Thermoplastic resin composition with improved UV resistance

Abstract

Thermoplastic resin composition comprising: (a1) at least one styrene-acrylonitrile copolymer component A1, (a2) at least one acrylonitrile styrene acrylate graft copolymer A2 as impact modifier, (a3) optionally at least one thermoplastic polymer A3 other than components A1 and A2, (b) at least one pigment B, (c) at least one hindered amine UV light stabilizer C1 and at least one UV absorber C2 different from C1, and (d) optionally further polymer additives D, other than components B, C1, C2, and E, (e) at least one metal scavenger component E.

Claims

1. A thermoplastic resin composition comprising: (a1) at least one styrene-acrylonitrile copolymer component A1, (a2) at least one acrylonitrile styrene acrylate graft copolymer A2 as impact modifier, (a3) optionally at least one thermoplastic polymer A3 other than components A1 and A2, (b) at least one pigment B, (c) at least one hindered amine UV light stabilizer C1 and at least one UV absorber C2 different from C1, (d) optionally further polymer additives D, other than components B, C1, C2, and E, and (e) at least one metal scavenger component E; wherein the styrene-acrylonitrile copolymer component A1 has an acrylonitrile content of from 5 to 35 wt.-% based on the total weight of the styrene-acrylonitrile copolymer component A1.

2. The thermoplastic resin composition according to claim 1, comprising 70.0 to 99.4 wt.-%, based on the total weight of the composition, of components A1, A2, and optionally A3, and comprising 0.5 to 7.0 wt.-%, based on the total weight of the composition, of component B, and comprising 0.1 to 1.5 wt.-% based on the total weight of the composition, of components C1 and C2.

3. The thermoplastic resin composition according to claim 1, comprising: (i) of from 87.5 to 99.3 wt.-%, based on the total weight of the composition, of A1, A2, and optionally A3, (ii) of from 0.5 to 7.0 wt.-%, based on the total weight of the composition, of component B, (iii) of from 0.1 to 1.5 wt.-%, based on the total weight of the composition, of at least one hindered amine UV light stabilizer C1 and from 0.1 to 1.5 wt.-% of at least one UV absorber C2 other than C1, (iv) of from 0.1 to 2.5 wt.-%, based on the total weight of the composition, of at least one further polymer additive D, and (v) of from 0.1 to 1.5 wt.-% based on the total composition of at least one metal scavenger component E.

4. The thermoplastic resin composition according to claim 1, wherein the impact-modified graft rubber acrylonitrile styrene acrylate A2 comprises: a graft base A2.1 of from 40 to 90 wt.-% based on the total weight of the impact-modified graft rubber acrylonitrile styrene acrylate A2 comprising: (i) from 70 to 99.9 wt.-% of n-butyl acrylate based on the total weight of A2.1, (ii) from 0 to 30 wt.-% of styrene based on the total weight of A2.1, and (iii) from 0.1 to 5 wt.-% of a crosslinking agent based on the total weight of A2.1; and a graft A2.2 of from 10 to 60 wt.-% comprising: (iv) from 65 to 95 wt.-% based on the total weight of A2.2 of styrene, and (v) from 5 to 35 wt.-% based on the total weight of A2.2 of acrylonitrile.

5. The thermoplastic resin composition according to claim 1, comprising from 1 to 70 wt.-% based on the total weight of components A1 and A2 of at least one thermoplastic polymer A3 selected from the group consisting of polycarbonate (PC), polyamide (PA), and mixtures thereof.

6. The thermoplastic resin composition according to claim 1, wherein the pigment component B is a metal-based pigment.

7. The thermoplastic resin composition according to claim 1, wherein component C1 is a hindered amine UV light stabilizer according to the following formula (Ia) and/or formula (Ib): ##STR00009## wherein R1 is H or methyl; each R2 is individually selected from the group consisting of hydrogen, methyl, and ethyl; R3 is selected from the group consisting of linear C.sub.1- to C.sub.18-esters which are connected to formula (Ia) via the oxygen atom of the ester function; and with R4 being selected from the group consisting of C.sub.1- to C.sub.10-alkylene.

8. The thermoplastic resin composition according to claim 7, wherein the component C1 is selected from the group consisting of a compound according to formula (II), a compound according to formula (III), and mixtures thereof ##STR00010##

9. The thermoplastic resin composition according to claim 1, wherein the component C2 is selected from the group consisting of benzophenone, benzotriazole, and cyanoacrylate.

10. The thermoplastic resin composition according to claim 1, wherein at least one component E is a metal scavenger comprising at least one hydrazide group.

11. The thermoplastic resin composition according to claim 1, wherein the composition shows a color shift dE of equal to or lower than 3.0 upon UV irradiation according to ISO-4892-2 after 6000 hours.

12. The thermoplastic resin composition according to claim 1, wherein the composition shows a color shift dE of equal to or lower than 4.0 upon UV irradiation according to ISO-4892-3 after 6000 hours.

13. A method for preparing the thermoplastic resin composition according to claim 1, comprising the step of mixing components A1, A2, B, C1, C2, E, and optionally A3, and D at temperatures of from 100° C. to 300° C. and a pressure of from 1 to 150 bar, in any order, followed by a kneading or extrusion step.

14. The method for preparing the thermoplastic resin composition according to claim 13, wherein at least two of components A1, A2, B, C1, C2, E, and optionally A3, and D are premixed to form a masterbatch.

15. A molded article prepared from the thermoplastic resin composition according to claim 1.

Description

EXAMPLES

(1) Commercially available ASA-copolymer Luran S 776SE was compounded with the pigment Colortherm Red 110M, the plasticizer Palatinol 10-P and different amounts of UV stabilizers (HALS and UV absorbers). Samples have been tested according to two different artificial weathering methods: ISO 4892-2 and ISO 4892-3. Total color shift has been measured every 1000 h. Addition of the metal scavenger Irganox MD 1024 to the standard UV package results in improved UV stability.

(2) TABLE-US-00002 Example 1 Comparative Example 1 Component A 94.97 95.69 (thermoplastic resin) Luran S 776SE Component D (additive) 1.42 1.44 Palatinol 10-P Component B (Pigment) 1.9 1.91 Iron Oxide Red01 Colortherm Red 110M Component C1 0.47 0.48 (HALS) Tinuvin 770 Component C2 (UV 0.47 0.48 absorber) Tinuvin P Component E (metal 0.76 0 scavenger) Irganox MD 1024 dE after 4000 h (ISO 0.98 3.12 4892-2) dE after 5000 h (ISO 1.73 — 4892-2) dE after 6000 h (ISO 2.25 3.04 4892-2) dE after 5000 h (ISO 1.0 3.4 4892-3) dE after 6000 h (ISO 1.0 4.3 4892-3)