GAS ANALYSER SYSTEM
20210033524 ยท 2021-02-04
Assignee
Inventors
Cpc classification
G01N21/31
PHYSICS
B01D46/71
PERFORMING OPERATIONS; TRANSPORTING
B01D2279/00
PERFORMING OPERATIONS; TRANSPORTING
International classification
G01N21/31
PHYSICS
B01D46/00
PERFORMING OPERATIONS; TRANSPORTING
G01L13/00
PHYSICS
Abstract
An extractive gas analyser system includes a supply channel, a measuring channel connected thereto between first and second ends, an analysing unit comprising an optical arrangement for analysing gaseous material in the measuring channel, which optical arrangement comprises first and second optical units arranged respectively at first and second ends of the measuring channel, a barrier arrangement near each end of the measuring channel and comprising a barrier gas inlet and outlet arranged in opposing manner across said measuring channel, each in connection with a gas source and provided with a nozzle opening directed toward the opposing outlet, said barrier arrangement arranged to provide pressurized gas creating a barrier gas curtain between the barrier gas inlet and outlet to force least a part of the gaseous material from the supply channel into the measuring channel and out through the outlet and thereby separate the gaseous material from said optical units.
Claims
1. A gas analyser system (1) for extractive measurement of a gaseous material, wherein the gas analyser system (1) comprises a supply channel (2) having an inlet supply opening at a first end and one or more outlet supply opening(s) at a second end of the channel (2), and a measuring channel (3) connected to said supply channel (2) between said first and second end, an analysing unit (5), comprising an optical arrangement (6) for analysing said gaseous material contained in said measuring channel (3), wherein the optical arrangement (6) comprises a first optical unit (7) arranged at a first end of the measuring channel (3) and a second optical unit (8) arranged at a second end of said measuring channel (3), a barrier arrangement (9) arranged near each end of the measuring channel (3) comprising a barrier gas inlet (10) and a barrier gas outlet (12) arranged in opposing manner across said measuring channel (3), each barrier gas inlet (10) is in connection with an gas source, such as an air source, and provided with a nozzle (11) having a nozzle opening (11a) being directed towards said opposing barrier gas outlet (12) having a barrier gas outlet opening (12a), said barrier arrangement (9) is arranged to provide pressurized gas creating a barrier gas curtain (14) between said barrier gas inlet (10) and said barrier gas outlet (12) so as to force least a part of said gaseous material from said supply channel (2) into said measuring channel (3) and out through said barrier gas outlet (12) and so as to separate the gaseous material from said optical units (7, 8).
2. A gas analyser system (1) according to any of the preceding claims, wherein said gas analyser system (1) further comprises a pressure system (15), wherein the pressure system (15) is arranged to provide a pressure difference (dP_s), defined as the difference between a first pressure (P1) near said first end of the supply channel (2) and a second pressure (P2) near the second end of the supply channel (2), wherein the first pressure (P1) is larger than the second pressure (P2).
3. A gas analyser system (1) according to any of the preceding claims, wherein said gas analyser system (1) comprises a first pressure sensor arranged near the first end of said supply channel (2) so as to measure said first pressure (P1) and provide a data output accordingly to said pressure system (15).
4. A gas analyser system (1) according to any of the preceding claims, wherein said gas analyser system (1) comprises a second pressure sensor arranged near the second end of said supply channel (2) so as to measure said second pressure (P2) and provide a data output accordingly to said pressure system (15).
5. A gas analyser system (1) according to any of the preceding claims, wherein the gas analyser system (1) comprises a control unit having a first pressure controller (17) for controlling said second pressure (P2) based on said first and second data outputs, preferably so as to maintain said pressure difference (dP_s) substantially constant or within a predetermined range.
6. A gas analyser system (1) according to any of the preceding claims, wherein the pressure system (15) comprises a pressure tank (16) in connection to said outlet supply opening(s), and wherein the pressure tank (16) is arranged to provide said second pressure (P2) to said outlet supply opening(s) by means of one or more pump(s).
7. A gas analyser system (1) according to any of the preceding claims, wherein the barrier arrangement (9) comprises curtain control means for controlling the flow rate of a barrier gas curtain (14), and thereby control the amount of gaseous material forced towards said barrier curtain (14).
8. A gas analyser system (1) according to any of the preceding claims, wherein for every amount of gaseous material reaching said measuring channel (3), a fraction A between 0.01-0.6, such as between 0.1-0.4, preferably between 0.1-0.3 is forced sideways towards said barrier gas curtain (14).
9. A gas analyser system (1) according to any of the preceding claims, wherein for every amount of gaseous material reaching the measuring channel (3), a fraction B continuous across said measuring channel (3) to said pressure tank (16), wherein the fraction B is between 0.40-0.99, such as between 0.6-0.9, preferably between 0.7-0.9.
10. A gas analyser system (1) according to any of the preceding claims, wherein the nozzle (11) is arranged so that the barrier gas curtain (14) is introduced in to the measuring channel (3) in a direction substantially perpendicular to the longitudinal extend of the measuring channel (3).
11. A gas analyser system (1) according to any of the preceding claims, wherein the barrier gas outlet opening (12a) is of a width (Wo) measured along the longitudinal extend of the barrier gas outlet opening (12a) which is at least equal or larger than the width of the nozzle opening (Wn), measured perpendicular to the longitudinal extend of the measuring channel (3).
12. A gas analyser system (1) according to any of the preceding claims, wherein the barrier gas outlet opening (12a) is of a length (Lo), measured perpendicular to the longitudinal extent of the barrier gas outlet opening (12a), which is at least equal or larger than the length (Ln) of the nozzle opening (11a), wherein the length is measured parallel to the longitudinal extent of the measuring channel (3).
13. A gas analyser system (1) according to any of the preceding claims, wherein the centre-point of the nozzle opening (11a) and the centre-point of the barrier gas outlet opening (12a) is displaced at a distance (d_tilt) relative to each other along the longitudinal extent of the measuring channel (3).
14. A gas analyser system (1) according to any of the preceding claims, wherein the optical units (7, 8) are arranged to provide a beam of electromagnetic radiation through said measuring channel (3), and wherein the barrier gas curtain is of a thickness (T_bg), being between 0.5-8 mm, such as between 1-6 mm, preferably between 2-4 mm, measured along a centreline of said electromagnetic beam.
15. A gas analyser system (1) according to any of the preceding claims, wherein the optical units (7, 8) are arranged to provide a beam of electromagnetic radiation through said measuring channel (3), and wherein the barrier gas curtain (14) is of a thickness (T_bg) extending over a isolation distance (d_isolation) making up between 0.1-2.0%, such as 0.2-1.0% of the total distance (d_total) that the beam travels through in the measuring channel (3).
16. A gas analyser system (1) according to any of the preceding claims, wherein the gas analyser system (1) further comprises a probe arrangement (18) for collecting said gaseous material from a gaseous environment, wherein the probe arrangement (18) is in connection with said supply channel (2), and wherein the probe arrangement (18) is equipped with one or more filter arrangement(s) (19) arranged to filter said gaseous material prior to entering the supply channel (2).
17. A gas analyser system (1) according to any of the claim 16, wherein the gas analyser system (1) comprises a cleaning device (24) for cleaning said filter arrangement (19) from particulates and dust, wherein the cleaning device (24) is in connection with an air source and configured to provide a portion of cleaning air, preferably a pulse of cleaning air out through at least the filter arrangement (19) to the gaseous environment.
18. A gas analyser system (1) according to any of the preceding claims, wherein the gas analyser system (1) comprises a calibration arrangement (22) for filling said measuring channel (3) with calibration gas, wherein the calibration arrangement (22) has one or more calibration gas inlet arranged in connection with said supply channel (2) between said first end of the supply channel and said measuring channel (3).
19. A gas analyser system (1) according to any of the claims 16-18, wherein the probe arrangement (18) comprises probe heating means for heating at least parts of said probe arrangement (18), such as the filter arrangement (19).
20. A gas analyser system (1) according to any of the preceding claims, wherein the gas analyser system (1) comprises channel heating means for heating said gaseous material in said supply channel (2) and/or said measuring channel (3) or both, and wherein the channel heating means comprises a channel heat controller for controlling said temperature in said channel(s) (2, 3).
21. A gas analyser system (1) according to any of the preceding claim, wherein the gas analyser system (1) comprises barrier gas heating means for heating said barrier gas curtain (14), wherein the barrier gas heating means comprises a barrier gas heat controller for controlling said temperature of said barrier gas curtain (14).
22. A gas analyser system (1) according to any of the preceding claims, wherein the gas analyser system (1) comprises one or more temperature sensor(s) for detecting a temperature within said gas analyser system (1) and provide an output accordingly.
23. A gas analyser system (1) according to any of the preceding claims, wherein the gas analyser system (1) comprises one or more temperature sensor(s) in connection to said barrier arrangement (9), preferably near said barrier gas inlet (10), so as to measure the temperature near said barrier arrangement (9) and so as to provide an output accordingly to said barrier gas heat controller.
24. A method for measuring a gaseous medium in a gas analyser system (1), wherein the gas analyser system (1) comprises a supply channel (2) having an inlet supply opening at a first end near a gaseous environment containing said gaseous medium, and one or more outlet supply opening(s) at a second end of the channel (2), and a measuring channel (3) connected to said supply channel (2) between said first and second end, an analysing unit (5), comprising an optical arrangement (6) for analysing said gaseous material contained in said measuring channel (3), wherein the optical arrangement (6) comprises a first optical unit (7) arranged at a first end of the measuring channel (3) and a second optical unit (8) arranged at a second end of said measuring channel (3), a barrier arrangement (9) arranged near each end of the measuring channel (3) comprising a barrier gas inlet (10) and a barrier gas outlet (12) arranged in opposing manner across said measuring channel (3), each barrier gas inlet (10) is in connection with an gas source, such as an air source, and provided with a nozzle (11) having a nozzle opening (11a) being directed towards said opposing barrier gas outlet (12) having a barrier gas outlet opening (12a), wherein the method comprises the steps of providing a pressure difference (dP_s) between the pressure of the gaseous material at said inlet supply opening and said outlet supply opening, so as to force gaseous medium from said supply inlet opening toward said supply outlet opening, providing a flow of barrier gas through said nozzle opening (11a) toward said barrier gas outlet opening (12a), so as to provide a barrier gas curtain (14) and so as to force at least a part of said gaseous material from said supply channel (2) into said measuring channel (3) towards said barrier gas curtain (14), and measuring said gaseous material in said measuring channel (3) using said optical arrangement (6).
25. A method according to claim 24, wherein the gas analyser system (1) further comprises a pressure system (15) and one or more pressor sensors for measuring and controlling pressures within said gas analyser system (1), wherein the method further comprises the step of measuring said pressure difference (dP_s) and provide a data output accordingly using said pressure system (15).
26. A method according to claim 25, wherein the method further comprises the step of controlling said pressure difference (dP_s) based on said data output using said pressure system (15).
27. A method according to any of the claims 25-26, wherein the pressure system (15) comprises a first pressure sensor arranged to measure a first pressure (P1) of the gaseous material near the inlet supply opening and a second pressure sensor arranged to measure a second pressure (P2) of the gaseous material near the outlet supply opening, and provide a first data output and second data output accordingly and wherein said method comprises the step of calculating said pressure difference (dP_s) by subtracting the measured second pressure (P2) from the measured first pressure (P1).
28. A method according to any of the claims 25-27, wherein the pressure system (15) comprises one or more pressure controller(s) (17) arranged to control said second pressure (P2), and wherein the method comprises the step of controlling said pressure difference (dP_s) based on said data output by controlling said second pressure (P2) using the one or more pressure controller(s) (17).
29. A method according to any of the claims 24-28, wherein the method comprises the step of providing a barrier gas curtain (14) from said barrier gas inlet (10) to said barrier gas outlet (12), wherein the barrier gas curtain (14) is of a width (W_bg) larger or equal to the width (W_mc) of the measuring channel (3).
30. A method according to any of the claims 24-29, wherein the method comprises the step of providing a barrier gas curtain (14) from said barrier gas inlet (10) to said barrier gas outlet (12) which is of a barrier gas curtain thickness (T_bg) being between 1-10 mm.
31. A method according to any of the claims 24-30, wherein the gas analyser system (1) is a gas analyser system (1) according to any of the claims 1-23.
32. Use of a gas analyser system (1) according to any of the claims 1-23 for analysing characteristics of a gaseous material, such as a flue gas.
Description
DRAWINGS
[0120] Aspects of the present disclosure will be described in the following with reference to the figures in which:
[0121]
[0122]
[0123]
[0124]
DETAILED DESCRIPTION OF THE INVENTION
[0125]
[0126] In one or more embodiments and in the present exemplary gas analyser 1 between the filter arrangement 19 and the supply channel 2 a calibration arrangement 22 is shown connected to the probe channel 18a. The calibration arrangement 22 is for introducing a calibration gas of known content into the gas analyser system for calibration of the analysing unit 5. The calibration arrangement 22 comprises a calibration inlet to said probe channel 18a, a calibration gas source 23 and preferably also a control device for selectively activating, deactivating and adjusting the flow of calibration gas from the calibration arrangement 22. A flow meter may be utilized to monitor and adjust the calibration gas flow.
[0127] In one or more embodiments, and in the present example, a cleaning device is arranged in connection to said probe channel 18a, e.g. in extension to said probe channel 18a from said filter arrangement 19. The cleaning device is arranged to provide a flow of cleaning gas towards said probe arrangement 18, so as to clean one or more filters of said filter arrangement 19 by a blow-back process, where the cleaning gas is directed through the filter into the gaseous environment. The flow of cleaning gas may be one or more pulse of cleaning gas.
[0128]
[0129] As shown in
[0130] In one or more embodiments of the present invention, and as illustrated in
[0131] In one or more embodiments, and as illustrated in
[0132] The barrier arrangement 9 is preferably configured to provide a flow of barrier gas across the measuring channel 3 due to the presence of a pressure gradient. The barrier gas is compressed to a pressure of e.g. 1-5 bar, such as 2-4 bar or such as 3 bar and creating a jet flow of barrier gas when exiting through the nozzle e.g. at a flow rate of about 1-3 litres/minute, thereby providing the barrier gas curtain 14. The design of the nozzle 11 provides a thin well-defined barrier gas curtain 14. The barrier gas curtain 14 is preferably a pressurized air plenum exiting through the elongated nozzle opening or slot in a laminar (uniform) flow pattern. As illustrated in
[0133] The barrier gas curtain is of a thickness (T_bg) measured along the along centreline of the electromagnetic radiation 6a, e.g. which preferably propagates parallel to the second axis (a2), and further be of a width (W_bg) measured along the third axis (a3) as illustrated in
[0134] In one or more embodiments, the optical units 7, 8 each comprise an optical window 6b, of an optical transparent material, facing the interior of the measuring channel and preferably separating the interior components of the optical units 7, 8 from the gases in the measuring channel 3. As illustrated in
[0135] The centre of the barrier gas outlet opening 12a and the centre of the nozzle opening 11a may be aligned on a same line extending through the centre's and parallel to the first axis (a1). In one or more examples and as shown in
[0136] In one or more embodiments, approximately 20-30% of the gaseous material entering the measuring channel 3 is directed sideways by the barrier gas curtain, while the remaining 70-80% of the gas material continuous to flow through the supply channel 2, as illustrated in
[0137] In one or more embodiments, and as an example shown in
[0138] The pressure tank 16, and the pressure control valve 17, is a part of a pressure system 15 which comprises further comprises one or more pressure sensors distributed in the system and displaying said measured pressure values and/or communicating the measured pressure values to a control unit of the pressure system 15. In one or more examples, a first pressure sensor may preferably be arranged in the supply channel 2 prior to the measuring channel 3 and arranged to measure a first pressure P1 and provide a data output accordingly. A second pressure sensor may be arranged in connection with the pressure tank 16 and measure the pressure within the tank 16, defined as the second pressure P2 and provide an output accordingly. When a difference exist between the first and second pressure, a pressure gradient is created forcing gaseous material from the first end of the supply channel 2, to the intersection between the supply channel 2 and the measuring channel 3 and towards the pressure tank 16. The pressure system 15 may preferably be arranged to control the pressure difference (dp_s) in response to the measured first pressure (P1) measured at first end of supply channel, by adjusting the second pressure (P2) by using the pressure control valve 17. The pressure system 15 may also be arranged to monitor and control the pressure of the barrier gas, defined as the third pressure (P3), in response to a pressure measurement device or sensor arranged to measure the barrier gas pressure (P3) prior to being discharged through the nozzle opening 11a. In one or more examples, as the second pressure (P2) is kept below the first pressure (P1) and as the pressure of the gaseous material is generally much less than the third pressure (P3) of the barrier gas, the second pressure (P2) will also be less than the barrier gas pressure (P3) thereby providing suction to the barrier gas outlet opening 12a.
[0139] The gas analyser system 1 according to embodiments of the invention is preferably arranged to utilize the high amount of barrier gas reaching the pressure tank 16 to dilute the gaseous material entering the pressure tank 16 from the second end of the supply channel 2. Du to this dilution of the gaseous material the pressure system components can be protected and no additional filtering or processing of the gas is needed. Preferably the mixture of gas in the pressure tank 16 contains a ratio between 1:30 to 1:70 of gaseous material to barrier gas, or of at least 1:50 of gaseous material to barrier gas.
[0140] In one or more embodiments of the present invention, in events that the filter(s) of the filter arrangement are extensively covered by dust or other blocking particulates, a drop in pressure near the first end of the supply channel 2, e.g. in the supply channel 2 nearest the probe arrangement 18 or in the probe channel 18a, will occur, which is detected by the pressure system 15. As a response to such pressure reduction, the aforementioned cleaning device 24 will be activated, and the filter arrangement 19 is cleaned.
[0141] In one or more embodiments, the supply channel 2 and the measuring channel 3 is preferably heated by a heating arrangement 20 comprising heating means 21a, 21b, such as electrical heating means. Furthermore, the barrier gas curtain 14 and/or the probe arrangement 18 and probe channel 18a may also be heated. Preferably the entire flow path for the gaseous material in the gas analyser system 1 is heated. The collected gaseous medium by the probe arrangement 18 may be of a high temperature, and furthermore contain species which may be harmful to the gas analyser system 1 if they are allowed to adhere to inner surfaces of the system 1. If the inner surfaces are colder than the gaseous material, condensation occurs due to the temperature difference and species are deposited to the surfaces. Therefore the heating means are preferably arranged to maintain the temperature of the inner surfaces and the barrier gas substantially equal to the temperature of the gaseous material throughout the probe section and analysing unit 5. In one or more examples, a number of temperature sensors are distributed in said gas analyser system 1 so as to monitor and detect any temperature difference between the gaseous material and the inner surfaces throughout the system 1. E.g. a temperature sensor may be arranged to measure the temperature at different positions scattered long the inner surface of the supply channel 2. A temperature sensor may also be arranged in said probe arrangement 18 and also near said barrier gas outlet 12 e.g. such as in a channel connection between said outlet opening 12a and the pressure tank 16. In one or more examples, a temperature control system may be comprised in said gas analyser system 1 for controlling the temperatures provided by the heating means based on outputs from the temperature sensors.
[0142] The gas analyser system 1 of the present invention may allow for several units 5 to be arranged in succession along the supply channel 2. In
LIST OF REFERENCES
[0143] 1 Gas analyser system [0144] 2 Supply channel [0145] 3 Measuring channel [0146] 3_x Further measuring channel [0147] 4 Four-channel intersection [0148] 4_x Further four-channel intersection [0149] 5 Analysing unit [0150] 6 Optical arrangement [0151] 6a Centre line of the electromagnetic radiation [0152] 6b Optical window [0153] 6_x Further optical arrangement [0154] 7 First optical unit [0155] 8 Second optical unit [0156] 9 Barrier arrangement [0157] 10 Barrier gas inlet [0158] 11 Nozzle [0159] 11a Nozzle opening [0160] 12 Barrier gas outlet [0161] 12a Barrier gas outlet opening [0162] 14 Barrier gas curtain e.g. air knife [0163] 15 Pressure system [0164] 16 Pressure tank [0165] 17 Pressure controller e.g. valve [0166] 18 Probe arrangement [0167] 18a Probe channel [0168] 19 Filter arrangement [0169] 19a Filter [0170] 22 Calibration arrangement [0171] 23 Calibration gas source [0172] 24 Cleaning device [0173] a1 First axis [0174] a2 Second axis [0175] a3 Third axis [0176] Lo Length of the barrier gas outlet opening [0177] Ln Length of the nozzle opening [0178] Lmc Length of the measuring channel [0179] Wo Width of the barrier gas outlet opening [0180] Wn Width of the nozzle opening [0181] Wmc Width of the measuring channel [0182] T_bg Thickness of the barrier gas curtain [0183] P1 First pressure [0184] P2 Second pressure [0185] P3 Third pressure [0186] dP_mc Pressure difference along the measuring channel [0187] dP_s Pressure difference, dP_s=P2P1 [0188] d_x distance between nozzle opening and the centre-line of the electromagnetic radiation.