Bicycle frame

Abstract

The invention relates to a bicycle frame made by injection molding pellets of a long glass fibre reinforced polypropylene composition having a core containing glass fibres and an impregnating agent and a sheath of polypropylene surrounding said core, wherein the pellets have an average length of at least 1 mm, the amount of the glass fibers is 10 to 70 wt % with respect to the composition and the polypropylene has a flexural modulus determined according to ASTM D790A of at least 1000 N/mm.sup.2.

Claims

1. A bicycle frame made by injection molding pellets of a glass fibre reinforced polypropylene composition having a core containing glass fibres and an impregnating agent and a sheath of polypropylene surrounding said core, wherein the pellets have an average length of at least 1 mm, the amount of the glass fibres is 10 to 70 wt % with respect to the composition, wherein the impregnating agent comprises at least one of branched poly(alpha-olefin) or a mineral oil, and the polypropylene has a flexural modulus determined according to ASTM D790A of at least 1000 N/mm.sup.2.

2. The bicycle frame according to claim 1, wherein the amount of the polypropylene in the composition is 25 to 80 wt % with respect to the composition, the amount of the glass fibres is 10 to 70 wt % with respect to the composition and the amount of the impregnating agent is 5 to 15 wt % with respect to the glass fibres.

3. The bicycle frame according to claim 1, wherein the polypropylene has a melt flow rate measured in accordance with ISO 1133-1:2011 (2.16 kg, 230° C.) of 10 to 100 g/10 min.

4. The bicycle frame according to claim 1, wherein the amount of the glass fibres is 30 to 50 wt % with respect to the composition.

5. The bicycle frame according to claim 1, wherein pellets have a length of 5 to 40 mm.

6. The bicycle frame according to claim 1, wherein the polypropylene has a flexural modulus determined according to ASTM D790A of at least 1200 N/mm.sup.2.

7. The bicycle frame according to claim 1, wherein the polypropylene has a tensile strength determined according to ASTM D638-10 based on injection molded specimens of at least 20 MPa.

8. The bicycle frame according to claim 1, wherein the polypropylene has a tensile elongation at yield determined according to ISO 527-1/-2 of at least 5%.

9. The bicycle frame according to claim 1, wherein the polypropylene has a notched Izod impact strength determined according to ASTM D256-10 at 23° C. of at least 10 J/m.

10. The bicycle frame according to claim 1, wherein the composition has a tensile modulus determined according to ISO527/1A of at least 4000 N/mm.sup.2.

11. The bicycle frame according to claim 1, wherein the composition has a tensile strength determined according to ISO527/1A of at least 70 N/mm.sup.2.

12. The bicycle frame according to claim 1, wherein the composition has a tensile elongation at break according to ISO527/1A of at least 1.5%.

13. The bicycle frame according to claim 1, wherein the composition has a flexural modulus determined according to ISO 178 of at least 4000 N/mm.sup.2 and/or a flexural strength determined according to ISO 178 of at least 120 N/mm.sup.2.

14. The bicycle frame according to claim 1, wherein the composition has a Charpy impact notched strength according to ISO 179/1eA of at least 12 kJ/m.sup.2 and/or a Charpy impact unnotched strength according to ISO 179/1eA of at least 35 kJ/m.sup.2.

15. A method for the manufacture of the bicycle frame according to claim 1, said method comprising the steps of a) providing at least one continuous glass multifibre strand, b) applying an impregnating agent to said continuous glass multifibre strand, c) applying a sheath of polypropylene around the strand obtained in step b) so as to form a sheathed continuous multifibre strand, d) cutting the sheathed continuous multifibre strand so as to form the pellets and e) injection moulding the pellets to obtain the bicycle frame.

16. The bicycle frame according to claim 1, wherein the impregnating agent comprises a microcrystalline wax.

17. The bicycle frame according to claim 1, wherein the impregnating agent is present in an amount of 7 to 15 wt % with respect to the glass fibres.

Description

EXAMPLES

(1) A computer simulation was performed on whether a long glass fibre reinforced polypropylene composition SABIC® STAMAX 40YM243 passes the tests 4.1 to 4.5 of ISO4210-6:2014. The results were pass for all of 4.1 to 4.5 of ISO4210-6:2014.

(2) Table 1 shows the various mechanical properties of various long glass fibre reinforced polypropylene compositions.

(3) TABLE-US-00001 TABLE 1 20YM243 30YM243 40YM243 50YM240 Glass fibre % ISO 3451 20 30 40 50 content Tensile Modulus N/mm.sup.2 ISO 527/1A 4600 6600 8200 10500 Tensile Strength N/mm.sup.2 ISO 527/1A 80 105 110 115 Tensile % ISO 527/1A 2.5 2.3 2.1 1.9 Elongation at break Flexural Modulus N/mm.sup.2 ISO 178 4600 6400 8700 Flexural strength N/mm.sup.2 ISO 178 130 160 180 Charpy impact kJ/m.sup.2 ISO 179/1eA 14 20 26 22 notched Charpy impact kJ/m.sup.2 ISO 179/1eU 40 60 55 50 unnotched

(4) Polypropylene SABIC® STAMAX 20YM243, 30YM243, 40YM243 and 50YM240 comprises a polypropylene homopolymer having the following properties shown in Table 2.

(5) TABLE-US-00002 TABLE 2 TEST PROPERTIES UNITS METHODS POLYMER PROPERTIES Melt Flow Rate at 230° C. and 2.16 kg  47 dg/min ISO 1133- 1:2011 Density at 23° C.  905 kg/m.sup.3 ASTM D1505 MECHANICAL PROPERTIES Tensile Strength at Yield .sup.(1)  35 Mpa ASTM D638 Tensile Elongation at Yield  11 % ISO 527-1/-2 Flexural Modulus (1% Secant) 1800 MPa ASTM D790 A Notched lzod Impact Strength at  20 J/m ASTM D256- 23° C. 10 .sup.(1) Based on injection molded specimens