INSULATED METAL SUBSTRATE AND METHOD FOR MANUFACTURING SAME
20220266572 · 2022-08-25
Inventors
- Feng-Chun YU (Yuanshan Township, TW)
- Kai-Wei LO (Zhubei City, TW)
- Wen Feng LEE (Taoyuan City, TW)
- Ru-Yi CAI (Linluo Township, TW)
Cpc classification
H01L23/36
ELECTRICITY
H05K1/056
ELECTRICITY
H05K3/44
ELECTRICITY
B32B2457/08
PERFORMING OPERATIONS; TRANSPORTING
B32B38/1833
PERFORMING OPERATIONS; TRANSPORTING
B32B2311/00
PERFORMING OPERATIONS; TRANSPORTING
H01L23/3737
ELECTRICITY
B32B15/20
PERFORMING OPERATIONS; TRANSPORTING
H05K2201/0376
ELECTRICITY
B32B38/10
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B15/20
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
H01L21/48
ELECTRICITY
H01L23/14
ELECTRICITY
Abstract
An insulated metal substrate (IMS) and a method for manufacturing the same are disclosed. The IMS includes an electrically conductive line pattern layer, an encapsulation layer, a first adhesive layer, a second adhesive layer, and a heat sink element. The encapsulation layer fills a gap between a plurality of electrically conductive lines of the electrically conductive line pattern layer. An upper surface of the encapsulation layer is flush with an upper surface of the electrically conductive line pattern layer. The first and second adhesive layer are disposed between the electrically conductive line pattern layer and the heat sink element. A bonding strength between the first adhesive layer and the second adhesive layer is greater than 80 kg/cm.sup.2.
Claims
1. A method for manufacturing an insulated metal substrate, comprising: providing a thermal conductive substrate including a metal base, a first adhesive layer and a metal layer from bottom to top; removing a portion of the metal layer to form an electrically conductive line pattern layer, such that a portion of the first adhesive layer is exposed; forming an encapsulation layer on the electrically conductive line pattern layer, the encapsulation layer filling a gap between a plurality of electrically conductive lines of the electrically conductive line pattern layer; removing a top portion of the encapsulation layer, so that an upper surface of the encapsulation layer is flush with an upper surface of the electrically conductive line pattern layer; removing the metal base; providing a heat sink element with a second adhesive layer being disposed on the heat sink element; and bonding the second adhesive layer to the first adhesive layer, whereby a physical contact is established between the first adhesive layer and the second adhesive layer, and a bonding strength between the first adhesive layer and the second adhesive layer is greater than 80 kg/cm.sup.2.
2. The method for manufacturing the insulated metal substrate of claim 1, wherein the electrically conductive line pattern layer comprises copper, and has a thickness of 0.3-10 mm.
3. The method for manufacturing the insulated metal substrate of claim 1, wherein Computer Numerical Control (CNC) is used to remove the portion of the metal layer.
4. The method for manufacturing the insulated metal substrate of claim 1, wherein the encapsulation layer is formed by infusion, screen printing, ink injection or injection molding, and the encapsulation layer comprises an insulation material selected from Epoxy Molding Compound (EMC), solder mask, thermal conductive ink, epoxy resin, polyetheretherketone (PEEK) or polyethersulfone (PES).
5. The method for manufacturing the insulated metal substrate of claim 1, wherein the heat sink element comprises a main plate and a plurality of protrusions, and the protrusions project outwardly along a direction that is vertical to an extending direction of the main plate.
6. The method for manufacturing the insulated metal substrate of claim 1, wherein each of the first adhesive layer and the second adhesive layer has a glass transition temperature Tg greater than 150° C.
7. The method for manufacturing the insulated metal substrate of claim 1, wherein after the bonding step, a bonding strength between the first adhesive layer and the electrically conductive line pattern layer is greater than 80 kg/cm.sup.2, and a bonding strength between the second adhesive layer and the heat sink element is greater than 80 kg/cm.sup.2.
8. The method for manufacturing the insulated metal substrate of claim 1, wherein each of the first adhesive layer and the second adhesive layer has a thickness of 25-100 μm, and the bonding strength between the first adhesive layer and the second adhesive layer falls within the range of 80-300 kg/cm.sup.2.
9. The method for manufacturing the insulated metal substrate of claim 1, further comprising a step of disposing a complementary jig on the heat sink element to bond the second adhesive layer to the first adhesive layer.
10. The method for manufacturing the insulated metal substrate of claim 1, wherein the first adhesive layer and the second adhesive layer have a same or different composition.
11. The method for manufacturing the insulated metal substrate of claim 10, wherein both the first adhesive layer and the second adhesive layer are made from an adhesive material, the adhesive material comprising: a polymeric component comprising 15-60% by volume of the adhesive material, and comprising thermoset epoxy resin and polymeric modifier configured to improve impact resistance of the thermoset epoxy resin, the polymeric modifier comprising thermoplastic, rubber or the mixture thereof; and the polymeric modifier comprising 4%-45% by volume of the polymeric component; a heat conductive filler evenly dispersed in the polymeric component, and comprises 40-85% by volume of the adhesive material; a curing agent configured to cure the thermoset epoxy resin at a temperature higher than 120° C.; and a curing accelerator including urea or urea compounds; wherein the adhesive material has a heat conductivity greater than 3 W/m−K.
12. The method for manufacturing the insulated metal substrate of claim 11, wherein the adhesive material in the form of a plate with a thickness of 100 μm has a thermal resistance below 0.5° C./W and withstands 500 volts or more.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0044] The present application will be described according to the appended drawings in which:
[0045]
[0046]
[0047]
[0048]
DETAILED DESCRIPTION OF THE INVENTION
[0049] The making and using of the presently preferred illustrative embodiments are discussed in detail below. It should be appreciated, however, that the present application provides many applicable inventive concepts that can be embodied in a wide variety of specific contexts. The specific illustrative embodiments discussed are merely illustrative of specific ways to make and use the invention, and do not limit the scope of the invention.
[0050]
[0051] An adhesive material used to form the adhesive layer is prepared by including plural ingredients to have a heat conductivity greater than 3 W/m−K, and the adhesive material in the form of a plate with a thickness of 100 μm has a thermal resistance below 0.5° C./W, which is measured according to ASTM 5470. Moreover, the adhesive material is insulative and can withstand 500 volts or more. In addition, a bonding strength between the adhesive layer and the metal plate is greater than 80 kg/cm.sup.2, and a bonding strength between two adjacent adhesive layers is greater than 80 kg/cm.sup.2 as well. The adhesive layer has a glass transition temperature Tg greater than 150° C. Therefore, the present invention is particularly suitable for high power applications. Further, the present invention uses Computer Numerical Control (CNC) to remove a portion of the metal layer, thus effectively avoiding misalignment problem and increasing product yield. The method for manufacturing the IMS is described in detail below.
[0052] Please see
[0053] Next, please see
[0054] As shown in
[0055] As shown in
[0056]
[0057] As shown in
[0058] In the present embodiment, each of the protrusions 22 is in shape of a rectangular plate, and all the rectangular plates are parallel to each other and are separated from each other with a constant interval. In other embodiments, the heat sink element 20 could include the main plate 21 solely, that is, without the protrusions 22. The main plate 21 in this case is thicker than that of the heat sink element 20 including protrusions 22. The main plate 21 having thicker thickness in this case may facilitate heat conduction along both horizontal direction and vertical direction of the main plate 21, so that, afterwards, heat could be efficiently and effectively dissipated to ambient environment to accomplish heat dissipation function.
[0059] The second adhesive layer 31 may have the same composition as the first adhesive layer 12. That is, they have the same ingredients, and the volume percentages of these ingredients are the same. Alternatively, the second adhesive layer 31 may have a composition different from that of the first adhesive layer 12. That is, they have different ingredients, or the volume percentage of these ingredients are different. Nevertheless, because both of the first adhesive layer 12 and the second adhesive layer 31 include a polymer and a large amount of heat conductive fillers evenly dispersed in the polymer, and both of them are suitable for bonding metal components, the first adhesive layer 12 and the second adhesive layer 31 have quite similar composition even if the compositions thereof are different. The bonding property, heat conductivity and insulative property of the two layers are approximately similar. Regarding this, it will be described in detail below.
[0060] Thereafter, please see
[0061] Such superior bonding strength would be much greater than that between an adhesive layer and a metal layer. The inventors find from experiments that the bonding strength between the first adhesive layer 12 and the second adhesive layer 31 is greater than 80 kg/cm.sup.2, such as falling within the range of 80-300 kg/cm.sup.2, or 100 kg/cm.sup.2, 150 kg/cm.sup.2, 200 kg/cm.sup.2, or 250 kg/cm.sup.2 in particular. Therefore, though protrusions 22 of the heat sink element 20 may make it difficult for the hot presser to uniformly apply a pressure on the topmost surface of the heat sink element 20 (i.e., the upper surface of the heat sink element 20 shown in
[0062] The first adhesive layer 12 and the second adhesive layer 31 cannot have a too thick or too thin thickness. A too thick thickness would increase thermal resistance. A too thin thickness would not have good voltage endurance, and the bonding strength between the two adhesive layers is not large enough for use in IMS's applications. In an embodiment, each of the first adhesive layer 12 and the second adhesive layer 31 has a thickness of 25-100 μm. As long as hot-pressing is finished, the first adhesive layer 12 and the second adhesive layer 31 together constitute a thermally conductive and electrically insulating layer. In other words, the thermally conductive and electrically insulating layer includes a first adhesive layer 12 and a second adhesive layer 31, and has a thickness falling within 50-200 μm.
[0063] In an embodiment, as shown in
[0064] In the step S7 of
[0065] To have excellent heat conductivity and electrical property and to meet the demand of required bonding strength, the first adhesive layer 12 and the second adhesive layer 31 are both made from an adhesive material. The adhesive material of the present application comprises a polymeric component, a heat conductive filler, a curing agent and a curing accelerator. The polymeric component comprises 15-60% by volume of the adhesive material, and comprises thermoset epoxy resin and polymeric modifier configured to improve impact resistance of the thermoset epoxy resin. The polymeric modifier comprises thermoplastic, rubber or the mixture thereof. The polymeric modifier comprises 4-45% by volume of the polymeric component. The heat conductive filler is evenly dispersed in the polymeric component, and comprises 40-85% by volume of the adhesive material.
[0066] The heat conductivity of the adhesive material is about 3-15 W/m−K, e.g., 5 W/m−K, 7 W/m−K, 10 W/m−K or 12 W/m−K. The adhesive material in the form of a plate with a thickness of 100 μm has a thermal resistance below 0.5° C./W or 0.4° C./W, which is measured according to ASTM 5470. The adhesive material has a hardness between 65-98 A, e.g., 75 A, 85 A or 95 A, which is measured according to ASTM D2240. As such, the adhesive material has good impact resistance, and therefore it is suitable for bonding metal components. The metal components may comprise copper, aluminum, nickel, iron, tin, gold, silver or alloy thereof. In an embodiment, the strength of the adhesive material bonding to the metal component is greater than 80 kg/cm.sup.2 after the adhesive material is pressed and cured. It is obvious that the addition of thermoplastic can increase adhesive strength, by which the adhesive material becomes tough but not fragile. Therefore, the adhesive material is able to be strongly and firmly adhered to metal components such as metal electrodes or substrates. The adhesive strength may be larger than 100 kg/cm.sup.2 or 120 kg/cm.sup.2. Preferably, the adhesive material in the form of a plate with a thickness of 100 μm has a thermal resistance below 0.5° C./W. Moreover, the adhesive material is insulative and can withstand a voltage higher than 500 volts, e.g., 600 volts, 800 volts, 1000 volts, 1200 volts, 1400 volts, 1600 volts, 1800 volts, 2000 volts or more. In addition, the adhesive layers 12 and 31 made from the adhesive material has a glass transition temperature Tg greater than 150° C., such as in the range of 150-380° C.
[0067] In the step S7 of
[0068] The thermoset epoxy resin can include end epoxy functional group epoxy resin, side chain epoxy functional group epoxy resin, tetra-functional group epoxy resin or the mixture thereof. For example, the thermoset epoxy resin includes bisphenol A epoxy resin.
[0069] The thermoplastic of the adhesive material may be essentially amorphous thermoplastic resin, such as phenoxy resin, polysulfone, polyethersulfone, polystyrene, polyphenylene oxide, polyphenylene sulfide, polyamide, polyimide, polyetherimide, polyetherimide/silicone block copolymer, polyurethane, polyester, polycarbonate, acrylic resin such as polymethyl methacrylate, styrene)/acrylonitrile and styrene block copolymers.
[0070] The rubber may be nitrile-butadiene rubber (NBR), such as carboxy-terminated polybutadieneacrylonitrile (CTBN), amino-terminated polybutadieneacrylonitrile (ATBN), hydroxy-terminated polybutadieneacrylonitrile (HTBN), epoxy-terminated polybutadieneacrylonitrile (ETBN), vinyl-terminated polybutadieneacrylonitrile (VTBN), or methacrylic-terminated polybutadieneacrylonitrile.
[0071] The curing temperature of the curing agent in the adhesive material of the present invention is higher than 120° C., or preferably at about 150° C., to cure (crosslink) or catalyze polymerize the thermoset epoxy resin. The curing agent is preferably dicyandiamide and may be used together with a curing accelerator. The commonly used curing accelerator includes urea or urea compounds, imidazole, or boron trifluoride. Moreover, the curing agent may be isophthaloyl dihydrazide, benzophenone tetracarboxylic dianhydride, diethyltoluene diamine, 3,5-dimethylthio-2,4-toluene diamine, dicyandiamide, or diaminodiphenyl sulfone (DDS). The curing agent may be substituted dicyandiamides, such as 2,6-xylenyl biguanide, solid polyamide, solid aromatic amine, solid anhydride hardener, phenolic resin hardener. For example, polyp-hydroxy styrene), amine complex, trimethylol propane triacrylate, bismaleimides or cyanate esters. In an embodiment, the curing agent and the curing accelerator, together with the polymeric component, comprises 15-60% by volume of the adhesive material.
[0072] The heat conductive filler may comprise one or more ceramic powders that can be selected from nitride, oxide or the mixture thereof. The nitride can be selected from the group consisting essentially of zirconium nitride, boron nitride, aluminum nitride, and silicon nitride. The oxide can be selected from the group consisting essentially of aluminum oxide, magnesium oxide, zinc oxide, silicon dioxide and titanium dioxide. In general, heat conductivity of oxide is relatively low, whereas the filling amount of nitride is relatively low. Therefore, oxide and nitride can be complementary to each other when they are mixed. The heat conductive filler is evenly dispersed in the polymeric component and comprises 40-85%, and preferably 50-70%, by volume of the adhesive material. In particular, the heat conductive filler may comprise 50%, 55%, 60%, 65%, 70% or 80% by volume of the adhesive material.
[0073] The IMS manufactured by the above-said method undergoes cycle test. An initial bonding strength before cycle test and a bonding strength after cycle test are measured, and appearance of IMS after cycle test is observed. The test results, which includes Comparative Examples 1 (CE1), and Embodiments 1-3 (E1-3), are shown in Table 1 below. The cycle test is conducted by putting IMS in an environment of −40° C. followed by 150° C. as a cycle with each temperature lasting for a duration of 30 minutes, and each cycle is repeated 1000 times. The electrically conductive line pattern layer is a copper layer with a thickness of 1 mm. The first and second adhesive layer each has a thickness of 50 In general, the bonding strength between layers in IMS depends on several possible factors, including hot-pressing parameters, layer material or composition, surface roughness of each layer, etc. Generally, the higher the pressure applied by the hot presser, the larger the bonding strength between layers after hot-pressing. The test results show that, for E1-E3, as long as the bonding strength between layers after hot-pressing is greater than 80 kg/cm.sup.2, the IMS can pass the cycle test without layer separation. For E1-E3, although, the bonding strength is decreased slightly after cycle test, these layers in the IMS are still firmly adhered to each other. In contrast, for CE1, if the bonding strength between layers after hot-pressing is less than 80 kg/cm.sup.2, such as 60 kg/cm.sup.2 in CE1, separation or peeling occurs in the IMS, obviously reveling that the bonding strength between layers is not strong enough.
TABLE-US-00001 TABLE 1 Cycle test at −40° C./150° C. Initial (executed for 1000 times) Bonding strength Bonding strength (kg/cm.sup.2) Appearance (kg/cm.sup.2) CE1 60 Peeling — E1 80 No abnormality 75 E2 120 No abnormality 116 E3 150 No abnormality
[0074] Table 2 records the test results of Embodiments 47 (E4-E7), in which the IMS manufactured by the above-said method undergoes cycle test. An initial bonding strength before cycle test and a bonding strength after cycle test are measured, and appearance of IMS after cycle test is observed. Likewise, the cycle test is conducted by putting IMS in an environment of −40° C. followed by 150° C. as a cycle with each temperature lasting for a duration of 30 minutes, and each cycle is repeated 1000 times. The electrically conductive line pattern layers in E4-E7 have different thicknesses, i.e., 0.3 mm, 1 mm, 5 mm and 10 mm, respectively. The first and second adhesive layer each has a thickness of 50 The test result shows that E4-E7 where the IMS includes an electrically conductive line pattern layer having a thickness falling within 0.3-10 mm still can pass the cycle test, and there is no peeling phenomenon occurring between the first adhesive layer and the electrically conductive line pattern layer. In addition, the thicker the electrically conductive line pattern layer, the more the decreased bonding strength after cycle test. For example, for E7, the electrically conductive line pattern layer has a thickness of 10 mm; however, the bonding strength after cycle test drops 25% as opposed to that there is no cycle test performed on IMS, i.e. dropping from 80 kg/cm.sup.2 to 60 kg/cm.sup.2. But, there is still not any peeling phenomenon occurring. Apparently, this proves that the present invention is quite suitable for applications in which the electrically conductive line pattern layer is a thick copper layer having a thickness of 0.3-10 mm.
TABLE-US-00002 TABLE Thickness Cycle test at of −40° C./150° C. electrically Initial (executed for 1000 times) conductive Bonding Bonding line pattern strength strength layer (mm) (kg/cm.sup.2) Appearance (kg/cm.sup.2) E4 0.3 80 No abnormality 78 E5 1 80 No abnormality 75 E6 5 80 No abnormality 70 E7 10 80 No abnormality 60
[0075] Tables 1 and 2 show the test results conducted on the IMS including a first adhesive layer and a second adhesive layer with each layer having a thickness of 50 In practice, the first and second adhesive layer each may have a thickness of 25-100 μm, such as 40 μm, 60 μm or 80 μm. Such thickness would not cause peeling.
[0076] In summary, in high power applications, an electrically conductive line pattern layer 14 of a large thickness, e.g., 0.3-10 mm, made of copper is usually used. Moreover, a heat sink element 20 having protrusions 22 are generally used as well. However, the traditional method for manufacturing IMS having such structure design would result in peeling problem between layers. In contrast thereto, the present invention provides a method for manufacturing an IMS which includes a series of steps to improve bonding strength between layers. Specifically, a thermal conductive substrate that has been hot-pressed is provided first, therefore the bonding strength between the metal layer and the first adhesive layer is excellent. Moreover, because the first adhesive layer and the second adhesive layer have the same or similar composition, hot-pressing step makes the two layers tightly bond to each other. Thus, despite of inclusion of protrusion 22 in the heat sink element 20, superior bonding strength would not cause separation problem. In addition, the adhesive material used to form the first and second adhesive layer 12 and 31 is prepared by including plural ingredients to have a heat conductivity greater than 3 W/m−K, and the adhesive material in the form of a plate with a thickness of 100 μm has a thermal resistance below 0.5° C./W, which is measured according to ASTM 5470. Further, the adhesive material is insulative and can withstand 500 volts or more. The adhesive layer made from the adhesive material also has a glass transition temperature Tg greater than 150° C. Therefore, for theses reasons, the present invention is particularly suitable for high power applications. Additionally, the present invention uses Computer Numerical Control (CNC) to remove a portion of the metal layer 13, thus effectively avoiding misalignment problem and increasing product yield.
[0077] Additionally, the present invention provides an IMS 300. Please see
[0078] In an embodiment, the electrically conductive line pattern layer 14 comprises copper, and has a thickness of 0.3-10 mm, such as 0.5 mm, 1 mm, 2 mm, 3 mm, 4 mm, 5 mm, 6 mm, 7 mm, 8 mm or 9 mm.
[0079] A bonding strength between the first adhesive layer 12 and the electrically conductive line pattern layer 14 is greater than 80 kg/cm.sup.2, or greater than 100 kg/cm.sup.2 or 120 kg/cm.sup.2 in particular.
[0080] The composition of the first adhesive layer 12 and the second adhesive layer 31 has been described in the embodiment of
[0081] In an embodiment, in order to improve heat dissipation efficiency by increasing heat dissipation area, the heat sink element 20 may include a main plate 21 and a plurality of protrusions 22. The protrusions 22 project outwardly along the direction that is vertical to an extending direction of the main plate 21. The protrusions 22 could be in shape of cylinder, elliptic cylinder, polygonal column, truncated cone or flat plate. In addition, there is a gap between the protrusions 22 to accommodate air to flow therein, so as to carry heat away. Alternatively, the heat sink element 20 could include the main plate 21 solely, that is, without the protrusions 22. The main plate 21 in this case is thicker than that of the heat sink element 20 including protrusions 22. The main plate 21 having thicker thickness may facilitate heat conduction along both horizontal direction and vertical direction of the plate 21, so that, afterwards, heat could be effectively dissipated to ambient environment to achieve efficient heat dissipation.
[0082] The present invention provides an IMS and a method for manufacturing the same. A thermal conductive substrate that has been hot-pressed is provided first, therefore the bonding strength between the metal layer and the first adhesive layer is excellent. Also, a mechanical way is used to remove a portion of the metal layer, thus avoiding the misalignment problem. Moreover, because the first adhesive layer and the second adhesive layer have the same or similar composition, hot-pressing step makes the two layers tightly bond to each other. Thus, according to the present invention, there is not any separation phenomenon occurring between layers of IMS, and misalignment problem is solved as well. The IMS has good heat conductivity and high glass transition temperature Tg as well. Therefore, the present invention is particularly suitable for high power applications, thus providing a solution to the traditional IMS which encounters the problems as described above.
[0083] The above-described embodiments of the present invention are intended to be illustrative only. Numerous alternative embodiments may be devised by persons skilled in the art without departing from the scope of the following claims.