervening elements may also be present. In contrast, when an element is referred to as being “directly on” or extending “directly onto” another element, there are no intervening elements present. It will also be understood that when an element is referred to as being “connected” or “coupled” to another element, it can be directly connected or coupled to the other element or intervening elements may be present. In contrast, when an element is referred to as being “directly connected” or “directly coupled” to another element, there are no intervening elements present.
(25) Relative terms such as “below” or “above” or “upper” or “lower” or “horizontal” or “lateral” or “vertical” may be used herein to describe a relationship of one element, layer or region to another element, layer or region as illustrated in the figures. It will be understood that these terms are intended to encompass different orientations of the device in addition to the orientation depicted in the figures.
(26) The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms “a”, “an”, and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises”, “comprising”, “includes”, and/or “including” when used herein, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
(27) Embodiments of the invention are described herein with reference to cross-sectional illustrations that are schematic illustrations of idealized embodiments and intermediate structures) of the invention. The thickness of layers and regions in the drawings may be enlarged relative to other layers and regions for clarity. Additionally, variations from the shapes of the illustrations as a result, for example, of manufacturing techniques and/or tolerances, are to be expected. Thus, embodiments of the invention should not be construed as limited to the particular shapes of regions illustrated herein but are to include deviations in shapes that result, for example, from manufacturing. For example, an implanted region illustrated as a rectangle will, typically, have rounded or curved features and/or a gradient of implant concentration at its edges rather than a discrete change from implanted to non-implanted region. Likewise, a buried region formed by implantation may result in some implantation in the region between the buried region and the surface through which the implantation takes place. Thus, the regions illustrated in the figures are schematic in nature and their shapes are not intended to illustrate the actual shape of a region of a device and are not intended to limit the scope of the invention.
(28) Embodiments of the present disclosure now will be described more fully hereinafter with reference to the accompanying drawings, in which embodiments of the disclosure are shown. This disclosure may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein.
(29)
(30) Step 102: providing a substrate structure including a substrate, a first dielectric layer on the substrate, and a metal interconnect line (wire) extending through the first dielectric layer.
(31) Step 104: removing a portion of the first dielectric layer on the metal interconnect line to form a recess and expose a surface of the metal interconnection line.
(32) Step 106: forming a graphene layer on the exposed surface of the metal interconnect line.
(33) Step 108: forming a second dielectric layer filling the recess and covering the graphene layer.
(34) The present inventor has discovered that the graphene atomic layer can insulate the metal interconnect line from contacting external active medium, and even under heating, there is no significant oxidation in the graphene atomic layer, and the graphene has good anti-oxidation performance.
(35) In the method of manufacturing the interconnect structure according to the present disclosure, the dielectric layer on the metal interconnect line is removed to expose a surface of the metal interconnect line, the graphene layer is formed on the exposed surface of the metal interconnect line, and a new (next) dielectric layer is formed. The graphene layer separates the metal interconnect line from the dielectric layer, so that metal atoms of the metal interconnect line can be prevented from diffusing into the dielectric layer. In addition, the high oxidation resistance of the graphene layer prevents the graphene layer from being oxidized even when the graphene layer is exposed to air, further preventing the metal interconnect line from being oxidized by the air, thereby improving the reliability of the device.
(36)
(37) Referring to
(38) It is to be understood that substrate 201 may include a semiconductor substrate, and a semiconductor device and a shallow trench isolation region (not shown) formed on the semiconductor substrate. In one embodiment, the metal interconnect line may be a damascene interconnect structure, i.e., metal interconnect line 203 may include a wide upper portion and a narrow lower portion, as shown in the left portion of metal interconnect line 203 in
(39) Next, referring to
(40) Wet or dry etching may be used to remove the portion of first dielectric layer 202 on the opposite sides of the metal interconnect line in accordance with the material of first dielectric layer 202. For example, in the case where the material of first dielectric layer 202 is a polyethylene oxide (PEOX), the PEOX may be removed using a dilute hydrofluoric acid. For example, in the case where the material of first dielectric layer 202 is a low-k or ultra-low-k silicon carbide (SiOCH), the SiOCH may be removed using a hydrogen-containing plasma.
(41) Next, referring to
(42) In one embodiment, graphene layer 205 may be formed using a chemical vapor deposition (CVD) process. The CVD process conditions may include supplying a reaction gas including methane, hydrogen, and a carrier gas, which may be, for example, nitrogen or argon; at a reaction temperature in the range between 600° C. and 1500° C.; and a reaction time in the range between 5 minutes and 300 minutes. The flow rate of the carrier gas is in the range between 50 sccm and 10,000 sccm, the ratio of the flow rate of methane to the flow rate of the carrier gas is in the range between 0.05% and 50%, and the ratio of the flow rate of the hydrogen gas to the flow rate of the carrier gas is in the range between 0.05% and 50%. In one embodiment, graphene layer 205 may include 1 to 30 layers of monoatomic graphene layers, e.g., 5 layers, 10 layers, 25 layers, etc. In addition, graphene layer 205 may include a layer of fluorinated graphene, which is thermally stable and chemically more stable to allow a better insulation of the metal interconnect line from the dielectric layer.
(43) Next, referring to
(44) Next, referring to
(45) An interconnect structure can thus be obtained according to the manufacturing method shown and described according to
(46) An interconnect structure according to an embodiment of the present disclosure will be described with reference to
(47) Referring to
(48) An interconnect structure according to another embodiment of the present disclosure will be described with reference to
(49) Referring to
(50)
(51) Referring to
(52) Next, referring to
(53) Next, referring to
(54) Next, referring to
(55) Next, referring to
(56) An interconnect structure can thus be obtained according to the manufacturing method shown and described in
(57) An interconnect structure according to an embodiment of the present disclosure will be described with reference to
(58) Referring to
(59) An interconnect structure according to another embodiment of the present disclosure will be described with reference to
(60) Further, the interconnect structures in
(61) Thereafter, a third barrier layer 208 may be formed on the interconnect structures in
(62) Comparing with the interconnect structure in
(63) Comparing with the interconnect structure in
(64)
(65) Referring to
(66) Next, referring to
(67) Thereafter, first dielectric layer 202 and first barrier layer 301 are sequentially etched using patterned first hardmask 401 as a mask to form a through-hole extending to substrate 201.
(68) In one embodiment, the through-hole is formed as a through-hole having a damascene structure. The formation of the through-hole will be described with reference to
(69) Referring to
(70) Referring to
(71) Referring to
(72) Next, referring to
(73) Next, referring to
(74) Thereafter, a planarization process is performed to remove patterned first hardmask 401 and expose a surface of the remaining first dielectric layer 202, thereby forming the substrate structure shown in
(75) In summary, embodiments of the present disclosure provide detailed description of a semiconductor device and method of manufacturing the same. In order not to obscure the concept of the present disclosure, some of the details known in the art are not described.
(76) As used herein, the term “substrate” may include, but is not limited to, a substrate of a semiconductor material (e.g., a silicon substrate). In an example embodiment, the term “substrate” may also include a semiconductor device formed on a substrate of a semiconductor material. In another example embodiment, the term “substrate” may also include a metal contact formed on a substrate of a semiconductor material.
(77) As used herein, the term “flush” may include, but is not limited to, a substantially flat surface instead of absolute flat, that allows for some errors within the process tolerance and coplanar with another flat surface. In other words, the term “flush” is defined to include surfaces that are substantially disposed on the same plane, but may include minor differences with the process tolerance.
(78) References in the specification to “one embodiment”, “an embodiment”, “an example embodiment”, “some embodiments”, etc., indicate that the embodiment described may include a particular feature, structure, or characteristic, but every embodiment may not necessarily include the particular feature, structure, or characteristic. Moreover, such phrases are not necessarily referring to the same embodiment. Further, when a particular feature, structure, or characteristic is described in connection with an embodiment, it is submitted that it is within the knowledge of one skilled in the art to affect such feature, structure, or characteristic in connection with other embodiments whether or not explicitly described.
(79) It is to be understood that the above described embodiments are intended to be illustrative and not restrictive. Many embodiments will be apparent to those of skill in the art upon reviewing the above description. The scope of the invention should, therefore, be determined not with reference to the above description, but instead should be determined with reference to the appended claims along with their full scope of equivalents.