Core-shell Nanoparticles and Their Use in Electrochemical Cells
20200335778 ยท 2020-10-22
Inventors
- Jackie Y. Ying (Singapore, SG)
- Jinhua Yang (Singapore, SG)
- Karim ZAGHIB (Montreal, CA)
- Michel L. TRUDEAU (Montreal, CA)
Cpc classification
H01M4/62
ELECTRICITY
B82Y40/00
PERFORMING OPERATIONS; TRANSPORTING
H01M4/0471
ELECTRICITY
H01M4/131
ELECTRICITY
H01M4/1391
ELECTRICITY
B82Y30/00
PERFORMING OPERATIONS; TRANSPORTING
Y02E60/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M10/0525
ELECTRICITY
International classification
H01M10/0525
ELECTRICITY
H01M4/36
ELECTRICITY
Abstract
Here are described core-shell nanoparticles comprising a porous core, a shell layer and sulfur diffused through the pores of the porous core, their use in electrode materials as well as their methods of preparation. Also described are composite materials, electrode materials, electrodes, and electrochemical cells comprising the core-shell nanoparticles and their use in lithium sulfur batteries.
Claims
1. Core-shell nanoparticles comprising a porous metal oxide core of formula M.sub.yO.sub.x, wherein M defines at least one transition metal, y is an integer selected from 1 to 4, and x is an integer selected from 1 to 8, x and y being selected to achieve electroneutrality; elemental sulfur (Ss) as an electrochemically active material, the elemental sulfur being incorporated into the pores of the metal oxide core; and an outer shell surrounding the core, the outer shell comprising TiO.sub.2.
2. The core-shell nanoparticles of claim 1, wherein M is Mn, Fe, Co, Ni, Zn or a combination thereof; y is an integer from 1 to 3; and x is an integer from 1 to 7.
3. The core-shell nanoparticles of claim 2, wherein M is Mn or wherein MA is MnO.
4. (canceled)
5. The core-shell nanoparticles of claim 1, wherein the TiO.sub.2 is in an amorphous form and/or wherein the metal oxide comprised in the core is in a crystalline form and/or wherein the nanoparticles have a cube-like morphology.
6.-7. (canceled)
8. The core-shell nanoparticles of claim 1, wherein a M:Ti molar ratio is about 10:1 to about 0.5:1, preferably about 4:1 to about 0.7:1, preferably about 3:1 to about 0.7:1, and most preferably about 2:1 to about 0.8:1.
9. The core-shell nanoparticles of claim 1, wherein an average size of the core-shell nanoparticles is in a range from about 10 nm to about 500 nm, preferably about 75 nm to about 200 nm, and an average thickness of the shell of the core-shell particle is in a range of about 1 nm to about 50 nm, preferably about 5 nm to about 20 nm.
10. The core-shell nanoparticles of claim 1, wherein the elemental sulfur comprises sulfur nanocrystals.
11. A nanocomposite material comprising the core-shell nanoparticles as defined in claim 1 and a first conductive nanomaterial.
12. The nanocomposite material of claim 11, wherein the core-shell nanoparticles are supported on the first conductive material.
13. The nanocomposite material of claim 11, wherein the first conductive nanomaterial is a conductive nanocarbon nano-wire, nano-sheet, nano-belt, or a combination thereof.
14. The nanocomposite material of claim 11, wherein the first conductive nanomaterial is a reduced graphene oxide nanosheet or a graphene nanosheet of a lateral size of about 50 nm to about 500 nm, preferably 100 nm to about 200 nm.
15. The nanocomposite material of claim 11, wherein a weight ratio of the first conductive nanomaterial to the nanoparticles excluding sulfur is about 1:1 to about 1:10, preferably about 1:2 to about 1:4 and/or wherein a weight ratio of sulfur to the nanocomposite material excluding sulfur is about 10:1 to about 1:2, preferably about 3:1 to about 1:1.
16. (canceled)
17. A method for producing core-shell nanoparticles as defined in claim 1 or a nanocomposite material comprising the core-shell nanoparticles and a first conductive nanomaterial, the method comprising: (a) contacting M.sub.y(CO.sub.3).sub.x nanoparticles with TiO.sub.2 or a TiO.sub.2 precursor to form TiO.sub.2 coated M.sub.y(CO.sub.3).sub.x nanoparticles (M.sub.y(CO.sub.3).sub.x/TiO.sub.2); (b) thermally treating the M.sub.y(CO.sub.3).sub.x/TiO.sub.2 nanoparticles from step (a) at elevated temperature under inert gas to form core-shell M.sub.yO.sub.x/TiO.sub.2 nanoparticles; (c) optionally thermally treating the core-shell M.sub.yO.sub.x/TiO.sub.2 nanoparticles with a first conductive nanomaterial under inert gas at elevated temperature, optionally in the presence of hydrogen gas, to form a nanocomposite material; (d) optionally partly removing M.sub.yO.sub.x after step (b) or (c) by treatment with an acid; (e) milling the obtained nanoparticles or nanocomposite material of step (b), (c), or (d) with elemental sulfur (Ss) to produce a mixture; and (f) heating the mixture obtained in step (e) at elevated temperature under inert gas to cause the sulfur to melt-diffuse into the pores of the nanoparticles and/or nanocomposite material.
18. (canceled)
19. The method of claim 17, wherein the TiO.sub.2 precursor is at least one organotitanium compound selected from the group consisting of titanium tetraisopropoxide, titanium tetra-n-butoxide, titanium tetrakis(2-ethylhexyloxide), titanium tetrastearyloxide, titanium acetylacetonate, titanium ethyl acetoacetate, salicylaldehyde ethyleneimine titanate, diacetone alkoxy titanium, octylene glycoxy titanium, triethanolamine titanate, titanium lactate, monocyclopentadienyltitanium trihalides, dicyclopentadienyltitanium dihalides, cyclopentadienyltitanium trimethoxide, cyclopentadienyltitanium triethoxide, and cyclopentadienyltitanium tripropoxide.
20. (canceled)
21. The method of claim 17, wherein the nanoparticles or nanocomposite material before the milling step has specific surface area measured by Brunauer-Emmett-Teller (B.E.T.) of about 40 m.sup.2/g to about 150 m.sup.2/g, or of about 60 m.sup.2/g to about 120 m.sup.2/g, preferably about 80 m.sup.2/q to about 100 m.sup.2/g and/or wherein the acid is a mineral acid, preferably H.sub.2SO.sub.4 or HCl, preferably used in a concentration of 0.1 M to 5 M.
22. (canceled)
23. The method of claim 17, wherein each thermal treatment step is independently performed at a temperature of about 200 C. to about 500 C., preferably about 300 C. to about 400 C. and/or wherein the heating step is performed at a temperature of about 140 C. to about 180 C. for about 5 hours to about 48 hours.
24.-25. (canceled)
26. An electrode material comprising core-shell nanoparticles as defined in claim 1 or a nanocomposite material comprising said core-shell nanoparticles and a first conductive nanomaterial.
27. The electrode material of claim 26, further comprising a second conductive material, a binder, and optionally one or more additives.
28. The electrode material of claim 27, wherein the second conductive material is selected from the group consisting of carbon black, carbon Ketjen acetylene black, graphite, graphene, carbon fibers (such as carbon nanofibers or VGCF), carbon nanotubes, and a combination of at least two of these and/or wherein the binder material is selected from the group consisting of a polymeric binder of the polyether type, a fluoropolymer, a water-soluble binder, and a combination thereof.
29. (canceled)
30. The electrode material of claim 28, wherein the polyether type polymer binder is a linear, branched, and/or crosslinked polymer based on polyethylene oxide (PEO), poly(propylene oxide) (PPO) or a mixture of the two (or an EO/PO copolymer), and optionally comprises crosslinkable units or wherein the water-soluble binder is SBR (styrene-butadiene rubber), NBR (acrylonitrile-butadiene rubber), HNBR (hydrogenated NBR), or CHR (epichlorohydrin rubber) acrylate), optionally comprising CMC (carboxymethylcellulose.
31.-32. (canceled)
33. A positive electrode comprising the electrode material claim 26 on a current collector.
34. An electrochemical cell comprising the positive electrode as defined in claim 33, a negative electrode, and an electrolyte.
35. (canceled)
36. A lithium sulfur battery comprising at least one electrochemical cell as defined in claim 34.
37. A lithium sulfur battery comprising the core-shell nanoparticles as defined in claim 1 or a nanocomposite material comprising said core-shell nanoparticles and a first conductive nanomaterial.
38. (canceled)
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
[0032] The following detailed description and examples are illustrative and should not be interpreted as further limiting the scope of the invention.
[0033] All technical and scientific terms and expressions used herein have the same definitions as those commonly understood by the person skilled in the art relating to the present technology. The definition of some terms and expressions provided below take precedence over their common meaning given in the literature.
[0034] The expressions nanocomposite material and nanocomposite used herein refer to a material made from at least two constituent materials with significantly different physical or chemical properties that, when combined, produce a material with characteristics different from the individual components.
[0035] The term nano as used herein refers to an object having a nanoscale size (e.g., not more than 100 or not more than 500 nm) at least in one direction.
[0036] Unless mentioned otherwise, all ratios mentioned in the present application are weight ratios.
[0037] When an interval of values is mentioned in the present application, the lower and upper limits of the interval are, unless otherwise indicated, always included in the definition.
[0038] The term approximately or the equivalent term about as used herein means approximately in the region of, and around. When the term approximately or about is used in relation to a numerical value, it modifies it, for example, above and below by a variation of 10% in relation to the nominal value. This term may also take into account, for example, the experimental error of a measuring apparatus or rounding.
[0039] This application relates to core-shell nanoparticles (NPs) for use in the manufacture of electrochemical cells, particularly in lithium-sulfur (LiS) electrochemical cells; and their methods of synthesis.
[0040] The present application thus proposes core-shell NPs which may be used in composite electrodes to improve the cyclability and to prevent electrochemical cells degradation.
[0041] The present application, for example relates to core-shell NPs comprising a porous nanocrystalline metal oxide (of formula M.sub.yO.sub.x) core which incorporates elemental sulfur (S.sub.8) as an electrochemically active material and an amorphous TiO.sub.2 outer shell. For example, core-shell NPs exhibit cubic or cubic-like morphology (e.g. rhombohedral). In one embodiment, the core-shell NPs may be deposited on a conductive nanomaterial, for instance, reduced graphene oxide (RGO) to form RGO-supported M.sub.yO.sub.x/TiO.sub.2 core-shell (M.sub.yO.sub.x/TiO.sub.2/RGO-S) nanocomposites which can be used in cathode materials of electrochemical cells with advantageous capabilities.
[0042] The uniqueness of these materials lies at least in (i) the amorphous TiO.sub.2 shell, which absorbs the volume expansion upon lithiation, and alleviates the Li.sub.2S.sub.x dissolution, and (ii) the porous nanocrystalline M.sub.yO.sub.x core, e.g. mesoporous, which provides strong chemical interactions with the lithium Li.sub.2S.sub.x ions. The M.sub.yO.sub.x/TiO.sub.2/RGO-S nanocomposites with different M:Ti molar ratios demonstrated good capacity, coulombic efficiency and cycling stability.
[0043] The present application, for example also relates to the synthesis of core-shell NPs defined herein via a wet chemical method. For instance, the process includes the preparation of monodispersed M.sub.y(CO.sub.3).sub.x nanoparticles, for example, via a microemulsion-mediated solvothermal synthesis. These M.sub.y(CO.sub.3).sub.x nanoparticles are then coated with a thin amorphous TiO.sub.2 layer using a wet chemical step by reacting the nanoparticles with a titanium oxide precursor, such as an organotitanium compound, in the presence of water. The M.sub.y(CO.sub.3).sub.x/TiO.sub.2 nanoparticles are then thermally treated, e.g. annealed, to afford M.sub.yO.sub.x/TiO.sub.2 core-shell nanoparticles. Without wishing to be bound by theory, one could believe that the elimination of CO.sub.2 during this last process step would contribute to the formation of a porous, e.g. mesoporous, core structure. The present description therefore also further relates to M.sub.yO.sub.x/TiO.sub.2 core-shell nanoparticles, wherein the core M.sub.yO.sub.x is porous (or mesoporous) and crystalline and the shell comprises TiO.sub.2 in amorphous form.
[0044] In another example, these core-shell NPs are used as intermediate to encapsulate elemental sulfur (S.sub.8), the S.sub.8 being incorporated in the core-shell NPs using a melt diffusion method. The synthesis of nanoparticles with several M:Ti molar ratio is also demonstrated in the present application as well as its effect on the performance of electrochemical cells.
[0045] The core-shell NPs as described herein have a porous core which allows for the incorporation of elemental sulfur (S.sub.8). NPs can exhibit improved sulfur absorption capabilities which is highly dependent upon porosity and pore size distribution. In one embodiment, the number and/or size of pores can be increased by the partial removal of M through acidic treatment, thereby reducing the M:Ti molar ratio and leading to improved sulfur absorption capabilities. The NPs can also be annealed with conductive nanomaterials beforehand and the elemental sulfur may then be diffused therein as well. The resulting nanocomposite materials can be used as high-capacity cathode materials for lithium sulfur batteries.
[0046] The porous M.sub.yO.sub.x core reduces or prevents leakage of soluble polysulfide ions during battery operation from the core-shell NPs by adsorbing them in the M.sub.yO.sub.x core. The NPs also show a tolerance for volume expansion under operation conditions of the lithium batteries.
[0047] The present application proposes core-shell nanoparticles comprising [0048] a porous metal oxide core of formula M.sub.yO.sub.x; [0049] elemental sulfur (S.sub.8) as an electrochemically active material, the elemental sulfur being incorporated into the pores of the porous metal oxide core; and [0050] an outer shell surrounding the core, the outer shell comprising TiO.sub.2.
[0051] M defines at least one transition metal, y is an integer selected from 1 to 4 and x is an integer selected from 1 to 8, x and y being selected to achieve electroneutrality.
[0052] In one example, M is Mn, Fe, Co, Ni, Zn, or a combination thereof; y is an integer selected from 1 to 3; and x is an integer selected within the range of from 1 to 7.
[0053] Non-limiting examples of metal oxide cores of formula M.sub.yO.sub.x include manganese(II) oxide (MnO), manganese oxide (Mn.sub.2O.sub.4), manganese(II,III) oxide (Mn.sub.3O.sub.4), manganese(III) oxide (Mn.sub.2O.sub.3), manganese dioxide (MnO.sub.2), manganese(VI) oxide (MnO.sub.3), manganese(VII) oxide (Mn.sub.2O.sub.7), iron(II) oxide (FeO), iron(III) oxide (Fe.sub.2O.sub.3), iron(II,III) oxide (Fe.sub.3O.sub.4), cobalt(II) oxide (CoO), cobalt(III) oxide (Co.sub.2O.sub.3), cobalt(II,III) oxide (Co.sub.3O.sub.4), nickel(II) oxide (NiO), nickel(III) oxide (Ni.sub.2O.sub.3) and the like. For example, M is Mn, e.g. M.sub.yO.sub.x is MnO.
[0054] In one embodiment, the TiO.sub.2 shell is in amorphous form, the metal oxide comprised in the core is in a crystalline form and the NPs have a cube-like morphology. In another example, the elemental sulfur comprises sulfur nanocrystals.
[0055] For example, the core-shell NPs as defined herein, have a M:Ti molar ratio of about 10:1 to about 0.5:1, preferably about 4:1 to about 0.7:1, preferably about 3:1 to about 0.7:1 and most preferably about 2:1 to about 0.8:1.
[0056] In another example, the core-shell NPs as defined herein, have an average size in the range of from about 10 to about 500 nm, preferably from about 75 to about 200 nm and an average shell thickness in the range of from about 1 to about 50 nm, preferably from about 5 to about 20 nm. The metal oxide core of the present nanoparticles has a porous morphology, for instance, a mesoporous morphology (i.e. pores having an average size below 50 nm). The specific surface area of the core-shell NPs before sulfur insertion, as measured by Brunauer-Emmett-Teller (B.E.T.), is between about 20 and about 150 m.sup.2/g, or between about 30 and about 100 m.sup.2/g, or between about 30 and about 60 m.sup.2/g.
[0057] In another embodiment, a nanocomposite material is also contemplated, where the nanocomposite material comprises the core-shell NPs as described herein together with a first conductive agent. For instance, the nanocomposite material comprising the core-shell NPs as defined herein, wherein the nanoparticles are thermally treated with, e.g. annealed to, the first conductive nanomaterial. For instance, the NPs are supported on the first conductive material. Such nanocomposites have been shown to provide high capacity and cycling stability in electrochemical cells.
[0058] In one embodiment, the first conductive nanomaterial is a conductive nanocarbon nano-wire, nano-sheet, nano-belt, or a combination thereof. The first conductive nanomaterial is selected for its ability to improve the electrical conductivity of the NPs. For example, the first conductive nanomaterial is a reduced graphene oxide (RGO) nanosheet or a graphene nanosheet having a lateral size of about 50 to about 500 nm, preferably of about 100 to about 200 nm wherein the first conductive nanomaterial to NPs (excluding sulfur) weight ratio is about 1:1 to about 1:10, preferably about 1:2 to about 1:4. In another embodiment, the nanocomposite material has specific surface area measured by Brunauer-Emmett-Teller (B.E.T.) of about 50 m.sup.2/g to about 150 m.sup.2/g, or about 50 m.sup.2/g to about 100 m.sup.2/g, preferably about 80 to about 100 m.sup.2/g, before addition of sulfur to the material. In another embodiment, the weight ratio of sulfur to the nanocomposite material before sulfur insertion is about 10:1 to about 1:2, preferably about 3:1 to about 1:1.
[0059] The core-shell NPs may be made through different methods. One method for the preparation of the present core-shell nanoparticles includes the steps of preparing core-shell M.sub.yO.sub.x/TiO.sub.2 nanoparticles, wherein the M.sub.yO.sub.x core is porous (e.g. mesoporous) and the TiO.sub.2 shell in amorphous; mixing the M.sub.yO.sub.x/TiO.sub.2 nanoparticles with elemental sulfur; and heating at a temperature allowing the sulfur to melt and diffuse into the pores of the core. One method for preparing core-shell nanoparticles or nanocomposite materials as herein defined involves:
[0060] (a) contacting M.sub.y(CO.sub.3).sub.x nanoparticles with TiO.sub.2 or a TiO.sub.2 precursor to form TiO.sub.2 coated M.sub.y(CO.sub.3).sub.x nanoparticles (i.e. M.sub.y(CO.sub.3).sub.x/TiO.sub.2);
[0061] (b) thermally treating (e.g. annealing) the M.sub.y(CO.sub.3).sub.x/TiO.sub.2 nanoparticles from step (a) at elevated temperature under inert gas to form core-shell M.sub.yO.sub.x/TiO.sub.2 nanoparticles;
[0062] (c) optionally thermally treating (e.g. annealing) the core-shell nanoparticles with a first conductive nanomaterial under inert gas at elevated temperature, optionally in the presence of hydrogen gas, to form a nanocomposite material;
[0063] (d) optionally partly removing M.sub.yO.sub.x after step (b) or (c) by treatment with an acid;
[0064] (e) milling the obtained nanoparticles or nanocomposite material with elemental sulfur (S.sub.8) to produce a mixture; and
[0065] (f) heating the obtained mixture obtained in step (e) at elevated temperature under inert gas to cause the sulfur to melt-diffuse into the pores of the nanoparticles and/or nanocomposite material.
[0066] The above process may further include step (c) or step (d) or both of steps (c) and (d) in any order. When step (c) is present, then the product obtained is a nanocomposite material.
[0067] For example, the acid of step (d) is a mineral acid, preferably H.sub.2SO.sub.4 or HCl, preferably used in a concentration of 0.1 to 5 M. In another example, the thermal treatment steps (b) and (c) when present, are performed each independently at a temperature of about 200 to about 500 C., preferably about 300 to about 400 C. and the heating step (f) is performed at a temperature of about 140 to about 180 C. for about 5 to about 48 hours.
[0068] Another method for producing the nanoparticles or nanocomposite material herein described, e.g. MnO/TiO.sub.2S, MnO/TiO.sub.2-acid-S, MnO/TiO.sub.2/RGO-S, or MnO/TiO.sub.2/RGO-acid-S, involves:
[0069] (a) synthesizing of MnCO.sub.3 nanoparticles by a microemulsion-mediated solvothermal reaction;
[0070] (b) reacting the MnCO.sub.3 nanoparticles from step (a) in a polar solvent with a TiO.sub.2 precursor, preferably an organotitanium compound, to produce MnCO.sub.3/TiO.sub.2 nanoparticles;
[0071] (c) thermally treating (e.g. annealing) the MnCO.sub.3/TiO.sub.2 nanoparticles at elevated temperature under inert gas to produce core-shell MnO/TiO.sub.2 nanoparticles;
[0072] (d) optionally thermally treating (e.g. annealing) the MnO/TiO.sub.2 core-shell nanoparticles with a first conductive nanomaterial under inert gas at elevated temperature, optionally in the presence of hydrogen gas, to form a nanocomposite material;
[0073] (e) optionally partly removing MnO after step (c) or (d) by treatment with an acid;
[0074] (f) milling the nanoparticles or nanocomposite obtained in step (c), (d) or (e) with elemental sulfur to produce a mixture; and
[0075] (g) heating the mixture obtained in step (f) at elevated temperature under inert gas to cause the sulfur to melt-diffuse into the nanocomposite.
[0076] The above process may further include step (d) or step (e) or both of steps (d) and (e) in any order. When step (d) is present, then the product obtained is a nanocomposite material.
[0077] For example, the acid of step (e) is a mineral acid, preferably H.sub.2SO.sub.4 or HCl, preferably used in a concentration of 0.1 to 5 M. In another example, the thermal treatment steps (c) and (d) when present are performed each independently at a temperature of about 200 to about 500 C., preferably about 300 to about 400 C. and the heating step (f) is performed at a temperature of about 140 to about 180 C. for about 5 to about 48 hours.
[0078] Non-limiting examples of titanium oxide precursors include one or more organotitanium compounds selected from titanium tetraisopropoxide, titanium tetra-n-butoxide, titanium tetrakis(2-ethylhexyloxide), titanium tetrastearyloxide, titanium acetylacetonate, titanium ethyl acetoacetate, salicylaldehyde ethyleneimine titanate, diacetone alkoxy titanium, octylene glycoxy titanium, triethanolamine titanate, titanium lactate, monocyclopentadienyltitanium trihalides, dicyclopentadienyltitanium dihalides, cyclopentadienyltitanium trimethoxide, cyclopentadienyltitanium triethoxide and cyclopentadienyltitanium tripropoxide. For example, the organotitanium compound is titanium tetra-n-butoxide (Ti(IV) butoxide).
[0079] Electrochemical cells and batteries comprising the nanocomposite as defined herein are also contemplated. For example, at least one element of the electrochemical cells comprises the nanocomposite as defined herein. Such element may be an electrode material, and more preferably the positive electrode material. The electrode material may further comprise a second conductive material, a binder and/or optional additives. For example, the electrode material may be mixed as a slurry with the second conductive material, the binder, a solvent and optionally one or more additives.
[0080] Non-limiting examples of the second conductive material may include a carbon source such as carbon black, carbon Ketjen, acetylene black, graphite, graphene, carbon fibers (such as carbon nanofibers or VGCF formed in the gas phase), and carbon nanotubes, or a combination of at least two of these. For example, the second conductive material is a combination of Ketjen black carbon (e.g. ECP600JD) and vapor grown carbon fibers (VGCF).
[0081] Non-limiting examples of binders include a linear, branched and/or crosslinked polymeric binder of the polyether type and may be based on poly(ethylene oxide) (PEO), poly(propylene oxide) (PPO) or a mixture of the two (or an EO/PO copolymer), which optionally comprises crosslinkable units; a fluorinated polymer such as polyvinylidene fluoride (PVDF) or polytetrafluoroethylene (PTFE); or a water-soluble binder such as SBR (styrene-butadiene rubber), NBR (acrylonitrile-butadiene rubber), HNBR (hydrogenated NBR), CHR (epichlorohydrin rubber) acrylate), optionally comprising CMC (carboxymethylcellulose). For example, the binder is PVDF.
[0082] According to one example, the positive electrode material can be applied to a current collector (e.g., aluminum, copper) to form the positive electrode. Alternatively, the positive electrode can be self-supporting. For example, the current collector is aluminum.
[0083] The present application also proposes an electrochemical cell comprising the positive electrode as defined herein, a negative electrode and an electrolyte.
[0084] For more certainty, the electrochemically active material of the negative electrode may be selected from any known material compatible with the use of the present positive electrode material, such as alkali metal films, e.g. metallic lithium film or an alloy thereof. For example, the negative electrode is a metallic lithium film.
[0085] The electrolyte is selected for its compatibility with the various elements of the electrochemical cell. Any type of electrolyte is contemplated including, for example, liquid, gel or solid electrolytes.
[0086] Compatible electrolytes generally comprise at least one lithium salt such as lithium hexafluorophosphate (LiPF.sub.6), lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), lithium bis(fluorosulfonyl)imide (LiFSI), 2-trifluoromethyl-4-dicyanoimidazolate (LiTDI), lithium 4,5-dicyano-1,2,3-triazolate (LiDCTA), lithium bis(pentafluoroethylsulfonyl)imide (LiBETI), lithium tetrafluoroborate (LiBF.sub.4), lithium bis(oxalato)borate (LiBOB), lithium nitrate (LiNO.sub.3), lithium chloride (LiCl), lithium bromide (LiBr), lithium fluoride (LiF), and compositions comprising them dissolved in a non-aqueous (organic) solvent or a solvating polymer.
[0087] Compatible liquid electrolytes may further include a polar aprotic solvent such as ethylene carbonate (EC), diethyl carbonate (DEC), propylene carbonate (PC), dimethyl carbonate (DMC), ethyl methyl carbonate (EMC), -butyrolactone (-BL), vinyl carbonate (VC), dimethoxyethane (DME), 1,3-dioxolane (DOL) and mixtures thereof, and lithium salts as defined above. Other examples of compatible liquid electrolytes include molten salt (ionic liquid) electrolytes. Non-limiting examples of liquid electrolytes of molten salts include lithium salts such as LiCl, LiBr, LiF, and compositions comprising them, or organic salts. Non-limiting examples of molten salts liquid electrolytes can be found in US20020110739 A1. The liquid electrolyte may impregnate a separator such as a polymer separator (e.g., polypropylene, polyethylene, or a copolymer thereof). For example, the electrolyte is lithium bis(trifluoromethane)sulfonamide and lithium nitrate (2%) in a solvent mixture of 1,3-dioxolane and 1,2-dimethoxy ethane (1:1 v/v) impregnating a polyethylene-based separator.
[0088] Compatible gel electrolytes may include, for example, polymer precursors and lithium salts (such as LiTFSI, LiPF.sub.6, etc.), an aprotic polar solvent as defined above, a polymerization and/or crosslinking initiator when required. Examples of such gel electrolytes include, without limitation, the gel electrolytes disclosed in the PCT applications published under WO2009/111860 (Zaghib et al.) and WO2004/068610 (Zaghib et al.). A gel electrolyte may also impregnate a separator as defined above.
[0089] Solid polymer electrolytes can generally comprise a crosslinked or non-crosslinked polar solvating solid polymer or polymers and salts, for example, lithium salts such as LiTFSI, LiPF.sub.6, LiDCTA, LiBETI, LiFSI, LiBF.sub.4, LiBOB, etc. Polyether polymers such as polymers based on poly(ethylene oxide) (PEO) may be used, but several other lithium compatible polymers are also known to produce solid polymer electrolytes. Examples of such polymers include star-shaped or comb-like multi-branched polymers such as those disclosed in PCT application no. WO2003/063287 (Zaghib et al.).
[0090] According to another aspect, an electrochemical cell of the present application is included in a lithium battery. For example, the lithium battery is a lithium-sulfur battery.
[0091] The present application also proposes an electrochemical cell of the present application included in a high performance all-solid-state lithium-sulfur battery. For example, the electrochemical cell comprises the positive electrode as defined herein, a negative electrode and a solid polymer electrolyte.
[0092] According to another aspect, the electrochemical cells of the present application are used in mobile devices, for example mobile phones, cameras, tablets or laptops, in electric or hybrid vehicles, or for the storage of renewable energy.
EXAMPLES
[0093] The following non-limiting examples are illustrative embodiments and should not be construed as further limiting the scope of the present invention. These examples will be better understood with reference to the accompanying figures.
[0094] The nanoparticles, nanocubes and nanocomposite materials described in the following example were characterized by TEM, HRTEM and HAADF-STEM (FEI Tecnai G.sup.2 F20 electron microscope). Samples for TEM studies were prepared by putting a droplet of the NPs solution on a copper grid coated with a thin carbon film, followed by evaporation in air at room temperature. The catalyst composition was determined in situ by an EDX attachment (Oxford Instruments X-Max 80TLE) to the microscope. XRD patterns were recorded on a Rigaku D/Max-3B diffractometer using Cu K.sub. radiation (A=1.54056 ). B.E.T. surface areas of the samples were calculated from nitrogen sorption at 77 K on a Micromeritics ASAP 2020 instrument. The TGA experiment was performed under flowing nitrogen on a TA Instruments Discovery TGA 55 (heating rate=5 C./min).
Example 1Synthesis of Core-Shell MnO/TiO.SUB.2 .NPs
[0095] (a) Synthesis of Monodispersed MnCO.sub.3 Precursor Nanoparticles
[0096] In one example, the core-shell MnO/TiO.sub.2 NPs are MnO/TiO.sub.2 NPs. The MnO/TiO.sub.2 NPs uses monodispersed MnCO.sub.3 NPs as a synthesis precursor. In the first step of the synthesis, monodispersed MnCO.sub.3 NPs were prepared as a self-template via a cationic surfactant-CTAB-microemulsion-mediated solvothermal method. To perform this synthesis, 2.0 g of cetyltrimethylammonium bromide (CTAB), 10 mmol of manganese(II) chloride tetrahydrate (MnCl.sub.2.4H.sub.2O), 2.0 mL of water, 3.0 mL of 1-butanol and 60 mL of cyclohexane were added to a first container and mixed to form a first miroemulsion. 8.0 g of CTAB, 19 mmol of potassium bicarbonate (KHCO.sub.3), 1.0 mmol of ammonium bicarbonate (NH.sub.4HCO.sub.3), 2.0 mL of water, 3.0 mL of 1-butanol and 240 mL of cyclohexane were added to a second container and mixed to form a second microemulsion. Both water-in-oil microemulsions were obtained after magnetic stirring at room temperature for 1 hour. The feedstock from the first container was then introduced in the second container under continuous stirring. The resulting microemulsion was then stirred for 30 minutes.
[0097] A size-selective separation process was then performed on the resulting microemulsion to obtain highly monodispersed manganese (II) carbonate (MnCO.sub.3) nanocubes. To do so, the resulting microemulsion was centrifuged at 8000 rpm for 5 minutes, the supernatant was removed, and the precipitate was dispersed in ethanol by ultrasonication to form a uniform suspension. The suspension was then centrifuged at 3000 rpm for 2 minutes; after these 2 minutes the milky supernatant suspension was saved, while the precipitate was discarded. The suspension was then centrifuged at 8000 rpm for 5 minutes and the precipitate was collected and re-dispersed in ethanol by ultrasonication to form a uniform MnCO.sub.3 nanocubes suspension. The concentration of the MnCO.sub.3 nanocubes suspension was determined by weighting dried MnCO.sub.3 nanocubes from a fixed volume of said MnCO.sub.3 nanocubes suspension and was determined to be about 0.1 M. The MnCO.sub.3 precursor NPs were obtained by drying the MnCO.sub.3 nanocubes suspension in an oven at 80 C.
[0098] The MnCO.sub.3 precursor NPs were then characterized using low and high magnification transmission electron microscopy (TEM) images. As can be appreciated from
[0099] (b) Preparation of the MnCO.sub.3/TiO.sub.2 Core-Shell Nanoparticles
[0100] The synthesis of the MnCO.sub.3/TiO.sub.2 core-shell nanomaterials was performed by dispersing 8 mL of the MnCO.sub.3 NPs from (a) at a concentration of 0.2 M in ethanol in 125 mL of acetonitrile, 375 mL of ethanol and 5.4 mL of deionized water. The solution was stirred vigorously for 30 minutes. Then, 1 mL of Ti(IV) tetra-n-butoxide (form Sigma-Aldrich) was added to the dispersion. The dispersion was allowed to react for 20 hours. The MnCO.sub.3/TiO.sub.2 core-shell NPs were collected by centrifugation, washed with ethanol and then dried.
[0101] The morphology of the MnCO.sub.3/TiO.sub.2 core-shell NPs was then characterized by TEM. As can be seen in
[0102] (c) Preparation of the MnO/TiO.sub.2 Nanoparticles
[0103] This example illustrates the process for producing MnO/TiO.sub.2 NPs. The MnO/TiO.sub.2 NPs were obtained by annealing at a temperature of about 350 C. the MnCO.sub.3/TiO.sub.2 core-shell NPs as described in Example 1 (b) under an argon atmosphere for 4 hours.
[0104] The MnO/TiO.sub.2 NPs were then characterized. The core-shell structure could be easily observed in
Example 2Production of Nanocomposite Material Comprising a Conductive Nanomaterial
[0105] This example illustrates the addition of a conductive nanomaterial to MnO/TiO.sub.2 NPs in order to increase its electronic conductivity. To do so, a uniform graphene oxide suspension was prepared by ultrasonically dispersing 100 mg of graphene oxide (GO) in 100 mL of deionized water with 100 mg of CTAB. 400 mg of as-prepared MnO/TiO.sub.2 NPs from Example 1 were then added to the GO suspension under magnetic stirring. After thorough mixing, the water was removed by centrifugation, and the sample was dried at room temperature in a vacuum oven overnight. The dried powder was annealed under argon atmosphere containing H.sub.2 (5%) at 350 C. for 4 hours to form the MnO/TiO.sub.2/RGO nanocomposite material.
[0106] The MnO/TiO.sub.2/RGO nanocomposite material was then characterized. The TEM images suggested that the MnO/TiO.sub.2 NPs were well-dispersed on the RGO nanosheets (
Example 3Elemental Sulfur (S.SUB.8.) Incorporation by Melt-Diffusion
[0107] This example illustrates the incorporation of elemental sulfur (S.sub.8) in the MnO/TiO.sub.2 nanoparticles of Example 1 or the MnO/TiO.sub.2/RGO nanocomposite material of Example 2 by melt-diffusion. An amount of 1 g of MnO/TiO.sub.2 NPs and of MnO/TiO.sub.2/RGO nanocomposite were each milled with 2 g of sulfur nanocrystals. The mixtures were each sealed in a polytetrafluoroethylene (PTFE) or Teflon container under inert atmosphere in a glove box and heated at 160 C. for 20 hours to incorporate the sulfur into the nanocomposite material by melt-diffusion to obtain MnO/TiO.sub.2S and MnO/TiO.sub.2/RGO-S nanocomposite materials.
[0108] TEM images and elemental maps of HAADF-STEM image (
Example 4Molar Ratios of MnO and TiO.SUB.2
[0109] MnO/TiO.sub.2/RGO-S with different molar ratios of MnO to TiO.sub.2 were also synthesized. The MnO/TiO.sub.2/RGO nanocomposite was treated with acid to remove excess MnO (partial removal). To prepare MnO/TiO.sub.2/RGO with different Ti:Mn ratios, the dried powder (500 mg) was dispersed in 100 mL of deionized water, and then treated with 10 mL of H.sub.2SO.sub.4 (1 M) to remove part of the MnO. After 1 hour of reaction, the nanocomposite was collected by centrifugation and dried in a vacuum oven to afford a nanocomposite referred to as MnO/TiO.sub.2/RGO-acid.
[0110] The EDX profile of an individual MnO/TiO.sub.2/RGO-acid core-shell NP confirmed that the Ti:Mn molar ratio was about 1:1 (
[0111] Sulfur nanocrystals were then incorporated by melt diffusion as described in Example 3. The resulting MnO/TiO.sub.2/RGO-acid-S still retained the cubic morphology of MnO/TiO.sub.2, and the NPs were well dispersed on the surface of RGO (
Example 5: Preparation of Cells
[0112] (a) Cathodes
[0113] Cathode materials comprising nanocomposite materials were prepared in the weight ratios detailed in Table 1. The materials were prepared by mixing the nanocomposite material using a SamplePrep 8000M Mixer/Mill high-energy ball miller from Spex for 1 hour, Ketjen black carbon (ECP600JD), vapor grown carbon fibers (VGCF), and polyvinylidene fluoride (PVDF) in N-methyl-2-pyrrolidone (NMP). The mixture was then rolled into thin sheets with a thickness of about 15 m, which were then punched and pressed onto round aluminum meshes.
TABLE-US-00001 TABLE 1 Cathode material weight concentration Nanocomposite material Carbon 1 Carbon 2 Binder Cathode (wt %) (wt %) (wt %) (wt %) C1 Sulfur nanocrystals C-Ketjen C-VGCF PVDF (60%) (15%) (15%) (10%) C2 MnO/TiO.sub.2-S C-Ketjen C-VGCF PVDF (60%) (15%) (15%) (10%) C3 MnO/TiO.sub.2/RGO-S C-Ketjen C-VGCF PVDF (60%) (15%) (15%) (10%) C4 MnO/TiO.sub.2/RGO- C- Ketjen C-VGCF PVDF acid-S (15%) (15%) (10%) (60%)
[0114] (b) Cells
[0115] The cells were assembled in standard CR2032 size coin cell casings (i.e. 20 mm diameter and 3.2 mm height), with the cathodes prepared in (a), a metallic lithium disk as the anode, 25 m polyethylene-based separators impregnated lithium bis(trifluoromethane)sulfonamide and lithium nitrate (2%) in a solvent mixture of 1,3-dioxolane and 1,2-dimethoxy ethane (1:1 v/v) as the electrolyte. All cells were assembled in an argon-filled glove box.
TABLE-US-00002 TABLE 2 Cell configurations Cell Cathode Cell 1 C1 Cell 2 C2 Cell 3 C3 Cell 4 C4
Example 6: Electrochemical Properties
[0116] (a) Cyclic Voltammetry
[0117] Cyclic voltammograms (CV) were recorded for the LiS cells prepared in Example 5, i.e. comprising the composite materials described in Examples 3 and 4 as cathode active material. The CV were recorded with the electrochemical workstation (from Autolab) at a scanning rate of 0.05 mVs.sup.1 in the range of 1.5 to 2.8 (V vs Li/Li.sup.+). As can be observed in
[0118] (b) Galvanostatic Charge and Discharge Profile
[0119] The galvanostatic charge and discharge profiles were studied to test the performances of cells prepared in Example 5 comprising the composite materials as described herein. The galvanostatic charge/discharge tests were performed using an Arbin Instruments testing system (Arbin BT-2000).
[0120] As shown in
[0121] (c) Impedance
[0122] Electrochemical impedance spectroscopy (EIS) was performed on the cells comprising the nanocomposites (see
[0123] Numerous modifications could be made to any of the embodiments described above without departing from the scope of the present invention. Any references, patents or scientific literature documents referred to in the present document are incorporated herein by reference in their entirety for all purposes.