PHOTO-RESPONSIVE SELF-DEFORMING STRUCTURE AND METHOD OF DRIVING SAME
20210016490 ยท 2021-01-21
Inventors
Cpc classification
B32B2535/00
PERFORMING OPERATIONS; TRANSPORTING
B32B27/18
PERFORMING OPERATIONS; TRANSPORTING
B32B2255/10
PERFORMING OPERATIONS; TRANSPORTING
B29C59/02
PERFORMING OPERATIONS; TRANSPORTING
B32B38/0008
PERFORMING OPERATIONS; TRANSPORTING
C09K19/54
CHEMISTRY; METALLURGY
B32B2307/40
PERFORMING OPERATIONS; TRANSPORTING
B29C61/00
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
C09K2219/03
CHEMISTRY; METALLURGY
International classification
B29C59/16
PERFORMING OPERATIONS; TRANSPORTING
B29C59/02
PERFORMING OPERATIONS; TRANSPORTING
B32B27/18
PERFORMING OPERATIONS; TRANSPORTING
B32B38/00
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The present invention relates to a photo-responsive shape-changing structure and a driving method thereof. The photo-responsive shape-changing structure (100) is characterized in that it includes a first body portion (200) including at least one polymer film that undergoes a bending deformation in response to light irradiation, a second body portion (300) including at least one polymer film that undergoes a bending deformation in response to light irradiation, and a connection portion (400) configured to allow the first body portion (200) and the second body portion (300) to be connected to each other, wherein adhesive support portions (500, 600) are formed at one ends of the first body portion (200) and the second body portion (300), which are in contact with the ground (20).
Claims
1. A photo-responsive shape-changing structure comprising: a first body portion comprising at least one polymer film that undergoes a bending deformation in response to light irradiation; a second body portion comprising at least one polymer film that undergoes a bending deformation in response to light irradiation; and a connection portion configured to allow the first body portion and the second body portion to be connected to each other, wherein adhesive support portions are formed at one ends of the first body portion and the second body portion, which are in contact with the ground.
2. The photo-responsive shape-changing structure of claim 1, wherein the first body portion comprises a 1-1 polymer film and a 1-2 polymer film that each undergo a bending deformation in response to light irradiation and the second body portion comprises a 2-1 polymer film and a 2-2 polymer film that each undergo a bending deformation in response to light irradiation.
3. The photo-responsive shape-changing structure of claim 2, wherein a first restricting portion is formed between the 1-1 polymer film and the 1-2 polymer film and a second restricting portion is formed between the 2-1 polymer film and the 2-2 polymer film.
4. The photo-responsive shape-changing structure of claim 1, wherein the polymer film comprises a polymer scaffold film, an azobenzene liquid crystal polymer applied on a surface of the polymer scaffold film by immersing the film in the polymer, and a protective film attached to a surface of the azobenzene liquid crystal polymer.
5. The photo-responsive shape-changing structure of claim 1, wherein an adhesive strength between the adhesive support portions and the ground is less than a force that causes bending deformation of the polymer film upon light irradiation.
6. The photo-responsive shape-changing structure of claim 1, wherein the connection portion connects the other ends of the first body portion and the second body portion to each other and acts as a joint to allow for bending or twisting deformation of the first body portion and the second body portion.
7. The photo-responsive shape-changing structure of claim 1, wherein the first body portion and the second body portion are provided in plurality.
8. A method of driving a photo-responsive shape-changing structure which comprises a first body portion comprising at least one polymer film that undergoes a bending deformation in response to light irradiation, a second body portion comprising at least one polymer film that undergoes a bending deformation in response to light irradiation, and a connection portion configured to allow the first body portion and the second body portion to be connected to each other, wherein adhesive support portions are formed at one ends of the first body portion and the second body portion, which are in contact with the ground, the method comprising the steps of: (a) producing a bending deformation by irradiating the polymer film of the first body portion and releasing the adhesive support portion of the first body portion from the contact with the ground; (b) causing the first body portion to move forward by producing a bending deformation by irradiating the polymer film of the second body portion; (c) producing a bending deformation in a direction opposite to that of the step (a) by irradiating the polymer film of the first body portion, and bringing the adhesive support portion of the body portion into contact with the ground; (d) producing a bending deformation in a direction opposite to that of the step (c) by irradiating the polymer film of the second body portion that is positioned at least below an irradiated portion of the step (b), and allowing the second body portion to move forward while releasing the adhesive support portion of the second body portion from the contact with the ground; and (e) producing a bending deformation in a direction opposite to that of the step (d) by irradiating the polymer film of the second body portion, and bringing the adhesive support portion of the second body portion into contact with the ground.
9. The method of claim 8, wherein the first body portion comprises a 1-1 polymer film and a 1-2 polymer film that each undergo a bending deformation in response to light irradiation, the second body portion comprises a 2-1 polymer film and a 2-2 polymer film that each undergo a bending deformation in response to light irradiation, a first restricting portion is formed between the 1-1 polymer film and the 1-2 polymer film, and a second restricting portion is formed between the 2-1 polymer film and the 2-2 polymer film.
10. The method of claim 9, wherein the step (a) comprises producing the bending deformation by irradiating the 1-1 polymer film of the first body portion and releasing the adhesive support portion formed on the 1-1 polymer film from the contact with the ground, the step (b) comprises allowing the first body portion to move forward as a pushing force is applied to the first body portion by producing the bending deformation by irradiating the 2-1 polymer film of the second body portion, the step (c) comprises producing the bending deformation in a direction opposite to that of the step (a) by irradiating the 1-1 polymer film of the first body portion, and bringing the adhesive support portion formed on the 1-1 polymer film into contact with the ground, the step (d) comprises producing the bending deformation in a direction opposite to that of the step (b) by irradiating the 2-1 polymer film and the 2-2 polymer film of the second body portion, and allowing the second body portion to move forward, and the step (e) comprises producing the bending deformation in a direction opposite to that of the step (d) by irradiating the 2-1 polymer film, and bringing the adhesive support portion formed on the 2-1 polymer film into contact with the ground.
Description
DESCRIPTION OF DRAWINGS
[0032]
[0033]
[0034]
[0035]
[0036]
[0037]
DESCRIPTION OF REFERENCE NUMERALS
[0038] 100: PHOTO-RESPONSIVE SHAPE-CHANGING STRUCTURE
[0039] 200: FIRST BODY PORTION
[0040] 210: 1-1 POLYMER FILM
[0041] 230: 1-2 POLYMER FILM
[0042] 250: FIRST RESTRICTING PORTION
[0043] 300: SECOND BODY PORTION
[0044] 310: 2-1 POLYMER FILM
[0045] 330: 2-2 POLYMER FILM
[0046] 350: SECOND RESTRICTING PORTION
[0047] 400: CONNECTION PORTION
[0048] 500, 600: ADHESIVE SUPPORT PORTION
MODE FOR INVENTION
[0049] In the following detailed description, reference is made to the accompanying drawings that show, by way of illustration, specific embodiments in which the invention may be practiced. These embodiments are described in sufficient detail to enable those skilled in the art to practice the invention. It is to be understood that the various embodiments of the invention, although different from one another, are not necessarily mutually exclusive. For example, a particular feature, structure, and characteristic described herein in connection with one embodiment may be implemented within other embodiments without departing from the spirit and scope of the present invention. Also, it should be understood that the positions or arrangements of individual elements in the embodiment may be changed without departing from the spirit and scope of the present invention. Accordingly, the following detailed description is not intended to be restrictive, and the scope of the present invention is determined only by the accompanying claims along with equivalents of what is claimed by the claims, if properly explained. In the drawings, like reference numerals denote like elements and lengths, areas, thicknesses or shapes may be exaggerated for the sake of convenience.
[0050] Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings in order to enable those skilled in the art to easily implement the present invention.
[0051]
[0052] Referring to
[0053] The first body portion 200 may correspond to a front portion of the photo-responsive shape-changing structure 100. The first body portion 200 may act as a front foot when the photo-responsive shape-changing structure 100 moves.
[0054] The first body portion 200 may include at least one polymer film 210 or 230 that can undergo a bending deformation in response to light irradiation. In the present specification, a description is made under the assumption that the first body portion 200 includes a 1-1 polymer film 210 and a 1-2 polymer film 230, but the first body portion 200 may be formed to include only one elongated polymer film.
[0055] The polymer film 10 may undergo a bending deformation in response to light irradiation. More specifically, the polymer film 10 may control bending deformation using cis-trans conversion of an azobenzene liquid crystal polymer, and may undergo a bending deformation through light of a specific bandwidth without thermal reaction. The 1-1 polymer film 210, the 1-2 polymer film 230, a 2-1 polymer film 310, a 2-2 polymer film 330, and the like may have the same composition as the polymer film 10.
[0056] Since the bending deformation of the polymer film 10 is a reversible reaction, it is possible for repetitive behavior to occur, so that a certain motion can be continuously repeated, and the same motion can be repeated even when in a transparent case or under water, which makes it possible to be driven in various environments.
[0057]
[0058] As shown in
[0059] Specifically, the polymer scaffold film 11 is a polymeric scaffold prepared in a film form. As the polymeric scaffold film 110, various materials such as poly(lactic acid) (PLA), poly(D,L-lactic-co-glycolic acid) (PLGA), poly(dimethylsiloxane) (PDMS), polycaprolactone (PCL) and the like may be used.
[0060] The polymeric scaffold is, for example, a two-dimensional weaving material with a ribbon or mesh structure prepared by spinning and discharging a polymer fiber having a m- or nm-scale diameter onto a dust-collecting plate through an electrospinning process. However, the polymeric scaffold film according to the present invention is not limited to a specific processing method or a micro structure. The polymeric scaffold may be fabricated, for example, through a micromolding process and a spincoating process for forming a polymer matrix with a pun-scale porous pattern or a microsyringe deposition method in which a polymer in a gel state is put into a syringe and then a two-dimensional pattern is drawn through a micro-needle located at an outermost edge of the syringe.
[0061] The azobenzene liquid crystal polymer 120 is applied on the polymeric scaffold film by permeating the polymer into a pattern in the film.
[0062] More specifically, the azobenzene liquid crystal polymer 12 is an azobenzene-based liquid crystal polymer containing azobenzene or azobenzene derivative, and has a photo-responsive behavior characteristic due to photo-isomerization of azobenzene.
[0063] Azobenzene is composed of two benzene rings linked by an NN double bond, and has a unique property in which two different geometric forms are interconverted by light. Benzene rings linked on both sides based on the NN double bond of azobenzene are linked by a single bond that is able to freely rotate. A case where benzene rings at both ends of the NN double bond are positioned on the same side is referred to as a cis form, and a case where benzene rings are positioned on opposing sides is referred to as a trans form. Azobenzene undergoes photo-isomerization in which the molecular structure thereof is converted from a trans form to a cis form upon irradiation with UV rays, and the molecular structure thereof is converted from a cis form to a trans form upon irradiation with visible rays.
[0064] That is, when a liquid crystal polymer with azobenzene in a trans form is irradiated with UV rays, azobenzene is isomerized, which induces nematic-isotropic phase transition characteristics of an adjacent liquid crystal polymer, and thereby bending deformation in which a polymer material is bent in a direction of receiving light occurs. As the photo-responsive deformation of the azobenzene liquid crystal polymer is a reversible reaction, the azobenzene liquid crystal polymer may be deformed to its original form upon irradiation with visible rays.
[0065] The protective film 13 may be attached to a surface of the azobenzene liquid crystal polymer 12. The protective film 130 supports a composite actuator so that a fracture does not occur even at high tension, and a flexible material which does not degrade the bending deformation of a composite actuator is used as the protective film.
[0066] When a position where bending is required in the polymer film 10 thus manufactured is irradiated with UV rays using a UV laser or UV LED, a surface which is irradiated with UV rays is locally contracted, and thus bending deformation occurs throughout the polymer film.
[0067] A direction in which bending deformation occurs may be an upper surface or lower surface of the polymer film according to a direction in which light is radiated, but, according to the present invention, the deformation characteristics of the polymer film are not related to an alignment direction of azobenzene molecules in the azobenzene liquid crystal polymer 12 applied on the polymeric scaffold film 11. That is, according to the present invention, the azobenzene liquid crystal polymer 12 does not require separate alignment other than being applied on the polymeric scaffold film 11.
[0068] A first restricting portion 250 may be formed between the 1-1 polymer film 210 and the 1-2 polymer film to allow the 1-1 polymer film 210 and the 1-2 polymer film 230 to be connected to each other.
[0069] The first restricting portion 250 may be formed to connect the 1-1 polymer film 210 and the 1-2 polymer film such that the 1-1 polymer film 210 and the 1-2 polymer film 230 undergo multiple bending deformations in different or the same directions. The first restricting portion may be formed of a tape that does not transmit light.
[0070] For example, the 1-1 polymer film 210 is formed at one side of the first restricting portion 250, and the 1-2 polymer film 230 is formed at the other side, and thereby, when light is irradiated to the 1-1 polymer film 210, the light is not transmitted to the 1-2 polymer film 230, and thus bending deformation may occur only in the 1-1 polymer film 210, and when light is irradiated to the 1-2 polymer film 230, the light is not transmitted to the 1-1 polymer film 210, and thus bending deformation may occur only in the 1-2 polymer film 230.
[0071] Meanwhile, the 1-1 polymer film 210 and the 1-2 polymer film 230 may be formed integrally as an elongated polymer film, and the first restricting portion 250 formed of a tape that does not transmit light may be attached to the middle of the polymer film to separate the 1-1 polymer film 210 and the 1-2 polymer film 230, thereby allowing the 1-1 polymer film 210 formed on the lower part and the 1-2 polymer film formed on the upper part to individually react.
[0072] The second body portion 300 may correspond to a rear portion of the photo-responsive shape-changing structure 100. The second body portion 200 may act as a rear foot when the photo-responsive shape-changing structure 100 moves.
[0073] The second body portion 300 may include at least one polymer film 310 or 330 that can undergo a bending deformation in response to light irradiation. In the present specification, a description is made under the assumption that the second body portion 300 includes the 2-1 polymer film 310 and the 2-2 polymer film 330, but the second body portion 300 may be formed to include only one elongated polymer film.
[0074] A second restricting portion 350 may be formed between the 2-1 polymer film 310 and the 2-2 polymer film to allow the 2-1 polymer film 310 and the 2-2 polymer film 330 to be connected to each other.
[0075] The configuration of the second body portion 300 is the same as that of the first body portion 200, and hence a detailed description thereof is omitted hereinafter.
[0076] The connection portion 400 may connect at least one first body portion 200 and at least one second body portion 300.
[0077] The connection portion 400 may connect the first body portion 200 and the second body portion 300 to each other, and at the same time, may act as a joint to allow for deformation, such as bending, twisting, or the like, of the first body portion 200 and the second body portion 300. To this end, the connection portion 400 may employ flexible polymer materials, tapes, other hinge means, and the like without limitation.
[0078] The adhesive support portions 500 and 600 may be formed at one ends (lower ends) of the first body portion 200 and the second body portion 300, respectively. The adhesive support portions 500 and 600 may allow the first body portion 200 and the second body portion 300 to be attached to the ground 20 (see
[0079] The adhesive strength between the adhesive support portions 500 and 600 and the ground 20 may be preferably less than the force that causes bending deformation of the polymer film 10 upon light irradiation. In other words, the adhesive support portions 500 and 600, which are formed, respectively, on the 1-1 polymer film 210 of the first body portion 200 or the 2-1 polymer film 310 of the second body portion 300, may release the adhesion from the ground 20 when the 1-1 polymer film 210 and the 2-1 polymer film 310 undergo bending deformation in response to light irradiation. As the adhesive support portion 500 on the 1-1 polymer film 210 and the adhesive support portion 600 on the 2-1 polymer film 310 release the adhesion from the ground 20, the 1-1 polymer film 210 and the 202 polymer film 310 may slide without being supported by the ground 20. Accordingly, it is possible to move the first body portion 200 and the second body portion 300.
[0080]
[0081] The photo-responsive shape-changing structure 100 and a system for driving the same are illustrated with reference to
[0082] First, referring to
[0083] Then, referring to
[0084] Then, referring to
[0085] Then, referring to
[0086] Then, referring to
[0087] Then, referring to
[0088] The state shown in
[0089]
[0090] Referring to
[0091] Each of the first body portions 200 (200-1 and 200-2) may include, respectively, a 1-1 polymer film 210 (210-1 and 210-2), a 1-2 polymer film 230 (230-1 and 230-2), a first restricting portion 250 (250-1 and 250-2), and an adhesive support portion 500 (500-1 and 500-2).
[0092] In addition, each of the second body portions 300 (300-1 and 300-2) may include, respectively, a 2-1 polymer film 310 (310-1 and 310-2), a 2-2 polymer film 330 (330-1 and 330-2), a second restricting portion 350 (350-1 and 350-2), and an adhesive support portion 600 (600-1 and 600-2).
[0093] A connection part 400 may connect ends (upper ends) of the two first body portions 200-1 and 200-2 and ends of the two second body portions 300-1 and 300-2 to each other.
[0094]
[0095] First, referring to (a) of
[0096] Then, referring to (b) and (c) of
[0097] Then, referring to (d) of
[0098] Then, referring to (e) and (f) of
[0099] Then, referring to (g) and (h) of
[0100] Then, referring to (i) and (j) of
[0101] Then, referring to (k) and (l) of
[0102] The state shown in (l) of
[0103]
[0104] First, referring to (a) of
[0105] On the ground 20, there is an obstacle 25, such as a step with a height from the ground 20.
[0106] Then, referring to (b) of
[0107] Then, referring to (c) of
[0108] Then, referring to (d) of
[0109] Then, referring to (e) of
[0110] Then, referring to (f) of
[0111] Then, referring to (g) of
[0112] Then, referring to (f) of
[0113] Then, referring to (i) of
[0114] Then, referring to (j) of
[0115] Then, referring to (k) of
[0116] Then, referring to (l) of
[0117] By repeating the process of
[0118] The photo-responsive shape-changing structure 100 is not limited to the embodiments illustrated in
[0119] As described above, the present invention has an effect in that bending deformation can be controlled using cis-trans conversion of an azobenzene liquid crystal polymer and moving, walking, ascending, descending, and the like are possible in response to light irradiation. In addition, the photo-responsive shape-changing structure undergoes a reaction through light of a specific bandwidth without thermal reaction, and since the reaction is a reversible reaction, it is possible for repetitive behavior to occur, so that a constant motion can be continuously repeated.
[0120] Although the invention has been described and illustrated with reference to specific illustrative embodiments thereof, it is not intended that the invention be limited to those illustrative embodiments. Those skilled in the art will recognize that variations and modifications can be made without departing from the spirit of the invention. It is therefore intended to include within the invention all such variations and modifications that fall within the scope of the appended claims and equivalents thereof.