Vegetable oil-based cartilage bionic cushioning and shock-absorbing material, and preparation method and use thereof

Abstract

A vegetable oil-based cartilage bionic cushioning and shock-absorbing material, and a preparation method and use thereof, is provided. The vegetable oil-based cartilage bionic cushioning and shock-absorbing material is prepared from a premix A and an isocyanate mixture B; the premix A including a vegetable oil-based modified polyol, a type 1 polyether polyol, a type 2 polyether polyol, a polymer polyol, a surfactant, a foaming agent, a chain extender, a catalyst and a cell regulator; the type 1 polyether polyol is a polyether polyol with a molecular weight of 400-1000 and a hydroxyl value of 110-280 mgKOH/g; and the type 2 polyether polyol is a polyether polyol with a molecular weight of 1000-10000 and a hydroxyl value of 25-56 mg KOH/g. The material provided by the present invention is environment-friendly and breathable with open cells, and has a high cushioning effect and a low permanent compression set value.

Claims

1. A vegetable oil-based cartilage bionic cushioning and shock-absorbing material prepared from raw materials comprising a premix A and an isocyanate mixture B; the premix A comprising a vegetable oil-based modified polyol, a type 1 polyether polyol, a type 2 polyether polyol, a polymer polyol, a surfactant, a foaming agent, a chain extender, a catalyst and a cell regulator; wherein the vegetable oil-based modified polyol is one or more of a soybean oil polyol and a castor oil polyol with a hydroxyl value of 160-220 mg KOH/g and a molecular weight of 550-4000; the type 1 polyether polyol is a polyether polyol with a molecular weight of 400-1000 and a hydroxyl value of 110-280 mg KOH/g; the type 2 polyether polyol is a polyether polyol with a molecular weight of 1000-10000 and a hydroxyl value of 25-56 mg KOH/g; the polymer polyol is a graft copolymer consisting of a propylene epoxide-ethylene epoxide copolyether grafting with acrylonitrile and styrene; the foaming agent is water or 1,1-dichloro-1-fluoroethane; the isocyanate mixture B comprising a polyether polyol modified isocyanate and an aliphatic isocyanate; wherein the isocyanate in the polyether polyol modified isocyanate is one of toluene diisocyanate and diphenylmethane diisocyanate; the polyether polyol used for modifying the isocyanate in the polyether polyol modified isocyanate has a functionality of 2-3 and a molecular weight of 60-200; the aliphatic isocyanate is one or more of hexamethylene diisocyanate and isophorone diisocyanate; the weight ratio of the polyether polyol modified isocyanate to the aliphatic isocyanate in the isocyanate mixture B is (65-85):(15-35); and wherein the polyether polyol modified isocyanate is prepared by melting the diphenylmethane diisocyanate, then adding the polyether diol, increasing the temperature to 70 C.-90 C. to react for 2-3 hours until the terminal-NCO group content becomes 22%-24%, and then increasing the temperature to 100 C-110 C. to react for 0.5-1 hours to form a modified diphenylmethane diisocyanate with a terminal-NCO group content of 19%-22%.

2. The vegetable oil-based cartilage bionic cushioning and shock-absorbing material according to claim 1, wherein the type 1 polyether polyol is a polypropylene oxide polyol; the type 2 polyether polyol is a polypropylene oxide-ethylene oxide block copolymer polyol; and the polymer polyol has a molecular weight of 3000-10000, a functionality of 2-4, a grafting rate of 20 wt. %-60 wt. %, and a hydroxyl value of 20-30 mg KOH/g.

3. The vegetable oil-based cartilage bionic cushioning and shock-absorbing material according to claim 1, wherein the surfactant is a silicone or polysiloxane-oxyalkylene block copolymer.

4. The vegetable oil-based cartilage bionic cushioning and shock-absorbing material according to claim 1, wherein the foaming agent is a physical foaming agent and/or a chemical foaming agent; the chain extender is one or more of ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,4-butanediol, diethylene glycol, dipropylene glycol, neopentyl glycol, methyl propanediol (2-methyl-1,3-propanediol) and hydroquinone bis(2-hydroxyethyl)ether; the catalyst is at least one of N,N-dimethylcyclohexylamine, bis(2-dimethylaminoethyl)ether, N,N,N,N-tetramethylalkylidene diamine, triethylamine, N,N-dimethylbenzylamine, triethylenediamine and an organic bismuth catalyst; the cell regulator is one of monofunctional polyethylene oxide and a block copolymer consisting of monofunctional polypropylene oxide and polyethylene oxide; and the molecular weight thereof is 400-1000.

5. The vegetable oil-based cartilage bionic cushioning and shock-absorbing material according to claim 1, wherein the premix A mainly consists of the following components in parts by weight: 10-30 parts of the vegetable oil-based modified polyol, 10-40 parts of the type 1 polyether polyol, 20-60 parts of the type 2 polyether polyol, 10-30 parts of the polymer polyol, 0.1-2.0 parts of the surfactant, 0.1-1.0 parts of the foaming agent, 1.0-10.0 parts of the chain extender, 0.3-3.0 parts of the catalyst and 1-5 parts of the cell regulator; and the molar ratio of the hydroxyl group in the premix A to the isocyanate group in the isocyanate mixture B is 100:(100-110).

6. A method for preparing the vegetable oil-based cartilage bionic cushioning and shock-absorbing material according to claim 1, comprising: (1) mixing the vegetable oil-based modified polyol, the type 1 polyether polyol, the type 2 polyether polyol, the polymer polyol, the foaming agent, the chain extender, the catalyst and the cell regulator to obtain the premix A; and (2) mixing the premix A and the isocyanate mixture B at a high speed, putting the mixture thus obtained into a mold for molding, and leaving the mixture to stand to obtain the cushioning and shock-absorbing material with a high cushioning performance.

7. The method for preparing the vegetable oil-based cartilage bionic cushioning and shock-absorbing material according to claim 6, wherein said mixing the premix A and the isocyanate mixture B at a high speed is carried out at a speed of 300-10000 rpm for 0.1-45 seconds; the premix A and the isocyanate mixture B are preheated at 18 C.-40 C.; said molding is carried out at 30 C-70 C. for 3-45 minutes, and the standing lasts for 1-12 hours.

8. The method for preparing the cushioning and shock-absorbing material with high cushioning performance according to claim 7, wherein the cushioning and shock-absorbing material with high cushioning performance has a density of 0.1-0.9 g/cm.sup.3 and a hardness of Shore A 10 to Shore C 90; and the permanent compression set thereof is no more than 5%.

9. Anti-impact protection products for human bodies, anti-falling and anti-impact protection of articles, shock absorption and anti-collision protection of automobiles, anti-riot products, anti-bullet products, anti-impact products, shock wave filtration and energy absorption protection of submarines and aircrafts, vibration protection of intelligent equipment, cushioning and shock absorption protection of aircrafts, anti-impact protection products for athletes, shock absorption and protection of medical products, shock absorption and energy absorption protection of floors, or anti-collision and energy absorption protection of walls, comprising the vegetable oil-based cartilage bionic cushioning and shock-absorbing material according to claim 1.

Description

DETAILED DESCRIPTION

(1) The present invention will be further described below in detail in combination with specific embodiments, but the embodiments of the present invention are not limited thereto. For unspecified process parameters, reference can be made to the conventional techniques.

(2) In examples 1-12:

(3) The vegetable oil-based polyol is a soybean oil polyol HM10200 produced by Guangzhou HAIRMA Vegetable Oil and Fat Co., Ltd., with a hydroxyl value of 200 mg KOH/g and a molecular weight of 3700.

(4) The type 1 polyether polyol is polypropylene glycol PPG-1000 produced by Jiangsu Haian Petrochemical Plant, with a hydroxyl value of 112 mg KOH/g.

(5) The type 2 polyether polyol is polyether polyol CHE-330N produced by Jiangsu Changhua Polyurethane Co., Ltd., with a hydroxyl value of 35 mg KOH/g.

(6) The polymer polyol is polymer polyol CHP-H30 produced by Jiangsu Changhua Polyurethane Co., Ltd., with a hydroxyl value of 27 mg KOH/g.

(7) The chain extender is ethylene glycol produced by BASF. The silicone surfactant is Y10366 produced by Momentive Performance Materials Inc., USA.

(8) The catalyst is a mixture of a solution obtained by dissolving bis(2-dimethylaminoethyl)ether of which the weight percentage thereof is 70 wt. % in the dipropylene glycol and a solution obtained by dissolving triethylenediamine of which the weight percentage thereof is 33 wt. % in the dipropylene glycol. The weight ratio of the bis(2-dimethylaminoethyl)ether to the triethylenediamine is 0.05:0.5.

(9) The cell regulator is a block copolymer of a monofunctional polypropylene oxide with a polyethylene oxide, with a molecular weight of 500 and an ethylene oxide content of 60%.

(10) A method for preparing the polyether polyol modified isocyanate is as follows: melting the diphenylmethane diisocyanate at a temperature of 45 C., then adding the PPG-400, rising the temperature to 70 C.-90 C. to react for 2-3 hours until the terminalNCO group content becomes 22%-24%, and then rising the temperature to 100 C.-110 C. to react for 0.5-1 hours to form a modified diphenylmethane diisocyanate with a terminalNCO group content of 21.8%.

(11) The HDI is 50M-HDI produced by Japan TOSOH NPU, with the NCO group content of 49.9%.

Example 1

(12) A method for preparing a vegetable oil-based cartilage bionic cushioning and shock-absorbing material with high cushioning performance specifically comprises the following steps:

(13) (1) well mixing 10 parts by weight of the vegetable oil-based polyol, 40 parts by weight of the type 1 polyether polyol, 40 parts by weight of the type 2 polyether polyol, 10 parts by weight of the polymer polyol, 0.1 parts by weight of water, 0.1 parts by weight of the silicone surfactant, 1.0 part by weight of the ethylene glycol, 1.2 parts by weight of the catalyst, and 5 parts by weight of the cell regulator to obtain a premix A, and maintaining the temperature at 40 C.;

(14) (2) mixing the polyether polyol modified isocyanate and hexamethylene diisocyanate at a weight ratio of 65:35 to form an isocyanate mixture B, and maintaining the temperature at 40 C.; and

(15) (3) well mixing the premix A and the isocyanate mixture B at a molar ratio 100:100 of OH to NCO in a high speed (the high-speed mixing revolving speed is 10000 rpm, and the mixing time is 0.1 seconds), then putting the mixture into a mold for molding (the molding temperature is 70 C., and the molding time is 3 minutes), and leaving the mixture to stand for 4 hours at room temperature to obtain the cushioning and shock-absorbing material with high cushioning performance, wherein the performance parameters thereof are shown in Table 1.

Example 2

(16) A method for preparing a vegetable oil-based cartilage bionic cushioning and shock-absorbing material with high cushioning performance specifically comprises the following steps:

(17) (1) well mixing 20 parts by weight of the vegetable oil-based polyol, 30 parts by weight of the type 1 polyether polyol, 40 parts by weight of the type 2 polyether polyol, 10 parts by weight of the polymer polyol, 0.1 parts by weight of water, 0.1 parts by weight of the silicone surfactant, 1.0 part by weight of the ethylene glycol, 1.2 parts by weight of the catalyst, and 5 parts by weight of the cell regulator to obtain a premix A, and maintaining the temperature at 40 C.;

(18) (2) mixing the polyether polyol modified isocyanate and hexamethylene diisocyanate at a weight ratio of 65:35 to form an isocyanate mixture B, and maintaining the temperature at 40 C.; and

(19) (3) well mixing the premix A and the isocyanate mixture B at a ratio 100:100 of OH to NCO in a high speed (the high-speed mixing revolving speed is 10000 rpm, and the mixing time is 0.1 seconds), then putting the mixture into a mold for molding (the molding temperature is 70 C., and the molding time is 3 minutes), and leaving the mixture to stand for 4 hours at room temperature to obtain the cushioning and shock-absorbing material with high cushioning performance, wherein the performance parameters thereof are shown in Table 1.

Example 3

(20) A method for preparing a vegetable oil-based cartilage bionic cushioning and shock-absorbing material with high cushioning performance specifically comprises the following steps:

(21) (1) well mixing 30 parts by weight of the vegetable oil-based polyol, 20 parts by weight of the type 1 polyether polyol, 40 parts by weight of the type 2 polyether polyol, 10 parts by weight of the polymer polyol, 0.1 parts by weight of water, 0.1 parts by weight of the silicone surfactant, 1.0 part by weight of the ethylene glycol, 1.2 parts by weight of the catalyst, and 5 parts by weight of the cell regulator to obtain a premix A, and maintaining the temperature at 40 C.;

(22) (2) mixing the polyether polyol modified isocyanate and hexamethylene diisocyanate at a weight ratio of 65:35 to form an isocyanate mixture B, and maintaining the temperature at 40 C.; and

(23) (3) well mixing the premix A and the isocyanate mixture B at a ratio 100:100 of OH to NCO in a high speed (the high-speed mixing revolving speed is 10000 rpm, and the mixing time is 0.1 seconds), then putting the mixture into a mold for molding (the molding temperature is 70 C., and the molding time is 3 minutes), and leaving the mixture to stand for 4 hours at room temperature to obtain the cushioning and shock-absorbing material with high cushioning performance, wherein the performance parameters thereof are shown in Table 1.

Example 4

(24) A method for preparing a vegetable oil-based cartilage bionic cushioning and shock-absorbing material with high cushioning performance specifically comprises the following steps:

(25) (1) well mixing 20 parts by weight of the vegetable oil-based polyol, 20 parts by weight of the type 1 polyether polyol, 30 parts by weight of the type 2 polyether polyol, 30 parts by weight of the polymer polyol, 0.5 parts by weight of water, 0.8 parts by weight of the silicone surfactant, 3.0 part by weight of the ethylene glycol, 0.6 parts by weight of the catalyst, and 3.0 parts by weight of the cell regulator to obtain a premix A, and maintaining the temperature at 35 C.;

(26) (2) mixing the polyether polyol modified isocyanate and hexamethylene diisocyanate at a weight ratio of 75:25 to form an isocyanate mixture B, and maintaining the temperature at 35 C.; and

(27) (3) well mixing the premix A and the isocyanate mixture B at a ratio 100:105 of OH to NCO in a high speed (the high-speed mixing revolving speed is 5000 rpm, and the mixing time is 0.2 seconds), then putting the mixture into a mold for molding (the molding temperature is 60 C., and the molding time is 7 minutes), and leaving the mixture to stand for 5 hours at room temperature to obtain the cushioning and shock-absorbing material with high cushioning performance, wherein the performance parameters thereof are shown in Table 1.

Example 5

(28) A method for preparing a vegetable oil-based cartilage bionic cushioning and shock-absorbing material with high cushioning performance specifically comprises the following steps:

(29) (1) well mixing 20 parts by weight of the vegetable oil-based polyol, 20 parts by weight of the type 1 polyether polyol, 40 parts by weight of the type 2 polyether polyol, 20 parts by weight of the polymer polyol, 0.5 parts by weight of water, 0.8 parts by weight of the silicone surfactant, 3.0 part by weight of the ethylene glycol, 0.6 parts by weight of the catalyst, and 3.0 parts by weight of the cell regulator to obtain a premix A, and maintaining the temperature at 35 C.;

(30) (2) mixing the polyether polyol modified isocyanate and hexamethylene diisocyanate at a weight ratio of 75:25 to form an isocyanate mixture B, and maintaining the temperature at 35 C.; and

(31) (3) well mixing the premix A and the isocyanate mixture B at a ratio 100:105 of OH to NCO in a high speed (the high-speed mixing revolving speed is 5000 rpm, and the mixing time is 0.2 seconds), then putting the mixture into a mold for molding (the molding temperature is 60 C., and the molding time is 7 minutes), and leaving the mixture to stand for 5 hours at room temperature to obtain the cushioning and shock-absorbing material with high cushioning performance, wherein the performance parameters thereof are shown in Table 1.

Example 6

(32) A method for preparing a vegetable oil-based cartilage bionic cushioning and shock-absorbing material with high cushioning performance specifically comprises the following steps:

(33) (1) well mixing 20 parts by weight of the vegetable oil-based polyol, 20 parts by weight of the type 1 polyether polyol, 50 parts by weight of the type 2 polyether polyol, 10 parts by weight of the polymer polyol, 0.5 parts by weight of water, 0.8 parts by weight of the silicone surfactant, 3.0 part by weight of the ethylene glycol, 0.6 parts by weight of the catalyst, and 3.0 parts by weight of the cell regulator to obtain a premix A, and maintaining the temperature at 35 C.;

(34) (2) mixing the polyether polyol modified isocyanate and hexamethylene diisocyanate at a weight ratio of 75:25 to form an isocyanate mixture B, and maintaining the temperature at 35 C.; and

(35) (3) well mixing the premix A and the isocyanate mixture B at a ratio 100:105 of OH to NCO in a high speed (the high-speed mixing revolving speed is 5000 rpm, and the mixing time is 0.2 seconds), then putting the mixture into a mold for molding (the molding temperature is 60 C., and the molding time is 8 minutes), and leaving the mixture to stand for 5 hours at room temperature to obtain the cushioning and shock-absorbing material with high cushioning performance, wherein the performance parameters thereof are shown in Table 1.

Example 7

(36) A method for preparing a vegetable oil-based cartilage bionic cushioning and shock-absorbing material with high cushioning performance specifically comprises the following steps:

(37) (1) well mixing 30 parts by weight of the vegetable oil-based polyol, 20 parts by weight of the type 1 polyether polyol, 30 parts by weight of the type 2 polyether polyol, 20 parts by weight of the polymer polyol, 0.8 parts by weight of water, 2.0 parts by weight of the silicone surfactant, 5.0 part by weight of the ethylene glycol, 0.3 parts by weight of the catalyst, and 2.0 parts by weight of the cell regulator to obtain a premix A, and maintaining the temperature at 20 C.;

(38) (2) mixing the polyether polyol modified isocyanate and hexamethylene diisocyanate at a weight ratio of 85:15 to form an isocyanate mixture B, and maintaining the temperature at 20 C.; and

(39) (3) well mixing the premix A and the isocyanate mixture B at a ratio 100:110 of OH to NCO in a high speed (the high-speed mixing revolving speed is 300 rpm, and the mixing time is 45 seconds), then putting the mixture into a mold for molding (the molding temperature is 30 C., and the molding time is 45 minutes), and leaving the mixture to stand for 12 hours at room temperature to obtain the cushioning and shock-absorbing material with high cushioning performance, wherein the performance parameters thereof are shown in Table 1.

Example 8

(40) A method for preparing a vegetable oil-based cartilage bionic cushioning and shock-absorbing material with high cushioning performance specifically comprises the following steps:

(41) (1) well mixing 30 parts by weight of the vegetable oil-based polyol, 20 parts by weight of the type 1 polyether polyol, 35 parts by weight of the type 2 polyether polyol, 15 parts by weight of the polymer polyol, 0.8 parts by weight of water, 2.0 parts by weight of the silicone surfactant, 5.0 part by weight of the ethylene glycol, 0.3 parts by weight of the catalyst, and 2.0 parts by weight of the cell regulator to obtain a premix A, and maintaining the temperature at 20 C.;

(42) (2) mixing the polyether polyol modified isocyanate and hexamethylene diisocyanate at a weight ratio of 85:15 to form an isocyanate mixture B, and maintaining the temperature at 20 C.; and

(43) (3) well mixing the premix A and the isocyanate mixture B at a ratio 100:110 of OH to NCO in a high speed (the high-speed mixing revolving speed is 300 rpm, and the mixing time is 45 seconds), then putting the mixture into a mold for molding (the molding temperature is 30 C., and the molding time is 45 minutes), and leaving the mixture to stand for 12 hours at room temperature to obtain the cushioning and shock-absorbing material with high cushioning performance, wherein the performance parameters thereof are shown in Table 1.

Example 9

(44) A method for preparing a vegetable oil-based cartilage bionic cushioning and shock-absorbing material with high cushioning performance specifically comprises the following steps:

(45) (1) well mixing 30 parts by weight of the vegetable oil-based polyol, 20 parts by weight of the type 1 polyether polyol, 20 parts by weight of the type 2 polyether polyol, 30 parts by weight of the polymer polyol, 0.8 parts by weight of water, 2.0 parts by weight of the silicone surfactant, 5.0 part by weight of the ethylene glycol, 0.3 parts by weight of the catalyst, and 2.0 parts by weight of the cell regulator to obtain a premix A, and maintaining the temperature at 20 C.;

(46) (2) mixing the polyether polyol modified isocyanate and hexamethylene diisocyanate at a weight ratio of 85:15 to form an isocyanate mixture B, and maintaining the temperature at 20 C.; and

(47) (3) well mixing the premix A and the isocyanate mixture B at a ratio 100:110 of OH to NCO in a high speed (the high-speed mixing revolving speed is 300 rpm, and the mixing time is 45 seconds), then putting the mixture into a mold for molding (the molding temperature is 30 C., and the molding time is 45 minutes), and leaving the mixture to stand for 12 hours at room temperature to obtain the cushioning and shock-absorbing material with high cushioning performance, wherein the performance parameters thereof are shown in Table 1.

Example 10

(48) A method for preparing a vegetable oil-based cartilage bionic cushioning and shock-absorbing material with high cushioning performance specifically comprises the following steps:

(49) (1) well mixing 30 parts by weight of the vegetable oil-based polyol, 20 parts by weight of the type 1 polyether polyol, 20 parts by weight of the type 2 polyether polyol, 30 parts by weight of the polymer polyol, 1.0 part by weight of water, 1.2 parts by weight of the silicone surfactant, 2.0 part by weight of the ethylene glycol, 2.0 parts by weight of the catalyst, and 4.0 parts by weight of the cell regulator to obtain a premix A, and maintaining the temperature at 18 C.;

(50) (2) mixing the polyether polyol modified isocyanate and hexamethylene diisocyanate at a weight ratio of 70:30 to form an isocyanate mixture B, and maintaining the temperature at 18 C.; and

(51) (3) well mixing the premix A and the isocyanate mixture B at a ratio 100:103 of OH to NCO in a high speed (the high-speed mixing revolving speed is 800 rpm, and the mixing time is 22 seconds), then putting the mixture into a mold for molding (the molding temperature is 40 C., and the molding time is 25 minutes), and leaving the mixture to stand for 4 hours at room temperature to obtain the cushioning and shock-absorbing material with high cushioning performance, wherein the performance parameters thereof are shown in Table 1.

Example 11

(52) A method for preparing a vegetable oil-based cartilage bionic cushioning and shock-absorbing material with high cushioning performance specifically comprises the following steps:

(53) (1) well mixing 30 parts by weight of the vegetable oil-based polyol, 20 parts by weight of the type 1 polyether polyol, 20 parts by weight of the type 2 polyether polyol, 30 parts by weight of the polymer polyol, 1.0 part by weight of water, 1.2 parts by weight of the silicone surfactant, 2.0 part by weight of the ethylene glycol, 2.0 parts by weight of the catalyst, and 4.0 parts by weight of the cell regulator to obtain a premix A, and maintaining the temperature at 18 C.;

(54) (2) mixing the polyether polyol modified isocyanate and hexamethylene diisocyanate at a weight ratio of 70:30 to form an isocyanate mixture B, and maintaining the temperature at 18 C.; and

(55) (3) well mixing the premix A and the isocyanate mixture B at a ratio 100:105 of OH to NCO in a high speed (the high-speed mixing revolving speed is 800 rpm, and the mixing time is 22 seconds), then putting the mixture into a mold for molding (the molding temperature is 40 C., and the molding time is 30 minutes), and leaving the mixture to stand for 6 hours at room temperature to obtain the cushioning and shock-absorbing material with high cushioning performance, wherein the performance parameters thereof are shown in Table 1.

Example 12

(56) A method for preparing a vegetable oil-based cartilage bionic cushioning and shock-absorbing material with high cushioning performance specifically comprises the following steps:

(57) (1) well mixing 30 parts by weight of the vegetable oil-based polyol, 20 parts by weight of the type 1 polyether polyol, 20 parts by weight of the type 2 polyether polyol, 30 parts by weight of the polymer polyol, 1.0 part by weight of water, 1.2 parts by weight of the silicone surfactant, 2.0 part by weight of the ethylene glycol, 2.0 parts by weight of the catalyst, and 4.0 parts by weight of the cell regulator to obtain a premix A, and maintaining the temperature at 18 C.;

(58) (2) mixing the polyether polyol modified isocyanate and hexamethylene diisocyanate at a weight ratio of 70:30 to form an isocyanate mixture B, and maintaining the temperature at 18 C.; and

(59) (3) well mixing the premix A and the isocyanate mixture B at a ratio 100:108 of OH to NCO in a high speed (the high-speed mixing revolving speed is 800 rpm, and the mixing time is 22 seconds), then putting the mixture into a mold for molding (the molding temperature is 40 C., and the molding time is 32 minutes), and leaving the mixture to stand for 8 hours at room temperature to obtain the cushioning and shock-absorbing material with high cushioning performance, wherein the performance parameters thereof are shown in Table 1.

(60) Performance tests of the cushioning materials in examples 1-12 and the prior art:

(61) 1. The breathability is measured by a Gurley tester, specifically, the material is cut into a 50 MM-thick specimen sheet which is then placed on a closed exhaust port of the device, compressed air of certain pressure is applied thereto, and the breathability of the material is determined according to the air block-up situation, wherein the material breathability is generally represented by three results, i.e., an open cell, a semi-open cell and a closed cell, the open cell represents good material breathability, the semi-open cell represents ordinary material breathability, and the closed cell represents material non-breathability.

(62) 2. The hardness is tested by using the ASTM D2240 method, wherein the test is respectively performed at a temperature of 23 C., 0 C. and 10 C., the humidity is 60%, the unit of the test value is Asker C-type, a test value of the test on glass is 100.

(63) 3. The compression set is tested according to the ASTM D395-B method, wherein the specimen is compressed by 50% in a thickness direction, and kept in a condition with a temperature of 70 C. and humidity of 50% for 22 hours, compressive stress release is performed for 30 minutes at room temperature, then the thickness thereof is measured and the compression set thereof is calculated according to the following formula:
compression set=(original specimen thicknessthickness after compression processing)/original specimen thickness*100%

(64) 4. The cushioning performance is tested by using a test method and device of the EN1621-2 standard, wherein the thickness of the specimen material is 13 MM, the length*width size is 35*25 CM; and the test condition is as follows: 23 C.2 C. and the humidity of 60%. Herein, the index value, i.e., the impact force peak value indicating the cushioning performance, is explained as follows: when an object of a weight of about 5 KG falls from a certain height onto the specimen material, an impact energy of 50 KN is generated, and the impact force received by an electronic stress sensor below the specimen after cushioning and shock absorption performed by the specimen material is referred to as the impact force peak value, of which the unit thereof is N. A smaller peak value represents a better cushioning and energy absorption effect of the material.

(65) TABLE-US-00001 TABLE 1 Performance test results of the vegetable oil-based cartilage bionic cushioning and shock-absorbing materials prepared in examples 1-12 Compression Hardness Impact force peak Breathability set % 23 C. 0 C. 10 C. value N Example 1 Breathable 3.7 25 28 35 13155 Example 2 Breathable 3.9 24 27 34 13280 Example 3 Breathable 4.2 23 25 33 13850 Example 4 Breathable 4.3 35 43 53 13005 Example 5 Breathable 4.5 32 40 50 13201 Example 6 Breathable 4.5 30 38 48 14025 Example 7 Breathable 4.8 40 48 58 12105 Example 8 Breathable 4.9 40 48 59 11850 Example 9 Breathable 4.9 42 50 61 11505 Example 10 Breathable 4.6 28 35 45 14550 Example 11 Breathable 4.7 30 38 48 14500 Example 12 Breathable 4.6 35 43 53 13800

(66) TABLE-US-00002 TABLE 2 Performance test data of the existing cushioning materials Existing cushioning Compression Hardness Impact force materials Breathability set % 23 C. 0 C. 10 C. peak value N EVA Cell-closed 42.8 40 55 70 30305 POLYYOU Breathable 15.5 25 32 40 30210 Sponge Breathable 22.1 18 25 33 35008 Rubber Cell-closed 6.8 35 50 65 28501 XPE Cell-closed 41.5 32 45 60 29151 Latex Breathable 28.1 25 35 45 33105 SBR Cell-closed 38.1 18 30 50 32158 EPS Cell-closed 45.1 60 85 95 24085

(67) It can be seen from the comparison between Table 1 and Table 2 that the cushioning material produced in the present invention has the following advantages:

(68) 1. The material has an excellent cushioning effect, a wide applicable temperature range and good low-temperature compliance, and is applicable to multiple cases in which the high cushioning effect is maintained.

(69) 2. The material is breathable with open cells, and has the features of heat dissipation, breathability and anti-bacteria in the production of sports products.

(70) 3. The material has a low compression set, good thermal stability, a stable size and durability.

(71) The above examples of the present invention are merely examples used for clearly describing the present invention, instead of limiting the implementation modes of the present invention. For one skilled in the art, other forms of changes or variations may also be made on the basis of the above description. There is no need and no way to exhaust all implementation modes here. Within the spirit and principle of the present invention, any modifications, equivalent replacements, improvements, etc., shall be included within the scope of protection of the present invention.