Oxide semiconductor phototransistor improved in visible light absorption rate and manufacturing method thereof
11393935 · 2022-07-19
Assignee
Inventors
- Hyun Jae Kim (Seoul, KR)
- Young Jun TAK (Seoul, KR)
- Jusung CHUNG (Seoul, KR)
- Jeong Min Moon (Paju-si, KR)
- Su Seok Choi (Paju-si, KR)
- Sungpil Ryu (Paju-si, KR)
- Jihwan Jung (Paju-si, KR)
- Kiseok Chang (Paju-si, KR)
Cpc classification
H10K59/00
ELECTRICITY
H01L31/101
ELECTRICITY
H01L31/032
ELECTRICITY
Y02P70/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01L31/1136
ELECTRICITY
H01L29/786
ELECTRICITY
H01L31/022408
ELECTRICITY
H01L31/02161
ELECTRICITY
International classification
H01L31/101
ELECTRICITY
Abstract
The present disclosure provides a phototransistor and a manufacturing method therefor, the phototransistor having a defective oxide ray absorption layer introduced to an oxide semiconductor phototransistor through a solution process or a defective oxide ray absorption part introduced to an interface between a gate insulation film and an oxide semiconductor layer through interface control, which forms damage, thereby improving light absorption in the range of a visible light region.
Claims
1. An oxide semiconductor photo-transistor comprising: a base substrate; a gate electrode disposed on the base substrate; a gate insulating layer disposed on the gate electrode; an oxide semiconductor layer disposed on the gate insulating layer; a source electrode and a drain electrode disposed on the oxide semiconductor layer; and a defective oxide-based optical-absorbing layer disposed on at least one surface of the oxide semiconductor layer, wherein the defective oxide-based optical-absorbing layer is disposed on a surface of the oxide semiconductor layer facing the gate insulating layer, and wherein the defective oxide-based optical-absorbing layer includes oxygen species undercoordinated with an organic material including carbons.
2. The oxide semiconductor photo-transistor of one of claim 1, wherein the oxide semiconductor layer is made of InGaZnO.
3. An oxide semiconductor photo-transistor comprising: a base substrate; a gate electrode disposed on the base substrate; a gate insulating layer disposed on the gate electrode; an oxide semiconductor layer disposed on the gate insulating layer; a source electrode and a drain electrode disposed on the oxide semiconductor layer; and a defective oxide-based optical-absorbing layer disposed on at least one surface of the oxide semiconductor layer, wherein the defective oxide-based optical-absorbing portion is disposed in a surface of the oxide semiconductor layer, facing opposite to the source and the drain electrodes, and wherein the defective oxide-based optical-absorbing layer has a roughness portion.
4. A method for manufacturing an oxide semiconductor photo-transistor, the method comprising: forming a gate electrode on a base substrate; forming a gate insulating layer on the gate electrode; forming an oxide semiconductor layer on the gate electrode; forming a defective oxide-based optical-absorbing layer on the oxide semiconductor layer; and forming a source electrode and a drain electrode on the defective oxide-based optical-absorbing layer, wherein the forming the defective oxide-based optical-absorbing layer includes applying thermal treatment in a range of 150° C. to 400° C. temperature to a solution containing In nitrate (In(NO.sub.3).sub.3) precursor, Ga nitrate (Ga(NO.sub.3).sub.3xH.sub.2O) precursor, and Zn nitrate (Zn(NO.sub.3).sub.26H.sub.2O) precursor to form oxygen species undercoordinated with remaining organic material.
5. The method of claim 4, wherein the solution has a concentration of 0.1 M to 0.25 M.
6. The method of claim 4, wherein the oxide semiconductor layer is made of InGaZnO.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The accompanying drawings, which are included to provide a further understanding of the disclosure and are incorporated in and constitute a part of the disclosure, illustrate aspects of the disclosure and together with the description serve to explain the principle of the disclosure.
(2) In the drawings:
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DETAILED DESCRIPTIONS
(14) Hereinafter, aspects according to the present disclosure will be described in detail with reference to the accompanying drawings. In the drawings, the same reference numerals are used to denote the same or similar elements.
(15) It will also be understood that when a first element or layer is referred to as being present “on” or “beneath” a second element or layer, the first element may be disposed directly on or beneath the second element or may be disposed indirectly on or beneath the second element with a third element or layer being disposed between the first and second elements or layers.
(16) It will be understood that when an element or layer is referred to as being “connected to”, or “coupled to” another element or layer, it can be directly on, connected to, or coupled to the other element or layer, or one or more intervening elements or layers may be present. In addition, it will also be understood that when an element or layer is referred to as being “between” two elements or layers, it can be the only element or layer between the two elements or layers, or one or more intervening elements or layers may also be present.
(17) The present disclosure provides an oxide semiconductor photo-transistor having a defective oxide-based optical-absorbing layer or a defective oxide-based optical-absorbing portion and a method for manufacturing the same.
(18) First, in one aspect of the present disclosure, an oxide semiconductor photo-transistor incorporating therein an oxide-based optical absorbing layer formed based on a solution process and a method for manufacturing the same are provided.
(19) Second, in another aspect of the present disclosure, an oxide semiconductor photo-transistor incorporating an optical absorbing layer and a method for manufacturing the same are provided in which interface control such as applying damage to the interface between a gate insulating layer and a oxide semiconductor layer is carried out to improve visible light absorption of the oxide semiconductor photo-transistor.
(20) As shown in
(21) Herein, methods for manufacturing the base substrate, the gate electrode, the gate insulating layer, the oxide semiconductor layer and the source electrode and the drain electrode, and a stack structure thereof may be known to those skilled in the art and thus detailed descriptions thereof will be omitted. Rather, main technical features of the present disclosure will be focused on.
(22) The defective oxide-based optical-absorbing layer 150 may be disposed on at least one face of the oxide semiconductor layer. In this connection, it is desirable to form the defective oxide-based optical-absorbing layer on a top face of the oxide semiconductor layer, which may receive visible light directly.
(23) The defective oxide-based optical-absorbing layer 150 may be formed by applying thermal treatment in a range of 150 □ to 400 □ temperature to a solution containing In nitrate (In(NO.sub.3).sub.3) precursor, Ga nitrate (Ga(NO.sub.3).sub.3xH.sub.2O) precursor, and Zn nitrate (Zn(NO.sub.3).sub.26H.sub.2O) precursor to form oxygen species undercoordinated with remaining organic material. In this connection, the remaining organic material may be formed because the solvent is not evaporated completely. For example, when 2-methoxyethanol(C.sub.3H.sub.8O.sub.2) is used as a solvent, 2-methoxyethanol (C.sub.3H.sub.8O.sub.2) is decomposed in an annealing process and cannot be evaporated, resulting in the residual organic material. This may be ascertained by measuring absorptivity of C═C bonds and CH bonds using Fourier transform infrared spectroscopy (FT-IR) analysis. The remaining organic material increases the sub-gap states within the bandgap of the oxide semiconductor, thereby allowing light of a long wavelength that conventionally cannot be absorbed using a wide bandgap to be absorbed using the sub-gap states.
(24) According to the present disclosure, the defective oxide-based optical-absorbing layer may be formed to contain oxygen species undercoordinated with the remaining organic material.
(25) In this connection, when the thermal treatment temperature is lower than 150° C., there is generated a considerable amount of remaining organic material in the optical absorbing layer. Thus, the transfer characteristic may not be achieved reliably. Further, when the thermal treatment temperature exceeds 400° C., there is almost no residual organic material left. Thus, the effect of light absorption is greatly reduced.
(26) In addition, the solution including the precursors may have a concentration of 0.1M to 0.25M. When forming the oxide-based optical absorbing layer using a solution having a concentration of lower than 0.1M, a thickness of the optical absorbing layer is greatly reduced and thus an amount of light absorbed per area is reduced. Thus, it is difficult to achieve the effect of light absorption reliably.
(27) In addition, when the oxide optical absorbing layer is formed using a solution having a concentration exceeding 0.25M, a thickness of the optical absorbing layer is too large to interfere with flow of electrons between the source/drain electrodes and channel layer. Thus, there is a disadvantage in that a proper current value may not be achieved due to high current leakage in an on-current region.
(28) Next, in another aspect of the present disclosure, a photo-transistor 200 incorporating an optical absorbing layer therein via an interface control to create a damage to the interface between the gate insulating layer and the oxide semiconductor layer may include, as shown in
(29) Specifically, the defective oxide-based optical-absorbing portion is formed on a bottom face of the oxide semiconductor layer. The defective oxide-based optical-absorbing portion may have roughness.
(30) In this connection, the defective oxide-based optical-absorbing portion on the bottom face of the oxide semiconductor layer may have the roughness by etching a surface of the gate insulating layer to impart roughness to the surface of the gate insulating layer.
(31) That is, when etching the surface of the gate insulating layer, the roughness may be imparted to the surface of the gate insulating layer. Since the oxide semiconductor layer is directly laminated on the roughness-imparted surface of the gate insulating layer, the roughness may be imparted to a bottom face of the oxide semiconductor layer in contact with the surface of the gate insulating layer.
(32) Hereinafter, Aspects and Comparative Examples will be compared with each other using Experimental Examples of the present disclosure.
First Experimental Example
(33) A photo-transistor according to the first Experimental Example of the present disclosure was formed based on an IGZO thin-film transistor. An InGaZnO oxide thin film was sputtered and deposited on p+-Si substrate having a thermal oxide SiO.sub.2 grown thereon using a sputtering target with In:Ga:Zn ratio of 1:1:1.
(34) Specifically, the SiO.sub.2/p+-Si substrate was subjected to ultrasonic cleaning for 10 minutes using acetone and then to ultrasonic cleaning for 10 minutes methanol and then was subjected to blowing using a nitrogen gun. Thereafter, a thin film of InGaZnO was deposited on the substrate using sputtering for 5 minutes at a working pressure of 5 mTorr under argon (Ar) deposition atmosphere._As a result, an oxide semiconductor layer of InGaZnO having a thickness of approximately 40 nm was manufactured. Thereafter, a thermal treatment process for activation was performed at a temperature above 300 □.
(35) An IGZO thin-film as an oxide optical absorbing layer formed based on the solution process according to the present disclosure was formed as follows. First, a 0.2M InGaZnO oxide solution was prepared using 2-methoxyethanol solvent, and using In nitrate (In(NO.sub.3).sub.3) precursor, Ga nitrate (Ga(NO.sub.3).sub.3xH.sub.2O) precursor, and Zn nitrate (Zn(NO.sub.3).sub.26H.sub.2O) precursor where the molar ratio of In:ga:Zn=5:2:1. The prepared solution was deposited on the sputtering-based InGaZnO oxide semiconductor layer as prepared above using spin coating at 3000 rpm for 30 seconds.
(36) The spin-coated solution then underwent a thermal treatment to form a thin film of the optical absorbing layer. In this connection, each thermal treatment was performed at each of the temperatures of 100 □, 200 □, and 300 □. Thus, the undercoordinated oxygen species incompletely coordinated with the residual organic material were formed in the thin film. Thus, the defective oxide-based layer was formed to absorb visible-light.
(37) Finally, in order to deposit the source and drain electrodes, a thickness/length of a channel were limited to 1500 μm/100 μm using a shadow mask and evaporation and then an aluminum (Al) layer having a thickness of 200 nm was deposited.
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(40) As be seen in Comparative Example 1, in the InGaZnO oxide semiconductor photo-transistor without the optical absorbing layer, due to the high bandgap energy of the InGaZnO oxide semiconductor layer, there is almost no change in the transfer characteristic in the laser irradiation of red light and green light. However, in blue light irradiation, an off-current was significantly changed due to formation of ionized oxygen vacancy in the oxide semiconductor layer due to high energy of the blue light laser.
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(47) However, the third aspect of the present disclosure has a threshold voltage shift and an off current change smaller than that of the first aspect of the disclosure which fabricates the optical absorbing layer with a solution of 0.2 M concentration. This is because the optical absorbing layer was fabricated with 0.1M solution and thus a thickness of the optical absorbing layer is reduced such that the amount of light absorbed per area is slightly reduced as compared to the first aspect of the present disclosure where the optical absorbing layer is fabricated with the 0.2M solution.
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(49) In the Comparative Example 3, the optical absorbing layer thin film is formed with the 0.3M solution, and, thus, the thickness of the optical absorbing layer is increased by about 10 nm compared to that of the first aspect of the present disclosure using the 0.2 M solution. The optical absorbing layer having the increased thickness is positioned between the source/drain electrode and the channel layer as the semiconductor layer, and thus not only absorbs the light but also interrupts the electron flow. Thus, the current value may not be achieved appropriately due to high current leakage in the on-current region.
Second Experimental Example
(50) A photo-transistor according to the second Experimental Example of the present disclosure was formed based on an IGZO thin-film transistor. In order to fabricate a photo-transistor for detecting the visible-light via the etching of the gate insulating layer, the SiO.sub.2 gate insulating layer was etched with BOE (buffered oxide etchant) containing a mixture of hydrofluoric acid (HF) and ammonium fluoride (NH.sub.4F).
(51) Specifically, for fabrication of the photo-transistor according to The fourth aspect of the present disclosure, the gate electrode and the gate insulating layer were sequentially thermally grown on a p+ doped silicon (Si) substrate having SiO.sub.2 thermally grown thereon.
(52) Next, for the etching of the gate insulating layer, BOE containing a mixture of HF and NH4F in a mixing ratio of 1:7 was used. DI water was added to BOE so that BOE: DI water ratio was 1:10 to control an etching rate. A channel layer of the photo-transistor was fabricated as an IGZO semiconductor layer via a RF sputtering process using a 3-inch target with a molar ratio of In.sub.2O.sub.3:Ga.sub.2O.sub.3:ZnO of 1:1:1. The thermal treatment was carried out at a hot plate temperature of 300° C. for 1 hour.
(53) Finally, in order to deposit the source and drain electrodes, aluminum Al was deposited to a thickness of 200 nm via thermal evaporation. In the Comparative Example 4, the photo-transistor was fabricated under the same condition as in the fourth aspect of the present disclosure above except that the gate insulating layer was etched.
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(55) Referring to
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(57) As shown in
(58) Further, in the green light irradiation shown in
(59) Finally, in the blue light irradiation shown in
(60) As a result, the oxide semiconductor-based photo-transistor fabricated with the etching of the gate insulating layer showed a visible-light detection level higher than that of the oxide semiconductor photo-transistor fabricated without etching the gate insulating layer. It may be confirmed that a degree by which the visible-light detection level improves is large particularly in the red light and green light irradiation.
(61) As described above, conventional studies for fabricating the oxide semiconductor photo-transistor that reacts with a visible light region have been conducted using a scheme for depositing a separate quantum dot or nanowire on an oxide semiconductor layer. However, there are many problems such as the complicated process, human hazard, and aggregation of quantum dots and nanowires in the thermal treatment process, resulting in lower uniformity.
(62) Further, actually, it is very difficult to fabricate and apply the oxide semiconductor photo-transistors using quantum dots or nanowires in a display industry using a large area substrate. In addition, when the organic material as the optical absorbing layer is formed on the oxide semiconductor layer, the layer has a significantly lower reliability than that of an inorganic absorbing layer due to a low compatibility between the organic layer and the oxide semiconductor layer.
(63) According to one aspect of the present disclosure, the defective oxide thin film, which can absorb visible light may be added as an optical absorbing layer to the oxide semiconductor photo-transistor using a solution process as a relatively simple process. This has effect of increasing the reactivity of the oxide semiconductor photo-transistor with the visible light. Further, the oxide semiconductor photo-transistor according to one aspect of the present disclosure may achieve a remarkable uniformity and thus may be easily applied to a large-area display.
(64) In addition, the method for manufacturing the oxide semiconductor photo-transistor according to another aspect of the present disclosure involves forming sub-gap states in an interface between the oxide semiconductor layer and the gate insulating layer by etching only the gate insulating layer. This may increase the reactivity of the oxide semiconductor photo-transistor with the visible light. Thus, this method may greatly simplify the manufacturing process of the oxide semiconductor photo-transistor, thereby maximizing efficiency in the production process thereof.
(65) While the foregoing disclosure has been described with reference to the aspects of the present disclosure, various modifications and variations may be made by those skilled in the art. Accordingly, it is to be understood that such variations and modifications are included within the scope of the present disclosure.