Multilayer laminate and method for producing multilayer printed wiring board using same
11285700 · 2022-03-29
Assignee
Inventors
Cpc classification
B32B2307/50
PERFORMING OPERATIONS; TRANSPORTING
H05K3/445
ELECTRICITY
H05K2201/0191
ELECTRICITY
B32B2457/08
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/31678
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H05K1/185
ELECTRICITY
Y10T428/24322
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B2305/30
PERFORMING OPERATIONS; TRANSPORTING
H05K2201/0195
ELECTRICITY
H05K2201/09309
ELECTRICITY
Y10T428/26
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H05K3/06
ELECTRICITY
H05K3/4644
ELECTRICITY
H05K3/4038
ELECTRICITY
H05K3/429
ELECTRICITY
B32B2307/54
PERFORMING OPERATIONS; TRANSPORTING
B32B27/18
PERFORMING OPERATIONS; TRANSPORTING
B32B7/02
PERFORMING OPERATIONS; TRANSPORTING
H05K3/4641
ELECTRICITY
Y10T29/49165
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/12903
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H05K3/4655
ELECTRICITY
Y10T29/49155
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H05K3/4652
ELECTRICITY
Y10T428/12535
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/12431
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B2307/212
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/12361
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/12438
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/12542
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B3/266
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/25
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10S428/901
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/12556
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B15/20
PERFORMING OPERATIONS; TRANSPORTING
H01G2/06
ELECTRICITY
B32B7/025
PERFORMING OPERATIONS; TRANSPORTING
B32B2250/40
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/269
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B27/20
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/266
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
B32B15/20
PERFORMING OPERATIONS; TRANSPORTING
H05K3/06
ELECTRICITY
H05K3/00
ELECTRICITY
H05K1/09
ELECTRICITY
B32B7/02
PERFORMING OPERATIONS; TRANSPORTING
H05K3/44
ELECTRICITY
H05K3/40
ELECTRICITY
H01G4/20
ELECTRICITY
H05K1/16
ELECTRICITY
Abstract
A multi-layered board includes: a middle conductive layer; a first dielectric layer that is disposed directly on a first surface of the middle conductive layer; a second dielectric layer that is disposed directly on a second surface of the middle conductive layer; a first outer surface conductive layer that is disposed directly on an outer side of the first dielectric layer; and a second outer surface conductive layer that is disposed directly on an outer side of the second dielectric layer. The first outer surface conductive layer serves as a first outer surface of the multi-layered board, and the second outer surface conductive layer serves as a second outer surface of the multi-layered board. The middle conductive layer is solidly formed over an entire planar direction of the multi-layered board. The first dielectric layer and the second dielectric layer each independently have a thickness variation of 15% or less.
Claims
1. A multi-layered board consisting of the following layers: a middle conductive layer; a first dielectric layer that is disposed directly on a first surface of the middle conductive layer; a second dielectric layer that is disposed directly on a second surface of the middle conductive layer; a first outer surface conductive layer that is disposed directly on an outer side of the first dielectric layer; and a second outer surface conductive layer that is disposed directly on an outer side of the second dielectric layer; wherein, in the multi-layered board, the first outer surface conductive layer serves as a first outer surface of the multi-layered board, and the second outer surface conductive layer serves as a second outer surface of the multi-layered board, the middle conductive layer is solidly formed over an entire planar direction of the multi-layered board, and the first dielectric layer and the second dielectric layer each independently have a thickness variation of 15% or less; wherein each of the first dielectric layer and the second dielectric layer comprises dielectric particles and a resin, the dielectric particles having a relative dielectric constant of at least 50 and at most 20000; wherein the first dielectric layer and the second dielectric layer are free of reinforcing material; wherein each of the first dielectric layer and the second dielectric layer has a strain energy at break of at most 1.8 MJ; wherein each of the first dielectric layer and the second dielectric layer has a tensile strength of at most 60.0 MPa; and wherein each of the first dielectric layer and the second dielectric layer has a tensile elongation at break of at least 0.05% or more, and at most 5.0%.
2. The multi-layered board according to claim 1, wherein a difference between a relative dielectric constant of the first dielectric layer and a relative dielectric constant of the second dielectric layer is 10% or less.
3. The multi-layered board according to claim 1, wherein the first dielectric layer and the second dielectric layer each independently have a thickness of 0.1 μm or more and 30 μm or less.
4. The multi-layered board according to claim 3, wherein the first dielectric layer and the second dielectric layer have the same thickness.
5. The multi-layered board according to claim 2, wherein the first dielectric layer and the second dielectric layer each independently have a thickness of 0.1 μm or more and 30 μm or less.
6. The multi-layered board according to claim 1, wherein a proportion of the dielectric particles in each of the first dielectric layer and the second dielectric layer is 60 mass % or more and 95 mass % or less.
7. The multi-layered board according to claim 6, wherein the first dielectric layer and the second dielectric layer have the same composition.
8. The multi-layered board according to claim 2, wherein a proportion of the dielectric particles in each of the first dielectric layer and the second dielectric layer is 60 mass % or more and 95 mass % or less.
9. The multi-layered board according to claim 3, wherein a proportion of the dielectric particles in each of the first dielectric layer and the second dielectric layer is 60 mass % or more and 95 mass % or less.
10. The multi-layered board according to claim 4, wherein a proportion of the dielectric particles in each of the first dielectric layer and the second dielectric layer is 60 mass % or more and 95 mass % or less.
11. The multi-layered board according to claim 1, wherein each of the conductive layers is made of a copper foil, and independently has a thickness of 0.1 μm or more and 70 μm or less.
12. The multi-layered board according to claim 2, wherein each of the conductive layers is made of a copper foil, and independently has a thickness of 0.1 μm or more and 70 μm or less.
13. The multi-layered board according to claim 3, wherein each of the conductive layers is made of a copper foil, and independently has a thickness of 0.1 μm or more and 70 μm or less.
14. A method for producing a multi-layer printed wiring board, the method comprising the steps of: preparing the multi-layered board according to claim 1; forming a first through hole that extends through the multi-layered board in a thickness direction of the multi-layered board; completely filling the first through hole with a non-electroconductive filler; and forming a second through hole having a diameter smaller than a diameter of the first through hole at a position where the filler is filled, such that the second through hole extends through the multi-layered board in the thickness direction.
Description
BRIEF DESCRIPTION OF DRAWINGS
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
DESCRIPTION OF EMBODIMENTS
(10) Hereinafter, the present invention will be described by way of a preferred embodiment with reference to the drawings.
(11) A first outer surface conductive layer 13a is provided on an outer side surface of the first dielectric layer 12a, or in other words, the one surface of the two main surfaces of the first dielectric layer 12a that does not oppose the middle conductive layer 11a. Likewise, a second outer surface conductive layer 13b is provided on an outer side surface of the second dielectric layer 12b. The first outer surface conductive layer 13a is disposed directly on the outer side surface of the first dielectric layer 12a. In other words, there is no layer between the first outer surface conductive layer 13a and the first dielectric layer 12a. Likewise, the second outer surface conductive layer 13b is disposed directly on the outer side surface of the second dielectric layer 12b, and thus there is no layer between the second outer surface conductive layer 13b and the second dielectric layer 12b.
(12) In the multi-layered board 10, the first outer surface conductive layer 13a serves as a first surface of the multi-layered board 10, and the second outer surface conductive layer 13b serves as a second surface of the multi-layered board 10. In other words, no layer is stacked on an outer surface of the first outer surface conductive layer 13a, or in other words, the one surface of the two main surfaces of the second outer surface conductive layer 13b that does not oppose the first dielectric layer 12a. Likewise, no layer is stacked on an outer surface of the second outer surface conductive layer 13b, or in other words, the one of the two main surfaces of the first outer surface conductive layer 13b that does not oppose the second dielectric layer 12b. Because the multi-layered board 10 is configured as described above, the multi-layered board 10 as a whole has a five-layer structure as described above.
(13) It is preferable that the first dielectric layer 12a of the multi-layered board 10 is made of the same material throughout the dielectric layer 12a. The same applies to the second dielectric layer 12b. However, in some cases, each of the dielectric layers 12a and 12b may be configured to include an arbitrarily defined first region and an arbitrarily defined second region which is different from the first region as viewed in planar view of the dielectric layers 12a and 12b, and a constituent material of the first region may be different from a constituent material of the second region. Also, in the case where the first dielectric layer 12a is made of the same material throughout the dielectric layer 12a, and the second dielectric layer 12b is made of the same material throughout the second dielectric layer 12b, the constituent materials of the first dielectric layer 12a and the second dielectric layer 12b may be the same or different.
(14) The same applies to the first outer surface conductive layer 13a and the second outer surface conductive layer 13b. It is preferable that the first outer surface conductive layer 13a is made of the same material throughout the first outer surface conductive layer 13a, and the second outer surface conductive layer 13b is made of the same material throughout the second outer surface conductive layer 13b. However, in some cases, each of the conductive layers 13a and 13b may be configured to include an arbitrarily defined first region and an arbitrarily defined second region which is different from the first region as viewed in planar view of the conductive layers 13a and 13b, and a constituent material of the first region may be different from a constituent material of the second region. Also, in the case where the first outer surface conductive layer 13a is made of the same material throughout the first outer surface conductive layer 13a, and the second outer surface conductive layer 13b is made of the same material throughout the second outer surface conductive layer 13b, the constituent materials of the first outer surface conductive layer 13a and the second outer surface conductive layer 13b may be the same or different.
(15) As shown in
(16) In contrast to the above, for example, according to the technique disclosed in Patent Literature 1, a circuit pattern is formed on a conductive layer, that is, there is a void portion that extends through the entire conductive layer in the thickness direction. Accordingly, when a dielectric layer is formed on the conductive layer, the dielectric layer may have different thicknesses in the void portion and the non-void portion, which is likely to cause a variation in the electrostatic capacity of the dielectric layer.
(17) In order to make it less likely that there is a variation in the electrostatic capacity of each of the dielectric layers 12a and 12b in the multi-layered board 10 according to the present embodiment, it is advantageous to make the thickness of each of the dielectric layers 12a and 12b as uniform as possible. From this viewpoint, it is preferable that the multi-layered board 10 is produced using a method as shown in
(18) As shown in
(19) The first element 14a and the second element 14b are preferably produced by placing a resin composition, which contains dielectric particles and a resin, onto one surface of each of the first outer surface conductive layer 13a and the second outer surface conductive layer 13b so as to form the first dielectric layer 12a and the second dielectric layer 12b from this resin composition. In order to place the resin composition onto one surface of each of the first outer surface conductive layer 13a and the second outer surface conductive layer 13b, for example, the resin composition may be applied. For example, in the case where a thermosetting resin is used as the resin, a resin composition that contains an A-stage thermosetting resin and dielectric particles and that is in a fluidized state like that of varnish may be applied. Then, by curing the applied resin composition by applying heat or energy rays, the thermosetting resin is brought into a B stage, and the first element 14a and the second element 14b are obtained. By producing the first element 14a and the second element 14b using the method described above, it is possible to conveniently form a first dielectric layer 12a and a second dielectric layer 12b that each have a uniform thickness.
(20) As the resin contained in the first dielectric layer 12a and the second dielectric layer 12b, as described above, it is preferable to use a thermosetting resin. In particular, it is preferable to use a resin that is highly insulative. As the thermosetting resin, it is possible to use any thermosetting resin that is conventionally used in the technical field of printed wiring boards. Examples of the thermosetting resin include epoxy resin, polyimide resin, polyamide resin, polyphenylene ether resin, cyanate resin, maleimide resin, phenol resin, phenoxy resin, styrene-butadiene resin, and the like. The thermosetting resin is preferably in an A stage or B stage in the first element 14a and the second element 14b, and is preferably in a C stage in the multi-layered board 10.
(21) For reinforcing the first dielectric layer 12a and the second dielectric layer 12b, the first dielectric layer 12a and the second dielectric layer 12b may contain a reinforcing material such as; a fibrous material including a glass woven fabric, glass non-woven fabric or paper; or a film-like material made of, for example, polyimide resin or the like. But it is preferable that the first dielectric layer 12a and the second dielectric layer 12b do not contain the reinforcing material. A reinforcing material is useful from the viewpoint of imparting strength to the dielectric layers 12a and 12b. However, there is a disadvantage in that the use of a reinforcing material increases the thickness of the dielectric layers 12a and 12b. An increase in the thickness of the dielectric layers 12a and 12b causes a reduction in the electrostatic capacity of the capacitor. For this reason, it is preferable that the dielectric layers 12a and 12b do not contain a reinforcing material so as to prioritize reducing the thickness of the multi-layered board 10 and increasing the capacity of the embedded capacitor over improving the strength of the dielectric layers 12a and 12b. The disadvantage caused by a reduction in the strength of the dielectric layers 12a and 12b can be overcome by attaching the dielectric layers 12a and 12b, which are in the form of elements 14a and 14b, to the middle conductive layer 11a.
(22) The following method can be used as another method for producing a multi-layered board 10. A middle conductive layer 11a, and metal foils that serve as the first outer surface conductive layer 13a and the second outer surface conductive layer 13b are prepared, and at the same time, two dielectric resin layers that serve as the first dielectric layer 12a and the second dielectric layer 12b are prepared. Then, the one dielectric resin layer is placed between the middle conductive layer 11a and the first outer surface conductive layer 13a, and the other dielectric resin layer is placed between the middle conductive layer 11a and the second outer surface conductive layer 13b, and thereafter these are stacked together. In this state, the resulting stack is heated and pressed so as to integrate them together. In this way, a multi-layered board 10 is obtained. The dielectric resin layers used in this method are the dielectric resin layers in which dielectric particles are dispersed in a B-stage thermosetting resin.
(23) The dielectric resin layers may each be configured from a sheet or a film that contains a thermosetting resin and dielectric particles. In some cases, the dielectric resin layers may each be a laminated sheet or a laminated film. The laminated sheet and the laminated film include more than one member that contains a fibrous material impregnated with a thermosetting resin in a B-stage. The fibrous material includes a glass woven fabric, glass non-woven fabric and paper. It is also possible to use a film instead of the fibrous material. Also, the dielectric resin layer may contain, in addition to these materials, an inorganic filler. Irrespective of the configuration of the dielectric resin layers, as the thermosetting resin, it is possible to use, for example, epoxy resin, cyanate resin, maleimide resin, polyphenylene ether resin, phenol resin, polyimide resin, or the like.
(24) The first dielectric layer 12a and the second dielectric layer 12b preferably have a relative dielectric constant of 10 or more, more preferably 20 or more, and even more preferably 40 or more. With a relative dielectric constant greater than or equal to the above values, it is possible to easily increase the electrostatic capacity while reducing the thickness of the dielectric layers 12a and 12b. The higher the relative dielectric constant of the dielectric layers 12a and 12b, the more preferable it is. However, considering the adhesiveness to the middle conductive layer 11a, and to the first outer surface conductive layer 13a and to the second outer surface conductive layer 13b, as well as the strength of the dielectric layers 12a and 12b, the first dielectric layer 12a and the second dielectric layer 12b preferably have a relative dielectric constant of 300 or less, more preferably 200 or less, and even more preferably 100 or less. As used herein, the term “relative dielectric constant” refers to a value obtained through measurement using a split post dielectric resonator method (measurement frequency: 1 GHz).
(25) As a means for satisfying the relative dielectric constant described above, the first dielectric layer 12a and the second dielectric layer 12b preferably contain dielectric particles described above. As the dielectric particles, it is preferable to use dielectric particles that have a relative dielectric constant of 50 or more and 20000 or less. The dielectric particles are preferably made of, for example, a complex oxide that has a perovskite structure such as a barium titanate ceramic, a calcium titanate ceramic, a magnesium titanate ceramic, a bismuth titanate ceramic, a strontium titanate ceramic, a lead zirconate ceramic, a barium zirconate ceramic, or a calcium zirconate ceramic. Among the complex oxides with a perovskite structure, it is preferable to use a barium titanate ceramic so as to obtain a high dielectric constant, but a complex oxide can be selected according to the quality of design of the multi-layered board 10.
(26) The dielectric particles preferably have a particle size of 0.01 μm or more and 1.0 μm or less from the viewpoint of keeping the dielectric constant of the dielectric layer 11 at a constant level throughout the dielectric layer 11. As used herein, the term “particle size” refers to a volume cumulative particle size D.sub.50 at 50% cumulative volume obtained using a laser diffraction/scattering particle size distribution measurement method.
(27) The first dielectric layer 12a and the second dielectric layer 12b each independently contain dielectric particles in a proportion of preferably 60 mass % or more and 95 mass % or less, more preferably 60 mass % or more and 90 mass % or less, and even more preferably 70 mass % or more and 90 mass % or less from the viewpoint of a balance between improving the electrostatic capacity and the strength of the dielectric layers 12a and 12b. The proportion of dielectric particles contained in each of the dielectric layers 12a and 12b can be obtained from the mass of remaining particles after the resin contained in the dielectric layer 12a or 12b has been sublimated.
(28) In general, a dielectric layer that does not contain a reinforcing material and that has been filled with dielectric particles at a high concentration is very brittle. Accordingly, if a high level of stress is applied during stacking, the dielectric layer may not be able to withstand the stress and may crack. In contrast, with the production method according to the present invention, stacking can be performed without damaging the dielectric layers.
(29) It is preferable to use strain energy at break as a physical property value that indicates the brittleness. Strain energy at break U (unit: MJ (mega joule)) is calculated by using the following integral equation in a stress σ-strain ε curve in a tensile test of a resin film for forming a dielectric layer, where cb is strain at breakage.
U=∫.sub.0.sup.ε.sup.
(30) When the dielectric layer filled with dielectric particles at a high concentration has a strain energy at break of 1.8 MJ or less, the effect of suppressing damage to the dielectric layer and the effect of suppressing a thickness variation, which are advantageous effects of the production method according to the present invention, are exhibited significantly. The strain energy at break U of the dielectric layer is typically 1.2 MJ or less, more typically 0.8 MJ or less, and even more typically 0.5 MJ or less. There is no particular limitation on the lower limit value of the strain energy at break U, but the lower limit value of the strain energy at break U is preferably 0.01 MJ or more, and more preferably 0.02 MJ or more. With a lower limit value within the range described above, the uniformity of thickness of the dielectric layers 12a and 12b in the multi-layered board according to the present invention can be sufficiently ensured. It is preferable that either one of the dielectric layers 12a and 12b in the multi-layered board according to the present invention satisfies the value of the strain energy at break U, and it is more preferable that both of the dielectric layers 12a and 12b satisfy the value of the strain energy at break U.
(31) In general, a dielectric layer that has a low strain energy at break has a low tensile strength. A dielectric layer that exhibits a relative dielectric constant typically has a tensile strength of 60.0 MPa or less, more typically 55.0 MPa or less, and even more typically 50.0 MPa or less. In this case, the advantageous effects of the present invention are more advantageously exhibited.
(32) On the other hand, from the viewpoint of sufficiently ensuring the adhesiveness between a dielectric layer and a conductive layer, the dielectric layer preferably has a tensile strength of 5.0 MPa or more, and more preferably 8.0 MPa or more.
(33) It is preferable that either one of the dielectric layers 12a and 12b in the multi-layered board according to the present invention satisfies the value of the tensile strength, and it is more preferable that both of the dielectric layers 12a and 12b satisfy the value of the tensile strength.
(34) Also, when the dielectric layer has a tensile elongation at break (strain at break) as low as 5.0% or less, or 4.0% or less, or 1.0% or less, the advantageous effects of the present invention are more advantageously exhibited.
(35) On the other hand, from the viewpoint of retaining flexibility sufficient to withstand at least handling during production of a printed wiring board, the dielectric layer preferably has a tensile elongation at break (strain at break) of 0.05% or more, and more preferably 0.2% or more.
(36) It is preferable that either one of the dielectric layers 12a and 12b in the multi-layered board according to the present invention satisfies the value of the tensile elongation at break, and it is more preferable that both of the dielectric layers 12a and 12b satisfy the value of the tensile elongation at break.
(37) With respect to the strain energy at break, the tensile strength, and the tensile elongation at break described above, values obtained from stress strain curves obtained through measurement in accordance with JIS K 7161 (1994) “Test Method for Tensile Properties of Plastics” at a measurement temperature of 25° C., a chuck-to-chuck distance of 50 mm, and a pulling speed of 1.0 mm/min (2%/min in terms of strain speed) are used as standard conditions. In a case where a sample of the dielectric layer is too short for the chuck-to-chuck distance, measurement may be performed with a method that uses a strain speed of 2%/min.
(38) Indentation elastic modulus Eit may be used as another physical property value that indicates the brittleness of the dielectric layer. The dielectric layer typically has an indentation elastic modulus Eit as high as 4800 N/mm.sup.2 or more, more typically 6000 N/mm.sup.2 or more, and even more typically 8000 N/mm.sup.2 or more. As the indentation elastic modulus Eit, a value obtained through measurement using a nanoindentation method in accordance with ISO 14577 (2015) is used. It is preferable that either one of the dielectric layers 12a and 12b in the multi-layered board according to the present invention satisfies the value of the indentation elastic modulus Eit, and it is more preferable that both of the dielectric layers 12a and 12b satisfy the value of the indentation elastic modulus Eit.
(39) As the thickness of each of the first dielectric layer 12a and the second dielectric layer 12b is reduced, the electric capacity increases, and the amount of electric power stored increases as well. The stored electric power is used as a part of power supply, which leads to power saving. The thickness of each of the dielectric layers 12a and 12b is determined at the time of product design and circuit design, and is determined considering the level required by the market. In the present invention, the first dielectric layer 12a and the second dielectric layer 12b each independently have a thickness of preferably 30 μm or less, more preferably 16 μm or less, even more preferably 12 μm or less, and most preferably 8 μm or less. There is no limitation on the lower limit of the thickness of each of the dielectric layers 12a and 12b as long as adjacent conductive layers do not short circuit. For example, the first dielectric layer 12a and the second dielectric layer 12b each independently have a thickness of, preferably 0.1 μm or more, and more preferably 0.5 μm or more from the viewpoint of more reliably preventing a short circuit between adjacent conductive layers as described above.
(40) Under the condition that the first dielectric layer 12a and the second dielectric layer 12b each have a thickness within the above-described range, it is preferable that there is little variation between thicknesses measured at a plurality of arbitrary positions. With little thickness variation, a variation is unlikely to occur in the electrostatic capacity of the capacitor formed from the dielectric layers 12a and 12b. From this viewpoint, the dielectric layers 12a and 12b each independently have a thickness variation of, preferably 15% or less, more preferably 10% or less, and even more preferably 8% or less.
(41) The thickness variation of the dielectric layers 12a and 12b is a value defined by the greater one of numerical values (unit: %) that are represented by the following expressions (1) and (2) after the highest, lowest, and average values are obtained by performing measurement at at least a total of ten spots on the first dielectric layer 12a or the second dielectric layer 12b including the center and edges (four corners if the dielectric layer is, for example, rectangular) by observing a cross section in the thickness direction that has been enlarged (for example, at a magnification of 500 times or more):
(42) [100×(highest value−average value)/average value] (1); and
(43) [100×(average value−lowest value)/average value] (2).
(44) As described above, the first dielectric layer 12a and the second dielectric layer 12b each have little thickness variation. The first dielectric layer 12a and the second dielectric layer 12b may have the same thickness, or may have different thicknesses. In either case, it is preferable that the difference between the relative dielectric constant of the first dielectric layer 12a and the relative dielectric constant of the second dielectric layer 12b is small. In particular, the difference between the relative dielectric constant ca of the first dielectric layer 12a and the relative dielectric constant εb of the second dielectric layer 12b is preferably 10% or less, more preferably 5% or less, and even more preferably 3% or less. With a small difference between the relative dielectric constant ca of the first dielectric layer 12a and the relative dielectric constant εb of the second dielectric layer 12b, it becomes easier to design the production of a multi-layer printed wiring board, by using the multi-layered board 10. From this viewpoint, it is particularly preferable that the first dielectric layer 12a and the second dielectric layer 12b have the same thickness. It is particularly preferable that the first dielectric layer 12a and the second dielectric layer 12b have the same composition (the composition of the resin composition). The difference between the relative dielectric constant εa of the first dielectric layer 12a and the relative dielectric constant εb of the second dielectric layer 12b is defined by [(|εa−εb|/εa)×100].
(45) There is no particular limitation on the thicknesses of the middle conductive layer 11a, the first outer surface conductive layer 13a and the second outer surface conductive layer 13b that sandwich the first dielectric layer 12a and the second dielectric layer 12b. These layers may be thin or thick. It is preferable that the conductive layers 11a, 13a, and 13b each independently have a thickness of, for example, 0.1 μm or more and 70 μm or less. The conductive layers 11a, 13a, and 13b may have the same thickness and/or may be of the same type, or may have different thicknesses and/or may be of different types. In general, the conductive layers 11a, 13a, and 13b are preferably made of metal foils from the viewpoint of production processes. The metal foils may be rolled foils, electrolytic foils, or vapor deposition foils. As the metal foils, for example, copper foils are typically used, but it is also possible to use metal foils other than copper foils. Also, an electric resistance layer (for example, a layer made of Ni—P, Ni—Cr or the like) may be provided on the surface, which oppose the corresponding dielectric layer 12, of the conductive layers 13a and 13b.
(46) From the viewpoint of sufficiently ensuring the thickness of each of the first dielectric layer 12a and the second dielectric layer 12b and obtaining a sufficiently high electrostatic capacity, it is preferable that the surfaces, which oppose the dielectric layers 12a or 12b, of the conductive layers 11a, 13a, and 13b have a low roughness. From this viewpoint, the surfaces, which oppose the first dielectric layer 12a or the second dielectric layer 12b, of the conductive layers 11a, 13a, and 13b preferably have a surface roughness Rz of 1.5 μm or less, more preferably 1.0 μm or less, and even more preferably they are not roughened, the surface roughness Rz being a ten-point average roughness Rz (JIS B0601-1994). With this configuration, the thicknesses of the first dielectric layer 12a and the second dielectric layer 12b can be easily made more uniform. In particular, with respect to the middle conductive layer 11a, the difference in surface roughness Rz between two surfaces of the middle conductive layer 11a is preferably 1.0 μm or less, and more preferably 0.5 μm or less. Because the two surfaces of the middle conductive layer 11a oppose the dielectric layers 12a and 12b, respectively, by reducing the difference in roughness between the two surfaces of the middle conductive layer 11a, the thicknesses of the first dielectric layer 12a and the second dielectric layer 12b can be made more uniform.
(47) The multi-layered board 10 configured as described above is preferably used as a material for producing a multi-layer printed wiring board. Accordingly, hereinafter, a preferred method for producing a multi-layer printed wiring board using the multi-layered board 10 will be described.
(48) First, as shown in
(49) Next, as shown in
(50) After the first through hole 15 has been filled with the filler 16, as shown in
(51) After the second through hole 17 has been formed in the manner described above, as shown in
(52) Next, as shown in
(53) After a circuit pattern has been formed, next, as shown in
(54) The insulating resin layer may be, for example, (i) a stack obtained by stacking the necessary number of prepregs each obtained by impregnating a fibrous material such as a glass woven fabric, glass non-woven fabric or paper with an insulating resin. The insulating resin used to impregnate the fibrous material may be, for example, epoxy resin, cyanate resin, maleimide resin, polyphenylene ether resin, phenol resin, polyimide resin, or the like. Alternatively, the insulating resin layer may be (ii) an insulating resin layer made of epoxy resin, polyimide resin, polyester resin, or the like (or in other words, a layer that does not contain a fibrous material). Irrespective of which of (i) and (ii) is used, the insulating resin layer can contain an inorganic filler. In the case where the insulating resin layer contains an inorganic filler, the filler in the second through hole 17 is composed of an insulating resin and an inorganic filler.
(55) After the insulating resin layer 20 has been stacked, as shown in
(56) Various types of methods can be used to stack the insulating resin layers 20 and 20, and the fifth conductive layers 21a and 21b. For example, first, semi-cured B stage insulating resin layers 20 and 20 are stacked on the surfaces of the multi-layered board 10, respectively, and fifth conductive layers 21a and 21b are stacked on the insulating resin layers 20 and 20. Then, the resulting stack is pressed under heat so as to cure the insulating resin layers 20, and as a result, the insulating resin layers 20 and 20, the fifth conductive layers 21a and 21b, and the multi-layered board 10 are bonded and integrated together. Instead of separately preparing the insulating resin layers 20 and 20, and the fifth conductive layers 21a and 21b, the above stack may be obtained by stacking resin-attached metal foils.
(57) Next, as shown in
(58) After the hole forming process has been performed on the insulating resin layer 20, and the third conductive layer 18b is exposed, next, as shown in
(59) After the third through hole 22 has been formed in the manner described above, as shown in
(60) Finally, as shown in
(61) In a multi-layer printed wiring board 100 (see
(62) As described above, by using the multi-layered board 10, it is possible to obtain a multi-layer printed wiring board 100 that incorporates an embedded capacitor, without compromising the uniformity in the thickness of the first dielectric layer 12a and the second dielectric layer 12b. Accordingly, in the embedded capacitor, a variation in the electrostatic capacity of the embedded capacitor is suppressed. Also, the middle conductive layer 11a, and the first outer surface conductive layer 13a and the second outer surface conductive layer 13b in the multi-layered board 10 can be easily connected to external conductive layers.
(63) Next, another preferred method for producing a multi-layer printed wiring board by using the multi-layered board 10 will be described with reference to
(64) In the production method according to the present embodiment, steps that are the same as those performed prior to the step shown in
(65) After the circuit pattern has been formed, next, as shown in
(66) Next, as shown in
(67) After patterning has been performed, as shown in
(68) Next, as shown in
(69) Furthermore, as shown in
(70) After the third through hole 22 has been formed in the manner described above, as shown in
(71) At the same time, a fourth conductive layer 19 is formed on the inner wall of the second through hole 17, and a seventh conductive layer 24 is formed on the inner wall of the third through hole 22. The fourth conductive layer 19 is formed so as to electrically connect the two third conductive layers 18a and 18b. Likewise, the seventh conductive layer 24 is formed so as to electrically connect the two third conductive layers 18a and 18b. Because the fourth conductive layer 19 is formed on a surface of the insulating resin layer 20 made of a non-electroconductive material, the fourth conductive layer 19 and the middle conductive layer 11a are insulated by the insulating resin layer 20 and are electrically disconnected from each other. On the other hand, the seventh conductive layer 24 is formed directly on the inner wall of the third through hole 22, and thus the middle conductive layer 11a that is exposed along the inner wall of the third through hole 22 is electrically connected to the seventh conductive layer 24.
(72) Finally, as shown in
(73) In a multi-layer printed wiring board 100 (see
(74) As described above, with the method for producing a multi-layer printed wiring board 100 according to the present embodiment as well, by using the multi-layered board 10, it is possible to obtain a multi-layer printed wiring board 100 that incorporates an embedded capacitor, without compromising the uniformity in the thickness of the first dielectric layer 12a and the second dielectric layer 12b. Accordingly, in the embedded capacitor, a variation in the electrostatic capacity of the embedded capacitor is suppressed.
(75) In the foregoing, the present invention has been described by way of preferred embodiments of the present invention. However, the present invention is not limited to the embodiments given above. For example, in the steps shown in
(76) Also, in the steps shown in
INDUSTRIAL APPLICABILITY
(77) According to the present invention, it is possible to provide a multi-layered board wherein a variation in the capacity of the embedded capacitor is suppressed.
LIST OF REFERENCE NUMERALS
(78) 10 multi-layered board 11a middle conductive layer 12a first dielectric layer 12b second dielectric layer 13a first outer surface conductive layer 13b second outer surface conductive layer 14a first element 14b second element 15 first through hole 16 filler 17 second through hole 18a, 18b third conductive layer 19 fourth conductive layer 20 insulating resin layer 21a, 21b fifth conductive layer 22 third through hole 23a, 23b sixth conductive layer 24 seventh conductive layer 25, 26 hole 100 multi-layer printed wiring board Ra first cavity portion Rb second cavity portion Rc third cavity portion