Stack of horizontally extending and vertically overlapping features, methods of forming circuitry components, and methods of forming an array of memory cells
11393748 · 2022-07-19
Assignee
Inventors
Cpc classification
G11C2213/11
PHYSICS
H01L2924/0002
ELECTRICITY
G11C13/0007
PHYSICS
H10B63/845
ELECTRICITY
H01L27/10
ELECTRICITY
H01L23/52
ELECTRICITY
G11C2213/31
PHYSICS
H10N70/882
ELECTRICITY
H01L2924/00
ELECTRICITY
H01L2924/0002
ELECTRICITY
H10B43/27
ELECTRICITY
H01L2924/00
ELECTRICITY
H10B41/27
ELECTRICITY
International classification
H01L27/10
ELECTRICITY
G11C13/00
PHYSICS
H01L23/52
ELECTRICITY
Abstract
A method of forming circuitry components includes forming a stack of horizontally extending and vertically overlapping features. The features extend horizontally though a primary portion of the stack with at least some of the features extending farther in the horizontal direction in an end portion. Operative structures are formed vertically through the features in the primary portion and dummy structures are formed vertically through the features in the end portion. Openings are formed through the features to form horizontally elongated and vertically overlapping lines from material of the features. The lines individually extend laterally about sides of vertically extending portions of both the operative structures and the dummy structures. Sacrificial material that is elevationally between the lines is at least partially removed in the primary and end portions laterally between the openings. Other aspects and implementations are disclosed.
Claims
1. A memory circuitry comprising: a memory array having a primary portion and a stair portion; the primary portion having memory cells comprising operative structures that extend vertically in a vertical stack over an upper surface of a substrate, the stack comprising conductive lines having silicon dioxide levels vertically there-between, the lowest conductive line being directly against the upper surface of the substrate; the stair portion having stairs comprising individual of the conductive lines over the upper surface of the substrate; dummy structures extending vertically through the stairs and into semiconductor material of the substrate; the dummy structures and the operative structures comprising programmable material.
2. The circuitry of claim 1 wherein the memory cells comprise cross-point memory cells.
3. The circuitry of claim 1 wherein the dummy structures comprise at least one of a conductive material and a semiconductive material.
4. The circuitry of claim 3 wherein the dummy structures comprise a conductive material.
5. The circuitry of claim 3 wherein the dummy structures comprise a semiconductive material.
6. The circuitry of claim 3 wherein the dummy structures comprise a semiconductive material and a conductive material.
7. The method of claim 1 wherein the operative and dummy structures comprise a common material relative to each other.
8. The method of claim 7 wherein the operative and dummy structures comprise a plurality of common materials relative to each other.
9. The method of claim 7 wherein the common materials are arranged in the same lateral order relative one another in the operative and dummy structures.
10. The method of claim 7 wherein the operative and dummy structures consist essentially of the common material.
11. A memory circuitry comprising: a memory array having a primary portion and a stair portion; the primary portion having memory cells comprising operative channel-material strings that extend vertically in a vertical stack, the stack comprising gate lines having silicon dioxide levels vertically there-between; the stair portion having stairs comprising individual of the gate lines; dummy structures extending vertically through the stairs, the dummy structures individually comprise an outer ring of material internally filled with dielectric material; and a charge-storage material extending between the dummy structures and the stack, the charge-storage material being present along the gate lines and being absent from along the silicon dioxide levels.
12. The circuitry of claim 11 wherein the outer ring of material comprises the channel-material.
13. A memory circuitry comprising: a memory array having a primary portion and a stair portion over an upper surface of a substrate; the primary portion having memory cells comprising operative structures that extend vertically in a vertical stack and into the substrate, the stack comprising conductive lines having silicon dioxide levels vertically there-between; the stair portion having stairs comprising individual of the conductive lines; dummy structures extending vertically through the stairs and into semiconductor material of the substrate; the dummy structures and the operative structures comprising Al.sub.2O.sub.3.
14. The circuitry of claim 13 wherein the memory cells comprise cross-point memory cells.
15. A memory array comprising: a first array region of a substrate; a second array region of the substrate laterally adjacent the first array region; a first conductive line structure over and in direct contact with an upper surface of the substrate, the first conductive line structure extending across the first array region and a first distance across the second array region; a second conductive line structure over the first conductive line structure, the second conductive line structure extending across the first array region and a second distance across the second array region, the second distance being less than the first distance; a first dielectric level between the first and second conductive line structures; a second dielectric level over the second conductive line structure; a plurality of operative structures extending vertically through the first and second conductive line structures and into the substrate within the first array region; a plurality of inoperative structures extending into semiconductor material of the substrate within the second array region, the plurality of inoperable features comprising a first inoperative feature that extends through the first conductive line structure and not through the second conductive line structure, and comprising a second inoperable feature extending through the first conductive line structure and the second conductive line structure; a first contact structure extending vertically over the first conductive line structure in the second array region, the first contact structure being in direct physical contact with an upper surface of the first conductive line structure; and a second contact structure extending vertically over the second conductive line structure, the second contact structure being in direct physical contact with an upper surface of the second conductive line structure.
16. The memory array of claim 15 wherein the operative structures and the inoperative structures each comprise a vertically extending tube of semiconductive material.
17. The memory array of claim 15, wherein the first and second conductive line structures each comprise: a conductive core; and a composite material along an upper surface, a lower surface and sidewall surfaces of the conductive core.
18. The memory array of claim 17 wherein the composite material comprises a charge-tunneling material, a charge-trapping material and a dielectric material.
19. The memory array of claim 18 wherein the operative and the inoperative structures each comprise a vertically extending pillar comprising semiconductive material, and wherein the composite material is against the vertically extending pillar.
20. The memory array of claim 18 wherein the operative and the inoperative structures each comprise a vertically extending tube comprising semiconductive material, and wherein the composite material is against the vertically extending tube.
21. The memory array of claim 20 wherein the charge-tunneling material of the conductive line structures is in direct physical contact with the semiconductor material of the vertically extending tube.
22. The memory array of claim 20 wherein the operative structures and the inoperative structures further comprise a dielectric material within the vertically extending tube.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF EXAMPLE EMBODIMENTS
(19) Example embodiments in accordance with the invention of methods of forming circuitry components are initially described with reference to
(20) Referring to
(21) The base substrate may or may not be a semiconductor substrate. In the context of this document, the term “semiconductor substrate” or “semiconductive substrate” is defined to mean any construction comprising semiconductive material, including, but not limited to, bulk semiconductive materials such as a semiconductive wafer (either alone or in assemblies comprising other materials thereon), and semiconductive material layers (either alone or in assemblies comprising other materials). The term “substrate” refers to any supporting structure, including, but not limited to, the semiconductive substrates described above.
(22) In one embodiment, substrate 10 comprises a stack of alternating sacrificial material 12 and dielectric material 14 formed over base substrate 13. Each material 12 and 14 may be homogenous or non-homogenous. In one embodiment, the respective sacrificial materials 12 are of the same composition relative one another. In one embodiment, the respective dielectric materials 14 are of the same composition relative one another. Regardless, sacrificial material 12 may be selectively etchable, in one embodiment highly selectively etchable, relative to dielectric material 14. In the context of this document, a “selective” etch requires removal of the stated one material relative to another at a rate of at least 1.5:1, and a highly selective etch at a rate of at least about 10:1. Sacrificial material 12 may be any one or more of conductive (e.g., current conductive), dielectric, or semiconductive. By way of an example only, dielectric material 14 may comprise silicon dioxide (whether doped or un-doped), and an example sacrificial material is a conductive or insulative nitride, for example titanium nitride or silicon nitride, respectively. A dielectric material 16 and a hardmask 18 have been provided outwardly of alternating materials 12, 14. Each material 16 and 18 may be homogenous or non-homogenous. Dielectric material 16 may be of the same composition as dielectric material 14, and hardmask material 18 may be of the same composition as sacrificial material 12.
(23) Stack of alternating materials 12, 14 may be considered as comprising a primary portion 18 and an end portion 20. The end portion in the depicted embodiment has been patterned to form a stair step-like construction. Such may be formed to provide horizontal area for later forming contacts to components, regions, or material in end portion 20 as will be apparent in the continuing discussion. In one embodiment and as shown, end portion 20 comprises individual stairs 21 which at least include sacrificial material 12.
(24) In one embodiment, materials 12 and 14 may be features (e.g., plates), such as plates or features that are plate-like, whether continuously and/or discontinuously formed. In one embodiment, a method of forming circuitry components comprises forming a stack of horizontally extending and vertically overlapping plates at least some of which increase in horizontal extent in the vertical inward direction in the end portion of the stack (i.e., at least some of which extend farther in the horizontal direction in the end portion moving deeper into the stack in the end portion). Either of collective materials 12 or 14 may be considered in such example embodiment as comprising such plates, or materials 12 and 14 in combination in the depicted embodiment may be considered as such plates. In one embodiment, the horizontally extending and vertically overlapping plates are dielectric, for example plates 14 regardless of the composition of sacrificial material 12. In one embodiment, all of the plates increase in horizontal extent in the vertical inward direction in the end portion of the stack. For example in the embodiment of
(25) In one embodiment, primary portion 18 and end portion 20 comprise a portion of an array area 22 within which a plurality of memory cells will be fabricated. Logic circuitry (not shown) may be fabricated outside of the array area. Control and/or other peripheral circuitry (not shown) for operating the memory array may or may not fully or partially be within the array area, with an example array area as a minimum encompassing all of the memory cells of the given array/sub-array. Further, multiple sub-arrays might also be fabricated and operated independently, in tandem, or otherwise relative one another. As used in this document, a “sub-array” may also be considered as an array.
(26) Referring to
(27) Referring to
(28) At least one of conductive material, semiconductive material, and programmable material is/are deposited into the openings. In one embodiment where conductive material is deposited into the openings, such may comprise current conductive material. In the context of this document, current conductive material can include a composition where electric current flow may inherently occur therein predominantly by movement of subatomic positive and/or negative charges when such are generated as opposed to predominantly by movement of ions. Example current conductive materials are elemental metals, alloys of elemental metals, current conductive metal compounds, and conductively doped semiconductive material, including any combinations thereof.
(29) In one embodiment, the depositing of the conductive material, semiconductive material and/or programmable material occurs simultaneously into all of the openings in the primary portion. In one embodiment, the depositing of such material occurs simultaneously into all of the openings in the end portion. In one embodiment, the depositing of such material occurs simultaneously into all of the openings in both of the primary and end portions. Operative structures (e.g., circuit components, such as local vertical extensions) are formed therewith within the openings in the primary portion, and dummy structures (e.g. dummy vertical extensions) are formed therewith within the openings in the end portion. In the context of this document, a “dummy” structure is a structure which is used to mimic a physical property of another structure (e.g., load carrying ability of an operative structure) and which may comprise a circuit inoperable electrical dead end (e.g., is not part of a current flow path of a circuit even if conductive). Openings in which dummy structures are formed may be considered as “dummy openings”.
(30) For example referring to
(31) Referring to
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(33) The above processing discloses but example embodiments of forming circuitry components in accordance with some aspects of the invention. In one embodiment, a method of forming circuitry components comprises forming a stack of horizontally extending and vertically overlapping features. By way of example only, such features may comprise plates, with the example depicted structure of plates 14 comprising but one example of such plates. Regardless, in such embodiment, the stack comprises a primary portion and an end portion wherein at least some of the features increase in horizontal extent in the vertical inward direction in the end portion of the stack (i.e., at least some of which extend farther in the horizontal direction in the end portion moving deeper into the stack in the end portion). Operative structures 31 (e.g., circuit components) are formed vertically through the features in the primary portion and dummy structures 32 (e.g., dummy circuit components) are formed vertically through the features in the end portion. The processing depicted through
(34) Additional processing may occur in fabricating integrated circuitry, for example in fabricating an array of memory cells as next described with reference to
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(36) In one embodiment, a respective contact may be formed to a stair extension of individual ones of horizontal conductive lines 42 in end portion 20 for making communicative connection to circuitry. One such example is diagrammatically shown in
(37) Circuitry components other than or in addition to components of memory cells may be fabricated in accordance with embodiments of the invention.
(38) An example embodiment of a method of forming an array of cross-point memory cells is next described with reference to
(39) Programmable material 30 may be solid, gel, amorphous, crystalline, or any other suitable phase. Any existing or yet-to-be developed programmable material may be used, with only some examples being provided below.
(40) One example programmable material is ion conductive material. Example suitable such materials comprise chalcogenide-type (for instance, materials comprising one or more of germanium, selenium, antimony, tellurium, sulfur, copper, etc.; with example chalcogenide-type materials being Ge.sub.2Sb.sub.2Te.sub.5, GeS.sub.2, GeSe.sub.2, CuS.sub.2, and CuTe) and/or oxides such as zirconium oxide, hafnium oxide, tungsten oxide, copper oxide, niobium oxide, iron oxide, silicon oxide (specifically, silicon dioxide), gadolinium oxide, etc. capable of inherently (or with additive) supporting electrolyte behavior. Such may have silver, copper, cobalt, and/or nickel ions, and/or other suitable ions, diffused therein for ionic conduction, analogously to structures disclosed in U.S. Pat. No. 7,405,967 and U.S. Patent Publication Number 2010/0193758.
(41) Additional example programmable materials include multi-resistive state metal oxide-comprising material. Such may comprise, for example, at least two different layers or regions generally regarded as or understood to be active or passive regions, although not necessarily. Alternately, such may only comprise active material. Example active cell region compositions which comprise metal oxide and can be configured in multi-resistive states include one or a combination of Sr.sub.xRu.sub.yO.sub.z, Ru.sub.xO.sub.y, and In.sub.xSn.sub.yO.sub.z. Other examples include MgO, Ta.sub.2O.sub.5, SrTiO.sub.3, SrZrO.sub.3, BaTiO.sub.3, Ba.sub.(1-x)Sr.sub.xTiO.sub.3, ZrO.sub.x (perhaps doped with La), and CaMnO.sub.3 (doped with one or more of Pr, La, Sr, or Sm). Example passive cell region compositions include one or a combination of Al.sub.2O.sub.3, TiO.sub.2, and HfO.sub.2. Regardless, a programmable material composite might comprise additional metal oxide or other materials not comprising metal oxide. Example materials and constructions for a multi-resistive state region comprising one or more layers including a programmable metal oxide-comprising material are described and disclosed in U.S. Pat. Nos. 6,753,561; 7,149,108; 7,067,862; and 7,187,201, as well as in U.S. Patent Application Publication Nos. 2006/0171200 and 2007/0173019. Further as is conventional, multi-resistive state metal oxide-comprising materials encompass filament-type metal oxides, ferroelectric metal oxides and others, and whether existing or yet-to-be developed, as long as resistance of the metal oxide-comprising material can be selectively changed.
(42) The programmable material may comprise memristive material. As an example, such material may be statically programmable semiconductive material which comprises mobile dopants that are received within a dielectric such that the material is statically programmable between at least two different resistance states. At least one of the states includes localization or gathering of the mobile dopants such that a dielectric region is formed and thereby provides a higher resistance state. Further, more than two programmable resistance states may be used. In the context of this document, a “mobile dopant” is a component (other than a free electron) of the semiconductive material that is movable to different locations within said dielectric during normal device operation of repeatedly programming the device between at least two different static states by application of voltage differential to the pair of electrodes. Examples include atom vacancies in an otherwise stoichiometric material, and atom interstitials. Specific example mobile dopants include oxygen atom vacancies in amorphous or crystalline oxides or other oxygen-containing material, nitrogen atom vacancies in amorphous or crystalline nitrides or other nitrogen-containing material, fluorine atom vacancies in amorphous or crystalline fluorides or other fluorine-containing material, and interstitial metal atoms in amorphous or crystalline oxides. More than one type of mobile dopant may be used. Example dielectrics in which the mobile dopants are received include suitable oxides, nitrides, and/or fluorides that are capable of localized electrical conductivity based upon sufficiently high quantity and concentration of the mobile dopants. The dielectric within which the mobile dopants are received may or may not be homogenous independent of consideration of the mobile dopants. Specific example dielectrics include TiO.sub.2, AlN, and/or MgF.sub.2. Example programmable materials that comprise oxygen vacancies as mobile dopants may comprise a combination of TiO.sub.2 and TiO.sub.2-x in at least one programmed resistance state depending on location of the oxygen vacancies and the quantity of the oxygen vacancies in the locations where such are received. An example programmable material that comprises nitrogen vacancies as mobile dopants is a combination of MN and AlN.sub.1-x in at least one programmed state depending on location of the nitrogen vacancies and the quantity of the nitrogen vacancies in the locations where such are received. An example programmable material that comprises fluorine vacancies as mobile dopants may is a combination of MgF.sub.2 and MgF.sub.2-x in at least one programmed resistance state depending on location of the fluorine vacancies and the quantity of the fluorine vacancies in the locations where such are received. As another example, the mobile dopants may comprise aluminum atom interstitials in a nitrogen-containing material.
(43) Still other example programmable materials include polymer materials such as Bengala Rose, AlQ.sub.3Ag, Cu-TCNQ, DDQ, TAPA, and fluorescine-based polymers.
(44) Referring to
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(46) Referring to
(47) Individual ones of the cross-point memory cells comprise crossing ones of the horizontal conductive lines in the primary portion and conductive material in the openings in the primary portion having the programmable material there-between, with some of such example memory cells being indicated with reference numeral 55 in the
(48) An embodiment of the invention includes a stack of horizontally extending and vertically overlapping features. The stack comprises a primary portion and an end portion. At least some of the features extend farther in the horizontal direction in the end portion moving deeper into the stack in the end portion. Operative structures extend vertically through the features in the primary portion. Dummy structures extend vertically through the features in the end portion. In one embodiment, the features may be horizontally extending lines, for example formed of any one or combination of conductive (e.g., current conductive), semiconductive, and/or dielectric material(s). In one embodiment, the features comprise a combination of horizontally extending conductive and dielectric lines (e.g., overlapping and alternating such lines). In one embodiment, contacts may be in the end portion, for example extending vertically to the lines. Any other attribute as described above may be used, for example as shown and described with respect to
(49) In compliance with the statute, the subject matter disclosed herein has been described in language more or less specific as to structural and methodical features. It is to be understood, however, that the claims are not limited to the specific features shown and described, since the means herein disclosed comprise example embodiments. The claims are thus to be afforded full scope as literally worded, and to be appropriately interpreted in accordance with the doctrine of equivalents.