METHOD OF MANUFACTURING A COMPOSITE PART COMPRISING A CORE AND AT LEAST ONE SKIN REGION

20200324493 ยท 2020-10-15

Assignee

Inventors

Cpc classification

International classification

Abstract

A method of manufacturing a composite part comprising, a core (16) and at least one skin region (20, 22) formed of a skin polymer attached thereto, the skin polymer being a low-friction thermoplastic polymer, by: a) providing a mold with a heatable mold cavity; b) loading into the mold cavity a core element having a surface with at least one contacting region provided with a plurality of anchoring sites (10), andpreviously or subsequentlyloading into the mold cavity a layer of the skin polymer in powder form adjacent said contacting region and embedding the anchoring sites; c) applying a heat pressing step melting the skin polymer powder to form a molten skin polymer matrix (20, 22, 32); d) applying a cooling step, solidifying the skin polymer matrix forming a skin region mechanically engaged into anchoring sites of the core element forming the core.

Claims

1. A method of manufacturing a composite part comprising a core (16) and at least one skin region (20, 22) formed of a skin polymer attached thereto, the skin polymer being a low-friction thermoplastic polymer, the method comprising the Mowing steps: a) providing a mold with a heatable mold cavity (4, 14); b) loading into the mold cavity a core element (6) having a surface with at least one contacting region provided with a plurality of anchoring sites (10, 28, 30, 34, 36), andpreviously or subsequentlyloading into the mold cavity a layer (2, 12) of the skin polymer in powder form adjacent said contacting region and embedding the anchoring sites; c) applying a heat pressing step whereby the skin polymer powder is molten to form a molten skin polymer matrix (20, 22, 32); d) applying a cooling step, whereby the skin polymer matrix solidifies to form a skin region mechanically engaged into the anchoring sites of the core element forming the core.

2. The method according to claim 1, wherein the skin polymer is ultra-high molecular weight polyethylene (UHMWPE).

3. The method according to claim 1, wherein the layer of skin polymer powder is applied above and below the core element.

4. The method according to claim 1, wherein the layer of skin polymer powder is applied patchwise.

5. The method according to claim 1, wherein the core element is forted of a thermoplastic fleece (8) with reinforcement fibers (10), wherein the thermoplastic fleece consists of a core thermoplastic polymer, and wherein cavernous surface structures of the thermoplastic fleece and/or surface portions of the reinforcement fibers act as said anchoring sites, the heat pressing step causing melting of the core thermoplastic polymer, whereby the core element is formed to the core.

6. The method according to claim 5, wherein the core thermoplastic polymer is polypropylene.

7. The method according to claim 5, wherein the skin polymer is UHMWPE and the heat pressing step is carried out at a temperature of 190 to 230 C. with a pressure of 20 to 60 bar.

8. The method according to claim 5, wherein the reinforcement fibers (10) are glass fibers.

9. The method according to claim 5, wherein the core element (6) further comprises at least one reinforcement layer (24a, 24b).

10. The method according to claim 9, wherein the reinforcement layer is selected from a fabric, multiaxial stitch or unidirectional reinforcement.

11. The method according to claim 1, wherein the core element (6) is formed as a solid or hollow body (36) and wherein the anchoring sites are configured as surface discontinuities such as recesses (30), rims or under-cuts (34).

12. A composite part comprising a core (16) and at least one skin region (20, 22, 32) formed of a skin polymer attached thereto, the skin polymer being a low-friction thermoplastic polymer, the core element having a surface with at least one contacting region provided with a plurality of anchoring sites (10, 28, 30, 34, 36), and the skin region being mechanically engaged into the anchoring sites of the core element, the skin region having a thickness of 0.5 to 10 mm.

13. The composite pan according to claim 11, wherein the skin polymer is UHMWPE.

14. The composite part according to claim 12, wherein the core comprises a solid matrix (18) of the core thermoplastic and reinforcement fibers (10), which together form anchoring sites embedded by the skin polymer (22).

15. The composite part according to claim 14, wherein the core thermoplastic is polypropylene

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0046] The above mentioned and other features and objects of this invention and the manner of achieving them will become more apparent and this invention itself will be better understood by reference to the following description of various embodiments of this invention taken in conjunction with the accompanying drawings, wherein:

[0047] FIGS. 1 to 4 show various embodiments of the invention as schematic vertical section views through the composite part, wherein in each figure, a) shows the situation before applying the skin polymer to the core element, b) shows the situation after applying the skin polymer and distributing the same within surface structures of the core element, and c) shows the situation after the heat pressing step, including an enlarged portion of a segment at the upper left of the composite part;

[0048] FIGS. 5 to 7 shows vertical section views of further embodiments of the composite part;

[0049] FIG. 8 shows a photographic reproduction of one embodiment of the composite part; and

[0050] FIG. 9 shows an enlarged section (micrograph) of an edge region of the composite part of FIG. 8.

DETAILED DESCRIPTION OF THE INVENTION

[0051] It will be understood that the figures are not necessarily drawn to scale. In some instances, relative dimensions are substantially distorted for ease of visualization. Identical or corresponding features in the various figures will generally be denoted with the same reference numerals.

[0052] In the following examples, UHMWPE was used as skin polymer, polypropylene was used as core thermoplastic polymer, and glass fibers were used as reinforcement fibers. As will be understood from the above, other suitable materials may be chosen. Depending on material choice, the temperature and possibly also the pressure applied in the heat pressing step may have to be adapted. For this purpose it may be appropriate to conduct a small series of test runs systematically changing temperature and pressure.

[0053] In the example of FIG. 1, a first layer 2 of approximately 2 mm of UHMWPE in powder form is uniformly distributed on a lower mold plate 4 of a heatable mold cavity (not shown). Subsequently, a core element 6 formed of a lofty mat comprising a thermoplastic fleece 8 containing reinforcement fibers 10, e.g. with 20 to 80% by weight of randomly oriented polypropylene (PP) fibers and 80 to 20% by weight of glass fibers is placed onto the first layer 2 of skin polymer powder. Thereafter second layer 12 of approximately 2 mm of UHMWPE in powder form is uniformly distributed onto the top of the core element 6. As seen from FIG. 1b, at this point a fraction of the skin polymer powder has penetrated into interstitial regions between the various PP and glass fibers in the regions near the surface of the core element.

[0054] The stacked arrangement thus prepared is then subjected to a heat pressing step by driving an upper mold plate 14 against lower mold plate 4 under appropriate heating. During this process, the UHMWPE powder is driven further into the core element and is caused to melt; simultaneously, the PP fibers of the core element are caused to also melt and the lofty fiber arrangement is compressed to some extent. After cooling down, the resulting composite part comprises a central core 16 made up of glass fibers 10 and a solid PP core matrix 18, which is stacked between a lower skin 20 and an upper skin 22 formed of a solid matrix of UWHMPE. As particularly seen from the enlarged section in FIG. 1c. the boundary region between skin and core regions comprises an arrangement of geometrically intertwined regions of solidified PP, solidified UHMWPE and glass fiber portions, thus providing an strong mechanical coupling of the various layers.

[0055] The same principle is applied in the examples of FIGS. 2 and 3, and therefore only the respective difference will be discussed.

[0056] In the example of FIG. 2, only an upper skin layer 12 is applied. Moreover, the core element 6 contains, in addition of PP fibers 8 and glass fibers 10, two internal reinforcement layers 24a and 24b. These reinforcement layers can be formed, e.g., of a reinforcement fabric or a multi-axial or unidirectional reinforcement layer. Such reinforcement layers are well known in the field of fiber reinforced thermoplastics. Alternatively, one could also use a plate-like solid element for reinforcement.

[0057] Analogously to the first example, the heat pressing step leads to formation of a composite part, wherein the core 16 now contains the reinforcement layers 24a and 24b. Depending on the type of reinforcement element, molten PP is driven into recesses and cavities of the reinforcement element and provides mechanical connection to the core matrix.

[0058] The example of FIG. 3 only differs from the example of FIG. 3 in that the upper skin 22 does not cover the entire uppers surface of core 16. Accordingly, the upper layer of UHMWPE powder is only applied as a patch 12a covering a part of the core element, and correspondingly, the upper skin is formed as a skin patch 22a.

[0059] A substantially different embodiment is shown in FIG. 4. In this case, the core element 6 is constituted of a plate element 26 provided with a plurality of vertical passages 28 and a plurality of horizontal recesses 30 disposed in the lateral plate surface. After applying a first layer 2 of approximately 10 mm of UHMWPE powder, the core element 6 is placed thereon and then further UHMWPE powder is applied taking care to fill the vertical passages 28 and the horizontal recesses 30 and also forming an upper UHMWPE layer 12. After heat pressing and cooling, a composite part as shown if FIG. 5c is formed. A UHMWPE skin 32 completely surrounds the solid core 16, which is essentially identical to the originally inserted core element 6. Anchoring of the UHWMPE skin 32 to the core 16 is provided by the geometric structure formed by the vertical passages 28 and horizontal recesses 30.

[0060] As already mentioned, various embodiments of the method and of the composite part are possible. FIG. 5 just shows one example of a composite part with a patchy UHMWPE skin, which can be shaped e.g. to provide low friction at selected, exposed regions 22a of the composite part. As shown in FIG. 6, a substantially solid core 16 with appropriate horizontal recesses 30 and vertical undercuts 34 can optionally contain an additional functional element 36. As shown in FIG. 7, the core 16 can be formed of a plurality of tubular elements 38 arranged substantially along a principal plane of the composite part. Mechanical anchoring between the skin matrix and the core is provided to some extent by the geometric arrangement of tubular elements 38. Nevertheless, it may be appropriate to provide further anchoring by applying a suitable adhesive on the surface of the tubular elements.

[0061] The composite part illustrated in FIGS. 8 and 9 comprises an upper UHMWPE skin layer and a bottom UHMWPE skin layer each consolidated to a skin thickness of about 2 mm. The core layer comprises an upper and a lower PP-GF fleece with approximately 50% GF content and each about 1 mm thick, and a stack of reinforcement PP-GF fabric layers sandwiched therebetween. A heat pressing was carried out starting from 25 C. and rising up to 200 C. under 20 bar pressure, After reaching 200 C. the pressure and temperature were maintained for 10 min, followed by a cooling from 200 C. to 70 C. still under 20 bar pressure. As seen from FIG. 8 and particularly from FIG. 9, the UHMWPE skin (bottom part of FIG. 9) intimately embeds various protruding structures of the PP-GF fleece, which in turn is anchored into the PP-GF fabric layer acting as reinforcement.