Patent classifications
H01M4/623
A PROTECTIVE LAYER FOR A METAL ELECTRODE AND LITHIUM BATTERY COMPRISING THE SAME
An electrode for a lithium battery contains a metal layer coated with a coating layer containing an organic binder and a metal compound. The metal compound is selected from aluminium oxide, silicon dioxide, zirconium oxide, mixed oxides including zirconium, mixed oxides including aluminium, lithium zirconium phosphate, and mixtures thereof. The metal compound is made of aggregates of primary particles with a number mean primary particle size d.sub.50 of 5 nm-100 nm, obtained by a pyrogenic process. The weight ratio of the metal compound to the organic binder in the coating layer is from 0.1 to 10.
SEPARATOR FOR NONAQUEOUS ELECTROLYTE SECONDARY BATTERY, AND NONAQUEOUS ELECTROLYTE SECONDARY BATTERY
This separator for a nonaqueous electrolyte secondary battery comprises a porous substrate, a heat-resistant layer that is formed on the porous substrate, and clusters of filler particles that are present in dot shapes on the surface of the heat-resistant layer. The filler particles are particles of a compound including at least one of phosphorus, silicon, boron, nitrogen, potassium, sodium, and bromine, and the transformation point at which the filler particles transform from a solid phase to a liquid phase or thermally decompose is in the range 180° C.-1000° C. This separator electrode for a nonaqueous electrolyte secondary battery can suppress heat production of the battery during a nail puncture test, while also suppressing an increase in battery resistance.
SLURRY FOR SOLID-STATE SECONDARY BATTERY, METHOD FOR FORMING LAYER FOR SOLID-STATE SECONDARY BATTERY, AND SOLID-STATE SECONDARY BATTERY
The present invention provides an oxide-based solid-state secondary battery which may be enlarged at a low cost and for which production costs are reduced. A binder for a solid-state secondary battery using an oxide-based solid-state electrolyte, wherein the binder contains a vinylidene fluoride unit and a fluorinated monomer unit excluding the vinylidene fluoride unit.
Ethyl cellulose as a dispersant for lithium ion battery cathode production
The process of making a lithium ion battery cathode comprises the step of forming a slurry of an active material, a nano-size conductive agent, a binder polymer, a solvent and a dispersant. The solvent consists essentially of one or more of a compound of Formula 1, 2, or 3, and the dispersant comprises an ethyl cellulose.
Lithium ion secondary battery
The present application discloses a lithium ion secondary battery comprising a positive electrode plate, a negative electrode plate, a separator and an electrolyte, wherein the positive electrode plate comprises a positive electrode current collector and a positive electrode film provided on at least one surface of the positive electrode current collector, and the positive electrode film comprises a first positive electrode active material represented by chemical formula Li.sub.1+xNi.sub.aCo.sub.bMe.sub.1-a-bO.sub.2-yA.sub.y and a second positive electrode active material represented by chemical formula Li.sub.1+zMn.sub.cN.sub.2-cO.sub.4-dB.sub.d; the positive electrode plate has a resistivity r of 3500 Ω.Math.m or less; and the electrolyte comprises a fluorine-containing lithium salt type additive. The lithium ion secondary battery provided by the present application is capable of satisfying high safety performance, high-temperature storage performance and cycle performance simultaneously.
ELECTRODE PLATE, ELECTROCHEMICAL APPARATUS, AND ELECTRONIC APPARATUS CONTAINING SAME
An electrode plate includes a current collector, a first active substance layer, a second active substance layer, and an insulation layer. The current collector includes a first surface, the first active substance layer includes a first active substance, and the second active substance layer includes a second active substance. The first active substance layer is sandwiched between the current collector and the second active substance layer and covers a first portion of the first surface, the insulation layer covers a second portion of the first surface, and the first active substance layer and the insulation layer are stacked to form an overlapped portion in a length direction of the electrode plate. The current collector can be covered by a high-resistance layer, thereby improving safety performance of the electrochemical apparatus and the electronic apparatus.
ELECTRODE MIXTURE, ELECTRODE, AND SECONDARY BATTERY
Provided is an electrode mixture containing a lithium-containing transition metal oxide; a conductive additive; a binder; and an organic solvent, wherein the conductive additive comprises at least one nanocarbon material selected from the group consisting of a multilayer carbon nanotube, a carbon nanohorn, a carbon nanofiber, a fullerene, and a graphene, the binder comprises a fluorine-containing copolymer comprising vinylidene fluoride unit and a fluorinated monomer unit, provided that vinylidene fluoride unit is excluded from the fluorinated monomer unit, and a content of vinylidene fluoride unit in the fluorine-containing copolymer is more than 50 mol % and 99 mol % or less with respect to all monomer units.
Electrode for Electrochemical Device Comprising Dry Electrode Film and Method for Manufacturing the Same
Disclosed is a method for manufacturing a dry electrode. The method allows determination of the micro-fibrilization degree of a binder resin from the crystallinity of the binder resin. Based on this, the processing conditions of mixed powder for electrode or an electrode film may be controlled. In this manner, it is possible to check and control the processing conditions easily and efficiently. In addition, the method for manufacturing a dry electrode includes a kneading step using a kneader under a low speed and high temperature and pulverization step. Therefore, there is no problem of blocking of a flow path caused by aggregation of the ingredients, which is favorable to mass production.
METHOD OF MANUFACTURING A SOLID-STATE LITHIUM BATTERY AND A BATTERY MANUFACTURED BY THE METHOD
The propose method of manufacturing a solid-state lithium battery consists of preparing an anode coated with a solid-state electrolyte precursor and a cathode unit coated with solid-state electrolyte, both precursors containing a predetermined amount of a redundant water. The thus prepared anode unit and cathode unit are pressed to each other through their respective electrolyte precursor layers in a closed chamber at a predetermined elevated temperature and under a predetermined mechanical pressure, whereby an integral pre-final solid-state battery unit is formed. The manufacture of the battery is completed by inserting the prefinal product into a casing that leaves parts of the metal current collectors of the prefinal product exposed for use as a battery anode and a battery cathode.
Method for stabilizing aqueous dispersions of fluorinated polymers
The present invention relates to a method for stabilizing aqueous dispersions, notably of polymers based on vinylidene fluoride (VDF), and to the use of the stabilized aqueous dispersion thus obtained in electrochemical applications.