POLYURETHANE PARTICLE FOAM WITH POLYURETHANE COATING

Abstract

Coated shaped articles contain at least one shaped article with foamed beads containing at least one polyurethane (A) and at least one coating containing at least one polyurethane (B), wherein polyurethane (A) and polyurethane (B) are each constructed from at least one polyol and at least one polyisocyanate and wherein not less than 50 wt % of the polyol component used for constructing polyurethane (A) and polyurethane (B) is identical and not less than 50 wt % of the at least one polyisocyanate component used for constructing polyurethane (A) and polyurethane (B) is identical. Processes for producing the coated shaped articles and the method of using the coated shaped articles for various applications can be utilized.

Claims

1. A coated shaped article, comprising: at least one shaped article comprising foamed beads comprising at least one polyurethane (A), and (b) at least one coating comprising at least one polyurethane (B), wherein polyurethane (A) and polyurethane (B) are each constructed from at least one polyol and at least one polyisocyanate, and wherein not less than 50 wt % of the at least one polyol component used for constructing polyurethane (A) and polyurethane (B) is identical and not less than 50 wt % of the at least one polyisocyanate component used for constructing polyurethane (A) and polyurethane (B) is identical.

2. The shaped article according to claim 1, wherein not less than 85 wt % of the at least one polyol component used for constructing polyurethane (A) and polyurethane (B) is identical and not less than 85 wt % of the at least one polyisocyanate component used for constructing polyurethane (A) and polyurethane (B) is identical.

3. The shaped article according to claim 1, wherein the at least one polyurethane (A) is a thermoplastic polyurethane.

4. The shaped article according to claim 1, wherein the at least one polyurethane (B) is a thermoplastic polyurethane having a Shore hardness A of below 98A, as determined to German standard specification DIN 53505.

5. The shaped article according to claim 1, wherein the at least one polyol is selected from the group consisting of polyether diols and polyester diols.

6. The shaped article according to claim 1, wherein the at least one polyisocyanate is selected from the group consisting of diphenylmethane diisocyanate, hexamethylene diisocyanate, 4,4,′-methylenedicyclohexyl diisocyanate, and 2,4- or 2,6- tolylene diisocyanate.

7. The shaped article according to claim 1, wherein the coating has a thickness in the range from 50 to 1000 μm.

8. A process for producing at least one coated shaped article, the process comprising: (i) providing foamed beads comprising at least one thermoplastic polyurethane (A), (ii) fusing or adhering the foamed beads in the desired shape to obtain a shaped article, and (iii) applying a coating comprising at least one polyurethane (B) to the shaped article, wherein polyurethane (A) and polyurethane (B) are each constructed from at least one polyol and at least one polyisocyanate and wherein not less than 50 wt % of the at least one polyol component used for constructing polyurethane (A) and polyurethane (B) is identical and not less than 50 w t% of the at least one polyisocyanate component used for constructing polyurethane (A) and polyurethane (B) is identical.

9. The process according to claim 8, wherein the coating of (iii) is applied in a form of a solution comprising at least one polyurethane (B).

10. The process according to claim 8, wherein the applying of (iii) is effected by brushing, dipping, or spraying.

11. The process according to claim 9, wherein a solvent used for the at least one polyurethane (B) does not break down the molecular weight of the at least one polyurethane (B).

12. The process according to claim 11, wherein the solvent is selected from the group consisting of tetrahydrofuran, ethyl acetate, and methyl ethyl ketone.

13. A method of shaping, the method comprising: shaping the coated shaped article according to claim 1 as a shoe sole, bicycle saddle, cushioning, mattresses, underlays, grips, protective foils, in structural components for the automotive interior and exterior, in balls and sports implements or as floor covering, athletic running tracks, sports halls, playgrounds, and footpaths.

14. A method of shaping, the method comprising: shaping a coated shaped article obtained by the process according to claim 8 as a shoe sole, bicycle saddle, cushioning, mattresses, underlays, grips, protective foils, in structural components for the automotive interior and exterior, in balls and sports implements or as floor covering, athletic running tracks, sports halls, playgrounds, and footpaths.

Description

EXAMPLES

1. Production of Samples

[0111] A thermoplastic polyurethane was dissolved in an organic solvent. Different color pigments may be added to this solution. This colored TPU solution is processed in the manner of a commercially available colored varnish by brushing it on. Owing to the high vapor pressure of the solvent, the thinly applied solution evaporates to leave behind a homogeneous resilient coating. This coating is notable for its good adherence to the coated material, grippiness and special visuals. The color of the coating is freely chooseable via the choice of color pigments used. A transparent coating is likewise possible.

[0112] The production and properties of TPU coatings are described in the examples which follow. The inventive solutions were produced in the lab on an electric rolling track.

1.1 Example 1 (Inventive) Transparent

[0113] A granular thermoplastic polyurethane material based on polytetrahydrofuran, butanediol and monomeric MDI and having a Shore hardness of 70A was weighed into a screw lid jar in a mass ratio of 20 parts together with 80 parts of tetrahydrofuran. For dissolution, the container was commixed on a rolling track at room temperature for not less than 12 h. After complete dissolution of the granular TPU, 100 parts of ethyl acetate were added followed by commixing to the point of homogenization. This solution was applied with a brush to fused ETPU panels. Test specimens were removed from these panels thus coated to perform mechanical and optical tests.

1.2 Example 2 (Inventive) Black

[0114] A granular thermoplastic polyurethane material based on polytetrahydrofuran, butanediol and monomeric MDI and having a Shore hardness of 70A was weighed into a screw lid jar in a mass ratio of 20 parts together with 80 parts of tetrahydrofuran. For dissolution, the container was commixed on a rolling track at room temperature for not less than 12 h. After complete dissolution of the granular TPU, 2.5 parts of black Isopur color paste and 100 parts of ethyl acetate were added followed by commixing to the point of homogenization. This solution was applied with a brush to fused ETPU panels. Test specimens were removed from these panels thus coated to perform mechanical and optical tests.

1.3 Example 3 (Inventive) Blue

[0115] A granular thermoplastic polyurethane material based on polytetrahydrofuran, butanediol and monomeric MDI and having a Shore hardness of 70A was weighed into a screw lid jar in a mass ratio of 20 parts together with 80 parts of tetrahydrofuran. For dissolution, the container was commixed on a roiling track at room temperature for not less than 12 h. After complete dissolution of the granular TPU, 2.5 parts of blue color pigment and 100 parts of ethyl acetate were added followed by commixing to the point of homogenization. This solution was applied with a brush to fused ETPU panels. Test specimens were removed from these panels thus coated to perform mechanical and optical tests.

2. Results

[0116] The test specimens obtained were tested. The results are summarized in table 1.

TABLE-US-00001 TABLE 1 Coated Coated Transparent Method* Uncoated black blue coating Density DIN EN ISO 1183-1, A 0.409 0.422 0.415 0.426 Tensile strength DIN 53504 3 3 3 3 Gloss measurement DIN 67530 8 19.5 10.1 11.3 (60°) Gloss measurement DIN 67530 8.7 11.3 7.3 7.3 (85°) Elongation at DIN 53504 240 260 290 310 break (edge) Abrasion DIN ISO 4649 236 234 240 176 Coefficient of friction *Ares Rheometer 0.302 0.291 0.289 0.272 The results show that the shaped articles coated according to the present invention exhibit an improvement in gloss, elongation at break and coefficient of friction. The thin coatings tested in the examples do not affect the tensile strength of the test specimens. An increase in gloss and elongation at break and a reduction in friction is considered to be more advantageous. *Parameters of Ares Rheometer: Principle: surface friction measurement Rubbing on standard tile with sodium laurylsulfate solution Contact pressure: 244 g on 110.7 mm.sup.2 Sample preparation: cleaned with 50:50 H.sub.2O:ethanol