Ceramsite produced by using river/lake/sea sludge and seashell powder as raw materials and preparation method thereof
10737238 ยท 2020-08-11
Assignee
Inventors
Cpc classification
C04B2235/96
CHEMISTRY; METALLURGY
C04B18/24
CHEMISTRY; METALLURGY
C04B38/009
CHEMISTRY; METALLURGY
C04B18/125
CHEMISTRY; METALLURGY
B01J20/043
PERFORMING OPERATIONS; TRANSPORTING
C04B2235/95
CHEMISTRY; METALLURGY
C04B2235/5436
CHEMISTRY; METALLURGY
C04B38/009
CHEMISTRY; METALLURGY
B01J20/20
PERFORMING OPERATIONS; TRANSPORTING
C04B18/125
CHEMISTRY; METALLURGY
C04B18/24
CHEMISTRY; METALLURGY
C02F1/288
CHEMISTRY; METALLURGY
C04B33/1321
CHEMISTRY; METALLURGY
B01J20/12
PERFORMING OPERATIONS; TRANSPORTING
Y02W30/91
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C04B33/138
CHEMISTRY; METALLURGY
Y02P40/60
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C04B2235/5427
CHEMISTRY; METALLURGY
International classification
B01J20/12
PERFORMING OPERATIONS; TRANSPORTING
C04B33/135
CHEMISTRY; METALLURGY
B01J20/20
PERFORMING OPERATIONS; TRANSPORTING
B01J20/04
PERFORMING OPERATIONS; TRANSPORTING
C04B38/00
CHEMISTRY; METALLURGY
Abstract
A ceramsite produced by using a river/lake/sea sludge and seashell powder as raw materials and a preparation method thereof are provided. The ceramsite is made of the following raw materials in parts by weight: 15-50 parts of shell powder, 5-15 parts of kaolin, 1-5 parts of peat ash, 15-30 parts of siliceous shale, 15-40 parts of furnace slag, 10-20 parts of fly ash, 15-40 parts of zeolite, 10-30 parts of river/lake/sea sludge, and 10-25 parts of peat. The shell powder is pulverized to a particle size of 60-200 mesh in fineness. A content of silica in the siliceous shale is 87.0%-89.5%. The preparation method of the ceramsite includes the following steps: taking raw materials, pulverizing, stirring, granulating, calcining, and naturally cooling, so as to obtain the ceramsite.
Claims
1. A ceramsite, comprising: as raw materials by weight 15-50 parts of seashell powder, 5-15 parts of kaolin, 1-5 parts of peat ash, 15-30 parts of siliceous shale, 15-40 parts of furnace slag, 10-20 parts of fly ash, 15-40 parts of zeolite, 10-30 parts of river/lake/sea sludge, and 10-25 parts of peat, wherein the ceramsite is obtained by calcination comprising drying ceramsite particles at 100 C.-120 C. for 1-3 hours, then preheating at 200 C.-300 C. for 0.5-2 hours, and subsequently, performing the calcination at 800 C.-950 C. for 40-70 minutes, and naturally cooling.
2. The ceramsite of claim 1, wherein, the shell powder is pulverized to a particle size of 60-200 mesh in fineness.
3. The ceramsite of claim 1, wherein, a content of silica in the siliceous shale is 87.0%-89.5%.
4. The ceramsite of claim 1, wherein, the ceramsite comprises as the raw materials by weight 26.8 parts of the seashell powder, 12.2 parts of the kaolin, 3.4 parts of the peat ash, 20.5 parts of the siliceous shale, 30.2 parts of the furnace slag, 18.4 parts of the fly ash, 32.6 parts of the zeolite, 25.5 parts of the river/lake/sea sludge, and 18.7 parts of the peat.
5. A preparation method of the ceramsite of claim 1, comprising the following steps: (1) taking raw materials: weighing the raw materials according to the parts by weight; (2) pulverizing: pulverizing the kaolin, the siliceous shale, the furnace slag, the fly ash, the zeolite, the river/lake/sea sludge, and the peat to a particle size of 20-60 mesh; (3) stirring: mixing the seashell powder, the peat ash and the materials in the step (2) uniformly, adding water and stirring, and adjusting a water content of a mixed material to 15%-25%; (4) granulating: conveying the mixed material after being stirred in the step (3) to a granulator for granulation to obtain spherical ceramsite particles; and (5) calcination: drying the ceramsite particles in the step (4) at 100 C.-120 C. for 1-3 hours, then preheating at 200 C.-300 C. for 0.5-2 hours, and subsequently, performing a calcination on the ceramsite at 800 C.-950 C. for 40-70 minutes, and naturally cooling to obtain the ceramsite produced by using the river/lake/sea sludge and the seashell powder as the raw materials.
6. The preparation method of claim 5, wherein, the ceramsite comprises as the raw materials by weight 26.8 parts of the seashell powder, 12.2 parts of the kaolin, 3.4 parts of the peat ash, 20.5 parts of the siliceous shale, 30.2 parts of the furnace slag, 18.4 parts of the fly ash, 32.6 parts of the zeolite, 25.5 parts of the river/lake/sea sludge, and 18.7 parts of the peat.
Description
DETAILED DESCRIPTION OF THE EMBODIMENTS
(1) The present invention will be further described below by combining with the embodiments.
Embodiment 1
(2) The ceramsite produced by using a river/lake/sea sludge and seashell powder as raw materials is made of the following raw materials in parts by weight: 26.8 parts of shell powder, 12.2 parts of kaolin, 3.4 parts of peat ash, 20.5 parts of siliceous shale, 30.2 parts of furnace slag, 18.4 parts of fly ash, 32.6 parts of zeolite, 25.5 parts of sea sludge, and 18.7 parts of peat.
(3) The shell powder is from a river, a lake or a sea, and is pulverized to a particle size of 100 mesh in fineness.
(4) The content of silica in the siliceous shale is 87.6%.
(5) The preparation method of the ceramsite produced by using a river/lake/sea sludge and seashell powder as the raw materials includes the following specific steps
(6) (1) taking raw materials: weighing the raw materials according to the above parts by weight;
(7) (2) pulverizing: pulverizing the kaolin, the siliceous shale, the furnace slag, the fly ash, the zeolite, the sea sludge, and the peat to a particle size of 40 mesh;
(8) (3) stirring: mixing the shell powder, the peat ash and the materials in the step (2) uniformly, adding water and stirring, and adjusting a water content of a mixed material to 18%;
(9) (4) granulating: conveying the mixed material after being stirred in the step (3) to a granulator for granulation to obtain spherical ceramsite particles; and
(10) (5) calcination: drying the ceramsite particles in the step (4) at 110 C. for 2 hours, then preheating at 240 C. for 1.5 hours, and subsequently, performing a calcination on the ceramsite at 850 C. for 60 minutes, and naturally cooling to obtain the ceramsite.
(11) The performance parameters of the ceramsite are shown in Table 1.
(12) TABLE-US-00001 TABLE 1 Performance Parameters of the Ceramsite of Embodiment 1 Cylindrical Water Grain Stacking compressive absorption Frost composition/ density/ strength at 1 hour resistance Stability mm (kg/mm.sup.3) (Mpa) (%) (%) (%) 5-10 635 4.48 8.16 3.78 1.01 10-20 780 4.42 7.94 3.55 0.95 20-30 860 4.45 7.76 3.32 0.92
(13) The above ceramsite is used as a filler in sewage treatment, and the sewage is pre-treated by a sewage treatment plant. The change of the water quality before and after the sewage treatment is as shown in Table 2.
(14) TABLE-US-00002 TABLE 2 Water Quality of Sewage before and after Treatment with Ceramsite in Embodiment 1 TP SS Pb Cr CODcr BOD.sub.5 Ni (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) Before 5.5 356 2.9 4.6 300 120 3.6 treatment After 0.35 58 0.75 1.1 72 20 0.5 treatment
(15) Specifically, TP is total phosphorus, SS is suspended matter, Pb is lead, Cr is chromium, COD.sub.cr is chromium chemical oxygen demand, BOD.sub.5 is 5-day biochemical oxygen demand, and Ni is nickel. The same English abbreviations in the other embodiments have the same meanings. It can be seen from the comparative data before and after sewage treatment with the ceramsite that when used for the sewage treatment, the ceramsite produced by the method of embodiment 1 can effectively reduce the heavy metal content in the sewage. Moreover, the total phosphorus and suspended matter content in the water is also significantly reduced. After the above treatment with the ceramsite, the water quality has been significantly improved.
Embodiment 2
(16) The ceramsite produced by using a river/lake/sea sludge and seashell powder as raw materials is made of the following raw materials in parts by weight: 15 parts of shell powder, 5 parts of kaolin, 1 part of peat ash, 15 parts of siliceous shale, 15 parts of furnace slag, 10 parts of fly ash, 15 parts of zeolite, 10 parts of lake sludge, and 10 parts of peat.
(17) The shell powder is from a river, a lake or the sea, and is pulverized to a particle size of 60 mesh in fineness.
(18) The content of silica in the siliceous shale is 88.4%.
(19) The preparation method of the ceramsite produced by using the river/lake/sea sludge and the seashell powder as the raw materials includes the following specific steps:
(20) (1) taking raw materials: weighing the raw materials according to the above parts by weight;
(21) (2) pulverizing: pulverizing the kaolin, the siliceous shale, the furnace slag, the fly ash, the zeolite, the lake sludge, and the peat to a particle size of 40 mesh;
(22) (3) stirring: mixing the shell powder, the peat ash and the materials in the step (2) uniformly, adding water and stirring, and adjusting a water content of a mixed material to about 18%;
(23) (4) granulating: conveying the mixed material after being stirred in the step (3) to a granulator for granulation to obtain spherical ceramsite particles; and
(24) (5) calcination: drying the ceramsite particles in the step (4) at 110 C. for 2 hours, then preheating at 240 C. for 1.5 hours, and subsequently, performing a calcination on the ceramsite at 850 C. for 60 minutes, and naturally cooling to obtain the ceramsite.
(25) When used for sewage treatment, the ceramsite can effectively reduce the heavy metal ion content in the sewage.
Embodiment 3
(26) The ceramsite produced by using a river/lake/sea sludge and seashell powder as raw materials is made of the following raw materials in parts by weight: 50 parts of shell powder, 15 parts of kaolin, 5 parts of peat ash, 30 parts of siliceous shale, 40 parts of furnace slag, 20 parts of fly ash, 40 parts of zeolite, 30 parts of Yangtze River sludge, and 25 parts of peat.
(27) The shell powder is from a river, a lake or a sea, and is pulverized to a particle size of 80 mesh in fineness.
(28) The content of silica in the siliceous shale is 88.4%.
(29) The preparation method of the ceramsite produced by using the river/lake/sea sludge and the seashell powder as the raw materials includes the following specific steps:
(30) (1) taking raw materials: weighing the raw materials according to the above parts by weight;
(31) (2) pulverizing: pulverizing the kaolin, the siliceous shale, the furnace slag, the fly ash, the zeolite, the Yangtze River sludge, and the peat to a particle size of 40 mesh;
(32) (3) stirring: mixing the shell powder, the peat ash and the materials in the step (2) uniformly, adding water and stirring, and adjusting a water content of a mixed material to 18%;
(33) (4) granulating: conveying the mixed material after being stirred in the step (3) to a granulator for granulation to obtain spherical ceramsite particles; and
(34) (5) calcination: drying the ceramsite particles in the step (4) at 110 C. for 2 hours, then preheating at 240 C. for 1.5 hours, and subsequently, performing a calcination on the ceramsite at 850 C. for 60 minutes, and naturally cooling to obtain the ceramsite.
(35) When used for sewage treatment, the ceramsite can effectively reduce the heavy metal ion content in the sewage.
Embodiment 4
(36) The ceramsite produced by using a river/lake/sea sludge and seashell powder as raw materials is made of the following raw materials in parts by weight: 28.7 parts of shell powder, 12.2 parts of kaolin, 3.4 parts of peat ash, 13.6 parts of siliceous shale, 15.2 parts of furnace slag, 6 parts of fly ash, 18.6 parts of zeolite, 24.2 parts of river bottom sludge, and 15.7 parts of peat.
(37) The shell powder is from a river, a lake or a sea, and is pulverized to a particle size of 100 mesh in fineness.
(38) The content of silica in the siliceous shale is 87.6%.
(39) The preparation method of the ceramsite produced by using the river/lake/sea sludge and the seashell powder as the raw materials is the same as that in embodiment 1.
(40) The ceramsite of the present embodiment is applied to building materials, and the specific conditions of the ceramsite such as strength and thermal conductivity are shown in Table 3.
(41) TABLE-US-00003 TABLE 3 Specific Parameters of the Ceramsite of Embodiment 4 Stacking Compressive Water Thermal density/ strength absorption conductivity (kg/mm.sup.3) (Mpa) (%) (W/m .Math. k) Treatment with 528 9.5 7.88 0.12 ceramsite of embodiment 4
(42) As can be seen from the above, the ceramsite of embodiment 4 has relatively high strength, good water absorption and good thermal conductivity, which can be applied to the field of building materials.
Embodiment 5
(43) The ceramsite produced by using a river/lake/sea sludge and seashell powder as raw materials is made of the following raw materials in parts by weight: 22.2 parts of shell powder, 12.2 parts of kaolin, 3.4 parts of peat ash, 10.5 parts of siliceous shale, 15.2 parts of furnace slag, 8.4 parts of fly ash, 18.6 parts of zeolite, 20.5 parts of sea sludge, and 15.7 parts of peat.
(44) The shell powder is from a river, a lake or a sea, and is pulverized to a particle size of 100 mesh in fineness.
(45) The content of silica in the siliceous shale is 87.6%.
(46) The preparation method of the ceramsite produced by using the river/lake/sea sludge and the seashell powder as the raw materials is the same as that in embodiment 1.
(47) The ceramsite of the present embodiment is applied to building materials, and the specific conditions of the ceramsite such as strength and thermal conductivity are shown in
(48) Table 4.
(49) TABLE-US-00004 TABLE 4 Specific Parameters of the Ceramsite of Embodiment 5 Stacking Compressive Water Thermal density/ strength absorption conductivity (kg/mm.sup.3) (Mpa) (%) (W/m .Math. k) Treatment with 539 9.5 7.88 0.12 ceramsite of embodiment 5
(50) As can be seen from the above, the ceramsite of embodiment 5 has a slightly larger stacking density than the ceramsite of embodiment 4, both ceramsites of embodiment 4 and embodiment 5 have relatively high strength, good water absorption and good thermal conductivity, and can be applied to the field of building materials.
Embodiment 6
(51) The ceramsite produced by using a river/lake/sea sludge and seashell powder as raw materials is made of the following raw materials in parts by weight: 26.8 parts of shell powder, 12.2 parts of kaolin, 3.4 parts of peat ash, 20.5 parts of siliceous shale, 30.2 parts of furnace slag, 18.4 parts of fly ash, 32.6 parts of zeolite, 25.5 parts of sea sludge, and 18.7 parts of peat.
(52) The shell powder is from a river, a lake or a sea, and is pulverized to a particle size of 100 mesh in fineness.
(53) The content of silica in the siliceous shale is 87.6%.
(54) The preparation method of the ceramsite produced by using the river/lake/sea sludge and the seashell powder as the raw materials includes the following specific steps:
(55) (1) taking raw materials: weighing the raw materials according to the above parts by weight;
(56) (2) pulverizing: pulverizing the kaolin, the siliceous shale, the furnace slag, the fly ash, the zeolite, the sea sludge, and the peat to a particle size of 40 mesh;
(57) (3) stirring: mixing the shell powder, the peat ash and the materials in the step (2) uniformly, adding water and stirring, and adjusting a water content of a mixed material to 18%;
(58) (4) granulating: conveying the mixed material after being stirred in the step (3) to a granulator for granulation to obtain spherical ceramsite particles; and
(59) (5) calcination: drying the ceramsite particles in the step (4) at 110 C. for 2 hours, then preheating at 240 C. for 1.5 hours, and subsequently, performing a calcination on the ceramsite at 850 C. for 60 minutes, and naturally cooling to obtain the ceramsite.
(60) The ceramsite in embodiment 6 was added into the textile wastewater taken from a textile factory in Shandong. The adding amount of the ceramsite was 6 g per liter of the wastewater, and the mixture was stirred at room temperature for 60 minutes after the ceramsite was added. The measured results are shown in Table 5.
(61) TABLE-US-00005 TABLE 5 Results of Treatment of Textile Wastewater with the Ceramsite of Embodiment 6 Chroma CODcr(mg/L) SS(mg/L) Original value 1485 1286 868 Treatment with 52 184.5 31.6 ceramsite of embodiment 6
(62) As can be seen from the above, the ceramsite of embodiment 6 can significantly reduce the content of CODcr and SS in the textile wastewater, and effectively adsorb heavy metals in the wastewater.
Embodiment 7
(63) The ceramsite produced by using a river/lake/sea sludge and seashell powder as raw materials is made of the following raw materials in parts by weight: 26.8 parts of shell powder, 12.2 parts of kaolin, 3.4 parts of peat ash, 20.5 parts of siliceous shale, 30.2 parts of furnace slag, 18.4 parts of fly ash, 32.6 parts of modified zeolite, 25.5 parts of a river/lake/sea sludge (the river/lake/sea sludge is a mixture of a Yangtze River sludge, a river sludge, a lake sludge and a sea sludge, and the proportion in parts by weight thereof is: the Yangtze River sludge:the river sludge:the lake sludge:the sea sludge=1:1:2:3), 18.7 parts of peat, and 2.4 parts of activated alumina.
(64) The shell powder is from a river, a lake or a sea, and is pulverized to a particle size of 120 mesh in fineness.
(65) The content of silica in the siliceous shale is 88.2%.
(66) The production method of the modified zeolite is as follows:
(67) selecting natural zeolite and dividing into three equal parts, denoted as A, B, C respectively;
(68) soaking the zeolite, A with 1 mol/L hydrochloric acid solution for 2 hours, washing and filtering, and recovering the zeolite A;
(69) soaking the zeolite B with a 1 mol/L aluminum sulfate solution for 2 hours, washing and filtering, and recovering the zeolite A;
(70) soaking the zeolite C with 1 mol/L hydrochloric acid solution for 2 hours, then soaking the zeolite C with 1 mol/L aluminum sulfate solution for 2 hours, washing and filtering, and recovering the zeolite C; and
(71) mixing the zeolite A, the zeolite B, and the zeolite C and calcining the zeolite A, the zeolite B, and the zeolite C at 450 C. for 60 minutes to obtain the modified zeolite.
(72) The preparation method of the ceramsite produced by using the river/lake/sea sludge and the seashell powder as the raw materials includes the following specific steps:
(73) (1) taking raw materials: weighing the raw materials according to the above parts by weight;
(74) (2) pulverizing: pulverizing the kaolin, the siliceous shale, the furnace slag, the fly ash, the modified zeolite, the river/lake/sea sludge, the peat, and the activated alumina to a particle size of 40 mesh;
(75) (3) stirring: mixing the shell powder, the peat ash and the materials in the step (2) uniformly, adding water and stirring, and adjusting a water content of a mixed material to 18%;
(76) (4) granulating: conveying the mixed material after being stirred in the step (3) to a granulator for granulation to obtain spherical ceramsite particles; and
(77) (5) calcination: drying the ceramsite particles in the step (4) at 110 C. for 2 hours, then preheating at 240 C. for 1.5 hours, and subsequently, performing a calcination on the ceramsite at 850 C. for 60 minutes, and naturally cooling to obtain the ceramsite.
(78) The ceramsite in embodiment 7 was added into the same textile wastewater as that in embodiment 6. The adding amount of the ceramsite was 6 g per liter of the wastewater, and the mixture was stirred at room temperature for 60 minutes after the ceramsite was added. The measured results are shown in Table 6.
(79) TABLE-US-00006 TABLE 6 Results of Treatment of Textile Wastewater with the Ceramsite of Embodiment 7 Chroma CODcr(mg/L) SS(mg/L) Original value 1485 1286 868 Treatment with 36 166.8 20.6 ceramsite of embodiment 7
(80) As can be seen from the above, the ceramsite of embodiment 7 can significantly reduce the content of CODcr and SS in the textile wastewater. Compared with the results of the textile wastewater treatment with the ceramsite of embodiment 6, it can be found that the ceramsite of embodiment 7 has a stronger adsorption capacity for heavy metals in the wastewater and a better treatment effect on the wastewater by modifying the zeolite and adding the activated alumina.
Embodiment 8
(81) The ceramsite produced by using a river/lake/sea sludge and seashell powder as raw materials is made of the following raw materials in parts by weight: 16.8 parts of oyster shell powder, 12.2 parts of kaolin, 5.4 parts of peat ash, 30.2 parts of furnace slag, 25.5 parts of fly ash, 18.4 parts of clay, 32.6 parts of modified zeolite, 25.5 parts of sludge (the sludge is a mixture of a Yangtze River sludge, a river sludge, a lake sludge and a sea sludge, and the proportion in parts by weight thereof is: the Yangtze River sludge:the river sludge:the lake sludge:the sea sludge=1:1:2:3), 18.7 parts of peat, and 2.4 parts of activated alumina.
(82) The production method of the modified zeolite is as follows:
(83) selecting natural zeolite and dividing into two equal parts, denoted as A, and B respectively;
(84) soaking the zeolite A with 1 mol/L sodium hydroxide solution for 2 hours, controlling the temperature at 100 C. during soaking, washing and filtering, and recovering the zeolite A; further soaking the zeolite A with 1 mol/L sodium hydroxide solution for 2 hours, controlling the temperature at 100 C. during soaking, washing and filtering, and recovering the zeolite A; stirring constantly during the above soaking processes;
(85) soaking the zeolite B with 1 mol/L ammonium chloride solution for 2 hours, controlling the temperature at 100 C. during soaking, washing and filtering, and recovering the zeolite B; further soaking the zeolite B with 1 mol/L ammonium chloride solution for 2 hours, controlling the temperature at 100 C. during soaking, washing and filtering, and recovering the zeolite B; stirring constantly during the above soaking processes;
(86) mixing the zeolite, A and the zeolite B and calcining the zeolite A and the zeolite B at 450 C. for 60 minutes to obtain the modified zeolite.
(87) The preparation method of the ceramsite produced by using the river/lake/sea sludge and the seashell powder as the raw materials includes the following specific steps:
(88) (1) taking raw materials: weighing the raw materials according to the above parts by weight;
(89) (2) pulverizing: pulverizing the kaolin, the furnace slag, the fly ash, the clay, the modified zeolite, the sludge, the peat, and the activated alumina to a particle size of 40 mesh;
(90) (3) stirring: pulverizing the oyster shell powder to a particle size of 40 mesh, mixing the oyster shell powder, the peat ash and the materials in the step (2) uniformly, adding water and stirring, and adjusting a water content of a mixed material to 18%;
(91) (4) granulating: conveying the mixed material after being stirred in the step (3) to a granulator for granulation to obtain spherical ceramsite particles; and
(92) (5) calcination: drying the ceramsite particles in the step (4) at 110 C. for 2 hours, then preheating at 240 C. for 1.5 hours, and subsequently, performing a calcination on the ceramsite at 850 C. to sinter for 60 minutes, and naturally cooling to obtain the ceramsite.
(93) The raw materials of the ceramsite of embodiment 8 were adjusted to obtain four new kinds of ceramsites. The treatment effects of the obtained four ceramsites on the sewage were compared to the treatment effect of the ceramsite of embodiment 8 on the sewage. The specific conditions of the four groups of comparative ceramsites are as follows:
(94) comparative group 1: the proportion of the fly ash is adjusted to 20 parts, the clay is adjusted to 25 parts, and the rest of the raw materials remain unchanged;
(95) comparative group 2: the oyster shell powder is replaced with the furnace slag, i.e., the parts by weight of the furnace slag are 35.2 parts, and the rest of the raw materials remain unchanged;
(96) comparative group 3: the oyster shell powder is replaced with the shell powder, and the rest of the raw materials remain unchanged; and
(97) comparative group 4: the modified zeolite is replaced with natural zeolite, and the rest of the raw materials remain unchanged.
(98) The sewage generated by a thermal power plant in Shandong Province was taken and treated with the ceramsites of embodiment 8 and the four comparative groups, and the adding amount of the ceramsite is 8 g per liter of the sewage. The measured results are shown in Table 7.
(99) TABLE-US-00007 TABLE 7 Sewage Treatment Results of Ceramsite of embodiment 8 and the Comparative Groups TP SS Pb Cr CODcr BOD.sub.5 Ni (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) Before 6.5 384 3.2 7.8 353 146 3.9 treatment Treatment 0.46 64 0.82 1.2 78 28 0.7 with ceramsite of embodiment 8 Treatment 0.68 88 1.37 1.66 95 63 0.94 with ceramsite of comparative group 1 Treatment 0.71 91 1.45 1.75 89 57 1.03 with ceramsite of comparative group 2 Treatment 0.45 69 0.81 1.3 82 30 0.6 with ceramsite of comparative group 3 Treatment 1.21 116 1.83 1.64 97 101 0.98 with ceramsite of comparative group 4
(100) As can be seen from the above data, the ceramsite of embodiment 8 has a significantly better effect than those of the comparative group 1 and the comparative group 2 on the treatment of wastewater, especially the wastewater having a high heavy metal content produced by the thermal power plant. In the comparative group 1, the parts by weight of the fly ash and the clay were adjusted, which makes a big difference. In the comparative group 2, the oyster shell powder were replaced and complemented by the furnace slag as the raw material in the parts by weight, which also makes a big difference. The data in the comparative group 3 shows that the ceramsite produced by using the shell powder as the raw material has a similar effect to the ceramsite produced by using the oyster shell powder as the raw material on the treatment of the wastewater contaminated with heavy metals. In the comparative group 4, the effect of the ceramsite where the modified zeolite is replaced with the natural zeolite is decreased as well, indicating that the modified zeolite used in the production of the ceramsite of the present invention has a better effect than the natural zeolite.
(101) In the present embodiment, the ratio of the various raw materials has an effect on the expansion coefficient and adsorption performance of the ceramsite. For example, in a high-temperature calcination, the oyster shell powder produces a more sufficient amount of gas, which increases the expansion degree of the ceramsite, thereby affecting the adsorption of the ceramsite, and further affecting the effect of the ceramsite on the water treatment. During the preparation process of the ceramsite, from drying to preheating, there is sufficient time for the components of the various raw materials to react with each other, so as to increase the expansion ratio of the ceramsite, and produce the ceramsite having the best expansion ratio.
(102) The ceramsite of embodiment 8 has a stacking density of 418 (kg/mm.sup.3), a compressive strength of 11.6 MPa, a water absorption of 7.94%, and a thermal conductivity of 0.06 (W/m. k). Based on the above indexes, the ceramsite can also be applied to building insulation materials.
(103) The specific implementing ways of the present invention are described in conjunction with the above-mentioned embodiments. However, it is not a limitation to the scope of the present invention. Those skilled in the art should understand that, on the basis of the technical scheme of the present invention, various modifications or variations made by those skilled in the art without any creative work are still within the scope of the present invention.