A Hermetic, Insecticidal Food Storage Bag, Use of It and a Method for Its Production

Abstract

A crop storage bag (1) made is of a high-strength textile (7) material which is extrusion-coated or laminated with a multilayer film (8) that comprises an insecticidal layer (9) in addition to a hermetic layer (10) which prevents oxygen from entering the bag. This oxygen barrier suffocates the insects inside the bag, and the insecticide kills insects that try to bore through the bag.

Claims

1. A method for producing a hermetic insecticidal crop storage textile bag (1), the bag comprising an inner side facing an inner volume and an opposite outer side facing the environment, wherein the method comprises providing the bag (1) with a polymer multilayer film (8, 18) only on the outer side; wherein the multilayer film (8) comprises an insecticidal polymer layer (9) in which an insecticide is melt-incorporated for preventing intrusion of insects into the bag (1) by the insecticidal polymer layer (9); wherein the method comprises including at least one oxygen barrier polymer layer (10) in the multilayer film (8, 18) for providing an Oxygen Transmission Rate, OTR, through the multilayer film (8) sufficiently low for preventing breeding or killing potential insects inside the bag (1) when the bag (1) is in closed condition.

2. A method according to claim 1, wherein the method comprises providing the multilayer film with an OTR less than 300 ccm/m2/day.

3. A method according to claim 1, wherein the method comprises providing a sheet of textile (7) for the bag and either extrusion-coating a multilayer stream (8) of molten polymer onto the textile (7) and solidifying the stream into the multilayer film (8) or laminating the multilayer film (18) onto the textile.

4. A method according to claim 2, wherein the method comprises providing the sheet of textile as an endless textile (7) web, flattening the textile (7) web into a flat two-layer textile web (15) with two opposite outer sides, and covering both outer sides with the multilayer film (8, 18) by the lamination or the extrusion-coating; wherein the insecticidal layer (9) is provided by a first thermoplastic polymer, and the oxygen barrier layer (10) is provided by a second thermoplastic polymer that is different from the first thermoplastic polymer; wherein the method comprises orienting the multilayer film (8, 18) with the oxygen barrier (10) between the textile (7) web and the insecticidal first polymer layer (9) for protecting the oxygen barrier (10) by the insecticidal first polymer layer (9).

5. A method according to claim 3, wherein the method comprises providing the endless textile (7) web as a seamless tubular textile web and coating the multilayer film (8, 18) onto the web, and then cutting (21) the web into portions, each portion for one bag, and finally closing one end (4) of the portion for providing a bag (1) with a closed seam (22, 23, 24) only at the bottom (3) or finally closing opposite ends of the portion for providing a bag (1) with a closed seam (22, 23, 24) at the bottom (3) and at the top of the bag (1) but no seam on a side of the bag (1) from the bottom to the top.

6. A method according to claim 3, wherein the method comprises providing the multilayer film (8, 18) with a width that is larger than the flattened web (15) in order for the multilayer films (8, 18) being fused on opposite sides of the web along and outside both edges (15A) of the web for providing a tight sealing along the web.

7-10. (canceled)

11. A method according to claim 1, wherein the method comprises providing the multilayer film (8) on the textile (7) as a four-layer structure with an inner bonding layer (11) towards the textile (7) web on one side of the EVOH oxygen barrier layer (10), and a second bonding layer (11) on the opposite side of the EVOH for bonding the EVOH to the insecticidal polyethylene or polypropylene first polymer layer (9).

12-13. (canceled)

14. A method according to claim 1, wherein the coating of the multilayer film (8) is provided as a lamination process that comprises melting the first and the second polymer in an extruder (17) and co-extruding the two layers (9, 10) as part of a multilayer stream (18), cooling the multilayer stream (18) to form a multilayer film (18) and rolling the multilayer film (18) onto rollers (19); at the lamination location, rolling the multilayer film (18) from the roller and laminating it onto the textile (7); laminating an additional outer polymer film layer (25) onto the multilayer film (18), which comprises a surface print but no insecticide.

15. (canceled)

16. A method according to claim 1, wherein the method comprises selecting the insecticide for the insecticidal layer among insecticides that are capable of migrating in the first thermoplastic polymer.

17. (canceled)

18. A hermetic insecticidal crop storage textile bag (1) with an inner side facing an inner volume and an opposite outer side facing the environment, wherein the bag (1) comprises a textile (7) sheet with an outer side covered with an extrusion-coated or laminated polymer multilayer film (8, 18), the film (8, 18) comprising an insecticidal layer (9) of a first thermoplastic polymer layer (9) containing an insecticide for preventing intrusion of insects into the bag by the insecticidal layer; wherein the multilayer film (8, 18) also comprises at least one oxygen barrier layer (10) made of a second thermoplastic polymer in order for the multilayer film (8) with the oxygen barrier layer (10) having an Oxygen Transmission Rate, OTR, sufficiently low for preventing breeding or killing potential insects inside the bag (1) when the bag (1) is in closed condition.

19. A textile bag according to claim 18, wherein the OTR is less than 300 ccm/m2/day at atmospheric pressure.

20-22. (canceled)

23. A textile bag according to claim 18, wherein the oxygen barrier layer (10) is between the textile (7) web and the insecticidal first polymer layer (9) for protecting the oxygen barrier layer (10) by the insecticidal first polymer layer (9); wherein the insecticidal first polymer has melt-incorporated therein the insecticide.

24. A textile bag according to claim 23, wherein the insecticide is capable of migrating in the first thermoplastic polymer.

25-29. (canceled)

30. A textile bag according to claim 18, wherein the multilayer film (8) is covered by an additional outer polymer film layer (25) comprising a surface print but no insecticide.

31. (canceled)

32. A textile bag according to claim 18, wherein the insecticide is deltamethrin.

33. (canceled)

Description

SHORT DESCRIPTION OF THE DRAWINGS

[0129] The invention will be explained in more detail with reference to the drawing, where FIG. 1 illustrates a textile bag with a hermetic insecticidal coating;

[0130] FIG. 2 illustrates an example of production process for a seamless tubular textile,

[0131] FIG. 3 illustrates an example of a extrusion-coating process,

[0132] FIG. 4 illustrates a) the extrusion of a multilayer film and its rolling onto a roller and b) an example of a lamination process;

[0133] FIG. 5 illustrates a production process for forming a bag, where the tubular bag material is a) cut and b) the cut ends are folded and fixed for providing a closed bottom, or alternatively c) a folded end-sealing strip added, or as a further alternative d) the ends are sealed by a welding.

DETAILED DESCRIPTION/PREFERRED EMBODIMENT

[0134] FIG. 1 illustrates a bag 1 with a tubular polymer sheet material 2 that has a closed bottom 3. For example, the bottom 3 has been provided by flattening the tubular material 2 and closing an end part 4 of it, for example by welding, gluing, sewing, or a combination of one or more of these. The bag 1 has an upward opening 5 that is open and ready for filling foodstuff into the bag 1, for example crop products, such as grains or rice.

[0135] A cross section 6 is shown enlarged to the right of the bag 1, although, not to scale. The sheet material 2 of the bag 1 comprises a textile 7 and a thermoplastic polymer multilayer film 8 coated onto the outer side of the textile 7. As the textile 7 is tubular, coating the outer side of the tubular textile 7 is much easier than coating the inside. This will become more apparent below when examples are given for production processes.

[0136] For example, the textile 7 is a weave of the type where flat yarns are interwoven. Such flat yarns are typically produced by extruding a thermoplastic polymer film, typically stretching the film for orienting the polymer for increased strength, and cutting the film into narrow strips, for example with a width in the range of 3-5 mm, which are then rolled onto bobbins from which they are later used for weaving.

[0137] Examples of polymer materials are polyolefins, for example polyethylene (PE) or polypropylene (PP). Examples of PE include High Density PolyEthylene (HDPE), Low Density PolyEthylene (LDPE), or Linear Low Density PolyEthylene (LLDPE), and mixtures thereof. Alternatives include polyester (PolyEthylene Terephtalate, PET). The list is not exhaustive.

[0138] In FIG. 1, also an example of a coating is illustrated, where the coating is a multilayer polymer film 8 with an outer insecticidal layer 9 that also add strength to the bag 1. Useful polymers for the insecticidal layer 9 are polyolefins, optionally PP and PE, for example LDPE or LLDPE.

[0139] Other layers of the multilayer film 8 comprise an oxygen barrier 10, for example ethylene vinyl alcohol (EVOH). An alternative is polyamide (PA). However, when using PP or PE for the insecticidal first polymer layer, EVOH has some advantages in the production process over PA which will be described in more detail below. For better bonding, the oxygen barrier 10 is, optionally, sandwiched between bonding layers 11, 11, also called tie-layers. Further additional layers are possible, however, the simple four layer structure has proven useful and sufficient.

[0140] FIG. 2 illustrates a possible production process for the textile 7. In a weaving station 12, flat yarns 13 are supplied from a plurality of bobbins 14 for weaving of the tubular woven textile 7. The tubular textile 7 is collapsed into a double layered flattened structure 15. A typical material for the flat yarns is a polyolefin, for example PP or PE, although, also PET is a good candidate. Typically, the textile 7 is provided at a separate location than the coating and, therefore, rolled onto rollers 16, which are then transported to the coating location and unrolled as needed. As an alternative to a woven textile 7, a knitted or non-woven tubular textile is also a possibility.

[0141] In some embodiments, for the production, the multilayer film is co-extruded as a multilayer stream and cooled for solidification, potentially stretched for orientation of the polymer, and then rolled onto rollers. In a subsequent step, the film is rolled off the rollers and laminated onto the weave.

[0142] In order to shortcut the process and for increased adhesion between the textile 7 and the multilayer film 8, the multilayer film 8 is co-extruded as a multilayer stream and, while the film 8 from the extruder is still in a molten or partially molten state, laid onto the textile 7 where it solidifies. This process is typically called extrusion-coating. This method is simpler in that it avoids a solidification process of the multilayer film 8 after co-extrusion, the rolling of the multilayer film 8 onto rollers, possible transport of the rollers, and a subsequent lamination process.

[0143] FIG. 3 illustrates such extrusion-coating process as part of an exemplified production. In more detail, the production is as follows. For the coating, a multilayer co-extruder system 17 is provided, which in the exemplified case comprises three screw-extruders 17A, 17B, 17C. One extruder 17A is used for the two tie layers 11, 11, one extruder 17B for the polymer of the oxygen barrier 10, for example EVOH, and one extruder 17C containing the polymer for the insecticidal first polymer layer 9, for example PP or PE. The molten polymers from the three extruders 17A, 17B, 17C are combined by co-extrusion into a molten multilayer stream 8 of the type as illustrated in FIG. 1 for the multilayer film 8 without mixing of the polymers. Thus, the extruded multilayer stream 8 keeps its multilayer structure until it in molten or partially molten state is laid down on the flattened structure 15 as a coating, bonded to the textile 7, and solidified as a multilayer film 8 on the textile 7. In order to coat both sides of the flattened structure 15, a similar extruder system 17 is provided further downstream. The final material 2 is a tubular woven textile 7 with a multilayer film 8 covering the outer surface of the textile 7.

[0144] Optionally, while the multilayer stream 8 is still in molten or partially molten state, it can be used as a bonding layer for one or more additional outer polymer layers 25, for example a printed BOPP layer.

[0145] Alternatively, such one or more additional outer polymer layers 25 are laminated onto the final multilayer film 8 in a subsequent step, for example with an additional bonding layer in between. This method can also be used in connection with the embodiment of FIG. 4b, although not illustrated.

[0146] FIG. 4a illustrates an alternative process, in which a multilayer film 18 is extruded as a multilayer stream 18, potentially stretched for orientation of the polymer, and after cooling and solidification in a cooling step 20, rolled onto rollers 19. As illustrated in FIG. 1, the multilayer film 18 in FIG. 4a does not comprise the bonding layer 11 that is used to bond the multilayer film 18 of FIG. 4a to the textile 7.

[0147] FIG. 4b illustrates a subsequent step, in which the multilayer film 18 without the inner bonding layer 11 is rolled off the rollers 19 and laminated onto the textile 7 by adding the still molten or partially molten bonding layer 11 from the extruder 17 between the multilayer film 18 and the flattened structure 15 of the textile 7. Also, this process is used on both sides of the flattened structure 15, which comprises two layers of textile 7.

[0148] Optionally, an outer polymer layer, for example a printed BOPP layer, or several layers is/are laminated onto the textile (7) in a subsequent step after having laminated the multilayer film (8) onto the textile.

[0149] FIG. 5a illustrates the textile 7 with the multilayer film 8 from a top view. It is observed that the multilayer film 8 comprises an overlay 8A that extends beyond the edge 15A of the flatted structure 15 of the textile 7. This makes sure that there is a tight bonding of the multilayer film 8 along and around the textile 7. The flattened structure 15 is cut along predetermined transverse paths 21.

[0150] FIG. 5b illustrates one way of closing the bottom 3, where a fold 22 is provided at the end part 4 which is fixed for providing a sealed bottom 3 of the bag 1.

[0151] In the case of the outermost film layer 9 being a polyolefin, especially PE or PP, it is ultrasound or heat weldable for a proper sealing. Alternative or additional sealing includes sewing or gluing.

[0152] FIG. 5c illustrates an alternative closure of the end part 4 where a sealing strip 23 is folded over the bottom part of the sheet material 2 across the entire sheet material 2 and then sealed against the polymer sheet material 2 of the bag 1 in order to provide a sealed bottom 3, for example by at least one of welding, gluing and sewing. The sealing strip 21 is typically a polymer film, for example PE or PP, which is weldable against at least the outer first polymer layer 9 of the multilayer film 8.

[0153] FIG. 5d illustrates an even further closure of the end part 4, wherein a welding 24, for example ultrasonic welding or heat welding, is provided through and across the double layer flattened structure 15, where the welding fuses the two textile 7 layers of the double layer flattened structure 15, typically including the multilayer film 8.

[0154] Optionally, the active agent in the outer insecticidal layer 9 is added to the extruder prior to extrusion of the polymer.

[0155] Examples of insecticides include pyrethroids, optionally permethrin or deltamehrin (DM).

[0156] With respect to the oxygen barrier 10, EVOH is advantageous, when combined in the multilayer film 8 with an insecticidal layer 9 of PE or PP because the necessary extrusion temperatures for EVOH and PA or PP are similar. In contrast thereto, PA has a higher extrusion temperature, which makes the process not only more difficult, but which also increases the temperature of the PE or PP, which can be detrimental for the insecticide in such layers. Especially, DM is heat sensitive.

[0157] For example, extrusion temperatures of the PE or PP multilayer film with EVOH is in the range of 250-270 C. in order to provide good adhesion to the textile 7, for example PE or PP weave. An improvement has been found by heating the textile 7 to a temperature of 70-80 degrees so that the cooling of the extruded multilayer stream 8 into a multilayer film 8 is slowed down. In this case, the extrusion temperature can be lowered to 220-250 C. for PP as the insecticidal first polymer layer or to 200-230 C. for PE, optionally LDPE. Both ranges are suitable for EVOH as well. The lower temperature is beneficial for insecticide in the insecticidal first polymer layer, especially pyrethroids, such as DM, which is heat sensitive and quickly degrades at such elevated temperatures. It should be noticed that such temperatures are not suitable for PA extrusion, as PA need a much higher extrusion temperature, why EVOH also from this standpoint is superior to PA as an oxygen barrier when combined with PE or PP.

[0158] In experiments, layer thicknesses of 5 microns for the bonding tie layers and EVOH layers, respectively, and 15 microns for the outer insecticidal layer were found practical. This is remarkable, and it must be stressed that a 5 micron EVOH layer cannot be handled properly in isolation, why the stabilizing and strength-giving multilayer film 8 with the thicker outer insecticidal layer 9 is highly advantageous. There is an interest to keep the layer thickness small in order to minimize weight and production costs. On the other hand, the multilayer film 8 cannot be made too thin, as the film stability is then lost. For extrusion coating as well as for lamination, such multilayers have proven feasible.

[0159] In successful experiments, the overall weight of the film 8 was about 30 g/m2, which is much less than the thickness of 60 micron and weight of 60 g/m2 of the prior art liner that is inserted into an outer strength giving woven bag. By incorporating insecticide and/or insect repellent and optionally rodenticide in the outer insecticidal layer 9, an efficient barrier was provided against insects and potentially rodents which are attempting to make their way through the bag material 2.

[0160] When providing the textile 7 as a seamless tubular web, the stability is higher than a bag with a seam along the side of the bag. Furthermore, the coating adds to the stability of the textile, why also the textile could be made thinner than in the prior art where the complete bag is provided as a double bag with an outer strength-giving textile bag and an oxygen barrier as an inner film bag.

[0161] As already mentioned, reduction of weight and cost while having high and long term stability are important features for this type of product. Accordingly, also from this perspective, the extrusion-coated textile proved synergistic effects by the production method.

REFERENCE NUMBERS

[0162] 1 bag [0163] 2 sheet material [0164] 3 bottom of bag 1 [0165] 4 end part of tubular weave 7 [0166] 5 upward opening of bag 1 [0167] 6 cross section [0168] 7 textile, for example tubular polymer weave [0169] 8 multilayer film [0170] 8 multilayer stream [0171] 8A overlay of multilayer film 8 [0172] 9 insecticidal first polymer layer [0173] 10 second polymer oxygen (02) barrier [0174] 11 bonding layer between O2 barrier 10 and insecticidal layer 9 [0175] 11 bonding layer between O2 barrier 10 and textile 7 [0176] 12 weaving station [0177] 13 flat yarns [0178] 14 bobbins [0179] 15 flattened weave structure [0180] 16 roll of textile [0181] 17 multilayer extruder system [0182] 17A extruder for tie layers [0183] 17B extruder for oxygen barrier 10 [0184] 17C extruder for insecticidal layer 9 [0185] 17 extruder for bonding layer 11 [0186] 18 multilayer film for lamination [0187] 18 multilayer stream of multilayer film 18 for lamination [0188] 19 roller of multilayer film 18 for lamination [0189] 20 cooling area for multilayer stream 18 [0190] 21 transverse path of cut [0191] 22 bent part at bottom 3 [0192] 23 bottom sealing strip [0193] 24 welding, illustrated as a double line welding, for example ultrasonic [0194] 25 additional outer polymer layer(s)