METHODS AND SYSTEMS FOR PRODUCING HIGH PURITY METHANOL FROM CARBON DIOXIDE HYDROGENATION USING NaA MEMBRANE REACTOR

Abstract

The dehydration membrane reactor for methanol production from CO.sub.2 hydrogenation includes one or more porous supports, a dehydration membrane on the one or more porous supports, and a catalyst layer on the dehydration membrane. The one or more porous supports include hollow ceramic fibers and the dehydration membrane includes NaA zeolite. The reactor is made by dip-coating the porous supports in a zeolite crystal seed solution and drying the coated porous support. The coated porous support is dried at about 80° C. and then heated to a temperature above about 200° C. The NaA zeolite membrane is then grown on the seeded support, and a catalyst layer is applied to the zeolite membrane. A feedstream including carbon dioxide and hydrogen is fed to the catalyst layer, where a product stream including methanol and water is evolved. The water is then removed from the product stream through the dehydration membrane to produce a high-purity methanol product.

Claims

1. A dehydration membrane reactor for methanol production from CO.sub.2 hydrogenation comprising: one or more porous supports; a dehydration membrane on the one or more porous supports; and a catalyst layer on the dehydration membrane, wherein in the one or more porous supports includes a lumen.

2. The dehydration membrane reactor according to claim 1, wherein the one or more porous supports include a tubular sidewall having an external surface and an internal surface, wherein the dehydration membrane is disposed on the exterior surface and the interior surface encloses the lumen.

3. The dehydration membrane reactor according to claim 1, wherein the one or more porous supports include hollow ceramic fibers.

4. The dehydration membrane reactor according to claim 1, wherein the dehydration membrane includes NaA zeolite.

5. The dehydration membrane reactor according to claim 1, wherein the catalyst layer includes copper, zinc oxide, and alumina.

6. The dehydration membrane reactor according to claim 1, further comprising a feedstream in communication with the catalyst layer, the feedstream including H.sub.2 and CO.sub.2 , wherein the molar ratio of H.sub.2 to CO.sub.2 is about 3:1.

7. The dehydration membrane reactor according to claim 1, wherein the dehydration membrane reactor is produced by a method comprising: providing the porous support; applying a plurality of NaA zeolite crystal seeds to the porous support to form a seeded support; heating the seeded support at a temperature above about 200° C.; growing an NaA zeolite membrane on the seeded support; and applying a catalyst layer to the zeolite membrane.

8. A method of making a membrane reactor for methanol production from CO.sub.2 hydrogenation comprising: providing a porous support; applying a plurality of zeolite crystal seeds to the porous support to form a seeded support; heating the seeded support at a temperature above about 150° C.; growing a zeolite membrane on the seeded support; and applying a catalyst layer to the zeolite membrane.

9. The method according to claim 8, wherein applying a plurality of zeolite crystal seeds to the porous support to form a seeded support further comprises: dip-coating the porous support in a zeolite crystal seed solution; and drying the coated porous support.

10. The method according to claim 8, wherein the coated porous support is dried at a temperature below about 80° C.

11. The method according to claim 8, wherein the porous support with the zeolite crystal seeds is heated above about 200° C.

12. The method according to claim 8, wherein the one or more porous supports include ceramic fibers.

13. The method according to claim 8, wherein the zeolite membrane includes NaA zeolite.

14. The method according to claim 13, wherein the zeolite crystal seeds are sized between about 20-250 nm.

15. A method for producing methanol comprising: providing a dehydration membrane reactor, the dehydration membrane reactor including one or more porous supports, a dehydration membrane on the one or more hollow porous supports, and a catalyst layer on the dehydration membrane, wherein the one or more porous supports includes a lumen; supplying a feedstream including carbon dioxide to the catalyst layer; evolving a product stream from the feedstream, the product stream including methanol and water; and transporting water from the product stream through the dehydration membrane to the lumen.

16. The method according to claim 15, wherein the porous supports include hollow ceramic fibers.

17. The method according to claim 15, wherein the zeolite membrane includes NaA zeolite.

18. The method according to claim 15, wherein the catalyst layer includes copper, zinc oxide, and alumina.

19. The method according to claim 15, wherein the feed stream includes H.sub.2 and CO.sub.2 , wherein the molar ratio of H.sub.2 to CO.sub.2 is about 3:1.

20. The method according to claim 15, wherein evolving a product stream from the feedstream occurs above about 20 bar and 200° C.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0011] The drawings show embodiments of the disclosed subject matter for the purpose of illustrating the invention. However, it should be understood that the present application is not limited to the precise arrangements and instrumentalities shown in the drawings, wherein:

[0012] FIG. 1 is a schematic representation of a membrane reactor according to some embodiments of the present disclosure;

[0013] FIG. 2A is a chart of a method of making a membrane reactor according to some embodiments of the present disclosure;

[0014] FIG. 2B is a chart of a method of making a membrane reactor according to some embodiments of the present disclosure; and

[0015] FIG. 3 is a chart of a method of producing methanol according to some embodiments of the present disclosure.

DETAILED DESCRIPTION

[0016] Referring now to FIG. 1, some embodiments of the present disclosure are directed to a membrane reactor 100. In some embodiments, membrane reactor 100 is configured to remove an unwanted component from a feedstream. In some embodiments, reactor 100 is configured to facilitate a reaction that generates a desired product, and also facilitate removal of unwanted components evolved during the reaction. In some embodiments, the reaction is a Fischer-Tropsch or other synthesis reaction or series of reactions. In some embodiments, the desired products are evolved and undated components removed by reactor 100 substantially simultaneously. In some embodiments, the desired product is methanol. In some embodiments, the methanol is formed via reactor 100 from a CO.sub.2 hydrogenation reaction, as will be discussed in greater detail below.

[0017] In some embodiments, reactor 100 includes one or more supports 102. In some embodiments, at least one of supports 102 is porous. In some embodiments, porous supports 102 includes a plurality of pores and/or internal channels sized to accommodate one or more nanocrystals, e.g., having a particle size between about 50 nm and about 250 nm, as will be discussed in greater detail below. In some embodiments, the size of the pores/internal channels is between about 100 nm and about 500 nm. In some embodiments, the size of the pores/internal channels is about 400 nm. In some embodiments, supports 102 can be any suitable shape. In some embodiments, supports 102 are generally tubular in shape. In some embodiments, supports 102 include a lumen 102L. In some embodiments, the one or more porous supports include a tubular sidewall 104. In some embodiments, tubular sidewall 104 has an external surface 104A and an internal surface 104B. In some embodiments, internal surface 104B encloses lumen 102L.

[0018] In some embodiments, supports 102 are composed of any suitable material capable of withstanding elevated temperatures, e.g., temperatures greater than about 100° C. In some embodiments, supports 102 include a ceramic. In some embodiments, supports 102 are ceramic fibers. In some embodiments, the ceramic fibers are hollow.

[0019] In some embodiments, reactor 100 includes a separation membrane 106. In some embodiments, membrane 106 is selective for the unwanted components evolved within reactor 100, facilitating separation of the unwanted component from the desired product. In some embodiments, membrane 106 is a dehydration membrane. As used herein, a dehydration membrane, e.g., membrane 106, is configured to selectively remove water from the environment surrounding the membrane. In some embodiments, membrane 106 is disposed on exterior surface 104A. In some embodiments, membrane 106 includes a zeolite. In some embodiments, the zeolite is zeolite A, zeolite X, zeolite Y, or combinations thereof. In some embodiments, the zeolites include one or more cations. In some embodiments, the cations include Na.sup.+. In some embodiments, membrane 106 includes NaA zeolite.

[0020] In some embodiments, reactor 100 includes a catalyst layer 108. In some embodiments, the catalyst layer is disposed on membrane 106. In some embodiments, catalyst layer 108 is configured, e.g., includes catalysts effective to at least in part catalyze a reaction that generates the desired product of reactor 100, e.g., methanol. In some embodiments, catalyst layer 108 includes copper, zinc oxide, and alumina. In some embodiments, catalyst layer 108 includes Cu/ZnO/Al.sub.2O.sub.3.

[0021] Without wishing to be bound by theory, the zeolite membranes of the present disclosure have a hydrophilic, microporous structure, making them excellent at removing water from the environment surrounding the membrane. In some embodiments, the membranes dehydrate the environment to treat a feedstream or product stream, e.g., a stream including syngas, natural gas, supercritical CO.sub.2 , etc., as will be discussed in greater detail below. For methanol production from catalytic CO.sub.2 hydrogenation, water is a major by-product that restricts CO.sub.2 conversion and inhibits reaction rate. Some embodiments of the present disclosure remove water in-situ, thus shifting the equilibrium towards methanol formation and leading to higher CO.sub.2 conversion and methanol yield.

[0022] In some embodiments, reactor 100 includes one or more feedstream inlets 110. In some embodiments, reactor 100 includes one or more feedstreams 110A in communication with feedstream inlets 110 and a surface 108S of catalyst layer 108. In some embodiments, feedstreams 110A include reactants whose reaction results in the desired product, e.g., methanol. In some embodiments, feedstream 110A includes CO.sub.2-rich syngas, CO.sub.2-free syngas, CO-rich syngas, natural gas, supercritical CO.sub.2, or combinations thereof. In some embodiments, feedstream 110A includes at least H.sub.2 and CO.sub.2, wherein the molar ratio of H.sub.2 to CO.sub.2 is about 3:1. In some embodiments, reactor 100 includes one or more product streams 112 that include the desired products evolved in the reactor. In some embodiments, reactor 100 is a packed bed reactor.

[0023] Referring now to FIGS. 2A-2B, some embodiments of the present disclosure are directed to a method 200 of making a membrane reactor for the generation of a desired product, e.g., for methanol production from CO.sub.2 hydrogenation as discussed above. At 202, one or more porous supports are provided. As discussed above, in some embodiments, the porous supports include a plurality of pores and/or internal channels sized to accommodate one or more nanocrystals. In some embodiments, the porous support is generally tubular in shape. In some embodiments, the porous support includes a lumen. In some embodiments, the porous support is composed of any suitable material capable of withstanding elevated temperatures, e.g., temperatures greater than about 100° C. In some embodiments, the porous support includes a ceramic. In some embodiments, the porous support includes ceramic fibers. In some embodiments, the ceramic fibers are hollow.

[0024] At 204, a plurality of nanocrystals are applied to the porous support to form a seeded support. As discussed above, in some embodiments, the nanocrystals have a particle size between about 50 nm and about 250 nm. In some embodiments, the nanocrystals have a particle size at least smaller than a pore size of the porous support. Thus, when applied to the porous support, the nanocrystals penetrate into the porous support to attach within as well to the surface of that support. In some embodiments, the nanocrystals are zeolite crystal seeds, e.g., NaA zeolite crystal seeds, as will be discussed in greater detail below. Referring specifically to FIG. 2B, in some embodiments, at 204A, the nanocrystals are applied to the porous support by dip-coating the support in a solution including the nanocrystals, e.g., zeolite crystal seeds. At 204B, the dip-coated support is then dried. In some embodiments, the dip-coated support is dried at a temperature below about 100° C. In some embodiments, the dip-coated support is dried at a temperature below about 80° C.

[0025] Referring again to FIGS. 2A-2B, at 206, the seeded support is heated at an elevated temperature. In some embodiments, the seeded support is heated to about 150° C. In some embodiments, the seeded support is heated above about 150° C. In some embodiments, the seeded support is heated to about 200° C. In some embodiments, the seeded support is heated to above about 200° C. At 208, a membrane, e.g., NaA zeolite membrane, is grown on the seeded support. Without wishing to be bound by theory, heating 206 increases the binding strength between the nanocrystals and the porous support. Growth of the membrane takes place both in the pores and on the surface of the support, creating a consistent and dense layer of membrane interfacing closely with the support with reduced boundary defects. Reducing the boundary defects improves the selectivity of the membranes, and further allows them to maintain that selectivity even at challenging industrial conditions.

[0026] At 210, a catalyst layer is applied to the membrane. As discussed above, in some embodiments, the catalyst layer includes copper, zinc oxide, and alumina. In some embodiments, the catalyst layer includes Cu/ZnO/Al.sub.2O.sub.3.

[0027] In some embodiments of the present disclosure, nano-sized zeolite seeds were hydrothermally synthesized. In an exemplary embodiment, NaA zeolite seeds with molar composition of 1.8 Al.sub.2O.sub.3: 11.25 SiO.sub.2: 0.6 Na.sub.2O: 13.4 (TMA)2O: 700 H.sub.2O were synthesized according to the following procedure: [0028] (1) 0.1361 g of sodium hydroxide (NaOH, 98 wt. %, Sigma-Aldrich), 13.8912 g of tetramethylammonium hydroxide pentahydrate (TMAOH.5H.sub.2O, 97 wt. %, Sigma), 6.7 g of deionized (DI) water were mixed with vigorous agitation; after the solution was clear, 2.0816 g of aluminum isopropoxide (Al(i-C.sub.3H.sub.7O)3, 98 wt. %, Sigma-Aldrich) was added into the resultant solution, and stirred for 12 h at room temperature; [0029] (2) 4.6875 g of Ludox colloidal silica (40 wt. % in water, Sigma-Aldrich) was added into the solution dropwise until the solution became clear; [0030] (3) The resultant solution was transferred to an autoclave, sealed and then the autoclave was put into the oven that had been preheated to 100° C. After 3 h of hydrothermal synthesis, crystals were collected by repeated centrifugation at 10,000 rpm for 0.5 h and rinsing with DI water until the solution pH reached 9, and then were dried at 100° C. overnight. 1

[0031] Referring now to FIG. 3, some embodiments of the present disclosure are directed to using the membrane reactors described above to generate one or more desired products, e.g., methanol. At 302, a membrane reactor, e.g., a dehydration membrane reactor, is provided. As discussed above, in some embodiments, the dehydration membrane reactor includes one or more porous supports, a dehydration membrane on the one or more hollow porous supports, and a catalyst layer on the dehydration membrane, and the one or more porous supports includes a lumen. At 304, one or more feedstreams including one or more reactants were supplied to the catalyst layer. In some embodiments, the feedstreams include carbon dioxide. At 306, a product stream is evolved from the feedstreams, having been generated via a reaction catalyzed by the catalyst layer. In some embodiments, the temperature and pressure within the reactor are maintained at desired levels to facilitate reactions and generation of desired products within. In some embodiments, the temperature inside the reactor is brought to above about 200° C. In some embodiments, the temperature inside the reactor is brought to above about 250° C. In some embodiments, the pressure inside the reactor is brought to above about 20 bar. In some embodiments, the pressure inside the reactor is brought to above about 30 bar. In some embodiments, the pressure inside the reactor is brought to above about 40 bar. In some embodiments, the pressure inside the reactor is brought to above about 50 bar. In some embodiments, the product stream includes a desired product and an unwanted component. At 308, one or more unwanted components are removed from the product stream. In some embodiments, an unwanted component is transported from the product stream through the membrane to the lumen of the porous support, facilitating separation of the unwanted component from the desired product. At 310, in some embodiments, the product stream is then removed.

[0032] In an exemplary embodiment, a packed-bed reactor including a plurality of hollow ceramic fibers is provided. The hollow ceramic fibers include NaA zeolite membranes disposed on an external surface thereof and enclose a lumen. A Cu/ZnO/Al.sub.2O.sub.3 catalyst layer is disposed on the NaA zeolite membranes. Feedstreams including H.sub.2 and CO.sub.2 are fed to the catalyst layer at a molar ration H.sub.2 to CO.sub.2 of about 3:1. Pressure and temperature within the reactor were brought to above about 200° C. and 20 bar. A product stream including methanol and water is generated according to the following reactions 1-3:

CO.sub.2+3H.sub.2.Math.CH.sub.3OH+ΔH.sub.2O H.sub.298 K=−49.5 kJ/mol   (1)

CO.sub.2+H.sub.2.Math.CO+H.sub.2O ΔH.sub.298 K=41 kJ per mol   (2)

CO+2H.sub.2.Math.CH.sub.3OH ΔH.sub.298 K=−90.5 kJ per mol   (3)

[0033] The water was transported from the product stream through the dehydration membrane to the lumen, resulting in a stream of high purity methanol.

[0034] Methods and systems of the present disclosure include improved NaA membranes with high separation performance for water/gas mixtures at high pressures and elevated temperatures, that are themselves advantageously produced by an improved seeding method. Incorporation of synthesized NaA membranes into a dehydration membrane reactor for methanol production from CO.sub.2 hydrogenation significantly enhanced CO.sub.2 conversion and methanol yield, approximately 3 times of that of PBR without these membranes. Catalyst deactivation was also greatly alleviated by in-situ water removal from the reactor. This technique is scalable and can be applied to other reactions with water as the by-product and that are thermodynamically limited.

[0035] Systems and methods of the present disclosure save a large amount of energy for product purification and make this process more economically feasible. The method of making the membrane is a simple but effective seeding method which shows high H.sub.2O/gas selectivity at high temperature and high pressure (for example, H.sub.2O/CO.sub.2 selectivity as high as ˜10,000 at 250° C. and 38 bar). The H.sub.2O/gas selectivity of NaA membrane prepared by this seeding method is 2 orders of magnitude higher than that of NaA membrane prepared by regular seeding method without heating the seeded support at high temperature before membrane synthesis.

[0036] Besides the above advantages, high purity methanol (˜95 wt. %), much higher than that of obtained in current industrial process (˜68 wt. %), can be directly produced by simply cooling down the product stream after the reactor. This saves a considerable amount of energy for methanol purification. These NaA membrane reactors make this process more economically feasible, and largely accelerate the industrial methanol production from CO.sub.2 hydrogenation. Long-term stability testing shows continuous production of high purity methanol can be achieved due to stability of the membrane.

[0037] Although the disclosed subject matter has been described and illustrated with respect to embodiments thereof, it should be understood by those skilled in the art that features of the disclosed embodiments can be combined, rearranged, etc., to produce additional embodiments within the scope of the invention, and that various other changes, omissions, and additions may be made therein and thereto, without parting from the spirit and scope of the present invention.