COMPOSITE FILM

Abstract

The invention relates to a composite film (1), preferably intended for use in the construction industry and/or preferably for use as a construction film, having at least one functional layer (2), at least one outer protective layer (3) and at least one inner protective layer (4), the functional layer (2) being arranged between the outer protective layer (3) and the inner protective layer (4). According to the invention, it is provided that the functional layer (2) is formed as at least a single-layer membrane layer, that the outer protective layer (3) and the inner protective layer (4) are formed as a nonwoven layer comprising a polyolefin, and that the outer protective layer (3) and/or the inner protective layer (4) comprises at least one bicomponent fiber (5) having a first component (6) and a second component (7), the first component (6) comprising a first polymer and the second component (7) comprising a second polymer as constituent.

Claims

1. A composite film adapted for use in the construction industry and/or adapted for use as a construction film, having at least one functional layer, at least one outer protective layer and at least one inner protective layer, the functional layer being arranged between the outer protective layer and the inner protective layer, wherein the functional layer is formed as at least a single-layer membrane layer, that the outer protective layer and the inner protective layer are formed as a nonwoven layer comprising polyolefin, and in that the outer protective layer and/or the inner protective layer comprises at least one bicomponent fiber with a first component and a second component, the first component comprising a first polymer and the second component comprising a second polymer as constituent.

2. The composite film according to claim 1, wherein the functional layer is a monolithic membrane layer.

3. The composite film according to claim 1, wherein the functional layer comprises as material plastic and/or synthetic resin, preferably an elastomeric material and/or a thermoplastic material, further preferably polyurethane plastic, in particular thermoplastic polyurethane (TPU), and/or consists thereof.

4. The composite film according to claim 1, wherein the functional layer has a grammage of less than 100 g/m.sup.2, preferably between 1 g/m.sup.2 to 70 g/m.sup.2, more preferably between 3 g/m.sup.2 to 40 g/m.sup.2, preferably between 4 g/m.sup.2 to 30 g/m.sup.2 and in particular between 5 g/m.sup.2 to 25 g/m.sup.2.

5. The composite film according to claim 1, wherein the functional layer comprises at least two layers of membrane layers, in particular wherein the individual layers are formed differently and/or at least two layers are formed at least substantially identically.

6. The composite film according to claim 1, wherein at least one membrane layer of the functional layer, in particular an outer membrane layer preferably facing the outer protective layer and/or inner protective layer, has thermoplastic copolyester (TPEE) and/or thermoplastic polyurethane (TPU) as material and/or in that the functional layer is formed from TPEE layers and/or TPU layers.

7. The composite film according to claim 1, wherein at least one outer membrane layer and/or one inner membrane layer of the multilayer functional layer comprises and/or consists of a foamed polymer, in particular wherein the outer membrane layer of the functional layer comprising the foamed polymer is bonded to the outer and/or inner protective layer by means of interlocking.

8. The composite film according to claim 1, wherein the outer protective layer and/or the inner protective layer is formed as a nonwoven layer comprising polypropylene and/or consisting thereof, in particular as a polypropylene needlefelt layer.

9. The composite film according to claim 1, wherein the outer protective layer and/or the inner protective layer is formed as a spunbonded layer.

10. The composite film according to claim 1, wherein the grammage of the outer protective layer and/or of the inner protective layer is less than or equal to 250 g/m.sup.2, preferably between 1 g/m.sup.2 and 250 g/m.sup.2, more preferably between 10 g/m.sup.2 and 150 g/m.sup.2, preferably between 20 g/m.sup.2 and 120 g/m.sup.2, and in particular between 30 g/m.sup.2 and 100 g/m.sup.2.

11. The composite film according to claim 1, wherein the outer protective layer and/or inner protective layer is formed as a mechanically, chemically and/or thermally, preferably thermally, consolidated nonwoven layer.

12. The composite film according to claim 1, wherein the functional layer is firmly bonded, preferably glued, to the outer protective layer and/or the inner protective layer.

13. The composite film according to claim 1, wherein the outer protective layer and/or the inner protective layer, in particular the outer protective layer and/or inner protective layer comprising the at least one bicomponent fiber, and/or the functional layer, in particular on the outside, has an adhesion-promoting layer, preferably comprising a polymer, in particular wherein the adhesion-promoting layer is firmly bonded to the functional layer and/or wherein the adhesion-promoting layer comprises a plastic and/or synthetic resin, preferably polyurethane.

14. The composite film according to claim 1, wherein the composite film is designed to be permeable to water vapor, open to diffusion, windproof, rainproof and/or water-repellent and/or waterproof, in particular wherein the composite film has an Sd value of less than or equal to 0.5 m, preferably from 0.008 m to 0.5 m, more preferably from 0.009 m to 0.2 m, more preferably from 0.01 m to 0.1 m.

15. The composite film according to claim 1, wherein the tear strength of the composite film is greater than 50 N/mm, preferably between 50 N/mm to 600 N/mm, more preferably between 100 N/mm to 400 N/mm, and/or that the tear propagation strength of the composite film is greater than 50 N/mm, preferably between 50 N/mm and 500 N/mm, more preferably between 100 N/mm to 300 N/mm.

16. The composite film according to claim 1, wherein at least one reinforcing layer is arranged between the functional layer and the outer protective layer and/or the inner protective layer, the reinforcing layer in the form of a leno fabric, in particular the reinforcing layer comprising and/or consisting of a plastic and/or synthetic resin, preferably a plastic polymer, in particular polypropylene (PP) and/or polyethylene terephthalate (PET).

17. The composite film according to claim 1, wherein at least one longitudinal-edge-side adhesive zone is provided on the topside and/or the underside of the composite film, in particular the longitudinal-edge-side adhesive zone being spaced apart from the longitudinal edge of the composite film, and/or the adhesive zone being in the form of strips, if appropriate as interrupted strips, and/or the adhesive zone having a width of between 2 and 10 cm.

18. The composite film according to claim 1, wherein the difference in the melting points of the first component and the second component is less than or equal to 8° C., in particular wherein the difference in the melting points of the first component and the second component is at most 6° C. or between 1° C. to 8° C., preferably between 1° C. to 6° C.

19. The composite film according to claim 1, wherein the difference between the melt flow indices of the first component and the second component is less than or equal to 25 g/10 min, preferably less than or equal to 20 g/10 min, particularly preferably 15 g/10 min.

20. The composite film according to claim 1, wherein the melt flow indices of the first component and the second component are each less than or equal to 50 g/10 min, preferably each less than or equal to 40 g/10 min.

21. The composite film according to claim 1, wherein the component with the lower melting point in the cross-section of the bicomponent fiber forms the outer surface of the bicomponent fiber, preferably surrounding, preferably completely, the component with the higher melting point.

22. The composite film according to claim 1, wherein the polymer of one of the two components has been polymerized with a metallocene catalyst.

23. The composite film according to claim 1, wherein the polymer of the other components has been polymerized with a Ziegler-Natta catalyst and subjected to a subsequent visbreaking treatment.

24. The composite film according to claim 1, wherein the first component comprises an additive, the mass fraction of the additive in the second component being smaller than in the first component, preferably at most 66.6%, further preferably at most 50%, in particular at most 33.3%, of the mass fraction of the additive in the first component.

25. The composite film according to claim 1, wherein the additive is a primary or secondary antioxidant, a UV absorber, a UV stabilizer, a flame retardant, an antistatic agent, a lubricant, a metal deactivator, a hydrophilizing agent, a hydrophobizing agent, an anti-fogging additive and/or a biocide.

26. The composite film according to claim 1, wherein the additive is selected from the group of: sterically hindered phenols, aromatic secondary or tertiary amines, aminophenols, aromatic nitro or nitroso compounds, organic phosphites or phosphonates, thioethers, thioalcohols, thioesters, sulfides and sulfur-containing organic acids, dithiocarbamates, thiodipropionates, aminopyrazoles, metal-containing chelates, mercaptobenzimidazoles, hydroxybenzophenones, cinnamates, oxalanilides, salicylates, resorcinol monobenzoates, benzotriazoles, triazines, benzophenones, titanium dioxide, carbon black, metal-containing complexes of organic sulfur or phosphorus compounds, sterically hindered amines (HALS), metal hydroxides, borates, organic bromine- or chlorine-containing compounds, organic phosphorus compounds, antimony trioxide, melamine, melamine cyanurate, exfoliated graphite or other intumescent systems, quaternary ammonium salts, alkyl sulfonates, alkyl sulfates, alkyl phosphates, dithiocarbamates, (alkaline earth) metal carboxylates, polyethylene glycols and their esters and ethers, ethoxylates, mono- and diglycerides, fatty alcohols, esters of fatty alcohols, fatty acids, fatty acid esters, dicarboxylic acid esters, fatty acid amides, metal salts of fatty acids, polyolefin waxes, natural or artificial kerosenes and their derivatives, fluoropolymers and fluoroligomers, antiblocking agents such as silicas, silicones, silicates, calcium carbonate, amides of mono- and dicarboxylic acids and their derivatives, cyclic amides, hydrazones and bishydrazones, hydrazides, hydrazines, melamine and its derivatives, benzotriazoles, aminotriazoles, sterically hindered phenols in combination with complexing metal compounds, benzylphosphonates, pyridithiols, thiobisphenol esters, polyglycols, ethoxylates, fluoropolymers and fluoroligomers montan waxes, in particular stearates, 10,10′-oxybisphenoxarsine (OBPA), N-(trihalogen-methylthiol)phthalimide, tributyltin oxide, zinc dimethyldithiocarbamate, diphenylantimony-2-ethylhexanoate, copper-8-hydroxyquinoline, isothiazolones, silver and silver salts as biocides or mixtures thereof.

27. The composite film according to claim 1 the first polymer and/or the second polymer is a polyolefin or a polyolefin copolymer, preferably a polymer and/or copolymer of ethylene, propylene, butylene, hexene or octene and/or a blend and/or a blend thereof, and/or a polyethylene terephthalate and/or a polyethylene terephthalate copolymer.

28. The composite film according to claim 1, wherein the mass fraction of the component with the lower melting point in the bicomponent fiber at most 50%, preferably at most 25%, further preferably at most 10%, in particular at most 5%.

29. (canceled)

Description

[0125] Further features, advantages and possible applications of the present invention will be apparent from the following description of examples of embodiments based on the drawing and the drawing itself. In this context, all the features described and/or illustrated constitute, individually or in any combination, the subject-matter of the present invention, irrespective of their summary in the claims and their relation back.

[0126] It shows:

[0127] FIG. 1 a schematic cross-sectional view of the composite film according to the invention,

[0128] FIG. 2 schematic cross-sectional view of a further embodiment of the composite film according to the invention,

[0129] FIG. 3 schematic cross-sectional view of a further embodiment of the composite film according to the invention,

[0130] FIG. 4 schematic cross-sectional view of a further embodiment of the composite film according to the invention,

[0131] FIG. 5 schematic cross-sectional view of a further embodiment of the composite film according to the invention,

[0132] FIG. 6 schematic cross-sectional view of a further embodiment of the composite film according to the invention,

[0133] FIG. 7 a schematic cross-sectional view of a further embodiment of the composite film according to the invention,

[0134] FIG. 8 schematic and perspective cross-sectional view of a further embodiment of the composite film according to the invention,

[0135] FIG. 9 schematic cross-sectional view of a further embodiment of the composite film according to the invention,

[0136] FIG. 10 schematic cross-sectional view of a further embodiment of the composite film according to the invention,

[0137] FIG. 11 cross-sectional view of an embodiment of a bicomponent fiber according to the invention as a core-sheath fiber,

[0138] FIG. 12 cross-sectional view of an embodiment of a bicomponent fiber according to the invention as a core-sheath fiber with a thin sheath,

[0139] FIG. 13 cross-sectional view of a further embodiment of a bicomponent fiber according to the invention as a core-sheath fiber with an eccentrically arranged core, and

[0140] FIG. 14 part of an exemplary spunbonded web according to the invention.

[0141] FIG. 1 shows a composite film 1 with an outer protective layer 3 and an inner protective layer 4. A functional layer 2 is arranged between the outer protective layer 3 and the inner protective layer 4. The composite film 1 shown is intended for use in the construction industry and for use as a construction film, in particular for covering buildings and/or for use as a roofing membrane.

[0142] The functional layer 2 shown in FIG. 1 is designed as at least a single-layer membrane layer. The outer protective layer 3 and the inner protective layer 4 are formed as nonwoven layers comprising polyolefin. In the embodiment example shown in FIG. 1, the outer protective layer 3 has at least one bicomponent fiber 5 (not shown, see FIG. 14)—in the embodiment example shown, a plurality of bicomponent fibers 5. The bicomponent fiber 5 has a first component 6 and a second component 7, the first component 6 having a first polymer and the second component 7 having a second polymer as a constituent. The first polymer and the second polymer may be different from each other in the illustrated embodiment.

[0143] In particular, the outer protective layer 3 and/or the inner protective layer 4 can be firmly bonded and/or fully bonded to the functional layer 2.

[0144] In another embodiment not shown, it is provided that the first polymer comprises polypropylene, in particular polymerized by a Ziegler-Natta catalyst, and the second polymer comprises polypropylene, in particular produced by metallocene catalysts, or vice versa.

[0145] In the embodiment example shown in FIG. 2, it is provided that the inner protective layer 4 comprises the at least one bicomponent fiber 5. In further embodiments, both the outer protective layer 3 and the inner protective layer 4 can be formed as a nonwoven layer comprising bicomponent fibers 5.

[0146] Insofar as the composite film 1 is used for weather protection of goods, the topside 12 may face the weather side or the weather, whereas the underside 13 may face the interior of a building, for example. The topside 12 is arranged on the outer side of the outer protective layer 3. The underside 13 is provided on the opposite outer side of the composite film 1. In principle, it is also possible not to expose the composite film 1 to the weather, in which case the underside 13 may face the goods, material or the like to be covered.

[0147] The functional layer 2 shown in FIG. 1 is designed as a monolithic membrane layer. A monolithic membrane layer is a selectively permeable membrane layer that is pore-free or closed-cell.

[0148] The functional layer 2 has plastic and/or synthetic resin as the material. In particular, an elastomeric material and/or a thermoplastic material is provided. In the embodiment example shown in FIG. 1, the functional layer 2 has a polyurethane plastic. In the embodiment example shown, the polyurethane plastic of the functional layer 2 is a thermoplastic polyurethane (TPU). In further embodiments, the functional layer 2 may not only comprise the thermoplastic polyurethane, but may also comprise it.

[0149] In addition, the functional layer 2 shown in FIG. 1 has a basis weight or grammage of less than 100 g/m.sup.2. In particular, the basis weight of the functional layer 2 is between 5 g/m.sup.2 and 25 g/m.sup.2.

[0150] FIG. 2 shows that the functional layer 2 has at least two layers of membrane layers—that is, two membrane layers 8. In the embodiment example shown, the membrane layers 8 are formed differently from one another and have, in particular, a different material composition and/or a different grammage.

[0151] In particular, the membrane layers 8 are firmly bonded to each other, proferably via a full-surface adhesive bond.

[0152] FIG. 3 shows that the functional layer 2 has a three-layer structure consisting of three membrane layers 8. In the embodiment example shown, the outer membrane layers 9 are of identical design and include a central membrane layer 8 having a different material composition and/or surround a central membrane layer 8. The identical design of the outer membrane layers 9 is to be understood as meaning that they have at least substantially the same material composition, the same material and/or the same material properties. In particular, the outer membrane layers 9 have the same functional design. In a further, not shown embodiment example, it can be provided that the membrane layers 8 differ from each other, so that also the outer membrane layers 9 are formed differently from each other.

[0153] In an embodiment not shown, the outer membrane layers 9 are identical, with the topside 12 and the underside 13 being functionally identical, in particular with the outer protective layer 3 being identical and/or functionally identical to the inner protective layer 4.

[0154] In another embodiment not shown, the composite film 1 has a symmetrical structure.

[0155] The outer membrane layer 9 is to be understood as the membrane layer 8 directly facing the outer protective layer 3 or the inner protective layer 4.

[0156] The functional layer 2 shown in FIG. 3 is designed in such a way that at least one membrane layer 8 comprises thermoplastic copolyester (TPEE) and/or thermoplastic polyurethane (TPU) as material and/or consists thereof. In particular, the outer membrane layer 9 has thermoplastic copolyester and/or thermoplastic polyurethane. In a further, not shown embodiment example, the functional layer 2 is formed of TPEE layers and/or TPU layers, wherein the layers can be firmly bonded to each other.

[0157] It is not shown that at least one outer membrane layer 9 and/or the inner membrane layer 8 of the multilayer functional layer 2 comprises and/or is formed from a foamed polymer. The outer membrane layer 9 comprising the foamed polymer can be bonded to the protective layer facing it—that is, either the outer protective layer 3 or the inner protective layer 4—by means of bonding. In particular, the outer-side membrane layer 9 comprising the foamed polymer penetrates the surface region or the outermost surface layer of the outer protective layer 3 and/or the inner protective layer 4. The interlocking may be achieved due to the manufacturing process of the composite film 1, in particular due to the slowed cooling caused due to the foaming of the outer-side membrane layer 9. Furthermore, the outer membrane layer 9 is also firmly bonded to the immediately adjacent membrane layer 8, wherein this bonding can also be caused by interlocking.

[0158] Furthermore, FIG. 3 shows that the outer protective layer 3 is formed as a nonwoven layer comprising polypropylene. In particular, the outer protective layer 3 is formed as a polypropylene needle-punched nonwoven layer—that is, a nonwoven layer consolidated by needle-punching. In further embodiments not shown, the inner protective layer 4 can additionally or alternatively be formed as a nonwoven layer comprising and/or consisting of polypropylene, in particular a polypropylene needle punched nonwoven layer.

[0159] FIG. 4 shows that the outer protective layer 3 and the inner protective layer 4 are formed as a spunbonded layer. In further embodiments, which are not shown, either the outer protective layer 3 or the inner protective layer 4 can be formed as a spunbonded layer. FIG. 14 shows the outer protective layer 3 in the form of a spunbonded layer, which is also composed of bicomponent fibers 5 each having a first component 6 and a second component 7.

[0160] In the embodiments shown in FIGS. 1 to 5, the outer protective layer 3 and the inner protective layer 4 have a grammage of less than 250 g/m.sup.2. In particular, the grammage of the outer protective layer 3 and/or the inner protective layer 4 is between 30 g/m.sup.2 and 100 g/m.sup.2.

[0161] In principle, various consolidation methods, such as mechanical, chemical and/or thermal consolidation, can be provided for consolidating the outer protective layer 3 and the inner protective layer 4. FIG. 5 shows a thermally consolidated outer protective layer 3.

[0162] FIG. 4 shows that the functional layer 2 is firmly connected to the outer protective layer 3 and the inner protective layer 4. The fixed connection of the functional layer 2 to the protective layers 3, 4 is provided over the entire surface via the connecting surfaces. In further embodiments, a partial-surface connection of the functional layer 2 to the outer protective layer 3 and/or the inner protective layer 4 may also be provided. In addition, FIG. 4 shows that the functional layer 2 is bonded to both the outer protective layer 3 and the inner protective layer 4. The bonding and/or adhesive layer and/or adhesion-promoting layer 10 or bonding layer is designed in particular in such a way that the composite film is and/or remains open to diffusion, in particular wherein a very thin adhesive layer application and/or a screen application of the adhesive is carried out.

[0163] For bonding the functional layer 2 to the protective layers 3, 4, an adhesion-promoting layer 10 is provided, which comprises an adhesion promoter polymer. FIGS. 4 to 6 show the different arrangement of the adhesion-promoting layer 10. For example, the adhesion-promoting layer 10—as shown in FIG. 5—can be formed as part of the functional layer 2 and/or the adhesion promoter polymer penetrates at least in some areas into the surfaces of the functional layer 2 facing the protective layers 3, 4.

[0164] FIG. 4 shows that the adhesion-promoting layer 10 is formed as a separate layer provided between the functional layer 2 and the protective layers 3, 4. This adhesion-promoting layer 10 can be applied to the protective layers 3, 4 and/or to the functional layer 2 during the manufacturing process of the composite film 1.

[0165] FIG. 6 again shows that the adhesion-promoting layer 10 is formed as part of the protective layers 3, 4. Thus, FIG. 6 shows that the adhesion promoter polymer has penetrated into the surface areas of the protective layers 3, 4 facing the functional layer 2.

[0166] In particular, the adhesion-promoting layer 10 is provided as a component of the protective layer or protective layers 3, 4 comprising the bicomponent fibers 5. The adhesion-promoting layer 10 is firmly bonded to the functional layer 2 or the protective layers 3, 4, in particular over the entire surface. The adhesion promoter polymer or the material of the adhesion-promoting layer 10 may be a plastic and/or a synthetic resin, preferably polyurethane.

[0167] The composite film 1 shown in FIG. 6 is designed to be permeable to water vapor, open to diffusion and rainproof. In further embodiments, the composite film 1 may be water vapor permeable, diffusion open, windproof, rainproof, water repellent and/or waterproof. The composite film 1 shown in FIG. 6 has an Sd value of less than or equal to 0.5 m. In further embodiments, the Sd value of the composite film 1 may be between 0.01 m to 0.1 m. The Sd value of the composite film 1 is such that the diffusion-open properties of the composite film 1 and/or the functional layer 2 can be adequately ensured.

[0168] Furthermore, in the embodiment shown in FIG. 6, the composite film 1 has a tear strength of greater than 50 N/mm. In further embodiments, the tear strength of the composite film 1 may be between 100 N/mm to 300 N/mm. In the embodiment example shown in FIG. 6, the tear propagation strength of the composite film 1 is greater than 50 N/mm. In further embodiments not shown, the tear propagation strength of the composite film 1 is between 100 N/mm to 300 N/mm.

[0169] FIG. 7 shows that a reinforcing layer 11 is introduced in the layer structure of the composite film 1. In the illustrated embodiment example, the reinforcing layer 11 is arranged between the outer protective layer 3 and the functional layer 2. In further embodiments not shown, the reinforcing layer 11 may be arranged between the inner protective layer 4 and the functional layer 2. The reinforcing layer 11 is formed as a leno fabric. Furthermore, the reinforcing layer 11 may comprise and/or consist of plastic and/or synthetic resin as the material. In particular, the reinforcing layer 11 has and/or consists of a plastic polymer, such as polypropylene (PP) and/or polyethylene terephthalate (PET).

[0170] FIGS. 8 to 10 show that the composite film 1 has at least one longitudinal edge-side adhesive zone 14. The longitudinal edge-side adhesive zone 14 is provided on the topside 12 and/or on the underside 13 of the composite film 1. FIG. 8 shows that the longitudinal edge-side adhesive zone 14 is spaced from the longitudinal edge 15 of the composite film 1.

[0171] It is not shown that the adhesive zone 14 is strip-shaped. Furthermore, it is not shown that the adhesive zone 14 can also be formed as interrupted strips.

[0172] The width of the adhesive zone 14 in the illustrated embodiment is between 2 to 10 cm.

[0173] FIG. 8 shows that in each case one adhesive zone 14 is provided on the topside 12 and on the underside 13. FIG. 9 shows that in each case two longitudinal edge-side adhesive zones 14 are provided both on the underside 13 and on the topside 12 of the composite film 1. FIG. 10 shows that two longitudinal edge-side adhesive zones 14 are provided on the underside 13.

[0174] In FIG. 8, the adhesive zone 14 is arranged in a longitudinal edge region, which comprises the longitudinal edge 15, of the topside 12 and the underside 13 of the composite film 1. In the embodiment example shown in FIG. 8, the longitudinal edge region extends from the longitudinal edge 15 of the composite film 1 over or greater than 1% of the width of the composite film 1, in the embodiment example shown over about 15%+/−10% of the width of the composite film 1. FIGS. 8 to 10 only schematically show the arrangement of the adhesive zones 14 and do not serve to draw conclusions for the dimensions for the lengths or widths of the adhesive zone 14.

[0175] The adhesive zones 14 shown in the illustrated embodiments are formed such that when adjacent composite films 1 are bonded together, wind-tight and/or airtight bonding occurs.

[0176] The offset of the adhesive zones 14 shown in FIG. 8 is selected in such a way that, when adjacent composite films 1 are bonded, an adhesive-in-adhesive bond is produced between the adhesive zones 14 of adjacent rows of the composite film 1. In the case of the laid composite film 1, it is provided that the adhesive zones 14 are arranged one above the other, at least in certain regions, so that an adhesive-in-adhesive bond is produced between the adhesives of the adhesive zones 14. Ultimately, it may be provided that different adhesives and/or adhesive properties, such as grammage and/or width of the adhesive application, are provided for different adhesive zones 14, it being preferred that the adhesive zones 14 are identical with respect to the adhesive used and all adhesive properties.

[0177] It is not shown that the mating surface for the adhesive zone 14 comprising the adhesive is covered with a liner and/or surface-treated. In particular, it is not shown that the adhesive zone 14 may be covered by a lacquer. The liner may serve to protect the adhesive zone 14, in particular from impurities and/or from contamination.

[0178] FIGS. 11 to 13 show cross-sectional views of exemplary bicomponent fibers 5 according to the invention. The bicomponent fibers 5 shown each have a first component 6 and a second component 7. In the case of the core-sheath fibers shown in FIGS. 11 to 13, the first component 6 surrounds the second component 7 and thus forms the outer surface of the bicomponent fiber 5. In cross section, the bicomponent fibers 5 shown have an at least approximately circular and/or round geometry. In further embodiments not shown, the bicomponent fiber 5 may also have non-circular cross-sections, for example a trilobal cross-section or other multilobal cross-sections. In the case of a very thin sheath of the bicomponent fiber 5 surrounding the second component 7, the sheath may well have defects. That is, the sheath does not completely surround the core, but is broken in some places, so that the core also forms the outer surface of the fiber in these places. Such fibers are also “core-sheath fibers”. In particular, in such fibers, the component forming the openwork sheath forms the outer surface of the fiber within the meaning of the present invention.

[0179] Not shown is that the bicomponent fiber 5 may also be formed as a side-by-side fiber. Side-by-side fibers may be characterized in that both the first component 6 and the second component 7 form part of the outer surface of the bicomponent fiber 5. Circular or at least approximately circular cross-sections are also possible for side-by-side fibers, as are multilobal cross-sections. Depending on which fiber properties and/or nonwoven properties are to be achieved, the first component 6 and the second component 7 can be combined in different ratios in different spatial arrangements relative to one another.

[0180] Also not shown is that the bicomponent fiber 5 may also be formed as a segmented-pie fiber. This fiber structure has a relationship to side-by-side fiber structures in that both the first component 6 and the second component 7 can form part of the outer surface of the bicomponent fiber 5.

[0181] Also, a design of the bicomponent fiber 5 as an Island-In-The-Sea structure as a modification of a core-cladding fiber is not provided in the embodiments shown. In an Island-In-The-Sea structure of the bicomponent fiber 5, a plurality of cores from the second component 7 may be present The individual cores from the second component 7 are surrounded by a common sheath from the first component 6.

[0182] Furthermore, mixed forms between core-sheath fibers and side-by-side fibers are possible in principle.

[0183] FIG. 14 shows how a plurality of exemplary bicomponent fibers 5 form a spunbonded fabric. In the embodiment shown, the spunbonded fabric is formed as an outer protective layer 3. The inner protective layer 4 can also be formed as a spunbonded fabric shown in FIG. 14. In this case, the spunbonded fabric forms a web with a transverse direction X, a thickness direction Y and a length direction Z, which is also referred to as the machine direction.

[0184] An exemplary spunbonded fabric may be made from bicomponent fibers 5 that have been thermally bonded by means of a calendar. In the illustrated embodiment example, the bicomponent fibers 5 are core-sheath fibers having a sheath of the first component 6 with polypropylene as the first polymer with a core of the second component 7 with a polypropylene as the second polymer. The grammage of the spunbonded web shown in FIG. 14 may be 70 g/m.sup.2+/−20 g/m.sup.2.

[0185] Not shown is that the difference in the melting point of the first component 6 and the second component 7 is less than or equal to 8° C. In particular, the difference in the melting points of the first component 6 and the second component 7 can range from 1° C. to 6° C.

[0186] Furthermore, it is not shown that the melt flow indices of the first component 6 and the second component 7 are less than or equal to 25 g/10 min. In addition, the melt flow indices of the first component 6 and the second component 7 can each be less than or equal to 50 g/10 min.

[0187] In particular, the component with the low melting point in the cross-section of the bicomponent fiber 5 may form the outer surface of the bicomponent fiber 5, in particular surrounding preferably completely, the component with the higher melting point.

[0188] The polymer of one of the two components 6, 7 may have been polymerized with a metallocene catalyst. The polymer of the other component may have been polymerized with a Ziegler-Natta catalyst and subsequently subjected to a visbreaking treatment.

[0189] Furthermore, it is not shown that the first component 6 comprises an additive, wherein the mass fraction of the additive in the second component 7 is smaller than in the first component 6, preferably at most 66.6%.

[0190] The additive may be a primary or secondary antioxidant, a UV absorber, a UV stabilizer, a flame retardant, an antistatic agent, a lubricant, a metal deactivator, a hydrophilizing agent, a hydrophobizing agent, an anti-fogging additive, and/or a biocide.

[0191] Where appropriate, the additive may be selected from the group consisting of: [0192] Sterically hindered phenols, aromatic secondary or tertiary amines, aminophenols, aromatic nitro or nitroso compounds, organic phosphites or phosphonates, thioethers, thioalcohols, thioesters, sulfides and sulfur-containing organic acids, dithiocarbamates, thiodipropionates, aminopyrazoles, metal-containing chelates, mercaptobenzimidazoles, hydroxybenzophenones, cinnamates, oxalanilides, salicylates, resorcinol monobenzoates, benzotriazoles, triazines, benzophenones, titanium dioxide, carbon black, metal-containing complexes of organic sulfur or phosphorus compounds, sterically hindered amines (HALS), metal hydroxides, borates, organic bromine- or chlorine-containing compounds, organic phosphorus compounds, antimony trioxide, melamine, melamine cyanurate, expandable graphite or other intumescent systems, quaternary ammonium salts, alkyl sulfonates, alkyl sulfates, alkyl phosphates, dithiocarbamates, (alkaline earth) metal carboxylates, polyethylene glycols and their esters and ethers, ethoxylates, mono- and diglycerides, fatty alcohols, esters of fatty alcohols, fatty acids, fatty acid esters, dicarboxylic acid esters, fatty acid amides, metal salts of fatty acids, polyolefin waxes, natural or artificial kerosenes and derivatives thereof, fluoropolymers and fluoroligomers, antiblocking agents such as silicas, silicones, silicates, calcium carbonate, amides of mono- and dicarboxylic acids and their derivatives, cyclic amides, hydrazones and bishydrazones, hydrazides, hydrazines, melamine and its derivatives, benzotriazoles, aminotriazoles, sterically hindered phenols in combination with complexing metal compounds, benzylphosphonates, pyridithiols, thiobisphenol esters, polyglycols, ethoxylates, fluoropolymers and fluoroligomers montan waxes, in particular stearates, 10,10′-oxybisphenoxarsine (OBPA), N-(trihalogen-methyl-thiol)phthalimide, tributyltin oxide, zinc dimethyldithiocarbamate, diphenylantimony-2-ethylhexanoate, copper-8-hydroxyquinoline, isothiazolones, silver and silver salts as biocides or mixtures thereof.

[0193] Furthermore, it is not shown that the first polymer and/or the second polymer is a polyolefin or a polyolefin copolymer, preferably a polymer and/or copolymer of ethylene, propylene, butylene, hexene or octene and/or a mixture and/or a blend thereof, and/or a polyethylene terephthalate and/or a polyethylene terephthalate copolymer.

[0194] The mass fraction of the component with the low melting point in the bicomponent fiber 5 can be at most 50%.

LIST OF REFERENCE SIGNS

[0195] 1 Composite film [0196] 2 Functional layer [0197] 3 outer protective layer [0198] 4 inner protective layer [0199] 5 Bicomponent fiber [0200] 6 first component [0201] 7 second component [0202] 8 Membrane layer [0203] 9 external membrane layer [0204] 10 Adhesion-promoting layer [0205] 11 Reinforcement layer [0206] 12 Topside [0207] 13 Underside [0208] 14 Adhesive zone [0209] 15 Longitudinal edge