CYANOACRYLATE COMPOSITIONS

Abstract

This invention relates to cyanoacrylate composition, comprising: (a) a -alkoxyakyl cyanoacrylate component, (b) a cyanoacrylate component selected from 2-methylbutyl cyanoacrylate, isoamyl cyanoacrylate, 2-ethylhexyl cyanoacrylate, 2-pentyl cyanoacrylate, 3-methylpentyl cyanoacrylate, 2-ethylbutyl cyanoacrylate, 3,7-dimethyloctyl cyanoacrylate, and combinations thereof; and (c) a rubber toughening component; (d) a humidity resistance conferring component; and (e) a thermal resistance conferring component. Cured products of the inventive cyanoacrylate compositions demonstrate improved toughening, and thermal and humidity resistance without the odor oftentimes experienced with conventional cyanoacrylate compositions or the blooming also experienced with compositions.

Claims

1. A cyanoacrylate composition, comprising: (a) a -alkoxyakyl cyanoacrylate component, (b) a cyanoacrylate component selected from the group consisting of 2-methylbutyl cyanoacrylate, isoamyl cyanoacrylate, 2-ethylhexyl cyanoacrylate, 2-pentyl cyanoacrylate, 3-methylpentyl cyanoacrylate, 2-ethylbutyl cyanoacrylate, 3,7-dimethyloctyl cyanoacrylate, and combinations thereof; (c) a rubber toughening component; (d) a humidity resistance conferring component; and (e) a thermal resistance conferring component.

2. The composition according to claim 1, wherein the -alkoxy cyanoacrylate component is selected from -methoxy ethyl cyanoacrylate, -ethoxy ethyl cyanoacrylate, and combinations thereof.

3. The composition according to claim 1, wherein the rubber toughening component is selected from the group consisting of (a) reaction products of the combination of ethylene, methyl acrylate and monomers having carboxylic acid cure sites, (b) dipolymers of ethylene and methyl acrylate, (c) vinylidene chloride-acrylonitrile copolymers, (d) vinyl chloride/vinyl acetate copolymer, (e) copolymers of polyethylene and polyvinyl acetate, and combinations thereof.

4. The composition according to claim 1, wherein the rubber toughening component is a reaction product of the combination of ethylene, methyl acrylate and monomers having carboxylic acid cure sites, wherein the reaction product is substantially free of release agents, anti-oxidants, stearic acid and polyethylene glycol ether wax.

5. The composition according to claim 1, wherein the humidity resistance conferring component is an anhydride.

6. The composition according to claim 1, wherein the humidity resistance conferring component is an aromatic anhydride.

7. The composition according to claim 1, wherein the humidity resistance conferring component is a hydrogenated aromatic anhydride.

8. The composition according to claim 1, wherein the humidity resistance conferring component is a hydrogenated phthalic anhydride.

9. The composition according to claim 1, wherein the humidity resistance conferring component is a tetrahydrophthalic anhydride.

10. The composition according to claim 1, wherein the thermal resistance conferring component is a benzonitrile.

11. The composition according to claim 1, wherein the thermal resistance conferring component is selected from the group consisting of 3,5-dinitrobenzonitrile; 2-chloro-3,5-dinitrobenzonitrile; Tetrafluoroisophthalonitrile pentafluorobenzonitrile; ,,-2-tetrafluoro-p-tolunitrile; and tetrachloroterphthalonitrile.

12. The composition according to claim 1, further comprising one or more of a thixotrope, a gelling agent, a thickener, an accelerator, and a shock resistance conferring agent.

13. The composition according to claim 12, wherein the thixotrope is a fumed silica.

14. The composition according to claim 12, wherein the accelerator is selected from the group consisting of calixarene, oxacalixarene, silacrown, cyclodextrin, crown ether, poly(ethyleneglycol) di(meth)acrylate, ethoxylated hydric compound, and combinations thereof.

15. The composition according to claim 14, wherein the calixarene is tetrabutyl tetra[2-ethoxy-2-oxoethoxy]calix-4-arene.

16. The composition according to claim 14, wherein the crown ether is selected from members within the group consisting of 15-crown-5, 18-crown-6, dibenzo-18-crown-6, benzo-15-crown-5-dibenzo-24-crown-8, dibenzo-30-crown-10, tribenzo-18-crown-6, asym-dibenzo-22-crown-6, dibenzo-14-crown-4, dicyclohexyl-18-crown-6, dicyclohexyl-24-crown-8, cyclohexyl-12-crown-4, 1,2-decalyl-15-crown-5, 1,2-naphtho-15-crown-5, 3,4,5-naphtyl-16-crown-5, 1,2-methyl-benzo-18-crown-6, 1,2-methylbenzo-5, 6-methylbenzo-18-crown-6, 1,24-butyl-18-crown-6, 1,2-vinylbenzo-15-crown-5, 1,2-vinylbenzo-18-crown-6, 1,24-butyl-cyclohexyl-18-crown-6, asym-dibenzo-22-crown-6, and 1,2-benzo-1,4-benzo-5-oxygen-20-crown-7 and combinations thereof.

17. The composition according to claim 14, wherein the poly(ethyleneglycol) di(meth)acrylate is within the following structure: ##STR00005## wherein n is greater than 3.

18. The composition according to claim 12, wherein the shock resistance conferring agent is citric acid.

19. The composition according to claim 1, wherein the -alkoxyalkyl cyanoacrylate component (a) and the cyanoacrylate component (b) are present in the composition in a by weight ratio in the range of about 50 to about 80: about 20 to about 50.

20. The composition according to claim 1, wherein the -alkoxyalkyl cyanoacrylate component (a) and the cyanoacrylate component (b) are present in the composition in a by weight ratio in the range of about 70:30.

21. The composition according to claim 1, further comprising a stabilizing amount of an acidic stabilizer and a free radical inhibitor.

22. Reaction products of the composition according to claim 1.

23. A composition comprising: (a) a cyanoacrylate component selected from the group consisting of 2-methylbutyl cyanoacrylate, isoamyl cyanoacrylate, 2-ethylhexyl cyanoacrylate, 2-pentyl cyanoacrylate, 3-methylpentyl cyanoacrylate, 2-ethylbutyl cyanoacrylate, 3,7-dimethyloctyl cyanoacrylate, and combinations thereof, and (b) a rubber toughening component.

24. The composition according to claim 23, wherein the cyanoacrylate component is isoamyl cyanoacrylate.

25. The composition according to claim 23, wherein the rubber toughening component is selected from the group consisting of (a) reaction products of the combination of ethylene, methyl acrylate and monomers having carboxylic acid cure sites, (b) dipolymers of ethylene and methyl acrylate, (c) vinylidene chloride-acrylonitrile copolymers, (d) vinyl chloride/vinyl acetate copolymer, (e) copolymers of polyethylene and polyvinyl acetate, and combinations thereof.

26. The composition according to claim 23, wherein the rubber toughening component is a reaction product of the combination of ethylene, methyl acrylate and monomers having carboxylic acid cure sites, wherein the reaction product is free of release agents, anti-oxidants, stearic acid and polyethylene glycol ether wax.

27. A composition comprising a rubber toughening component dissolved in an amount of up to about 20 weight percent in a cyanoacrylate component selected from the group consisting of 2-methylbutyl cyanoacrylate, isoamyl cyanoacrylate, 2-ethylhexyl cyanoacrylate, 2-pentyl cyanoacrylate, 3-methylpentyl cyanoacrylate, 2-ethylbutyl cyanoacrylate, 3,7-dimethyloctyl cyanoacrylate, and combinations thereof.

28. The composition according to claim 27, wherein the cyanoacrylate component is isoamyl cyanoacrylate.

29. The composition according to claim 27, wherein the rubber toughening component is selected from the group consisting of (a) reaction products of the combination of ethylene, methyl acrylate and monomers having carboxylic acid cure sites, (b) dipolymers of ethylene and methyl acrylate, (c) vinylidene chloride-acrylonitrile copolymers, (d) vinyl chloride/vinyl acetate copolymer, (e) copolymers of polyethylene and polyvinyl acetate, and combinations thereof.

30. The composition according to claim 27, wherein the rubber toughening component is a reaction product of the combination of ethylene, methyl acrylate and monomers having carboxylic acid cure sites, wherein the reaction product is substantially free of release agents, anti-oxidants, stearic acid and polyethylene glycol ether wax.

31. A method of bonding together two substrates, comprising the steps of: applying a cyanoacrylate composition according to claim 1 to at least one of the substrates, and mating together the substrates for a time sufficient to permit the composition to fixture.

32. A method of preparing a cyanoacrylate composition according to claim 1, comprising the steps of: providing a rubber toughening component dissolved in a cyanoacrylate component selected from the group consisting of 2-methylbutyl cyanoacrylate, isoamyl cyanoacrylate, 2-ethylhexyl cyanoacrylate, 2-pentyl cyanoacrylate, 3-methylpentyl cyanoacrylate, 2-ethylbutyl cyanoacrylate, 3,7-dimethyloctyl cyanoacrylate, and combinations thereof, and combining therewith with mixing a -alkoxyalkyl cyanoacrylate component.

33. A method of conferring at least one of improved peel strength and side impact strength to a cured product of a cyanoacrylate composition, comprising the steps of: providing a -alkoxyalkyl cyanoacrylate component; and providing a rubber toughening component dissolved in a cyanoacrylate component selected from the group consisting of 2-methylbutyl cyanoacrylate, isoamyl cyanoacrylate, 2-ethylhexyl cyanoacrylate, 2-pentyl cyanoacrylate, 3-methylpentyl cyanoacrylate, 2-ethylbutyl cyanoacrylate, 3,7-dimethyloctyl cyanoacrylate, and combinations thereof.

34. The composition of claim 1, wherein when the composition is disposed between aluminum substrates to form a cured product and exposed to a temperature of 100 C. for a period of time of about 6 weeks, the cured product demonstrates improved temperature performance over a comparable composition without components (d) and (e).

35. The composition of any of claim 1, wherein when the composition is disposed between mild steel substrates to form a cured product and exposed to a temperature of 100 C. for a period of time of about 6 weeks or relative humidity conditions of 98% and a temperature of 40 C. for a period of time of about 6 weeks, the cured product demonstrates improved temperature performance over a comparable composition without components (d) and (e).

36. The composition of claim 1, wherein the thermal resistance conferring component is tetrafluoroisophthalonitrile and when the composition is disposed between aluminum or mild steel substrates to form a cured product and exposed to a temperature of 120 C. for a period of time of about 6 weeks, the cured product demonstrates improved temperature performance over a comparable composition without components (d) and (e).

Description

BRIEF DESCRIPTION OF THE FIGURES

[0023] FIG. 1A depicts a bar chart of the data captured in Table A of the T-Peel strength performance of Sample A on mild steel substrates after curing at room temperature over time, with and without a spacer element which when present forms a 55 m gap between the substrates.

[0024] FIG. 1B depicts a bar chart of the data captured in Table B of the T-Peel strength performance of Samples A-C on mild steel substrates after curing at room temperature for one week, with and without a spacer element which when present forms a 55 m gap between the substrates.

[0025] FIG. 2 depicts a bar chart of side impact strength on mild steel substrates for Samples A-C shown in Table C as compared with LOCTITE Power Easy (referred to in the Tables and FIGs. as PE) and LOCTITE 454.

[0026] FIG. 3 depicts a bar chart of bond strengths on mild steel substrates after room temperature aging for the time periods noted for Samples A-C shown in Table 1 compared with LOCTITE Power Easy and LOCTITE 454.

[0027] FIG. 4 depicts a bar chart of bond strengths on aluminum substrates after room temperature aging for the time periods noted for Samples A-C shown in Table 1 compared with LOCTITE Power Easy and LOCTITE 454.

[0028] FIG. 5 depicts a bar chart of bond strengths observed on mild steel substrates after aging at a temperature of 100 C. for the time periods noted for Samples A-C shown in Table 1 compared with LOCTITE Power Easy and LOCTITE 454.

[0029] FIG. 6 depicts a bar chart of bond strengths observed on mild steel substrates after aging at a temperature of 120 C. for the time periods noted for Samples A-C shown in Table 1 compared with LOCTITE Power Easy and LOCTITE 454.

[0030] FIG. 7 depicts a bar chart of bond strengths on mild steel substrates after moisture durability aging at 40 C./98% RH of Samples A-C shown in Table 1 compared with LOCTITE Power Easy and LOCTITE 454.

[0031] FIG. 8 depicts a bar chart of bond strengths observed on mild steel substrates after 6 weeks of aging at room temperature, heat aging at 100 C. and 120 C., and 98% relative humidity and 40 C. of Samples A-C shown in Table 1 compared with LOCTITE Power Easy and LOCTITE 454.

[0032] FIG. 9 depicts a bar chart of bond strengths observed on aluminum substrates after 6 weeks of aging at room temperature, heat aging at 100 C. and 120 C., and 98% relative humidity and a temperature of 40 C. for Samples A-C shown in Table 1 compared with LOCTITE Power Easy and LOCTITE 454.

DETAILED DESCRIPTION

[0033] As noted above, this invention is directed to a cyanoacrylate composition, which includes (a) a -alkoxyakyl cyanoacrylate component, (b) a cyanoacrylate component selected from 2-methylbutyl cyanoacrylate, isoamyl cyanoacrylate, 2-ethylhexyl cyanoacrylate, 2-pentyl cyanoacrylate, 3-methylpentyl cyanoacrylate, 2-ethylbutyl cyanoacrylate, 3,7-dimethyloctyl cyanoacrylate, and combinations thereof; (c) a rubber toughening component; (d) a humidity resistance conferring component; and (e) a thermal resistance conferring component.

[0034] The -alkoxyalkyl cyanoacrylate component (a) may be chosen from -methoxymethyl cyanoacrylate, -methoxyethyl cyanoacrylate, -ethoxymethyl cyanoacrylate, -ethoxyethyl cyanoacrylate and combinations thereof. Particularly desirable among those -alkoxyalkyl cyanoacrylates is -methoxyethyl cyanoacrylate.

[0035] The -alkoxyalkyl cyanoacrylate component (a) should be included in the compositions in an amount within the range of from about 40% to about 90% by weight, with the range of about 55% to about 75% by weight being desirable, such as from about 55% to about 70% by weight or from about 55% to about 65% by weight, and about 60% by weight of the total composition being particularly desirable.

[0036] The cyanoacrylate component (b) may be selected from 2-methylbutyl cyanoacrylate, isoamyl cyanoacrylate, 2-ethylhexyl cyanoacrylate, 2-pentyl cyanoacrylate, 3-methylpentyl cyanoacrylate, 2-ethylbutyl cyanoacrylate, 3,7-dimethyloctyl cyanoacrylate, and combinations thereof. Particularly desirable among those cyanoacrylate components is isoamyl cyanoacrylate.

[0037] The cyanoacrylate component (b) should be included in the compositions in an amount within the range of from about 10% to about 50% by weight, with the range of about 20% to about 35% by weight being desirable, and about 30% by weight of the total composition being particularly desirable.

[0038] The rubber toughening component (c) may be selected from (i) reaction products of the combination of ethylene, methyl acrylate and monomers having carboxylic acid cure sites, (ii) dipolymers of ethylene and methyl acrylate, (iii) vinylidene chloride-acrylonitrile copolymers, (iv) vinyl chloride/vinyl acetate copolymer, (v) copolymers of polyethylene and polyvinyl acetate, and combinations thereof.

[0039] Desirably, the reaction products (c) (i) of the combination of ethylene, methyl acrylate and monomers having carboxylic acid cure sites, where the reaction products are substantially free of release agents, anti-oxidants, stearic acid and polyethylene glycol ether wax, -alkoxyalkyl cyanoacrylate are chosen for use. DuPont supplies such a reaction product under the trade name VAMAC VCS 5500.

[0040] The rubber toughening component (c) should be included in the compositions in an amount within the range of from about 3% to about 20% by weight, with the range of about 5% to about 15% by weight being desirable, and about 8% by weight of the total composition being particularly desirable.

[0041] As a thermal resistance conferring component (d), benzonitriles should be used, such as those chosen from mono-, poly- or hetero-aromatic compounds characterized by at least three substitutions on an aromatic ring thereof, with two or more of the substitutions being electron withdrawing groups. Specific examples of such benzonitriles include 3,5-dinitrobenzonitrile; tetrafluoroisophthalonitrile 2-chloro-3,5-dinitrobenzonitrile; pentafluorobenzonitrile; ,,-2-tetrafluoro-p-tolunitrile; and tetrachloroterphthalonitrile.

[0042] The thermal resistance conferring component (such as a benzonitrile) should be present in an amount up to about 3% by weight, like about 0.01% to about 3% by weight, such as about 0.1% to about 1% by weight, with about 0.5% by weight being particularly desirable.

[0043] As a humidity resistance conferring component (e), hydrogenated anhydrides ordinarily the hydrogenated anhydride should be a hydrogenated phthalic anhydride, such as 3,4,5,6-tetrahydro phthalic anhydride. However, isomeric versions thereof and partially hydrogenated versions of phthalic anhydride may also be used.

[0044] The humidity resistance conferring component (such as a hydrogenated phthalic anhydride) should be used in an amount up to about 0.1% by weight, such as within the range of about 0.01 to about 0.09, desirably within the range of about 0.03 to about 0.05% by weight. At such level, a product label generated under the EINECS regulatory regime in Europe would not need to carry a skin sensitizer warning in order to be in compliance with that portion of the regulations.

[0045] Desirably, the 3,4,5,6-tetrahydrophthalic anhydride should be used in an amount of up to about 1% by weight, such as about 0.01% to about 1% by weight, and the pentafluorobenzonitrile should be used in an amount of up to about 0.5% by weight, such as about 0.01% to about 0.5% by weight.

[0046] A particularly desirable set of constituents to form the inventive compositions may include those listed below, in the broad ranges and the desired ranges. In a parcularly preferred embodiment, the inventive compositions also include citric acid in an amount of about 50-100 ppm, desirably in an amount of about 100 ppm.

TABLE-US-00001 Broad Desirable Constituents Range Range Type Identity (wt %) (wt %) Cyanoacrylate Isoamyl cyanoacrylate 10-50 20-35 -Methoxy ethyl 40-90 55-75 cyanoacrylate Rubber toughener VAMAC VCS 5500 3-20 5-15 Thickener Silica 3-10 5-6 Thermal Tetrafluoroiso- 0.1-3 0.1-1 resistance phthalonitrile conferring 2,3,4,5,6- 0.1-3 0.1-1 component Pentafluorobenzo- nitrile Humidity resistance 3,4,5,6- 0.1-3 0.1-1 conferring Tetrahydrophthalic component anhydride

[0047] Accelerators may also be included in the inventive cyanoacrylate compositions, such as any one or more selected from calixarenes and oxacalixarenes, silacrowns, crown ethers, cyclodextrins, poly(ethyleneglycol) di(meth)acrylates, ethoxylated hydric compounds and combinations thereof.

[0048] Of the calixarenes and oxacalixarenes, many are known, and are reported in the patent literature. See e.g. U.S. Pat. Nos. 4,556,700, 4,622,414, 4,636,539, 4,695,615, 4,718,966, and 4,855,461, the disclosures of each of which are hereby expressly incorporated herein by reference.

[0049] For instance, as regards calixarenes, those within the following structure are useful herein:

##STR00001##

where R.sup.1 is alkyl, alkoxy, substituted alkyl or substituted alkoxy; R.sup.2 is H or alkyl; and n is 4, 6 or 8.

[0050] One particularly desirable calixarene is tetrabutyl tetra[2-ethoxy-2-oxoethoxy]calix-4-arene.

[0051] A host of crown ethers are known. For instance, any one or more of 15-crown-5, 18-crown-6, dibenzo-18-crown-6, benzo-15-crown-5-dibenzo-24-crown-8, dibenzo-30-crown-10, tribenzo-18-crown-6, asym-dibenzo-22-crown-6, dibenzo-14-crown-4, dicyclohexyl-18-crown-6, dicyclohexyl-24-crown-8, cyclohexyl-12-crown-4, 1,2-decalyl-15-crown-5, 1,2-naphtho-15-crown-5, 3,4,5-naphtyl-16-crown-5, 1,2-methyl-benzo-18-crown-6, 1,2-methylbenzo-5, 6-methylbenzo-18-crown-6, 1,2-t-butyl-18-crown-6, 1,2-vinylbenzo-15-crown-5, 1,2-vinylbenzo-18-crown-6, 1,2-t-butyl-cyclohexyl-18-crown-6, asym-dibenzo-22-crown-6 and 1,2-benzo-1,4-benzo-5-oxygen-20-crown-7 may be used. See U.S. Pat. No. 4,837,260 (Sato), the disclosure of which is hereby expressly incorporated herein by reference. Of the silacrowns, again many are known, and are reported in the literature.

[0052] Specific examples of silacrown compounds useful in the inventive compositions include:

##STR00002##

See e.g. U.S. Pat. No. 4,906,317 (Liu), the disclosure of which is hereby expressly incorporated herein by reference.

[0053] Many cyclodextrins may be used in connection with the present invention. For instance, those described and claimed in U.S. Pat. No. 5,312,864 (Wenz), the disclosure of which is hereby expressly incorporated herein by reference, as hydroxyl group derivatives of an , or -cyclodextrin which is at least partly soluble in the cyanoacrylate would be appropriate choices for use herein as the first accelerator component.

[0054] For instance, poly(ethylene glycol) di(meth)acrylates suitable for use herein include those within the following structure:

##STR00003##

where n is greater than 3, such as within the range of 3 to 12, with n being 9 as particularly desirable. More specific examples include PEG 200 DMA, (where n is about 4) PEG 400 DMA (where n is about 9), PEG 600 DMA (where n is about 14), and PEG 800 DMA (where n is about 19), where the number (e.g., 400) represents the average molecular weight of the glycol portion of the molecule, excluding the two methacrylate groups, expressed as grams/mole (i.e., 400 g/mol). A particularly desirable PEG DMA is PEG 400 DMA.

[0055] And of the ethoxylated hydric compounds (or ethoxylated fatty alcohols that may be employed), appropriate ones may be chosen from those within the following structure:

##STR00004##

where C.sub.m can be a linear or branched alkyl or alkenyl chain, m is an integer between 1 to 30, such as from 5 to 20, n is an integer between 2 to 30, such as from 5 to 15, and R may be H or alkyl, such as C.sub.1-6 alkyl.

[0056] When used, the accelerator embraced by the above structures should be included in the compositions in an amount within the range of from about 0.01% to about 10% by weight, with the range of about 0.1 to about 0.5% by weight being desirable, and about 0.4% by weight of the total composition being particularly desirable.

[0057] A stabilizer package is also ordinarily found in cyanoacrylate compositions. The stabilizer package may include one or more free radical stabilizers and anionic stabilizers, each of the identity and amount of which are well known to those of ordinary skill in the art. See e.g. U.S. Pat. Nos. 5,530,037 and 6,607,632, the disclosures of each of which are hereby incorporated herein by reference.

[0058] Other additives may be included in the inventive cyanoacrylate compositions, such as certain acidic materials (like citric acid), thixotropy or gelling agents, thickeners, dyes, and combinations thereof.

[0059] Of the accelerators and these additives, those listed in the table below are desirable examples, particularly in the amounts noted.

TABLE-US-00002 Constituent Broad Range Desirable Range Crown Ether 0.1-0.5% 0.1-0.2% Citric Acid 50-100 ppm 100 ppm Silica 0-10% 5-6%

[0060] The cyanoacrylate component (b) may further include cyanoacrylate monomers which may be chosen with a raft of substituents, such as those represented by H.sub.2CC(CN)COOR, where R is selected from C.sub.1-15 alkyl, alkoxyalkyl, cycloalkyl, alkenyl, aralkyl, aryl, allyl and haloalkyl groups. Desirably, these additional cyanoacrylate monomers may be selected from methyl cyanoacrylate, ethyl-2-cyanoacrylate, propyl cyanoacrylates, butyl cyanoacrylates (such as n-butyl-2-cyanoacrylate), octyl cyanoacrylates, allyl cyanoacrylate, and combinations thereof. A particularly desirable one is ethyl-2-cyanoacrylate.

[0061] In another aspect of the invention, there is provided a method of bonding together two substrates, which method includes applying to at least one of the substrates a composition as described above, and thereafter mating together the substrates for a time sufficient to permit the adhesive to fixture.

[0062] In yet another aspect of the invention, there is provided reaction products of the so-described compositions.

[0063] When the composition is disposed between aluminum substrates and forms a cured product and is exposed to a temperature of 100 C. for a period of time of about 6 weeks, the cured product demonstrates improved temperature performance over a comparable composition without components (d) and (e).

[0064] When the composition is disposed between mild steel substrates and forms a cured product and is exposed to a temperature of 100 C. for a period of time of about 6 weeks or relative humidity conditions of 98% and a temperature of 40 C. for a period of time of about 6 weeks, the cured product demonstrates improved temperature performance over a comparable composition without components (d) and (e).

[0065] When the thermal resistance conferring component is tetrafluoroisophthalonitrile and when the composition is disposed between aluminum or mild steel substrates and forms a cured product and is exposed to a temperature of 120 C. for a period of time of about 6 weeks, the cured product demonstrates improved temperature performance over a comparable composition without components (d) and (e).

[0066] In still another aspect of the invention, there is provided a method of preparing the so-described compositions. The method includes providing a cyanoacrylate component, and combining therewith with mixing a hydrogenated anhydride and optionally a benzonitrile compound.

[0067] The invention will be further illustrated by the examples which follow.

EXAMPLES

[0068] All samples were prepared by mixing together the noted constituents for a sufficient period of time to ensure substantial homogeneity of the constituents. Ordinarily, about 30 minutes should suffice, depending of course on the quantity of the constituents used. Each of the samples also contained citric acid in an amount of 50 ppm, and a stabilizer package.

[0069] As controls, LOCTITE Power Easy and LOCTITE 435, were used. LOCTITE Power Easy is a -methoxy ethyl cyanoacrylate thickened in a gel form with PMMA; LOCTITE 454 is an ethyl cyanoacrylate, rubber toughened with VAMAC VCS 5500, also in gel form.

TABLE-US-00003 TABLE 1 Samples/Amt (wt %) Components A B C Isoamyl cyanoacrylate 25.8 25.0 25.0 -Methoxyethyl 60.2 59.5 59.5 cyanoacrylate VCS 5500 8 8 8 Silica 6 6 6 TFIPN.sup.* 0.5 PFBN.sup.+ 0.5 THPA.sup. 1 1 .sup.*Tetrafluoroisophthalonitrile .sup.+2,3,4,5,6-Pentafluorobenzonitrile .sup.3,4,5,6-Tetrahydrophthalic anhydride

[0070] Table A below shows the data captured for T-Peel strength performance on mild steel substrates of Sample A after ageing at room temperature, both with and without a 55 m gap.

TABLE-US-00004 TABLE A Time (weeks) @ Sample A/T-Peel (N/mm) room temperature 1 2 4 8 0 gap 4.1 2.8 3 3.2 55 m 2.5 5 5.3 5.

[0071] Reference to FIG. 1A shows the T-Peel strength performance from Table A.

[0072] FIG. 1A shows that toughness on mild steel substrates is maintained over a period of time of 8 weeks at room temperature. Surprisingly, toughness is enhanced over time in the presence of a 55 m gap.

[0073] Table B below shows the data captured for T-Peel strength performance on mild steel substrates of Samples A-C after ageing at room temperature for 1 week, both with and without a 55 m gap. The two LOCTITE-branded products, Power Easy and 454, showed no performance under these conditions; consequently, no data is reported.

TABLE-US-00005 TABLE B Sample/T-Peel (N/mm) A B C 0 gap 4.1 4.6 4.3 55 m 2.5 4.0 4.3

[0074] Samples B and C illustrate an improvement in toughness as measured by T-Peel strength performance on mild steel substrates.

[0075] Table C below shows the data captured for side impact strength performance on mild steel and aluminum substrates, respectively, of Samples A-C and LOCTITE Power Easy and LOCTITE 454 after ageing at room temperature for 1 week.

TABLE-US-00006 TABLE C Sample/Side Impact (J) LOCTITE LOCTITE Substrate A B C Power Easy 454 Mild steel >13.56 >13.56 >13.56 5.4 4.4 Aluminum 8.5 9.4 8.7 3.2 2.4

[0076] Side impact strength performance on mild steel substrates after room temperature curing for 1 week of each of Samples A-C exceeded 13.56 J, which is the maximum value observable in the test method. These values were at a minimum over two times as high as the LOCTITE-branded controls. Superior performance was also observed for these samples on aluminum substrates after curing at room temperature for 1 week. These values were at a minimum nearly three times as high as the LOCTITE-branded controls. See FIG. 2.

[0077] Table D below shows the data captured for tensile strength performance on mild steel and aluminum substrates, respectively, of Samples A-C and LOCTITE Power Easy and LOCTITE 454 after ageing at room temperature for 3 days, 1 week, 3 weeks and 6 weeks.

TABLE-US-00007 TABLE D Sample/Tensile Strength (MPa) Time (weeks)/ LOCTITE LOCTITE Substrate A B C Power Easy 454 3 days/MS 11.0 9.3 9.1 12.0 17.5 1 week/MS 13.1 12.0 12.5 13.6 17.5 3 week/MS 18.1 16.6 18.1 17.5 20.3 6 week/MS 18.5 16.9 18.3 16.9 19.0 3 days/Al 10.6 10.3 12.6 9.3 10.8 1 week/Al 11.5 13.0 14.0 9.8 8.1 3 week/Al 10.0 11.7 12.8 9.6 5.2 6 week/Al 13.0 14.3 13.8 8.2 3.6

[0078] FIGS. 3 and 4 show this data for room temperature aging of Samples A-C and LOCTITE Power Easy and LOCTITE 454 on mild steel substrates and aluminum substrates, respectively. The bond strengths on the mild steel substrates were somewhat lower initially compared to the two LOCTITE-branded products used as controls. However, overtime the bond strengths were observed to increase. And in the case of the aluminum substrates exceptional durability was observed over the aging period.

[0079] Table E below shows the data captured for tensile strength performance on mild steel and aluminum substrates, respectively, of Samples A-C and LOCTITE Power Easy and LOCTITE 454 after ageing for 1 week at room temperature followed by aging at a temperature of 100 C. for 3 weeks and 6 weeks.

TABLE-US-00008 TABLE E Sample/Tensile Strength (MPa) Time (weeks)/ LOCTITE LOCTITE Substrate A B C Power Easy 454 1 @ RT/MS 13.1 12.0 12.5 13.6 17.5 3 @ 100 C./MS 18.9 15.5 18.1 12.9 5.9 6 @ 100 C./MS 20.0 18.9 16.3 10.5 5.4 1 @ RT/Al 11.5 13.0 14.0 9.8 8.1 3 @ 100 C./Al 6.7 15.8 12.3 5.5 1.3 6 @ 100 C./Al 4.4 13.6 9.1 3.8 1.5

[0080] Reference to FIG. 5 shows these data for Samples A-C and LOCTITE Power Easy and LOCTITE 454 on mild steel substrates after ageing for 1 week at room temperature followed by aging at a temperature of 100 C. for 3 weeks and 6 weeks. Sample A was observed to show significant improved performance over the LOCTITE-branded products used as controls. The addition of the thermal resistance conferring component was observed to show little impact here. However, as discussed below, at a temperature of 120 C., particularly on the mild steel substrates, considerable improvement in performance is observed compared to the LOCTITE-branded products used as controls and Sample A. Significant durability improvement was observed for Samples B and C on aluminum substrates.

[0081] Table F below shows the data captured for tensile strength performance on mild steel and aluminum substrates, respectively, of Samples A-C and LOCTITE Power Easy and LOCTITE 454 after ageing for 1 week at room temperature followed by aging at a temperature of 120 C. for 3 weeks and 6 weeks.

TABLE-US-00009 TABLE F Sample/Tensile Strength (MPa) Time (weeks)/ LOCTITE LOCTITE Substrate A B C Power Easy 454 1 @ RT/MS 13.1 12.0 12.5 13.6 17.5 3 @ 120 C./MS 8.4 14.6 10.4 3.4 5.5 6 @ 120 C./MS 0 5.5 0 0 3.8 1 @ RT/Al 11.5 13.0 14.0 9.8 8.1 3 @ 120 C./Al 2.2 13.2 3.7 2.8 1.3 6 @ 120 C./Al 0 8.6 0 0 1.6

[0082] Reference to FIG. 6 shows these data for Samples A-C and LOCTITE Power Easy and LOCTITE 454 on mild steel substrates after ageing for 1 week at room temperature followed by aging at a temperature of 120 C. for 3 weeks and 6 weeks. The combination of the TFIPN and THPA in Sample B significantly contributes to the durability at 120 C. Similarly, the same sample used to bond aluminum substrates and aged for 6 weeks has resulted in significant retention of bond strength as reflected in Table F.

[0083] Table G below shows data captured for tensile strength performance on mild steel and aluminum substrates, respectively, of Samples A-C and LOCTITE Power Easy and LOCTITE 454 after ageing at 1 week at room temperature followed by aging at 98% relative humidity and a temperature of 40 C. for 3 weeks and 6 weeks.

TABLE-US-00010 TABLE G Sample/Tensile Strength (MPa) Time (weeks)/ LOCTITE LOCTITE Substrate A B C Power Easy 454 1 @ RT/MS 13.1 12.0 12.5 13.6 17.5 3 @ 40 C./98% RH/MS 8.3 16.0 17.2 7.7 6.3 6 @ 40 C./98% RH/MS 12.6 19.2 19.6 5.1 7.4 1 @ RT/Al 11.5 13.0 14.0 9.8 8.1 3 @ 40 C./98% RH/Al 3.2 3.3 2.3 1.8 0 6 @ 40 C./98% RH/Al 2.4 2.5 0 1.1 0

[0084] Reference to FIG. 7 shows these data for Samples A-C and LOCTITE Power Easy and LOCTITE 454 on mild steel substrates after ageing at 98% relative humidity and a temperature of 40 C. for 3 weeks and 6 weeks. Once again, the addition of both the thermal resistance conferring component and the humidity resistance conferring component have significantly enhanced the performance profile, such as is reflected with reference to the data observed with Samples B and C.

[0085] FIGS. 8 and 9 show 6 week data for room temperature, 100 C., 120 C. and 98% relative humidity/40 C. aging of Samples A-C and LOCTITE Power Easy and LOCTITE 454 on mild steel substrates and aluminum substrates, respectively. These data are captured above in Tables E-G.

[0086] At 100 C., the inventive samples outperformed the controls. At 120 C., temperature resistance is demonstrated, particularly over time, with the inventive samples, in particular Sample B on mild steel substrates. Impressive moisture durability is observed with the inventive samples, which significantly outperformed the controls.