TRENCH SPLIT-GATE DEVICE AND METHOD FOR MANUFACTURING THE SAME
20210028289 ยท 2021-01-28
Inventors
Cpc classification
H01L29/41766
ELECTRICITY
H01L21/28556
ELECTRICITY
H01L29/41
ELECTRICITY
H01L29/407
ELECTRICITY
H01L29/66734
ELECTRICITY
International classification
H01L29/423
ELECTRICITY
H01L29/40
ELECTRICITY
Abstract
A method for manufacturing a trenched split-gate device, comprising: etching a semiconductor substrate to form a trench (120); depositing an oxide in the trench to form a floating-gate oxide layer in which the floating-gate oxide layer gradually thickens from top to bottom along a side wall of the trench, and a thickness of the floating gate oxide layer at a lower part of the side wall of the trench is the same as that of the floating gate oxide layer at a bottom of the trench; depositing polysilicon into the trench to form a floating-gate polysilicon layer (123); growing an insulation medium on an upper surface of the floating-gate polysilicon layer to form an isolation layer (124); and forming a control gate on the isolation layer in the trench.
Claims
1. A method for manufacturing a trench split-gate device, comprising: etching a semiconductor substrate to form a trench; depositing oxide in the trench to form a floating gate oxide layer, wherein the floating gate oxide layer is gradually thickened from top to bottom along a side wall of the trench, and a thickness of the floating gate oxide layer at a lower part of the side wall of the trench is the same as that of the floating gate oxide layer at a bottom of the trench; depositing polysilicon into the trench to form a floating gate polycrystalline layer; growing an insulating medium on an upper surface of the floating gate polycrystalline layer to form an isolation layer; and forming a control gate on the isolation layer in the trench.
2. The method according to claim 1, wherein said etching a semiconductor substrate to form a trench comprises: etching the semiconductor substrate vertically to enable the side wall of the trench vertical up and down.
3. The method according to claim 2, wherein the depositing oxide in the trench to form a floating gate oxide layer comprises: forming a first oxide layer on an inner surface of the trench; forming a second oxide layer on the first oxide layer; controlling the second oxide layer to thicken from top to bottom along the side wall of the trench, a thickness of the second oxide layer at the lower part of the side wall of the trench being the same as that of the second oxide layer at the bottom of the trench.
4. The method according to claim 3, wherein a thickness of the first oxide layer on the inner surface of the trench is the same everywhere.
5. The method according to claim 4, wherein said controlling the second oxide layer to thicken from top to bottom along the side wall of the trench comprises: gradually thickening the second oxide layer from top to bottom along the side wall of the trench by controlling a pressure of a reaction chamber and a flow rate of a gas flowing into the reaction chamber, the thickness of the second oxide layer at the lower part of the side wall of the trench being the same as that of the second oxide layer at bottom of the trench.
6. The method according to claim 5, wherein the flow rate of the reaction gas includes: 15%-20% for silane, 20%-25% for oxygen, 25%-35% for hydrogen, and 20%-40% for helium.
7. The method according to claim 1, wherein said etching a semiconductor substrate to form a trench comprises: etching the semiconductor substrate to form a vertical upper half trench; etching the semiconductor substrate obliquely downward from a bottom of the upper half trench to form a lower half trench extending downward from the bottom of the upper half trench and with a width gradually increased from top to bottom, and a bottom of the lower half trench being concave arc-shaped, and the trench being constituted by the upper half trench and the lower half trench together.
8. The method according to claim 7, wherein the depositing oxides in the trench to form a floating gate oxide layer comprises: forming a first oxide layer on an inner surface of the trench; etching the first oxide layer to enable a side wall of the first oxide layer vertical up and down; forming a second oxide layer on the first oxide layer at the bottom of the lower half trench using high density plasma chemical vapor deposition process, wherein the floating gate oxide layer is gradually thickened from top to bottom along a side wall of the lower half trench, and the thickness of the floating gate oxide layer at a lower part of the side wall of the lower half trench is the same as that of the floating gate oxide layer at the bottom of the lower half trench.
9. The method according to claim 8, wherein said forming a first oxide layer on an inner surface of the trench comprises: forming the first oxide layer on the inner surface of the trench using thermal oxidation method.
10. The method according to claim 1, wherein before the growing an insulating medium on an upper surface of the floating gate polycrystalline layer to form an isolation layer, the method further comprises a step of removing the first oxide layer above the floating gate polycrystalline layer.
11. The method according to claim 1, wherein the forming a control gate on the isolation layer in the trench comprises: forming a control gate oxide layer on the side wall of the trench above the isolation layer; depositing polysilicon on the isolation layer in the trench to form a control gate polycrystalline layer; etching back or grinding the control gate polycrystalline layer to form the control gate.
12. A trench split-gate device, comprising: a semiconductor substrate in which a trench is provided; a floating gate oxide layer provided on an inner wall of the trench, a thickness of the floating gate oxide layer being gradually increased along a side wall of the trench to a bottom of the trench, and the thickness of the floating gate oxide layer at a lower part of the side wall of the trench is the same as that of the floating gate oxide layer at the bottom of the trench; a floating gate polycrystalline layer provided on a surface of the floating gate oxide layer; an isolation layer provided on the floating gate polycrystalline layer; and a control gate provided on the isolation layer to control on and off of the device.
13. The trench split-gate device according to claim 12, wherein the side wall of the trench is vertical from top to bottom, and the floating gate oxide layer includes a first oxide layer on the inner wall of the trench and a second oxide layer on the first oxide layer, the second oxide layer being gradually thickened from top to bottom along the side wall of the trench, wherein the thickness of the first oxide layer on the inner wall of the trench is the same everywhere; a thickness of the second oxide layer at the lower part of the side wall of the trench being the same as that of the second oxide layer at the bottom of the trench.
14. The trench split-gate device according to claim 13, wherein the trench includes an upper half trench and a lower half trench, a width of the lower half trench is gradually increased from a position of the isolation layer to a position of a bottom of the lower half trench, and the bottom of the lower half trench is concave arc-shaped.
15. The trench split-gate device according to claim 14, wherein the floating gate oxide layer includes a first oxide layer on the inner wall of the trench and a second oxide layer provided on the first oxide layer and at the bottom of the trench, and the first oxide layer is gradually thickened from top to bottom along the side wall of the lower half trench.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0009] In order to better describe and explain the embodiments or examples of those applications disclosed herein, reference can be made to one or more drawings. The additional details or examples used to describe the drawings should not be considered to limit the scope of any of the disclosed inventions, the embodiments and/or examples currently described, and the best model of these applications as currently understood.
[0010]
[0011]
[0012]
[0013]
[0014]
DETAILED DESCRIPTION OF THE EMBODIMENTS
[0015] As shown in
[0016] At S100: a semiconductor substrate is etched to form a trench.
[0017] At S110: an oxide is deposited in the trench to form a floating gate oxide layer, in which the floating gate oxide layer is gradually thickened from top to bottom along the side wall of the trench, and a thickness of the floating gate oxide layer at the lower part of the side wall of the trench is the same as that of the floating gate oxide layer at the bottom of the trench.
[0018] At S120: polysilicon is deposited into the trench to form a floating gate polycrystalline layer.
[0019] At S130: an insulating medium is grown on the upper surface of the floating gate polycrystalline layer to form an isolation layer.
[0020] At S140: a control gate is formed on the isolation layer in the trench.
[0021] In the above method for manufacturing a trench split-gate device, a gradually changing floating gate oxide layer is grown on the trench side wall, in order that the thickness of the floating gate oxide layer is gradually increased from the isolation layer position to the bottom position of the trench and the thickness of the floating gate oxide layer at the lower part of the side wall of the trench is the same as that of the floating gate oxide layer at the bottom of the trench. The thickness of the floating gate oxide gradually changing can reduce the width of the trench and further reduce the cell area and the specific on resistance of the device. In addition, the thickness of the floating gate oxide layer is gradually increased from the side wall of the trench, and the thickness of the floating gate oxide at the lower part of the side wall of the trench is the same as that at the bottom of the trench. Said floating gate oxide layer also adapts to the continually increasing voltage from the control gate to the bottom of the trench, such that the device will not be broken down due to a non-adaptive voltage.
[0022] In one of embodiments, etching the semiconductor substrate to form a trench specifically comprises: etching the semiconductor substrate vertically to make the side wall of the trench vertical up and down. The step of depositing an oxide into the trench to form a floating gate oxide layer comprises: forming a first oxide layer on the inner surface of the trench; forming a second oxide layer on the first oxide layer using high density plasma chemical vapor deposition process in which the thickness of the second oxide layer is controlled to gradually increase from top to bottom along the trench side wall and the thickness of the second oxide layer at the lower part of the side wall of the trench is the same as that of the second oxide layer at the bottom of the trench. In the example, by controlling the pressure of the reaction chamber and the flow rate of the reaction gas flowing into the reaction chamber, the thickness of the second oxide layer along the side wall of the trench can be controlled to gradually increase.
[0023] Specifically, referring to
[0024] At S200: a semiconductor substrate is etched to form a trench.
[0025] A semiconductor substrate is a kind of semiconductor material, which provides mechanical supports and electrical properties for manufacturing a transistor and an integrated circuit. In the present embodiment, the semiconductor substrate can include semiconductor elements such as monocrystal, polycrystalline, or amorphous silicon or germanium, and can also include a mixed semiconductor structure such as silicon carbide, indium antimonide, lead telluride, indium arsenide, indium phosphide, gallium arsenide or gallium antimonide, alloy semiconductors or combinations thereof.
[0026] Specifically, referring to
[0027] At S210: a first oxide layer is formed on the inner surface of the trench.
[0028] In the embodiment, a first oxide layer can be formed on the inner surface of the trench using the furnace tube oxidation method, and the first oxide layer can be silicon oxide.
[0029] Specifically, the semiconductor substrate can be placed in a certain gas atmosphere and a certain temperature atmosphere to have the semiconductor substrate react with oxygen or water vapor to generate silicon dioxide during the preparation. The gas atmosphere refers to nitrogen and/or oxygen and/or hydrogen, and the temperature range is from about 700 C. raised to about 1100 C. and then back to about 700 C. As shown in
[0030] At S220: a second oxide layer is formed on the first oxide layer using high density plasma chemical vapor deposition process. By controlling the pressure of the reaction chamber and the flow rate of the reaction gas flowing into the reaction chamber, the thickness of the second oxide layer is gradually increased from top to bottom along the side wall of the trench, and the thickness of the second oxide layer at the lower part of the side wall of the trench is the same as that of the second oxide layer at the bottom of the trench.
[0031] As shown in
[0032] Compared with the ordinary atmospheric pressure chemical vapor deposition method, the thickness of the second oxide layer 122 formed by the deposition can be controlled by the HDP CVD process used in the embodiment of present disclosure, such that the thickness of the second oxide layer 122 deposited on the side wall of the trench 120 is gradually increased from the top to the bottom, and the thickness of the second oxide layer 122 at the bottom of the trench 120 is the same as that of the second oxide layer 122 at the lower part of the side wall of the trench 120. On the one hand, increasing the thickness of the the floating gate oxide at the bottom of the trench can make the device adapt to withstand voltage and avoid the device to be broken down by high voltage. On the other hand, under the condition that the thickness of the floating gate oxide at the bottom of the trench is the same, the floating gate oxide layer on the side wall of the trench in the present disclosure is thinner than the floating gate oxide layer on the side wall of the trench in a traditional process, and the width of the trench is smaller than that of the trench in a traditional process. Therefore the cell area is reduced, the number of cell per unit area on the chip is increased and the specific on resistance of the device is reduced.
[0033] At S230: polysilicon is deposited into the trench to form a floating gate polycrystalline layer.
[0034] Referring to
[0035] At S240: an insulating medium is grown on the surface of floating gate polycrystalline layer to form an isolation layer.
[0036] Referring to
[0037] Further, before the step of forming the isolation layer 124 on the upper surface of the floating gate polycrystalline layer 123, the method further comprises a step of removing the first oxide layer 121 above the floating gate polycrystalline layer 123. Specifically, the first oxide layer 121 above the floating gate polycrystalline layer 123 can be removed using dry etching technology.
[0038] At S250: a control gate is formed on the isolation layer in the trench.
[0039] Further, referring to
[0040] Specifically, in the present embodiment, the polysilicon can be deposited in the trench 120 using low-pressure chemical vapor deposition method, and the polysilicon is doped at the same time. The polysilicon outside the trench 120 can be etched using dry etching process to form a control gate.
[0041] In the method for manufacturing a trench split-gate device provided by the embodiment, by using the high-density plasma chemical vapor deposition process, the thickness of the second oxide layer at the bottom and on the side wall of the trench can be adjusted by adjusting the pressure of the reaction chamber and the flow rate of the reaction gas. The thickness of the floating gate oxide on the side wall of the trench is gradually increased from top to bottom, and the thickness of the floating gate oxide at the lower part of the side wall of the trench is the same as that of the floating gate oxide at the bottom of the trench. Therefore, on the one hand, it can meet the requirement of withstanding the gradually changing voltage, and at the same time, the width of the trench can be reduced by the gradually changing thickness of the floating gate oxide, thereby further reducing the cell area, increasing the number of cell receivable per unit area on the chip, and reducing the specific on resistance of the device.
[0042] Referring to
[0043] A trench split-gate device is also provided by the embodiment, which is manufactured according to the steps of the method shown in
[0044] In the trench split-gate device provided by the embodiment of the disclosure, the second oxide layer is formed using HDP CVD process at the bottom and on side wall of the trench, such that the thickness of the second oxide layer is gradually increased from top to bottom along the side wall of the trench, and the thickness of the second oxide layer at the lower part of the side wall of the trench is the same as that of the second oxide layer at the bottom of the trench. Furthermore, the total thickness of the floating gate oxide constituted of the first oxide layer and the second oxide layer is gradually increased from top to bottom along the side wall of the trench, and the thickness of the floating gate oxide layer at the lower part of the side wall of the trench is the same as that of the floating gate oxide layer at the bottom of the trench. Therefore, on the one hand, it can meet requirement of withstanding the gradually changing voltage, and at the same time, the width of the trench can be reduced by the gradually changing thickness of the floating gate oxide, and thus the cell area is further reduced and the specific on resistance of the device is reduced.
[0045] In another embodiment, the step of etching a semiconductor substrate to form a trench specifically comprises: etching the semiconductor substrate to form a vertical upper half trench. The semiconductor substrate is etched obliquely downward from the bottom of the upper half trench to form a lower half trench extending downward from the bottom of the half trench and with a width gradually increased from the top to the bottom. And the bottom of the lower half trench is concave arc-shaped. The step of depositing oxide into the trench to form a floating gate oxide layer includes: forming a first oxide layer on the inner surface of the trench; etching the first oxide layer to make the side wall of the first oxide layer vertical up and down; forming a second oxide layer on the first oxide layer at the bottom of the lower half trench using high density plasma chemical vapor deposition process, in which the thickness of the floating gate oxide layer constituted of the first oxide layer and the second oxide layer is gradually increased from top to bottom along the side wall of the trench. The thickness of the floating gate oxide at the lower part of the side wall of the lower half of the trench is the same as that of the floating gate oxide at the bottom of the lower half of the trench.
[0046] Specifically, referring to
[0047] At S300: a semiconductor substrate is etched to form a vertical upper half trench.
[0048] Referring to
[0049] At S310: the semiconductor substrate is etched obliquely downward from the bottom of the upper half trench to form a lower half trench extending downward from the bottom of the upper half trench and with a width gradually increased from the top to the bottom.
[0050] Referring to
[0051] At S320: a first oxide layer is formed on the inner surface of the trench.
[0052] Referring to
[0053] At S330: the first oxide layer is etched to enable the side wall of the first oxide layer vertical up and down.
[0054] After the growing process is completed, the first oxide layer 223 is dry etched, so that the side wall of the first oxide layer 223 of the inner wall of the trench is vertical up and down, and the thickness of the first oxide layer 223 of the side wall of the lower half trench 222 is gradually increased from top to bottom.
[0055] At S340: a second oxide layer is formed on the first oxide layer at the bottom of the lower half trench using high density plasma chemical vapor deposition process, in which the thickness of the floating gate oxide layer formed by the combination of the first oxide layer and the second oxide layer gradually increased from top to bottom along the side wall of the trench, and the thickness of the floating gate oxide layer at the lower part of the side wall of the trench is the same as that of the floating gate oxide layer at the bottom of the trench.
[0056] Referring to
[0057] At S350: polysilicon is deposited into the trench to form a floating gate polycrystalline layer.
[0058] As shown in
[0059] At S360: an insulating medium is grown on the surface of the floating gate polycrystalline layer to form an isolation layer.
[0060] As shown in
[0061] Further, before the step of forming an isolation layer 226 on the upper surface of the floating gate polycrystalline layer 225, the method can further include the step of removing the first oxide layer 222 above the floating gate polycrystalline layer 225. Specifically, the first oxide layer 223 above the floating gate polycrystalline layer 225 can be removed using dry etching technology.
[0062] At S370: a control gate is formed on the isolation layer in the trench.
[0063] Further, as shown in
[0064] Specifically, in this embodiment, polysilicon can be deposited in trench 220 using low-pressure chemical vapor deposition method, and polysilicon is doped at the same time. The polysilicon outside the trench 220 can be etched using dry etching process to form the control gate.
[0065] In the method for manufacturing the trench split-gate device provided by the present embodiment, the lower half trench with the width gradually increased from the top to the bottom is formed by etching the vertical upper half trench firstly and then etching obliquely downward from the bottom of the upper half trench. The trench is constituted by the upper half trench and the lower half trench together. Then a first oxide layer is grown on the inner side of the trench, in which the thickness of the first oxide layer in the lower half trench gradually increases from top to bottom along the side wall of the lower half trench. Next, a second oxide layer is deposited on the first oxide layer at the bottom of the lower half trench to increase the thickness of the floating gate oxide layer at the bottom of the lower half trench, in order that the total thickness of the floating gate oxide layer constituted of the first oxide layer and the second oxide layer is gradually increase from top to bottom along the side wall of the lower half trench, and the thickness of the floating gate oxide layer at the lower part of the lower half trench is the same as that of the floating gate oxide layer at the bottom of the lower half trench. Therefore, on the one hand, it can meet the requirement of withstanding the gradually changing voltage, and at the same time, it can reduce the cell area and the specific on resistance of the device.
[0066] Referring to
[0067] The present embodiment also provides a trench split-gate device, which is manufactured according to the steps of the method shown in
[0068] In the trench split-gate device provided by the embodiment of the invention, the width of the lower half trench is gradually increased from top to bottom, and the thickness of the first oxide layer which is grown on the inner wall of the lower half trench is gradually increased from top to bottom, and the second oxide layer is used to thicken the bottom of the trench, such that the total thickness of the floating gate oxide layer constituted by the first oxide layer and the second oxide layer is gradually increased from top to bottom along the side wall of the lower half trench. The thickness of floating gate oxide at the lower part of the sided wall of the lower half trench is the same as that of the floating gate oxide at the bottom of the lower half trench. Therefore, on the one hand, it can meet the requirement of withstanding the gradually changing voltage. At the same time, the gradually changing thickness of the floating gate oxide can reduce the width of the trench, and further reduce the cell area and the specific on resistance of the device.
[0069] It should be understood that although the steps in the flowchart of