Process for purification of vinyl acetate for use in polymerization in the presence of ethylene

Abstract

Process for purification of unreacted vinyl acetate monomers comprising the steps of preliminarily loading an adsorbent agent bed with a mixture comprising an inert gas and fresh vinyl acetate; and feeding said adsorbent agent bed with unreacted vinyl acetate monomers to remove acetic acid.

Claims

1. A process for purification of unreacted vinyl acetate monomers comprising: i) drying a fresh vinyl acetate monomer stream in a molecular sieve bed; ii) subjecting the fresh vinyl acetate to a polymerization process in the presence of ethylene to produce an ethylene vinyl acetate (EVA) polymer; iii) recovering unreacted vinyl acetate monomers from the polymerization process; iv) drying the unreacted vinyl acetate monomers in the molecular sieve bed; v) preliminarily loading an adsorbent agent bed with a mixture comprising an inert gas and the fresh vinyl acetate at low concentration; and vi) feeding the adsorbent agent bed with dried unreacted vinyl acetate monomers to remove the acetic acid, wherein the unreacted vinyl acetate monomer is a vinyl acetate monomer recovered from the EVA polymerization process, and the inert gas is a nitrogen or saturated hydrocarbon selected from the group consisting of methane, ethane, propane, butane and combinations thereof.

2. The process according to claim 1, wherein in the dehydration steps i) and iv) the vinyl acetate monomers are dried by feeding through the molecular sieve bed at room temperature and positive pressure.

3. The process according to claim 1, further comprising subjecting the molecular sieve bed to a dehydration treatment at a temperature range of 170 to 270 C., and at a pressure range of 0 and 760 mmHga for a period between 2 and 24 hours, by contacting said bed with an inert gas.

4. The process according to claim 1, further comprising subjecting the molecular sieve bed to a dehydration treatment at a temperature range between 250 and 270 C., and at a pressure range between 0 and 76 mmHga, for from 2 to 8 hours, by contacting said bed with inert gas.

5. The process according to claim 1, wherein the fresh vinyl acetate is previously stored in a vessel at pressure range of 0 and 2280 mmHga and passed through the molecular sieve bed at room temperature and at the same pressure range of the fresh vinyl acetate storage vessel.

6. The process according to claim 1, wherein in step ii) a polymerization reactor is fed with fresh and dried vinyl acetate and a polymerization process is performed in the presence of ethylene to obtain ethylene vinyl acetate copolymer.

7. The process according to claim 6, wherein the unreacted vinyl acetate is separated from the copolymer and the unreacted ethylene.

8. The process according to claim 6, wherein the step iv) comprises passing the unreacted vinyl acetate through the molecular sieve bed at room temperature and at a pressure range of 0 to 2280 mmHga.

9. The process according to claim 1, wherein the step v) further comprises subjecting the adsorbent agent bed to a dehydration treatment at a temperature range of 170 to 270 C., and at a pressure range of 760 and 3040 mmHga, for a period between 2 and 24 hours, by contacting said bed with the inert gas.

10. The process according to claim 9, wherein in step v) the adsorbent agent bed is subjected to a dehydration treatment at a temperature range between 250 C. and 270 C., and at a pressure range between 1140 and 1900 mmHga, for a period between 2 and 8 hours, by contacting said bed with the inert gas.

11. The process according to claim 9, wherein in step v) the adsorbent agent bed further comprises a preliminary load by contacting the adsorbent agent with a mixture of fresh vinyl acetate and inert gas at a temperature below 100 C., at pressure range of 760 and 3040 mmHga, and at a ratio of 0.1% to 50% by weight of fresh vinyl acetate based on the weight of mixture for between 30 and 1440 minutes.

12. The process according to claim 11, further comprising the preliminary load at a temperature below 100 C., at a pressure range from 760 to 1900 mmHga, and at a ratio of 0.1 and 10% by weight of fresh vinyl acetate based on the weight of the mixture, for between 30 and 600 minutes.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 depicts a schematic flow diagram for an ethylene vinyl acetate (EVA) production process.

(2) FIG. 2 depicts a thermogram of EVA with 28% wt. of vinyl acetate with heating rate of 10 C./min.

(3) FIG. 3 is a graph (corresponding to Example 3) which shows the temperature from the top and bottom of the column during preload and vinyl acetate treatment steps.

(4) FIG. 4 is a graph (corresponding to Example 3) which shows acetic acid concentration during vinyl acetate monomer treatment.

(5) FIG. 5 is a graph (corresponding to Example 4) which shows the temperature from the top and bottom of the column during the preload and vinyl acetate treatment step.

(6) FIG. 6 is a graph (corresponding to Example 4) which shows acetic acid concentration during vinyl acetate monomer treatment.

DETAILED DESCRIPTION OF THE INVENTION

(7) In one embodiment of the present invention, the process for purification of unreacted vinyl acetate monomer comprises the steps of preliminarily loading an adsorbent agent bed with a mixture comprising an inert gas and fresh vinyl acetate; and feeding said adsorbent agent bed with unreacted vinyl acetate monomer to remove acetic acid.

(8) The unreacted vinyl acetate monomer of the present invention is preferably vinyl acetate monomer recovered from the EVA polymerization process.

(9) The inert gas used in the present invention is preferably nitrogen or saturated hydrocarbon. The saturated hydrocarbon may be selected among methane, ethane, propane, butane and combinations thereof.

(10) The preliminary load is preferably performed with a mixture comprising an inert gas and fresh vinyl acetate at low concentration, wherein the acetic acid adsorption occurs at controlled conditions. The preliminary contact of adsorbent agent with the mixture of vinyl acetate and inert gas is necessary to control the heating generated in the reaction due to vinyl acetate adsorption. After this controlled adsorption, the unreacted vinyl acetate is fed into the adsorbent agent bed to remove acetic acid.

(11) Optionally, water is removed from the fresh vinyl acetate monomer before the polymerization process step and, optionally, water is removed from the unreacted vinyl acetate monomer before the acetic acid removal step.

(12) In a preferred embodiment, the process for purification of unreacted vinyl acetate monomers comprises the steps of

(13) 1) Drying a fresh vinyl acetate monomer stream in a molecular sieve bed;

(14) 2) Subjecting the fresh vinyl acetate to a polymerization process in the presence of ethylene to produce EVA polymer;

(15) 3) Recovering the unreacted vinyl acetate monomers from the polymerization process;

(16) 4) Drying said unreacted vinyl acetate monomer in a molecular sieve bed;

(17) 5) Preliminarily loading an adsorbent agent bed with a mixture comprising an inert gas and fresh vinyl acetate at low concentration;

(18) 6) Feeding the adsorbent agent bed with the dried unreacted vinyl acetate monomers to remove the acetic acid.

(19) The obtained purified vinyl acetate is suitable to be recycled to the polymerization process to produce ethylene vinyl acetate copolymers (EVA).

(20) Eventually, the molecular sieve may become fully loaded with water and the adsorbent agent bed may become fully loaded with acetic acid. In this case, a regeneration process of said beds may be necessary.

(21) Preferably, in the dehydration steps (1) and (4), the vinyl acetate monomers are dried by feeding them through the beds of a molecular sieve at room temperature and positive pressure. Also, said molecular sieve beds may be previously dehydrated with inert gas at high temperature.

(22) In step (5), the preliminary loading occurs with a mixture of fresh vinyl acetate and an inert gas at room temperature.

(23) In step (6), the acetic acid present in dried unreacted vinyl acetate is removed, preferably, by feeding the dried unreacted vinyl acetate through the adsorbent agent bed, at room temperature and positive pressure, therefore obtaining a purified vinyl acetate that may be recycled to the polymerization process.

(24) In a most preferred embodiment, the process for purification of unreacted vinyl acetate monomers comprises the steps of

(25) 1) Subjecting a molecular sieve bed to a dehydration treatment at a temperature range of 170 to 270 deg C., preferably between 250 and 270 deg C., at a pressure range of 0 and 760 mmHga, preferably between 0 and 76 mmHga, for a period of time varying between 2 and 24 hours, preferably from 2 to 8 hours, by contacting said bed with an inert gas;

(26) 2) Passing a fresh vinyl acetate (previously stored in a vessel at pressure range of 0 and 2280 mmHga, preferably between 760 and 1520 mmHga) through the molecular sieve bed at room temperature at the same pressure range of fresh vinyl acetate storage vessel. The fresh vinyl acetate stream may be recycled to a storage vessel until fresh vinyl acetate is completely dried. The fresh vinyl acetate may pass through the molecular sieve bed and recycled to a storage vessel for a period varying between 2 and 24 hours, preferably from 2 to 8 hours. Alternatively, the fresh vinyl acetate may pass through a dehydrated molecular sieve bed at room temperature, at a pressure range of 22.800 mmHga and 228.000 mmHga, preferably from 22.800 mmHga and 38.000 mmHga;

(27) 3) Feeding a polymerization reactor with the fresh and dried vinyl acetate and performing the polymerization process in the presence of ethylene to obtain the ethylene vinyl acetate copolymer;

(28) 4) Separating the unreacted vinyl acetate from the polymer and unreacted ethylene;

(29) 5) Passing the unreacted vinyl acetate through a dehydrated molecular sieve bed at room temperature at pressure range of 0 do 2280 mmHga, preferably between 760 and 1520 mmHga to remove water from unreacted vinyl acetate monomer;

(30) 6) Subjecting an adsorbent agent bed to a dehydration treatment at a temperature range of 170 to 270 deg. C., preferably between 250 deg. C. and 270 deg. C., at pressure range of 760 and 3040 mmHga, preferably between 1140 and 1900 mmHga, for a period of time varying between 2 and 24 hours, preferably between 2 and 8 hours, by contacting said bed with an inert gas;

(31) 7) Subjecting the adsorbent agent bed of step 6 to a preliminary load by contacting the adsorbent agent with a mixture of fresh vinyl acetate and an inert gas, at temperature below 100 deg. C. or below 50 deg. C. or at room temperature, at pressure range of 760 to 3040 mmHga, preferably between 760 and 1900 mmHga, at a ratio of 0.1 to 50% by weight, preferably between 0.1 and 10% by weight of fresh vinyl based on the weight of the mixture, for a period of time varying between 30 and 1440 minutes, preferably between 30 and 600 minutes;

(32) 8) Passing the dried unreacted vinyl acetate obtained in step 5 through the dehydrated preloaded adsorbent agent of step 7 at room temperature, at pressure range of 760 and 228 mmHga, preferably between 760 and 1520 mmHga for remove water and acetic acid from unreacted vinyl acetate monomer.

(33) After the molecular sieve beds and adsorbent agent beds are saturated, it may be necessary to subject said beds to a regeneration step. Preferably, the regeneration process comprises the following steps:

(34) a. Feeding the molecular sieve and or adsorbent agent beds with an inert gas at room temperature, at pressure range of 760 and 3040 mmHga, preferably between 1140 and 1900 mmHga for a period of time varying between 2 and 24 hours, preferably between 2 and 6 hours;

(35) b. Feeding said beds with an inert gas at temperature range of 30 to 110 deg. C., for a period of time varying between 2 and 24 hours, preferably between 2 and 12 hours;

(36) c. Subjecting said beds to a dehydration treatment with inert gas, at a temperature range from 170 to 270 deg. C., preferably between 250 and 270 deg. C., at pressure range of 760 and 3040 mmHga, preferably between 1140 and 1900 mmHga, for a period of time varying between 2 and 24 hours, preferably from 2 to 8 hours, by passing an inert gas through said beds.

(37) According to the present invention, the molecular sieve dryer may be a crystalline aluminosilicate with a sodalite unit type X, as shown in Equation 9 or a sodalite unit type Y, as shown in Equation 10,

(38) TABLE-US-00001 NA.sub.12(AlO.sub.2).sub.12(SiO.sub.2).sub.12 Type X (Eq. 9) NA.sub.6(AlO.sub.2).sub.6(SiO.sub.2).sub.18 Type Y (Eq. 10)

(39) forming molecular sieve type A, X or Y with porous diameter between 3 and 13 .

(40) Further, according to the present invention, the molecular sieve dryer used in the dehydration of fresh vinyl acetate monomer and unreacted vinyl acetate monomer may be alumina in 714 Tyler mesh with nominal ball size between and inch of diameter.

(41) The adsorbent agent of the present invention used to remove acetic acid may be selected from alumina in 714 Tyler mesh with nominal ball size between and inch of diameter or a molecular sieve type X or Y with porous diameter between 4 and 13 .

(42) The purified vinyl acetate obtained by the process of the present invention may contain an amount of acetic acid below 3000 ppm wt, or below 1000 ppm wt or even below 200 ppm wt.

(43) The purified vinyl acetate obtained by the process of the present invention may contain an amount of water below 3000 ppm wt, or below 1000 ppm wt or even below 200 ppm wt.

EXAMPLES

Example 1

(44) 76.1 g of activate carbon was added on 200 mL of vinyl acetate monomer, at room temperature in a stirred Schlenk flask under nitrogen atmosphere. The mixture of active carbon and vinyl acetate was stirred during 2 hours.

(45) Table 1 shows the acetic acid concentration reduction in an unreacted vinyl acetate sample according the treatment method of example 1.

(46) TABLE-US-00002 TABLE 1 Before Treatment After Treatment Acetic Acid (ppm w.t.) >40.000 29.614

(47) The vinyl acetate solubilized partially the activate carbon which makes the activate carbon unviable on industrial application.

Example 2

(48) 50 g of alumina (Basf SelexorbCD) was added in 200 mL of vinyl acetate monomer, at room temperature in a stirred Schlenk flask under nitrogen atmosphere. The mixture of alumina and vinyl acetate was stirred during 2 hours.

(49) Table 2 shows the acetic acid concentration according to the method of Example 2 and the result of Example 1 for comparative analysis.

(50) TABLE-US-00003 TABLE 2 Example 2 Comparative Example 1 Adsorbent Agent Alumina Activate Carbon Acetic Acid concentration >40.000 >40.000 Before Treatment (ppm w.t.) Acetic Acid concentration 2.580 29.614 After Treatment (ppm w.t.)

(51) As shown in Table 2, the alumina was more efficient than activate carbon to remove the acetic acid from an unreacted vinyl acetate sample. On the other hand, the vinyl acetate did not solubilize alumina turning its industrial application viable.

Example 3

(52) 500 g alumina (Basf Selexsorb CD) was added in a stainless steel column. The alumina was subjected at preliminary load feeding through a bed of a mixture of nitrogen containing 10% by weight of vinyl acetate monomer during 4 hours. After preload was fed vinyl acetate monomer containing 22078 ppm wt. of acetic acid. During testing, 17 liters of vinyl acetate monomer was treated.

(53) FIG. 3 shows the temperature from the top and bottom of the column during preload and vinyl acetate treatment steps.

(54) As shown in FIG. 3, the temperature of the bed during the preload step was 102 deg. C. and after the temperature remained at 30 deg. C.

(55) FIG. 4 shows acetic acid concentration during vinyl acetate monomer treatment.

(56) As shown in FIG. 4, the adsorption ratio was 10.6%, near to 1 g alumina adsorbing 0.106 g of acetic acid.

Example 4

(57) 500 g of alumina (Basf Selexsorb CD) was dried in an oven with nitrogen at 270 deg. C. for 4 hours, and then added in a stainless steel column. The alumina was subjected at preliminary load feeding through a bed of a mixture of nitrogen containing until 13% by weight of vinyl acetate monomer for 10 hours. After preload, vinyl acetate monomer containing until 48.770 ppm wt. of acetic acid was fed. During testing, 20.4 liters of vinyl acetate monomer was treated.

(58) FIG. 5 shows the temperature from the top and bottom of the column during the preload and vinyl acetate treatment step.

(59) As shown in FIG. 5, the temperature of the bed during the preload step was 49 deg. C. and after the temperature remained at 28 deg. C.

(60) FIG. 6 shows acetic acid concentration during vinyl acetate monomer treatment.

(61) As shown in FIG. 6, the adsorption ratio was 26.4%; this means that 1 g of alumina adsorbs 0.264 g of acetic acid.