Method of manufacturing foam molded article
11141905 · 2021-10-12
Assignee
Inventors
Cpc classification
B29K2023/00
PERFORMING OPERATIONS; TRANSPORTING
B29C49/42
PERFORMING OPERATIONS; TRANSPORTING
B29C49/04102
PERFORMING OPERATIONS; TRANSPORTING
B29C44/105
PERFORMING OPERATIONS; TRANSPORTING
B29L2031/30
PERFORMING OPERATIONS; TRANSPORTING
B29C49/4252
PERFORMING OPERATIONS; TRANSPORTING
International classification
B29C44/10
PERFORMING OPERATIONS; TRANSPORTING
B29C49/42
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method of manufacturing a foam molded article is disclosed. The method includes the steps of forming a foam parison by extruding a molten, kneaded resin containing a foaming agent through an annular slit in an extrusion direction in which a molding region between a pair of split molds lies, and molding a foam molded article by closing the split molds with respect to the foam parison located in the molding region. The parison formation step includes performing pre-blowing by injecting air toward an inner surface of the foam parison in a direction which forms an angle of 45° or more and 135° or less with the extrusion direction.
Claims
1. A method of manufacturing a foam molded article, comprising: a parison formation step of forming a foam parison by extruding a molten, kneaded resin containing a foaming agent through an annular slit in an extrusion direction in which a molding region between a pair of split molds lies, and a molding step of molding a foam molded article by closing the split molds with respect to the foam parison located in the molding region, wherein the parison formation step includes performing pre-blowing by injecting air toward an inner surface of the foam parison in a direction which forms an angle of 45° or more and 135° or less with the extrusion direction, and wherein, in the parison formation step, the foam parison is pinched between pinchers and sealed before a lower end of the foam parison reaches a lower end of the molding region, and the pre-blowing is performed while lowering the pinchers as the lower end of the foam parison is lowered.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
(17)
(18)
DESCRIPTION OF EMBODIMENTS
(19) Now, embodiments of the present invention will be described. Various features described in the embodiments below can be combined with each other. Inventions are established for the respective features.
(20) A first aspect of the present invention provides a method of manufacturing a foam molded article. The method includes an extrusion step of extruding a molten, kneaded resin containing a foaming agent through an annular slit between a die core and a die shell surrounding the die core to form a cylindrical foam parison and extruding the foam parison between a pair of split molds, a lower-pinching step of pinching the foam parison between lower pinchers disposed under the split molds, and a molding step of molding the foam parison by closing the split molds, after the lower-pinching step. H/D is 1.33 to 3.33 and L/D is 0.33 to 2.00 where D represents a diameter of the die core; H represents a distance between a lower surface of the die core and an upper surface of each of the split molds; and L represents a distance between a lower surface of each of the split molds and an upper surface of the corresponding lower pincher.
(21) A second aspect of the present invention provides a method of manufacturing a foam molded article. The method includes a parison formation step of forming a foam parison by extruding a molten, kneaded resin containing a foaming agent through an annular slit in an extrusion direction in which a molding region between a pair of split molds lies, a molding step of molding a foam molded article by closing the split molds with respect to the foam parison located in the molding region. The parison formation step includes performing pre-blowing by injecting air toward an inner surface of the foam parison in a direction which forms an angle of 45° or more and 135° or less with the extrusion direction.
1. First Embodiment
(22) First, there will be described a foam molded article manufacturing apparatus suitable to perform a foam molded article manufacturing method according to a first embodiment of the present invention. Then, the foam molded article manufacturing method according to the first embodiment will be described.
(23) 1.1 Foam Molded Article Manufacturing Apparatus
(24) As shown in
(25) The respective elements will be described in detail below.
(26) Resin Inlet 5
(27) The resin inlet 5 is a so-called “hopper”, and a raw-material resin is introduced therethrough. The raw-material resin may be in any form and is typically in the form of pellets. The raw-material resin is, for example, a thermoplastic resin such as polyolefin. Examples of polyolefin include low-density polyethylene, linear low-density polyethylene, high-density polyethylene, polypropylene, ethylene-propylene copolymer, and mixtures thereof. After being introduced to the cylinder 3 through the resin inlet 5, the raw-material resin is heated and thus molten in the cylinder 3 to give a molten resin. The molten resin is transferred toward the resin extrusion outlet 11 disposed at one end of the cylinder 3 by the rotation of the screw 7 disposed in the cylinder 3.
(28) Screw 7
(29) The screw 7 is disposed in the cylinder 3 and transfers the molten resin toward the resin extrusion outlet 11 by the rotation thereof while kneading the molten resin. The screw 7 is provided with a gear device 30 at one end thereof and is rotationally driven by the gear device 30. The number of screws 7 disposed in the cylinder 3 may be one, or two or more.
(30) Foaming Agent Inlet P
(31) The cylinder 3 is provided with the foaming agent inlet P for introducing a foaming agent to the cylinder 3. The foaming agent inlet P may be disposed in any position. However, the foaming agent inlet P is preferably disposed in a position represented by 0.3L to 0.7L (preferably 0.4L to 0.6L) where 0 represents the position of the end close to the resin inlet 5, of the cylinder 3; and L represents the position of the end close to the resin extrusion outlet 11 thereof. If the foaming agent inlet P is disposed in a position closer to the resin inlet 5 than a position represented by 0.3L, the foaming agent may be introduced with the molten resin insufficiently kneaded, resulting in insufficient dispersion of the foaming agent. On the other hand, if the foaming agent inlet P is disposed in a position closer to the resin extrusion outlet 11 than a position represented by 0.7L, the temperature of the molten resin may become excessively low in the area in which the foaming agent is introduced, resulting in introduction of a smaller amount of foaming agent. This is because the temperature of the molten resin is typically controlled so as to gradually decrease toward the resin extrusion outlet 11.
(32) Examples of the foaming agent introduced through the foaming agent inlet P include physical foaming agents, chemical foaming agents, and mixtures thereof. Examples of physical foaming agents include inorganic physical foaming agents such as air, carbon dioxide, nitrogen gas, and water, organic physical foaming agents such as butane, pentane, hexane, dichloromethane, and dichloroethane, and supercritical fluids thereof. A supercritical fluid is preferably prepared using carbon dioxide, nitrogen, or the like. If nitrogen is used, a supercritical fluid is prepared by setting the critical temperature to −149.1° C. and the critical pressure to 3.4 MPa or more; if carbon dioxide is used, a supercritical fluid is prepared by setting the critical temperature to 31° C. and the critical pressure to 7.4 MPa or more. Examples of chemical foaming agents include ones that generate carbon dioxide by chemical reaction between acid (e.g., citric acid or salt thereof) and base (e.g., sodium bicarbonate). A chemical foaming agent may be introduced through the resin inlet 5 rather than the foaming agent inlet P.
(33) Temperature Controller 9
(34) The temperature controller 9 is configured to control the temperatures of the respective portions of the cylinder 3 by individually controlling multiple temperature controlling units disposed along the cylinder 3. The temperature controller 9 is also able to control the temperature of the die head 12 for forming a foam parison 13 and the temperature of a coupler 10 between the cylinder 3 and die head 12.
(35) Resin Extrusion Outlet 11 and Die Head 12
(36) A molten, kneaded resin obtained by melting and kneading the raw-material resin and foaming agent is extruded through the resin extrusion outlet 11 and introduced to the die head 12 through the coupler 10. As shown in
(37) Split Molds 14 and Lower Pinchers 15
(38) The pair of split molds 14 are used to mold the foam parison 13 into a foam molded article. As shown in
(39) The foam parison 13 may be molded using any molding method that uses the split molds 14. For example, blow molding, which involves molding the foam parison 13 by blowing air into the cavities of the split molds 14, vacuum molding, which involves molding the foam parison 13 by decompressing the cavities of the split molds 14 from the inner surfaces of the cavities, or a combination thereof may be used. As shown in
(40) As shown in
(41) 2. Foam Molded Article Manufacturing Method
(42) The foam molded article manufacturing method according to the first embodiment of the present invention includes an extrusion step, a lower-pinching step, and a molding step.
(43) As shown in
(44) As shown in
(45) As shown in
(46) If the method includes a step of decompressing the split molds 14 so that the foam parison 13 is adsorbed by the split molds 14, the start timing of decompression of one split mold 14 is preferably delayed by one sec or more (e.g., 1 to 5 sec) compared to the start timing of decompression of the other split mold 14. In particular, it is preferred to delay the start timing of decompression of the split mold 14 in which a fold is more likely to occur. For example, if the decompression of the right split mold 14 is started first, the foam parison 13 present in the cavities 14b is moved to the right, and the gap between the left split mold 14 and the foam parison 13 is increased. If the decompression of the left split mold 14 is started in this state, the foam parison 13 is expanded in a larger space. Thus, the wrinkles of the foam parison 13 are more likely to be stretched, and a fold is less likely to occur. Accordingly, if a fold is more likely to occur on a left portion of the foam parison 13, it is desirable to first start the decompression of the right split mold 14. Conversely, if a fold is more likely to occur on a right portion of the foam parison 13, it is desirable to first start the decompression of the left split mold 14.
(47) In the extrusion step, it is preferred to control the thickness of the foam parison 13 so that the thickness T1 of the area where a fold is more likely to occur, of the foam parison 13 becomes smaller than the thickness T2 of another area of the foam parison 13. T1/T2 is preferably 0.8 to 0.9. Thus, the area where a fold is more likely to occur, of the foam parison 13 is easily stretched, resulting in suppression of a fold. If the foam molded article is a tubular object including a main channel 17 and sub-channels 18 connected to the main channel 17, as shown in
(48) 3. Foam Molded Article
(49) The foam molded article manufacturing method of the first embodiment is a method that can be suitably used to manufacture a foam molded article having any shape and expansion ratio and that effectively suppresses occurrence of a fold. For this reason, this method is particularly suitable to manufacture a foam molded article having a shape or expansion ratio which makes a fold more likely to occur.
(50) In this respect, the expansion ratio of the foam molded article is preferably 2.5 or more. The reason is that higher expansion ratios result in greater reductions in the strength of the foam parison 13, making wrinkles and thus a fold more likely to occur on the foam parison 13. The upper limit of the expansion ratio may be any value and is, for example, 5. Specifically, the expansion ratio is, for example, 2.5, 3, 3.5, 4, 4.5, or 5, or may be between any two of the values presented. The average thickness of the foam molded article is preferably 2 mm or more. The reason is that if the same amount of resin is used, greater average thicknesses result in greater increases in the expansion ratio and greater reductions in the strength of the foam parison 13, making a fold more likely to occur. The upper limit of the average thickness may be any value and is, for example, 6 mm. Specifically, the average thickness is, for example, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, or 6 mm, or may be between any two of the values presented.
(51) As shown in
(52) A section S which forms an angle β of 0 to 45° with the extrusion direction of the foam parison 13 preferably has a blow ratio of 0.5 to 0.8. In
Examples
(53) Foam molded articles were manufactured using the foam molded article manufacturing apparatus shown in
(54) Foam parisons formed under the above conditions were blow-molded into foam molded articles having a shape shown in
(55) As shown in Table 1, folds were formed on Samples Nos. 3 to 8 and 11 to 16. Any of the folds was formed on the junction 19 so as to extend in a direction which forms an angle β of 0 to 45° with the extrusion direction of the foam parison 13. Also, the blow ratio of a section along the direction in which each fold extends was calculated. As shown in Table 1, it was found that a fold is more likely to occur in positions where the blow ratio is 0.5 to 0.8.
(56) No fold was formed on Samples Nos. 1, 2, 9, and 10 having H/D of 1.33 to 3.33 and L/D of 0.33 to 2.00, regardless of the blow ratio.
(57) Based on these results, it was found that by setting H/D to 1.33 to 3.33 and L/D to 0.33 to 2.00, even a foam molded article having an expansion ratio of 2.5 or more and a blow ratio of the junction 19 of 0.5 to 0.8 can prevent occurrence of a fold. Note that Samples having expansion ratios of 2 or less made no fold even if H/D and L/D fall outside the ranges.
(58) TABLE-US-00001 TABLE 1 Whether a fold is present Expan- Blow Blow Blow Sample sion Average ratio ratio ratio No. rate thickness H/D L/D 0.5-0.6 0.6-0.7 0.7-0.8 1 3 4 mm 1.33 0.33 2 3 4 mm 3.33 2.00 3 3 4 mm 1.00 0.33 Present Present 4 3 4 mm 1.33 0.20 Present 5 3 4 mm 1.00 0.20 Present Present Present 6 3 4 mm 4.00 2.00 Present 7 3 4 mm 3.33 2.33 Present Present 8 3 4 mm 4.00 2.33 Present Present Present 9 2.5 2 mm 1.33 0.33 10 2.5 2 mm 3.33 2.00 11 2.5 2 mm 1.00 0.33 Present 12 2.5 2 mm 1.33 0.20 Present 13 2.5 2 mm 1.00 0.20 Present Present 14 2.5 2 mm 4.00 2.00 Present 15 2.5 2 mm 3.33 2.33 Present 16 2.5 2 mm 4.00 2.33 Present Present
2. Second Embodiment
(59) The foam molded article manufacturing apparatus and method according to the first embodiment may perform pre-blowing by injecting air in the direction of an arrow B.sub.0 (extrusion direction) using a pre-blow nozzle, as shown in
(60) (1) As shown in
(2) The melt tension of a thermoplastic resin in foam blow molding is lower than that in typical blow molding, and a foam parison is stretched in the direction of gravity (typically, in the extrusion direction) due to the effect of gravity. As a result, the parison diameter is reduced.
(61) To solve these problems, the foam molded article manufacturing apparatus and method according to the second embodiment have an ingenious idea that allows for the formation of a foam parison into an approximately cylindrical shape without shrinking it and allows for the ease of reduction of the parison diameter. Also, this ingenious idea has been found to allow for a greater reduction in the incidence of a fold (in particular, a curtain phenomenon shown in
(62) 2.1 Pre-Blow Nozzle 20
(63) In the second embodiment and later, the region between split molds 14 is defined as a molding region U for the convenience of description. A pre-blow nozzle 20 has multiple micropores (not shown) in the side surface thereof, and air is injected through the micropores. The micropores may have any shapes and may have, for example, circular or oval shapes, or polygonal shapes such as quadrangular shapes. If the micropores are circular, the diameter of one micropore is preferably about 0.3 mm to 40.0 mm, more preferably 3.0 mm. If the diameter is smaller than the above range, the effect of expanding a foam parison 13 by pre-blowing would not be sufficiently obtained. Also, in case a resin adheres to the micropores, the micropores may be blocked. On the other hand, if the diameter is larger than the above range, processing itself is difficult (is limited by the size of the die core 47), and the resin may flow into the micropores. Although the number of micropores depends on the diameters thereof, it is preferably 3 to 8, more preferably 4.
(64) As shown in
(65) The pre-blow nozzle 20 is disposed under a die head 12 and in the approximate center of an annular slit 49. The pre-blow nozzle 20 may be configured such that the position thereof is vertically controllable, or may be disposed so as to be detachable. The pre-blow nozzle 20 may also be configured so as to rotate during air injection.
(66) 2.2. Foam Molded Article Manufacturing Method
(67) Next, a foam molded article manufacturing method according to the second embodiment of the present invention will be described.
(68) First, as shown in
(69) As shown in
(70) Then, as shown in
(71) Then, as shown in
3. Third Embodiment
(72) In the second embodiment, the pre-blow nozzle 20 is disposed under the die head 12 and in the approximate center of the annular slit 49. In the third embodiment, on the other hand, a pre-blow nozzle 20 is disposed so as to extend from below lower pinchers 15, as shown in
(73) In the third also, pressure is applied to the foam parison 13 in the outer circumference direction thereof, resulting in expansion of the foam parison 13, as shown in
4. Fourth Embodiment
(74) In the first to third embodiments, the lower pinchers 15 are located under the region (molding region U) between the split molds 14, as represented by the name thereof. In the fourth embodiment, on the other hand, upper pinchers 15a are disposed in an upper portion of a molding region U (or over the molding region U, depending on the size of split molds 14) in place of lower pinchers 15, as shown in
(75) The extrusion of the foam parison 13 in a predetermined amount and pre-blowing may be alternately performed multiple times as follows: first, the foam parison 13 is extruded in a predetermined amount so that the foam parison 13 is located in the upper portion of the molding region U, as shown in
(76) In other words, in the fourth embodiment, the foam parison 13 is pinched between the upper pinchers 15a and sealed before the lower end of the foam parison 13 reaches the lower end of the molding region U, and pre-blowing is performed while lowering the upper pinchers 15a as the lower end of the foam parison 13 is lowered.
(77) In the fourth embodiment also, pressure is applied to the foam parison 13 in the outer circumference direction thereof, resulting in expansion of the foam parison 13, as shown in
(78) 4.1 Modification of Fourth Embodiment
(79) In the fourth embodiment, upper-pinching need not be performed, as shown in
DESCRIPTION OF REFERENCE SIGNS
(80) 1: foam extruder 3: cylinder 5: resin inlet 7: screw 9: temperature controller 10: coupler 11: resin extrusion outlet 12: die head 13: foam parison 13a: closed space 13b: foam molded article 14: split mold 14a: pinch-off part 14b: cavity 14c: part 15: lower pincher 15a: upper pincher 16: foam molded article 17: main channel 18: sub-channel 19: junction 20: pre-blow nozzle 30: gear device 41: die case 43: mandrel 45: ring-shaped piston 46: space 47: die core 48: die shell 49: annular slit P: foaming agent inlet PL: parting line