FOAM FABRIC
20210187800 · 2021-06-24
Assignee
Inventors
Cpc classification
C08J9/33
CHEMISTRY; METALLURGY
B29C44/3426
PERFORMING OPERATIONS; TRANSPORTING
C09J163/00
CHEMISTRY; METALLURGY
B29C44/22
PERFORMING OPERATIONS; TRANSPORTING
B29C44/1285
PERFORMING OPERATIONS; TRANSPORTING
B29C44/3442
PERFORMING OPERATIONS; TRANSPORTING
B29C44/56
PERFORMING OPERATIONS; TRANSPORTING
C08J9/35
CHEMISTRY; METALLURGY
C08J2363/00
CHEMISTRY; METALLURGY
B29K2105/0097
PERFORMING OPERATIONS; TRANSPORTING
International classification
B29C44/22
PERFORMING OPERATIONS; TRANSPORTING
B29C44/12
PERFORMING OPERATIONS; TRANSPORTING
B29C44/56
PERFORMING OPERATIONS; TRANSPORTING
C09J163/00
CHEMISTRY; METALLURGY
Abstract
The present invention is related to a foam fabric and method of making it.
Claims
1. A foam fabric comprised of: foam particles; a foaming agent comprising azodicarbonamide, thiazinyl triazine, ethanolamine, aluminum potassium sulfate; an antibacterial agent comprised of 2,4,4-trichloro-2′-hydroxydiphenyl ether and ethylene oxide; a filler selected from the group consisting of titanium dioxide, iron oxide, mica powder and combinations thereof a glue comprising a rosin resin and an epoxy composite resin, wherein the epoxy composite resin is comprised of an epoxy resin, a terpene resin, aluminum oxide, polybutene and an emulsifier and a solvent.
2. The foam fabric of claim 1, wherein the terpene resin is GT-3-A liquid terpene resin, the epoxy resin is CYD-118 bisphenol, the rosin resin is KL1000W liquid rosin resin, the emulsifier is OP-10 and the solvent is comprised of cyclohexane, diethyl ether and acetone.
3. The foam fabric of claim 1, wherein the foam fabric is comprised of from about 8 to about 13% glue, from about 62 to about 80% foam, from about 4 to about 8% color agent, from about 3 to about 8% antibacterial agent, from about 8 to about 12% foaming surfactant agent and from about 10 to about 20% of a filler.
4. The foam fabric of claim 1, wherein the foam particles are foam scraps and fragments remaining from the manufacture of other products.
5. A method of making a foam fabric comprising the steps of: 1) forming foam into particles of different sizes; 2) evenly dispersing the different sized foam particles and then adding to them a foaming surfactant agent, an antibacterial agent, a filler, and optionally a color agent; 3) stirring the ingredients from step 2 to obtain a mixture; 4) adding a glue comprised of a rosin resin and an epoxy composite resin into the mixture of step 3 and then stirring the mixture and the glue together, wherein the epoxy composite resin is comprised of an epoxy resin, a terpene resin, aluminum oxide, polybutene, an emulsifier and a solvent; 5) adding the mixture of step 4 to molding equipment and then apply pressure and steam to the mixture to form molded foam; 6) steam foaming the molded foam treatment. 7) removing the molded foam mixture from the molding equipment 8) cutting the molded foam into sections having a desired length and thickness to form a foam fabric.
6. The method of making a foam fabric of claim 5, wherein the terpene resin is GT-3-A liquid terpene resin, the epoxy resin is CYD-118 bisphenol, the rosin resin is KL1000W liquid rosin resin, the emulsifier is OP-10 and the solvent is comprised of cyclohexane, diethyl ether and acetone.
7. The method of making a foam fabric of claim 5, wherein the foam fabric is comprised of from about 8 to about 13% glue, from about 62 to about 80% foam, from about 4 to about 8% color agent, from about 3 to about 8% antibacterial agent, from about 8 to about 12% foaming surfactant agent and from about 10 to about 20% of a filler 8. The method of making a foam fabric of claim 5, wherein the foam particles are foam scraps and fragments remaining from the manufacture of other products.
9. The method of making a foam fabric of claim 5, wherein the mixing weight ratio of particle waste, foam surfactant agent, antibacterial agent, colorant and filler is 70-80:10-12:3-6:5-8:18-20 and the mixing weight ratio of the mixture of step 3 and the glue is 8-12:1.
10. The method of making a foam fabric of claim 5, wherein the particles of foam are a mixture of small particles, medium particles and large particles with a weight ratio of 5-8:3-6:2.
11. The method of making a foam fabric of claim 10, wherein the average size of the small particles are from about 1 to about 3 mm, the average size of the medium particles is from about 4 to about 6 mm, and the average size of the large particles is from about 10 to about 12 mm.
12. The method of making a foam fabric of claim 5, wherein the foaming agent comprises 3-6 parts of azodicarbonamide, 1-2 parts of trihydrazine triazine, 2-3 parts of ethanolamine and 1-2 parts of aluminum potassium sulfate, the antibacterial agent is a mixture of 2,4,4-trichloro-2′-hydroxydiphenyl ether and ethylene oxide with a weight ratio of 2-4:1, and the filler is comprised of titanium dioxide, iron oxide, mica powder and combinations thereof.
13. The method of making a foam fabric of claim 5, wherein the mixture is steam foamed at a temperature of from about 200 to about 260° C. for about 20 to about 30 minutes and the mixture is molded at a pressure of about 180 to about 220 tons.
14. The method of making a foam fabric of claim 6, wherein the epoxy composite resin adhesive is prepared by the following steps: 1) adding epoxy resin, terpene resin and aluminum oxide into two-thirds of the total amount of solvent, heating to temperature of from about 35 to about 45° C., and then stirring for about 25 to about 28 minutes to prepare material A; 2) adding the emulsifier OP-10 into the remaining one-third of the total amount of solvent, heating to a temperature of from about 45 to about 48° C., and then mixing the ingredients to prepare material B; 3) adding material B into material A and then heating the combination at a temperature of from about 52 to about 56° C., for approximately 30-40 minutes, 4) adding polybutene and stirring the mixture for approximately 18 to 20 minutes at from about 52 to about 56° C.; 5) heating the mixture at a temperature of about 60° C. for approximately 30 to 35 minutes to prepare epoxy composite resin adhesive.
15. The method of making a foam fabric of claim 5, wherein the density of the foam fabric is from about 300 to about 450 g/m2.
16. The foam fabric of claim 1, wherein the density of the foam fabric is from about 300 to about 450 g/m2.
17. Claim 1. A foam fabric comprised of: foam particles; a glue comprising a rosin resin and an epoxy composite resin, wherein the epoxy composite resin is comprised of an epoxy resin, a terpene resin, aluminum oxide, polybutene and an emulsifier and a solvent.
18. A method of making a foam fabric comprising the steps of: 1) forming foam into particles of different sizes and evenly dispersing the different sized foam particles; 2) adding a glue comprised of a rosin resin and an epoxy composite resin into the mixture of step 3 and then stirring the foam pieces and the glue together, wherein the epoxy composite resin is comprised of an epoxy resin, a terpene resin, aluminum oxide, polybutene, an emulsifier and a solvent; 3) adding the mixture of step 4 to molding equipment and then apply pressure and steam to the mixture to form molded foam; 4) steam foaming the molded foam treatment. 5) removing the molded foam mixture from the molding equipment 6) cutting the molded foam into sections having a desired length and thickness to form a foam fabric.
19. The method of making a foam fabric of claim 5, wherein the glue is sprayed into the mixture.
20. The method of claim 18, comprising adding an ingredient selected from the group consisting of a foaming surfactant agent, an antibacterial agent, a filler, a color agent and combinations thereof to the foam particles and mixing before addition of the glue in step 2.
Description
DETAILED DESCRIPTION OF THE INVENTION
[0039] In preferred embodiments of the present invention, the epoxy composite resin adhesive comprises the following ingredients and percentages:
TABLE-US-00001 Epoxy resin 25-28% Terpene resin 18-20% Aluminum oxide 1.5-3.5% Polybutene 10-12% Emulsifier OP-10 3-8% Solvent 30-35%
[0040] In a preferred embodiment of the present invention, the epoxy resin is CYD-118 bisphenol a liquid epoxy resin; the terpene resin is GT-30A liquid terpene resin; and the solvent is a mixture of cyclohexane, diethyl ether and acetone with a weight ratio of 1:3:2-2.5.
[0041] The preferred epoxy composite resin adhesive results in a foam fabric having better softness, high temperature resistance and improved processing formability. The preferred epoxy composite resin adhesive also does not easily harden, and therefore will not affect the soft texture of the foam fabric which can be caused by the hardening of a traditional glue after high temperature foaming. When terpene resin and epoxy resin are compounded, the resulting composite resin adhesive has good compatibility with the foam, the viscosity of the foaming material system is reduced, the adhesion and adhesion is improved, and the resulting foam fabric has a strong resistance to temperature change and chemical stability, and does not age easily or become brittle. The alumina strengthens the composite resin adhesive and improves the dispersion of the composite resin adhesive and other materials in the foaming material. The polybutene has better viscosity, which improves the viscosity of composite resin adhesive, resulting in improved dispersion uniformity of the composite resin adhesive to other materials. The emulsifier OP-10 improves the emulsification degree of the resin components, and gives the composite resin adhesive better tear strength, tensile strength, oxidation resistance, aging resistance, etc. A preferred solvent improves the spray ductility of the composite resin adhesive, makes the glue easy to spray evenly in the mixture, and is easy to volatilize and remove in the process of steam foaming, thus increasing the viscosity of the glue. It also can glue the mixture into a group, forming the new foam structure.
[0042] In preferred embodiments of the present invention, the epoxy composite resin adhesive is prepared by the following steps: step 1) adding an epoxy resin, a terpene resin and aluminum oxide into two-thirds of the total amount of solvent, heating to about 35-45° C., and then stirring for 25-28 minutes to prepare material A; step 2) adding the emulsifier OP-10 into the remaining solvent, and increasing the temperature to 45-48° C., after which the emulsifier OP-10/solvent mix is mixed evenly to prepare material B; step 3): adding material B into material A and then heating to a temperature of from about 52 to about 56° C., while stirring for about 30-40 minutes, then adding polybutene, continue stirring for about 18-20 minutes at about 52 to about 56° C., then increasing the heat to about 60° C. and continuing to heat at that temperature for about 30-35 minutes to prepare epoxy composite resin adhesive for use in the glue.
[0043] In certain embodiments, the epoxy resin and terpene resin are dispersed by most of the solvents, and alumina is added to further improve the dispersion of the resin system, and also to improve the high temperature resistance, aging resistance and strength of the resin system. The combination of the emulsifier OP-10 with the remaining solvent improves the dispersion compatibility of the subsequent emulsifier solution and the resin system of material A. Controlling the temperature and mixing time of material B and material A after mixing, makes the resin system fully emulsified and improves the viscosity and cohesion of the glue. The addition of polybutene adjusts the viscosity of the composite resin glue and keeping the temperature at 60° C., further improves the cohesion of the glue and makes the glue have desired fluidity and ductility and also easy to spray out to adhere to the mixture of Step D.
[0044] The foam used as an ingredient of the present invention is formed using foam prepared from known manufacturing techniques. In certain embodiments, the foam is made from waste scraps and fragments of foam left over from the manufacturing of other products such as cosmetic sponges, couch cushions, pillows, etc.
[0045] The mold into which the mixture is poured in the molding step can be of varying sizes and shapes. In certain embodiments the mold has a length of 2 meters, a width of 1 meter and a thickness of 9 cm. A determination is made of the thickness of the fabric needed and then the molded foam is cut into fabric sections of the desired length and thickness. The foam fabric can used as is or can be stitched or glued together to form products such as cosmetic carriers, bags of a variety of sizes and shapes, brush holders, note book covers, garbage boxes and yoga mats. A fabric or paper lining can be glued, or stitched to the foam fabric to increase strength of the product or to create a lining on the interior of a product. Alternatively, it is possible to laminate a fabric lining to the foam fabric to increase the strength of the foam fabric.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0046] The following examples are not meant to be limiting and represent certain embodiments of the present invention.
Example 1
[0047] The manufacture of the foam fabric includes the following steps: [0048] Step A: Cutting the foam into 70% small particles (approximately 1 mm), 20% medium particles (approximately 4 mm) and 10% large particles (approximately 12 mm) sized particles [0049] Step B: Dispersing the different sized foam particles evenly, and then adding to them a foaming surfactant agent, an antibacterial agent, a filler, and a color agent after which the combination of [0050] Step C: Spraying glue into the mixture from step B and stirring evenly, with the glue comprising 10-15% of the final fabric; Need exact number and really amount of each ingredient that comprises the glue [0051] Step D: Adding the mixture of step C to molding equipment and then molded at a pressure of 180 tons by pressing it in the molding equipment; [0052] Step E: The molded foam is subjected to a steam foaming treatment in the molding equipment at a temperature of 200° C., for 30 minutes, at a pressure of the molding of 180 tons; [0053] Step F: Removing the molded foam mixture from the molding equipment and cutting the molded foam into sections of foam fabric.
TABLE-US-00002 Example 1 Foam Particles 62% Foam Surfactant 10% Antibacterial Agent 3% Color 5% Filler 12% Glue 8% Total 100%
[0054] In Step B, the mixing weight ratio of particle waste, foam surfactant agent, antibacterial agent, colorant and filler is 70-80:10-12:3-6:5-8:18-20. The foam surfactant agent includes 3 parts of Azodicarbonamide, 1 part of triazinyl triazine, 2 parts of ethanolamine and 1 part of aluminum potassium sulfate. The antibacterial agent is a mixture of 2,4,4-trichloro-2′-hydroxydiphenyl ether and ethylene oxide with a weight ratio of about 2:1; the color agent is lemon yellow; and the filler is titanium dioxide. The foaming surfactant agent comprises about 9 to about 11% in the final foam fabric.
[0055] In step C, the mixing weight ratio of the mixture and the glue is from about 8 to about 12 with the percentage of glue in the final foam fabric being about 8% to about 11%.
[0056] The foam is a mixture of small particles, medium particles and large particles with a weight ratio of 5-8:3-6:2, with the total amount of foam (including the filler) comprising from 70 to 80% of the foam fabric and with the foam in step A without inclusion of the filler comprising 63-72% of the foam fabric.
[0057] The glue is a mixture of rosin resin and epoxy composite resin with a weight ratio of 1-2:3-6; the rosin resin is KL1000W liquid rosin resin. In step B, the glue is about 8 to about 12% and the glue comprises about 8 to about 11% of the foam fabric.
[0058] The epoxy composite resin adhesive comprises the following weight parts of raw materials:
TABLE-US-00003 Epoxy resin 25 parts Terpene resin 18 parts Aluminum oxide 1.5 parts Polybutene 10 parts Emulsifier OP-10 3 parts Solvent 30 parts
[0059] The epoxy resin is CYD-118 bisphenol a liquid epoxy resin; the terpene resin is GT-30A liquid terpene resin; the solvent is a mixture of cyclohexane, diethyl ether and acetone with a weight ratio of 1:3:2.
[0060] The epoxy composite resin adhesive is prepared by the following steps: [0061] Step (1): According to the weight, Adding epoxy resin, terpene resin and Aluminum oxide into two-thirds of the total amount of solvent—heating to 35° C., stirring for 28 minutes to prepare material A; [0062] Step (2): According to the weight, Adding the emulsifier OP-10 into the remaining solvent, rising the temperature to 45° C., and then mixing then evenly to preparing material B; [0063] Step (3): Adding prepared material B into prepared material A, Heating up to 52° C., stirring for 40 minutes, then adding polybutene, continue into stir for 20 minutes at 52° C., then heating up to 60° C. and keeping for 30 minutes to prepare epoxy composite resin adhesive for standby.
TABLE-US-00004 TABLE B Example total Chemical components name percentage grams = 100 Foam particles: 62% large medium small Foaming agent: 10% Azodicarbonamide Tiazinyl triazine Ethanolamine Aluminum potassium sulfate Antibacterial agent: 3% 2,4,4-trichloro-2′-hydroxydiphenyl ether Ethylene oxide Color agent - lemon yellow 5% Filler - titanium dioxide 12% Glue: 8% 1. Rosin resin - KL1000W liquid rosin resin 2. Epoxy composite resin: Epoxy resin- CYD-118 bisphenol Terpene resin- GT-30A liquid terpene resin Aluminum oxide Polybutene Emulsifier OP-10 Solvent: Cyclohexane Diethyl ether acetone
[0064] The resultant foam fabric has a density of the foam of 200/m2.
Example 2
[0065] The manufacture of the foam fabric includes the following steps: [0066] Step A: Cutting the foam into 37% to 60% small particles, and preferably 37 to 45% small particles (approximately 0.1-3 mm), 12-30% medium particles, and preferably 12% to 23% medium particles (approximately 4-8 mm) and 6-15% large particles, and preferably 6% to 12% large particles (approximately 10 mm) sized particles. [0067] Step B: Dispersing the different sized foam particles evenly, and then adding to them a foaming surfactant agent, an antibacterial agent, a filler, and a color agent after which the combination of ingredients is stirred to obtain a mixture; [0068] Step C: Spraying a glue into the mixture from step B and stirring evenly with the glue comprising 8-12% of the final fabric; [0069] Step D: Adding the mixture of step C to molding equipment and then molded at a pressure of 180 tons by pressing it in the molding equipment; [0070] Step E: The molded foam is subjected to a steam foaming treatment in the molding equipment at a temperature of 200° C., for 30 minutes, at a pressure of the molding of 180 tons. [0071] Step F: Removing the molded foam mixture from the molding equipment and cutting the molded foam into sections of foam fabric.
TABLE-US-00005 Example 2 Foam Particles 67% Foam Surfactant 8% Atibacterial Agent 0% Color 6% Filler 10% Glue 9% Total 100%
[0072] In step B, the mixing weight ratio of particle waste, foaming agent, antibacterial agent, color agent and filler is 72:10.5:4:7:18.5; in step C, the mixing weight ratio of mixture and glue is 9:1.
[0073] The particle waste is a mixture of small particle waste, medium particle waste and large particle waste with a weight ratio of 6:5:2. The average particle size of the small particle waste is 1.5 mm, the average particle size of the medium particle waste is 4.5 mm, and the average particle size of the large particle waste is 11.5 mm.
[0074] In step B, the foaming surfactant agent comprises 4 parts of Azodicarbonamide, 1.2 parts of triazinyl triazine, 2.2 parts of ethanolamine and 1.2 parts of aluminum potassium sulfate; the antibacterial agent is a mixture of 2,4,4-trichloro-2′-hydroxydiphenyl ether and ethylene oxide in a weight ratio of 2.5:1; the color agent is indigo; the filler is mica powder.
[0075] In step C, the glue is a mixture of rosin resin and epoxy composite resin glue with a weight ratio of 1.2:5; the rosin resin is KL1000W liquid rosin resin.
[0076] In the step C, the temperature of the steam foaming treatment is 220° C., the time is 28 minutes, and the pressure of the molding is 190 tons.
[0077] The epoxy composite resin adhesive comprises the following weight parts of raw materials:
TABLE-US-00006 Epoxy resin 26 parts Terpene resin 18.5 parts Aluminum oxide 2.0 parts Polybutene 10.5 parts Emulsifier OP-10 4 parts Solvent 31 parts
[0078] The epoxy resin is CYD-118 bisphenol a liquid epoxy resin; the terpene resin is GT-30A liquid terpene resin; the solvent is a mixture of cyclohexane, diethyl ether and acetone with a weight ratio of 1:3:2.1.
[0079] The epoxy composite resin adhesive is prepared by the following steps: [0080] Step 1): According to the weight, adding epoxy resin, terpene resin and Aluminum oxide into two-thirds of the total amount of solvent, heating to 38° C., stirring for 27 minutes to prepare material A; [0081] Step 2): According to the weight, Adding the emulsifier OP-10 into the remaining solvent, rising the temperature to 46° C., then mixing them evenly to prepare material B; [0082] Step 3): Adding prepared material B into prepared material A, Heating up to 53° C., stirring for 38 minutes, then adding polybutene, continue into stir for 19.5 minutes at 53° C., then heating up to 60° C. and keeping for 31 minutes to prepare epoxy composite resin adhesive for standby.
[0083] The resultant foam fabric has a density of the foam of 340/m2.
TABLE-US-00007 TABLE C Example total Chemical components name percentage grams= Foam particles: 67% large medium small Foaming agent: 8% Azodicarbonamide Tiazinyl triazine Ethanolamine Aluminum potassium sulfate Antibacterial agent: 0% 2,4,4-trichloro-2′-hydroxydiphenyl ether Ethylene oxide Color agent - indigo 6% Filler - mica powder 10% Glue: 9% 1. Rosin resin - KL1000W liquid rosin resin 2. Epoxy composite resin: Epoxy resin- CYD-118 bisphenol Terpene resin- GT-30A liquid terpene resin Aluminum oxide Polybutene Emulsifier OP-10 Solvent: Cyclohexane Diethyl ether acetone
Example 3
[0084] The manufacture of the foam fabric includes the following steps: [0085] Step A: Cutting the foam into 38-43% small particles (approximately 0.1 mm-3 mm), 12-21% medium particles (approximately 4-8 mm) and 6-10% large particles (approximately 10-12 mm) sized particles; [0086] Step B: Dispersing the different sized foam particles evenly, and then adding to them a foaming surfactant agent, an antibacterial agent, a filler, and a color agent after which the combination of ingredients is stirred to obtain a mixture; [0087] Step C: Spraying a glue into the mixture from step B and stirring evenly; [0088] Step D: Adding the mixture of step C to molding equipment and then molded at a pressure of 180 tons by pressing it in the molding equipment; [0089] Step E: The molded foam is subjected to a steam foaming treatment in the molding equipment at a temperature of 200° C., for 30 minutes, at a pressure of the molding of 180 tons. [0090] Step F: Removing the molded foam mixture from the molding equipment and cutting the molded foam into sections of foam fabric. [0091] ingredients is stirred to obtain a mixture;
TABLE-US-00008 Example 3 Foam Particles 70% Foam Surfactant 0% Atibacterial Agent 0% Color 8% Filler 11% Glue 11% Total 100%
[0092] In step B, the mixing weight ratio of particle waste, foaming agent, antibacterial agent, color agent and filler is 75:11:3-6:6.5:19; in step C, the mixing weight ratio of mixture and glue is 10:1.
[0093] The particle waste is a mixture of small particle waste, medium particle waste and large particle waste with a weight ratio of 6.5:4.5:2. The average particle size of the small particle waste is 2 mm, the average particle size of the medium particle waste is 5 mm, and the average particle size of the large particle waste is 11 mm.
[0094] In step B, each surfactant foaming agent comprises 4.5 parts of Azodicarbonamide, 1.5 parts of triazinyl triazine, 2.5 parts of ethanolamine and 1.5 parts of aluminum potassium sulfate; the antibacterial agent is a mixture of 2,4,4-trichloro-2′-hydroxydiphenyl ether and ethylene oxide in a weight ratio of 3:1; the color agent is bright blue; the filler is titanium dioxide, iron oxide and mica powder in a weight ratio of 2:1:4 mixture of ingredients.
[0095] In step C, the glue is a mixture of rosin resin and epoxy composite resin with a weight ratio of 1.5:4.5; the rosin resin is KL1000W liquid rosin resin.
[0096] In the step C, the temperature of the steam foaming treatment is 230° C., the time is 25 minutes, and the pressure of the molding is 200 tons.
[0097] The epoxy composite resin adhesive comprises the following weight parts of raw materials:
TABLE-US-00009 Epoxy resin 26.5 parts Terpene resin 19 parts Aluminum oxide 2.5 parts Polybutene 11 parts Emulsifier OP-10 5 parts Solvent 33 parts
[0098] The epoxy resin is CYD-118 bisphenol a liquid epoxy resin; the terpene resin is GT-30A liquid terpene resin; the solvent is a mixture of cyclohexane, diethyl ether and acetone with a weight ratio of 1:3:2.3
[0099] The epoxy composite resin adhesive is prepared by the following steps: [0100] Step 1): According to the weight, adding epoxy resin, terpene resin and Aluminum oxide into two-thirds of the total amount of solvent, heating to 40° C., stirring for 26.5 minutes to prepare material A; [0101] Step 2): According to the weight, adding the emulsifier OP-10 into the remaining solvent, rising the temperature to 46.5° C., and then mixing them evenly to prepare material B; [0102] Step 3): Adding prepared material B into prepared material A, Heating up to 54° C., stirring for 35 minutes, then adding polybutene, continue into stir for 19 minutes at 54° C., then heating up to 60° C. and keeping for 32 minutes to prepare epoxy composite resin adhesive for standby.
[0103] The resultant foam fabric has a density of the foam of 380/m2.
TABLE-US-00010 TABLE D Example total Chemical components name Percentage grams= Foam particles: 70% large medium small Foaming agent: 0% Azodicarbonamide Tiazinyl triazine Ethanolamine Aluminum potassium sulfate Antibacterial agent: 0% 2,4,4-trichloro-2′-hydroxydiphenyl ether Ethylene oxide Color agent - bright blue 8% Filler 11% Titanium dioxide Iron oxide Mica powder Glue: 11% 1. Rosin resin - KL1000W liquid rosin resin 2. Epoxy composite resin: Epoxy resin- CYD-118 bisphenol Terpene resin- GT-30A liquid terpene resin Aluminum oxide Polybutene Emulsifier OP-10 Solvent: Cyclohexane Diethyl ether acetone
Example 4
[0104] The manufacture of the foam fabric includes the following steps: [0105] Step A: Cutting the foam into small (approximately 1 mm), medium (approximately 4 mm) and large (approximately 12 mm) sized particles; [0106] Step B: Dispersing the different sized foam particles evenly, and then adding to them a foaming surfactant agent, an antibacterial agent, a filler, and a color agent after which the combination of ingredients is stirred to obtain a mixture; [0107] Step C: Spraying a glue into the mixture from step B and stirring evenly; [0108] Step D: Adding the mixture of step C to molding equipment and then molded at a pressure of 180 tons by pressing it in the molding equipment; [0109] Step E: The molded foam is subjected to a steam foaming treatment in the molding equipment at a temperature of 200° C., for 30 minutes, at a pressure of the molding of 180 tons. [0110] Step F: Removing the molded foam mixture from the molding equipment and cutting the molded foam into sections of foam fabric.
TABLE-US-00011 Example 4 Foam Particles 73% Foam Surfactant 0% Atibacterial Agent 0% Color 9% Filler 6% Glue 12% Total 100%
[0111] In step B, the mixing weight ratio of particle waste, foaming agent, antibacterial agent, color agent and filler is 778:11.5:5:6:19.5; in step C, the mixing weight ratio of mixture and glue is 11:1.
[0112] The particle waste is a mixture of small particle waste, medium particle waste and large particle waste with a weight ratio of 7:4:2. The average particle size of the small particle waste is 1 mm with the range being approximately 0.1 mm to 3 mm, the average particle size of the medium particle waste is 5.5 mm, and the average particle size of the large particle waste is 10.5 mm.
[0113] In step B, the foaming surfactant agent comprises 5 parts of Azodicarbonamide, 1.8 parts of triazinyl triazine, 2.8 parts of ethanolamine and 1.8 parts of aluminum potassium sulfate; the antibacterial agent is a mixture of 2,4,4-trichloro-2′-hydroxydiphenyl ether and ethylene oxide in a weight ratio of 3.5:1; the color agent is Lac Red; the filler is titanium dioxide, iron oxide and mica powder in a weight ratio of 4:1:3 A mixture of ingredients.
[0114] In step C, the glue is a mixture of rosin resin and epoxy composite resin with a weight ratio of 1.8:4; the rosin resin is KL1000W liquid rosin resin.
[0115] In step C, the temperature of steam foaming treatment is 240° C., the time is 22 min, and the pressure of molding is 210 tons.
[0116] The epoxy composite resin adhesive comprises the following weight parts of raw materials:
TABLE-US-00012 Epoxy resin 27 parts Terpene resin 19 parts Aluminum oxide 3 parts Polybutene 11.5 parts Emulsifier OP-10 7 parts Solvent 34 parts
[0117] The epoxy resin is CYD-118 bisphenol a liquid epoxy resin; the terpene resin is GT-30A liquid terpene resin; the solvent is a mixture of cyclohexane, diethyl ether and acetone with a weight ratio of 1:3:2.4.
[0118] The epoxy composite resin adhesive is prepared by the following steps: [0119] Step 1): According to the weight, Adding epoxy resin, terpene resin and Aluminum oxide into two-thirds of the total amount of solvent, heating to 43° C., stirring for 26 minutes to prepare material A; [0120] Step 2): According to the weight, Adding the emulsifier OP-10 into the remaining solvent, rising the temperature to 47° C., and then mixing the ingredients evenly to prepare material B; [0121] Step 3): Adding prepared material B into prepared material A, heating up to 55° C., stirring for 32 minutes, then adding polybutene, continue into stir for 18.5 minutes at 55° C., then heating up to 60° C. and keeping for 33 minutes to prepare epoxy composite resin adhesive for standby.
[0122] The resultant foam fabric has a density of the foam of 420/m2.
TABLE-US-00013 TABLE E Example total Chemical components name percentage grams= Foam particles: 73% large medium small Foaming agent: 0% Azodicarbonamide Tiazinyl triazine Ethanolamine Aluminum potassium sulfate Antibacterial agent: 0% 2,4,4-trichloro-2′-hydroxydiphenyl ether Ethylene oxide Color agent -Lac Red 9% Filler: 6% Titanium dioxide Iron oxide Mica powder Glue: 12% 1. Rosin resin - KL1000W liquid rosin resin 2. Epoxy composite resin: Epoxy resin- CYD-118 Terpene resin- GT-30Aliquid terpene resin Aluminum oxide Polybutene Emulsifier OP-10 Solvent: Cyclohexane Diethyl ether acetone
Example 5
[0123] The manufacture of the foam fabric includes the following steps: [0124] Step A: Cutting the foam into small (approximately 1 mm), medium (approximately 4 mm) and large (approximately 12 mm) sized particles; [0125] Step B: Dispersing the different sized foam particles evenly, and then adding to them a foaming surfactant agent, an antibacterial agent, a filler, and a color agent after which the combination of ingredients is stirred to obtain a mixture; [0126] Step C: Spraying a glue into the mixture from step B and stirring evenly; [0127] Step D: Adding the mixture of step C to molding equipment and then molded at a pressure of 180 tons by pressing it in the molding equipment; [0128] Step E: The molded foam is subjected to a steam foaming treatment in the molding equipment at a temperature of 200° C., for 30 minutes, at a pressure of the molding of 180 tons. [0129] Step F: Removing the molded foam mixture from the molding equipment and cutting the molded foam into sections of foam fabric.
[0130] In step B, the mixing weight ratio of particle waste, foaming agent, antibacterial agent, color agent and filler is 80:12:6:5:20; in step C, the mixing weight ratio of mixture and glue is 12:1.
[0131] The particle waste is a mixture of small particle waste, medium particle waste and large particle waste with a weight ratio of 8:3:2. The average particle size of the small particle waste is 3 mm, the average particle size of the medium particle waste is 6 mm, and the average particle size of the large particle waste is 10 mm.
[0132] In step B, each foaming agent includes 6 parts of Azodicarbonamide, 2 parts of triazinyl triazine, 3 parts of ethanolamine and 2 parts of aluminum potassium sulfate; the antibacterial agent is a mixture of 2,4,4-trichloro-2′-hydroxydiphenyl ether and ethylene oxide in a weight ratio of 4:1; the color agent is red pigment of cowberry; the filler is iron oxide.
[0133] In step C, the glue is a mixture of rosin resin and epoxy composite resin with a weight ratio of 2:3; the rosin resin is KL1000W liquid rosin resin.
[0134] In step C, the temperature of the steam foaming treatment is 260° C., the time is 20 minutes, and the molding pressure is 220 tons.
[0135] The epoxy composite resin adhesive comprises the following weight parts of raw materials:
TABLE-US-00014 Epoxy resin 28 parts Terpene resin 20 parts Aluminum oxide 3.5 parts Polybutene 12 parts Emulsifier OP-10 8 parts Solvent 35 parts
[0136] The epoxy resin is CYD-118 bisphenol a liquid epoxy resin; the terpene resin is GT-30A liquid terpene resin; the solvent is a mixture of cyclohexane, diethyl ether and acetone with a weight ratio of 1:3:2.5.
[0137] The epoxy composite resin adhesive is prepared by the following steps: [0138] Step 1): According to the weight, Adding epoxy resin, terpene resin and Aluminum oxide into two-thirds of the total amount of solvent, heating to 45° C., stirring for 25 minutes to prepare material A; [0139] Step 2): According to the weight, Adding the emulsifier OP-10 into the remaining solvent, rising the temperature to 48° C., and then mixing them evenly to preparing material B; [0140] Step 3): Adding prepared material B into prepared material A, heating up to 56° C., stirring for 30 minutes, then adding polybutene, continue into stir for 18 minutes at 56° C., then heating up to 60° C. and keeping for 35 minutes to prepare epoxy composite resin adhesive for standby.
TABLE-US-00015 TABLE F Foam particles: large medium small Foaming agent: Azodicarbonamide Tiazinyl triazine Ethanolamine Aluminum potassium sulfate Antibacterial agent: 2,4,4-trichloro-2′-hydroxydiphenyl ether Ethylene oxide Color agent - red pigment of cowberry Filler - Iron oxide Glue: 1. Rosin resin - KL1000W liquid rosin resin 2. Epoxy composite resin: Epoxy resin- CYD-118 bisphenol Terpene resin- GT-30A liquid terpene resin Aluminum oxide Polybutene Emulsifier OP-10 Solvent: Cyclohexane Diethyl ether acetone
Parallel Contrast 1
[0141] Parallel contrast 1, follows the process and ingredients of Example 3 above, except that in step C, the glue is a mixture of rosin resin and GT-30A liquid terpene resin with a weight ratio of 1.5:4.5; the rosin resin is KL1000W liquid rosin resin.
TABLE-US-00016 TABLE G Foam particles: large medium small Foaming agent: Azodicarbonamide Tiazinyl triazine Ethanolamine Aluminum potassium sulfate Antibacterial agent: 2,4,4-trichloro-2′-hydroxydiphenyl ether Ethylene oxide Color agent - bright blue Filler Titanium dioxide Iron oxide Mica powder Glue: 1. Rosin resin - KL1000W liquid rosin resin 2. GT-30A liquid terpene resin
Parallel Contrast 2
[0142] Parallel contrast 2, follows the process and ingredients of Example 3 above, except that the epoxy composite resin adhesive comprises the following weight parts of raw materials, substituting in particular allyl glycidyl ether for polybutene:
TABLE-US-00017 Epoxy resin 26.5 parts Terpene resin 19 parts Aluminum oxide 2.5 parts Allyl glycidyl ether 11 parts Emulsifier OP-10 5 parts Solvent 33 parts
[0143] The epoxy resin is cyd-118 type bisphenol a liquid epoxy resin; the terpene resin is GT-30A liquid terpene resin; the solvent is a mixture of cyclohexane, diethyl ether and acetone with a weight ratio of 1:3:2.3.
[0144] The epoxy composite resin adhesive is prepared by the following steps: [0145] Step 1): According to the weight, adding epoxy resin, terpene resin and Aluminum oxide into two-thirds of the total amount of solvent, heating to 40° C., stirring for 26.5 minutes to prepare material A; [0146] Step 2): According to the weight, adding the emulsifier OP-10 into the remaining solvent, rising the temperature to 46.5° C., and then mixing them evenly to preparing material B; [0147] Step 3): Adding prepared material B into prepared material A, Heating up to 54° C., stirring for 35 minutes, then adding, continue into stir for 19 minutes at 54° C., then heating up to 60° C. and keeping for 32 minutes to prepare epoxy composite resin adhesive for standby.
[0148] The resultant foam fabric has a density of the foam of 450/m2.
TABLE-US-00018 TABLE H Foam particles: large medium small Foaming agent: Azodicarbonamide Tiazinyl triazine Ethanolamine Aluminum potassium sulfate Antibacterial agent: 2,4,4-trichloro-2′-hydroxydiphenyl ether Ethylene oxide Color agent - bright blue Filler Titanium dioxide Iron oxide Mica powder Glue: 1. Rosin resin - KL1000W liquid rosin resin 2. Epoxy composite resin: Epoxy resin- CYD-118 bisphenol Terpene resin- GT-30A liquid terpene resin Aluminum oxide allyl glycidyl ether Emulsifier OP-10 Solvent: Cyclohexane Diethyl ether acetone
[0149] A tensile strength test was carried out for each Example above by the standard for determination of tensile strength and elongation at break of GB/T 6344-1996 soft foamed polymer material. The tear strength test was carried out using the “GB 10808-1989 soft foam plastic tear test method” standard to determine the tearing strength of the foam mask. The resilience test was carried out by the standard for determination of resilience of GB/T6670-1997 soft polyurethane foam.
TABLE-US-00019 TABLE I Comparison of Examples 1-5 and Parallel contrast Examples 1-2: tensile tear compression strength resistance/ Resilience deformation (MPa) (N/mm) rate(%) (%) Example 1 22.3 56 91.6 26 Example 2 25.1 59 92.8 25 Example 3 28.3 64 94.2 23 Example 4 26.8 63 93.7 24 Example 5 23.4 60 92.2 27 Parallel 18.6 46 84.8 32 contrast 1 Parallel 20.7 57 88.2 29 contrast 2
[0150] The compression deformation test uses the “GB/T6669-1986 soft foam polymer compression permanent deformation measurement” standard to determine the compression permanent deformation performance of the foam mask. The test environment is (27+2) ° C. and the relative humidity is 65%±5%.
[0151] In Parallel contrast 1, the glue is composed of rosin resin and GT-30A liquid terpene resin instead of the rosin resin and epoxy composite resin glue of the present invention. Table I shows that this change in the glue of Proportion 1 result in reduced tensile strength, tear resistance, resilience and compression deformation of the foam fabric when compared to the results for Examples 1-5 directed to the present invention. The results also show that the viscosity of the glue when comprised of rosin resin and GT-30A liquid terpene resin is relatively low and the mixed adhesion to foam material is relatively low, so that the tear strength, tensile strength and resilience of foam are low. The combination of the epoxy composite resin adhesive and rosin resin in the present invention significantly increases the viscosity of the glue in the system, improves the stickiness and cohesion of the glue, improves the dispersion and adhesion of the glue to the materials and improves the foam tenacity, stability, softness, comfort and gives the foam high elasticity.
[0152] In Parallel contrast 2, allyl glycidyl ether is substituted for the polybutene used in the glue of the present invention. As seen in Table I above, Proportion 2 has reduced tensile strength, tear resistance, resilience and compression deformation of the foam fabric when compared to Examples 1-5 directed to the present invention. The results show that the viscosity of the composite resin glue of the present invention using polybutene has improved dispersion uniformity of the composite resin glue to other materials and results in a foam fabric having stable mechanical properties, soft and comfortable texture and high elasticity.
CONCLUSION
[0153] In the preceding specification, the invention has been described with reference to specific exemplary embodiments and examples thereof. It will, however, be evident that various modifications and changes may be made thereto without departing from the broader spirit and scope of the invention as set forth in the claims that follow. The specification and drawings are accordingly to be regarded in an illustrative manner rather than a restrictive sense.