DIFFERENTIAL SG/EG SPACER INTEGRATION WITH EQUIVALENT NFET/PFET SPACER WIDTHS & DUAL RAISED SOURCE DRAIN EXPITAXIAL SILICON AND TRIPLE-NITRIDE SPACER INTEGRATION ENABLING HIGH-VOLTAGE EG DEVICE ON FDSOI
20180012973 · 2018-01-11
Inventors
- George Robert MULFINGER (Wilton, NY, US)
- Ryan SPORER (Mechanicsville, NY, US)
- Rick J. CARTER (Saratoga Springs, NY, US)
- Peter BAARS (Dresden, DE)
- Hans-Jürgen THEES (Dresden, DE)
- Jan HÖNTSCHEL (Dresden, DE)
Cpc classification
H01L29/7838
ELECTRICITY
H01L21/823814
ELECTRICITY
H01L29/6653
ELECTRICITY
H01L29/66628
ELECTRICITY
H01L27/1203
ELECTRICITY
H01L21/823412
ELECTRICITY
H01L29/6656
ELECTRICITY
H01L21/823807
ELECTRICITY
H01L21/823864
ELECTRICITY
International classification
H01L29/66
ELECTRICITY
H01L29/161
ELECTRICITY
H01L29/08
ELECTRICITY
H01L29/16
ELECTRICITY
H01L27/12
ELECTRICITY
Abstract
A method of forming matched PFET/NFET spacers with differential widths for SG and EG structures and a method of forming differential width nitride spacers for SG NFET and SG PFET structures and PFET/NFET EG structures and respective resulting devices are provided. Embodiments include providing PFET SG and EG structures and NFET SG and EG structures; forming a first nitride layer over the substrate; forming an oxide liner; forming a second nitride layer on sidewalls of the PFET and NFET EG structures; removing horizontal portions of the first nitride layer and the oxide liner over the PFET SG and EG structures; forming RSD structures on opposite sides of each of the PFET SG and EG structures; removing horizontal portions of the first nitride layer and the oxide liner over the NFET SG and EG structures; and forming RSD structures on opposite sides of each of the NFET SG and EG structures.
Claims
1. A device comprising: p-type field effect transistor (PFET) core device (SG) and I/O device (EG) gate structures and n-type field effect transistor (NFET) SG and EG gate structures formed on a substrate, the PFET and NFET structures laterally separated; a pair of L-shaped nitride spacers formed on the substrate and adjacent to sidewalls of each of the PFET and NFET SG and EG gate structures; an L-shaped oxide spacer formed on and adjacent to each L-shaped nitride spacer of the PFET and NFET EG gate structures; a nitride spacer formed on and adjacent to each L-shaped oxide spacer; faceted raised source/drain (RSD) structures formed on opposite sides of each of the PFET and NFET SG gate structures; and RSD structures formed on opposite sides of each of the PFET and NFET EG gate structures.
2. The device according to claim 1, wherein each L-shaped nitride spacer is thick enough to prevent epitaxial silicon growth on or around the RSD structures, but thin enough to optimize overlap of source/drain regions.
3. The device according to claim 2, wherein each L-shaped nitride spacer has a thickness of 4 nanometer (nm) to 8 nm.
4. The device according to claim 3, wherein each L-shaped nitride spacer and each nitride spacer is formed of silicon oxycarbonitride (SiOCN), high-temperature iRad™ nitride, or silicon borocarbonitride (SiBCN).
5. The device according to claim 1, wherein each L-shaped oxide spacer is formed of undoped oxide (UDOX), iRad™ oxide, or ozone tetraethyl orthosilicate (TEOS).
6. The device according to claim 1, wherein a horizontal surface of each L-shaped nitride spacer and of each L-shaped oxide spacer is 2 nm to 6 nm in length.
7. The device according to claim 1, further comprising a thin oxide liner over each of the faceted RSD structures.
8. The device according to claim 7, wherein the thin oxide layer has a thickness of 2 nm to 3 nm.
9. The device according to claim 1, wherein each L-shaped nitride spacer and each nitride spacer have matched widths.
10. A method comprising: providing n-type field effect transistor (NFET) core device (SG) and I/O device (EG) gate structures and p-type field effect transistor (PFET) SG and EG gate structures on a fully depleted silicon-on-insulator (FDSOI) substrate, the SG and EG structures laterally separated and each including a gate and a gate cap layer; forming a conformal first nitride layer over the NFET and PFET SG and EG gate structures and the substrate; forming an oxide liner over the NFET and PFET SG and EG gate structures and substrate; forming a second conformal nitride layer over the NFET and PFET SG and EG structures and substrate; removing horizontal portions of the second nitride layer; masking the NFET and PFET EG gate structures; removing vertical portions of the second nitride layer adjacent to the NFET and PFET SG structures and exposed oxide liner; masking NFET or PFET EG and SG gate structures; removing horizontal portions of the first nitride layer; forming raised source/drain (RSD) structures on the substrate adjacent to the PFET or NFET, respectively, SG and EG structures; forming a third nitride layer over the entire substrate; masking PFET or NFET, respectively, SG and EG gate structures; removing horizontal portions of the third nitride layer; forming RSD structures on opposite sides of the PFET or NFET, respectively, SG and EG gate structures; and removing the first, second, and third nitride layers and the gate cap layer or the first, second, and third nitride layers, the gate cap layer, and the oxide liner down to an upper surface of the gate.
11. The method according to claim 10, comprising: masking the NFET and PFET SG structures after forming the oxide liner; removing the oxide liner from the NFET and PFET EG gate structures; and removing the masking.
12. The method according to claim 10, comprising removing the horizontal portions of the second nitride layer by: etching the second nitride layer down to the oxide liner.
13. The method according to claim 10, comprising: removing the masking of the NFET and PFET EG gate structures prior to masking the NFET and PFET SG and EG gate structures.
14. The method according to claim 10, comprising removing the masking of the NFET and PFET SG and EG gate structures prior to forming the RSD structures adjacent to the PFET or NFET SG and EG structures.
15. The method according to claim 10, comprising removing the masking of the PFET or NFET SG and EG gate structures prior to the removing of the first, second, and third nitride layers and the gate cap layer or the first, second, and third nitride layers, the gate cap layer, and the oxide liner down to an upper surface of the gate.
16. The method according to claim 15, comprising: removing the third nitride layer from over the RSD structures on the opposite sides of the NFET or PFET EG and SG gate structures; and performing spacer nitride deposition, etch, and silicidation subsequent to the removing of the first, second, and third nitride layers and the gate cap layer or the first, second, and third nitride layers, the gate cap layer, and the oxide liner down to an upper surface of the gate.
17. A device comprising: a fully depleted silicon on insulator (FDSOI) substrate; p-type field effect transistor (PFET) core device (SG) and I/O device (EG) gate structures and n-type field effect transistor (NFET) SG and EG gate structures formed on the FDSOI substrate, the SG and EG structures laterally separated; a dual nitride layer spacer formed on each sidewall of the NFET and PFET SG gate structures; a triple nitride layer spacer formed on each sidewall of the NFET and PFET EG gate structures; and raised source/drain (RSD) structures formed on opposite sides of the NFET and PFET SG and EG gate structures.
18. The device according to claim 17, wherein the dual nitride layer spacer is thinner than the triple nitride layer spacer.
19. The device according to claim 17, wherein the PFET SG gate structure is formed over a layer of silicon germanium (SiGe) and the PFET EG and NFET SG and EG structures are formed over a layer of silicon.
20. The device according to claim 17, wherein a layer of oxide is formed between a first and a second layer of nitride of the NFET and PFET EG structures.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0017] The present disclosure is illustrated by way of example, and not by way of limitation, in the figures of the accompanying drawing and in which like reference numerals refer to similar elements and in which:
[0018]
[0019]
[0020]
DETAILED DESCRIPTION
[0021] In the following description, for the purposes of explanation, numerous specific details are set forth in order to provide a thorough understanding of exemplary embodiments. It should be apparent, however, that exemplary embodiments may be practiced without these specific details or with an equivalent arrangement. In other instances, well-known structures and devices are shown in block diagram form in order to avoid unnecessarily obscuring exemplary embodiments. In addition, unless otherwise indicated, all numbers expressing quantities, ratios, and numerical properties of ingredients, reaction conditions, and so forth used in the specification and claims are to be understood as being modified in all instances by the term “about.”
[0022] The present disclosure addresses and solves the current problems of unbalanced PFET and NFET SG and EG gate structures in terms of performance and reliability and spacer breakdown from high drain voltages attendant upon integrated RSD formation. The present disclosure also addresses and solves the current problem of a difficulty controlling nitride/oxide spacer formation attendant upon FDSOI HKMG formation.
[0023] Methodology in accordance with embodiments of the present disclosure includes providing PFET SG and EG gate structures and NFET SG and EG gate structures on a substrate, the PFET and NFET structures laterally separated. A first conformal nitride layer and an oxide liner are formed over the substrate and a second conformal nitride layer is formed on sidewalls of the PFET and NFET EG gate structures. Horizontal portions of the first nitride layer and the oxide liner are removed from over the PFET SG and EG gate structures and substrate and RSD structures are formed on opposite sides of each of the PFET SG and EG gate structures. Horizontal portions of the first nitride layer and the oxide liner are removed from over the NFET SG and EG gate structures and substrate and RSD structures are formed on opposite sides of each of the NFET SG and EG gate structures.
[0024] Still other aspects, features, and technical effects will be readily apparent to those skilled in this art from the following detailed description, wherein preferred embodiments are shown and described, simply by way of illustration of the best mode contemplated. The disclosure is capable of other and different embodiments, and its several details are capable of modifications in various obvious respects. Accordingly, the drawings and description are to be regarded as illustrative in nature, and not as restrictive.
[0025]
[0026] Next, a nitride layer 115 is conformally formed over the substrate 109. The nitride layer 115 is formed of the same material as the nitride layer 111 and may be formed, e.g., to a thickness of 3 nm to 15 nm depending on the technology (i.e., poly pitch or fin pitch), reliability constraints, and operating drain voltage. The nitride layer 115 must be selective to the sacrificial hardmask that follows in the process. The nitride layer 115 is then etched, e.g., by reactive ion etching (RIE) using tetrafluoromethane (CF.sub.4), down to the oxide liner 113 forming outer spacers. A photoresist layer 117 is then formed over the PFET and NFET EG gate structures 103 and 107, respectively, and the nitride layer 115 is removed from the PFET and NFET SG gate structures 101 and 105, respectively, by an etchant that is isotropic and selective to the oxide liner 113, as depicted in
[0027] Adverting to
[0028] Next, the oxide liner 113 and the nitride layer 111 are anisotropically etched down to the substrate 109 and gate caps 110, e.g., by RIE using CF.sub.4, forming nitride L-shaped spacers 111′ and oxide L-shaped spacers 113′ on opposite sides of the PFET EG gate structure 103, as depicted in
[0029] Adverting to
[0030] The oxide liner 113 and the nitride layer 111 are then anisotropically etched down to the substrate 109 and gate caps 110, e.g., by RIE using CF.sub.4, forming nitride L-shaped spacers 111′ and oxide L-shaped spacers 113′ on opposite sides of the NFET SG and EG gate structures 105 and 107, respectively. After the final NFET spacer etch, the photoresist layer 603 is removed. Again, the oxide liner 113 may also be removed by a HF pre-clean forming the nitride L-shaped spacers 111′ on the NFET SG gate structure 105. Next, the RSD structures 701 are formed by epitaxial growth while the complimentary devices are protected by the sacrificial hard mask 601. Optionally, after the RSD structures 701 are grown, a thin oxide liner (not shown for illustrative convenience) may again be formed, e.g., by plasma oxidation or by a deposited oxide, to protect the RSD structures 701 during the subsequent removal of the hardmask layer 601. The hardmask layer 601 over the PFET SG and EG gate structures 101 and 103, respectively, is then isotropically removed, e.g., using hot phosphoric acid or RIE using CH.sub.3F/O.sub.2, as depicted in
[0031]
[0032] Adverting to
[0033] A soft cleaning is performed, and then a photoresist layer 1301 is formed over the NFET and PFET EG gate structures 903 and 907, respectively, as depicted in
[0034] Adverting to
[0035] Next, the RSD structures 1801 are formed by epitaxial growth on the SiGe layer 919 and the Si layer 917 adjacent to the PFET SG and EG structures 905 and 907, respectively, or on the Si layers 917 adjacent to the NFET SG and EG structures 901 and 903, respectively, depending on which gate structures are masked first, as depicted in
[0036] Adverting to
[0037]
[0038] Next, a nitride layer 2227 is conformally formed to a thickness of 60 Å to 80 Å by MLD over the substrate, as depicted in
[0039] Adverting to
[0040]
[0041] Next, the RSD structures 2801 are formed by epitaxial growth on the SiGe layer 2219 and the Si layer 2217 adjacent to the PFET SG and EG structures 2205 and 2207, respectively, or on the Si layers 2217 adjacent to the NFET SG and EG structures 2201 and 2203, respectively, depending on which gate structures are masked first, as depicted in
[0042] Adverting to
[0043] Next, the gate caps 2212 are removed, and the nitride layers 2223, 2227, and 2901 and the oxide liner 2225 are etched, e.g., by RIE or by an appropriate wet etch using hot phosphoric acid, down to the upper surface of the silicon layer 2211, as depicted in
[0044] The embodiments of the present disclosure can achieve several technical effects including requiring only one additional mask layer (re-using the existing EG mask); forming NFET and PFET EG spacers that are thicker to improve reliability without sacrificing SG performance; forming matched PFET and NFET spacers; and forming SG devices that have faceted RSD due to L-shaped spacers, reducing Gate-to-RSD capacitance and improving parasitic capacitance (Ceff), which directly translates to improved AC performance. The embodiments of the present disclosure can also achieve several additional technical effects including forming different and independent spacer thicknesses for SG NFET, SG PFET, and PFET/NFET EG gate structures on FDSOI and all of the gate structures having full nitride spacers. Embodiments of the present disclosure enjoy utility in various industrial applications as, for example, microprocessors, smart phones, mobile phones, cellular handsets, set-top boxes, DVD recorders and players, automotive navigation, printers and peripherals, networking and telecom equipment, gaming systems, and digital cameras. The present disclosure therefore enjoys industrial applicability in FDSOI devices and/or any technology requiring RSD epitaxy.
[0045] In the preceding description, the present disclosure is described with reference to specifically exemplary embodiments thereof. It will, however, be evident that various modifications and changes may be made thereto without departing from the broader spirit and scope of the present disclosure, as set forth in the claims. The specification and drawings are, accordingly, to be regarded as illustrative and not as restrictive. It is understood that the present disclosure is capable of using various other combinations and embodiments and is capable of any changes or modifications within the scope of the inventive concept as expressed herein.