METHOD OF MANUFACTURING A BUILDING ELEMENT AND A BUILDING ELEMENT
20200223197 · 2020-07-16
Assignee
Inventors
Cpc classification
B32B27/42
PERFORMING OPERATIONS; TRANSPORTING
B32B37/10
PERFORMING OPERATIONS; TRANSPORTING
B32B27/12
PERFORMING OPERATIONS; TRANSPORTING
B32B2264/065
PERFORMING OPERATIONS; TRANSPORTING
B32B2305/30
PERFORMING OPERATIONS; TRANSPORTING
B32B29/005
PERFORMING OPERATIONS; TRANSPORTING
B32B37/1027
PERFORMING OPERATIONS; TRANSPORTING
B32B9/005
PERFORMING OPERATIONS; TRANSPORTING
B05D1/30
PERFORMING OPERATIONS; TRANSPORTING
E04F15/041
FIXED CONSTRUCTIONS
B32B2264/104
PERFORMING OPERATIONS; TRANSPORTING
B32B37/06
PERFORMING OPERATIONS; TRANSPORTING
E04F2290/042
FIXED CONSTRUCTIONS
B32B9/02
PERFORMING OPERATIONS; TRANSPORTING
B32B21/14
PERFORMING OPERATIONS; TRANSPORTING
B32B21/02
PERFORMING OPERATIONS; TRANSPORTING
E04F15/107
FIXED CONSTRUCTIONS
B32B13/10
PERFORMING OPERATIONS; TRANSPORTING
E04F13/18
FIXED CONSTRUCTIONS
E04F15/105
FIXED CONSTRUCTIONS
E04F15/102
FIXED CONSTRUCTIONS
E04F13/16
FIXED CONSTRUCTIONS
B32B13/02
PERFORMING OPERATIONS; TRANSPORTING
B32B29/02
PERFORMING OPERATIONS; TRANSPORTING
B32B27/20
PERFORMING OPERATIONS; TRANSPORTING
B05D2601/20
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B27/20
PERFORMING OPERATIONS; TRANSPORTING
B32B27/42
PERFORMING OPERATIONS; TRANSPORTING
B32B37/06
PERFORMING OPERATIONS; TRANSPORTING
B32B37/10
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method of manufacturing a building element, including applying a first layer on a first surface of a substrate, the first layer including a mixture of a binder, at least one filler and fine non-pigment cohesive particles, wherein an amount of the fine non-pigment cohesive particles in the mixture may be between 0.05 wt % and 9 wt % of the mixture, and applying heat and/or pressure to the first layer and/or the substrate thereby forming the building element. The disclosure further relates to such a building element.
Claims
1. A method of manufacturing a building element, comprising applying a first layer on a first surface of a substrate, the first layer comprising a mixture of a binder, at least one filler and fine non-pigment cohesive particles, wherein an amount of the fine non-pigment cohesive particles in the mixture is between 0.05 wt % and 9 wt % of the mixture, applying heat and/or pressure to the first layer and/or the substrate thereby forming the building element.
2. The method according to claim 1, wherein a cohesion force of said cohesive particles is exceeding a cohesive force of said at least one filler.
3. The method according to claim 1, wherein a cohesion force of said cohesive particles is at least 0.25 kPa, as measured with standard Shear Cell Program, 50 mm shear 6 kPa.
4. The method according to claim 1, wherein the mixture is applied in a dry form.
5. The method according to claim 1, wherein at least 70% of the fine non-pigment cohesive particles have a length in their largest dimension of 2.5 m or less.
6. The method according to claim 1, wherein the fine non-pigment cohesive particles have a refractive index of less than 1.9.
7. The method according to claim 1, wherein the fine non-pigment cohesive particles are selected from silicates or silicon oxides.
8. The method according to claim 7, wherein SiO.sub.2 is provided as fumed silica.
9. The method according to claim 1, wherein the fine non-pigment cohesive particles is selected from calcium carbonate, barium sulphate, polytetrafluoreten.
10. The method according to claim 1, wherein said at least one filler comprises wood powder.
11. The method according to claim 1, wherein the binder is a thermosetting binder.
12. The method according to claim 1, wherein the first layer further comprises wear resistant particles.
13. The method according to claim 1, wherein the first layer further comprises pigment particles.
14. The method according to claim 1, wherein the substrate is a wood-based board, a particleboard, a thermoplastic board, a plywood, a lamella core, a veneer layer.
15. A building element, comprising a first layer arranged on a substrate, the first layer formed by a mixture comprising a binder, at least one filler and fine non-pigment cohesive particles, wherein an amount of the fine non-pigment cohesive particles in the mixture is between 0.05 wt % and 9 wt % of the mixture, wherein said building element is formed by applying heat and/or pressure.
16. The building element according to claim 15, wherein a cohesion force of said cohesive particles is exceeding a cohesive force of said at least filler.
17. The building element according to claim 15, wherein a cohesion force of said cohesive particles is at least 0.25 kPa, as measured with standard Shear Cell Program, 50 mm shear 6 kPa.
18. The building element according to claim 15, wherein the mixture is applied in a dry form.
19. The building element according to claim 15, wherein at least 70% of the fine non-pigment cohesive particle has a length in its largest dimension of 2.5 m or less.
20. The building element according to claim 15, wherein the fine non-pigment cohesive particles have a refractive index of less than 1.9.
21. The building element according to claim 15, wherein the fine non-pigment cohesive particles are selected from silicates or silicon oxides.
22. The building element according to claim 21, wherein SiO2 is provided as fumed silica.
23. The building element according to claim 15, wherein the fine non-pigment cohesive particles is selected from calcium carbonate, barium sulphate, polytetrafluoreten.
24. The building element according to claim 15, wherein said at least one filler comprises wood powder.
25. The building element according to claim 15, wherein the binder is a thermosetting binder.
26. The building element according to claim 15, wherein the first layer further comprises wear resistant particles.
27. The building element according to claim 15, wherein the first layer further comprises pigment particles.
28. The building element according to claim 15, wherein the substrate is a wood-based board, a particleboard, a thermoplastic board, a plywood, a lamella core, a veneer layer.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0089] Embodiments of the present invention will by way of example be described in more detail with reference to the appended schematic drawings, which show embodiments of the present invention.
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DETAILED DESCRIPTION
[0101] It is disclosed herein a method of manufacturing a building element 10, comprising applying a first layer 1 on a first surface of a substrate 2, the first layer 1 comprising a mixture of a binder, at least one filler and cohesive particles 4, applying heat and/or pressure to the first layer and/or the substrate thereby forming the building element 10.
[0102] The method of manufacturing the building element 10, and the building element 10 thereby formed, will now be described with reference to
[0103] The building element 10 may be a building panel, such as floor panel, a ceiling panel, a wall panel, a door panel, a worktop, a furniture component or part of a furniture component, skirting boards, mouldings, edging profiles etc.
[0104] The method comprises providing a substrate 2. The substrate is preferably a pre-fabricated substrate, produced prior to the method of manufacturing a building element 10. A substrate may comprise at least one wood veneer layer. The substrate may comprise several wood veneer layers, such as being plywood. Preferably, the veneered element includes an uneven number of wood veneer layers. The substrate may comprise a wood-based panel. The wood-based panel may be selected from the group comprising of HDF, MDF, OSB, lamella core, and solid wood. The substrate may be a thermoplastic board. The substrate may comprise a thermoplastic material. The substrate may be a mineral composite board. The substrate may be a fibre cement board. The substrate may comprise a sheet such as a paper sheet or sheet of non-woven material or a conveyor. The substrate is preferably a pre-fabricated substrate, produced prior to the method of manufacturing a building element 10. The wood-based substrate may be a wood fibre-based board such as MDF, HDF, particleboard or plywood board. The substrate may be a Wood Plastic Composite (WPC). The substrate may be a mineral composite board. The substrate may be magnesium oxide cement board. The substrate may be a ceramic board. The substrate may be a plastic board such as a thermoplastic board.
[0105] The substrate 2 may be a carrier, such as a sheet of paper, a non-woven sheet, or a wood veneer.
[0106] When the first layer 1 is permanently attached to the substrate 2 the building element 10 is a building panel. Permanently means that the substrate cannot be detached from the at least a first layer after they are attached to the substrate by applying heat and/or pressure.
[0107] When substrate is a temporary carrier, such as a sheet of paper or non-woven sheet or a conveyor, the first layer is reversibly attached to the substrate 10. Reversibly means that the at least a first layer 1 may be detached from the substrate 2 after application of heat and/or pressure.
[0108] The substrate 2 has two surfaces. The first surface is facing the first layer 1. The second surface is the surface of the substrate 2 opposite of the first surface. If, optionally, a balancing layer 5 is applied to the substrate, the second surface of the substrate 2 is facing the balancing layer 5.
[0109] According to another aspect, the method further comprises applying a balancing layer 5 on a second surface of a substrate 2, the second surface being opposite to the first surface of the substrate 2.
[0110] The balancing layer 5 may be a powder based balancing layer being applied as a powder. The powder based balancing layer may comprise wood particles such as lignocellulosic and/or cellulosic particles and a binder, preferably a thermosetting binder such as an amino resin. The balancing layer may be a resin impregnated paper, preferably impregnated with a thermosetting binder. The balancing layer may have the same composition as the first layer 1.
[0111] A first layer 1 is applied on a first surface of the substrate 2. The first layer 1 may be applied by scattering, as shown in
[0112] The first layer 1 is formed by a mixture comprising a binder, at least one filler, and cohesive particles.
[0113] The mixture is applied in dry form. The mixture is preferably applied in dry powder form.
[0114] Said least one filler may be particles or fibres, for example, wood fibres or particles, or mineral particles or fibres. The wood particles may be lignocellulosic particles and/or cellulosic particles. The wood particles may be at least partially bleached or have the original wood colour. Particles may be also coloured prior to adding them to a mixture. A filler may be rice, straw, corn, jute, linen, flax, cotton, hemp, bamboo particles or fibres. A filler may be metals, ceramic filler, a composite filler, etc.; for example, silicates or silicone oxides.
[0115] In the following, particles and fibres will be used as substitutes.
[0116] It may be the case that more than one filler is present in a mixture. The mixture may comprise a combination of two or more fillers discussed above.
[0117] A binder may be a thermosetting or thermoplastic binder.
[0118] The first layer 1 may comprise a thermosetting binder. The thermosetting binder may be an amino resin such as melamine formaldehyde, urea formaldehyde, or a combination thereof. The thermosetting binder may be phenol formaldehyde.
[0119] The first layer 1 may comprise a thermoplastic binder. The thermoplastic binder may be polyvinyl chloride (PVC), polyethylene (PE), polypropylene (PP), polyurethane (PU), polyvinyl alcohol (PVOH), polyvinyl butyral (PVB), and/or polyvinyl acetate (PVAc), or a combination thereof. The thermoplastic binder simultaneously bonds the first surface of the substrate 2 to the first layer 1.
[0120] According to another aspect, the first layer 1 may comprise, as a thermosetting binder, a urea formaldehyde resin, urea formaldehyde resin, or a co-polymer comprising urea formaldehyde resin, phenol formaldehyde resin, phenol formaldehyde resin, or a co-polymer comprising phenol formaldehyde resin, melamine formaldehyde resin, melamine formaldehyde resin, or a co-polymer comprising melamine formaldehyde resin or mixtures thereof.
[0121] The mixture may further comprise cohesive particles, such as fine non-pigment cohesive particles.
[0122] A particle is a powder component with a discrete quantity of matter and with the surface to the immediate surrounding, meaning either a single discrete component or two or more such components bound together chemically or physically by a coupling agent to form one solid unit of greater mass and/or size.
[0123] The cohesive particles may be fine cohesive particles.
[0124] The cohesive particles may be non-pigment particles, such as fine non-pigment cohesive particles.
[0125] The cohesive particles, such as fine non-pigment cohesive particles, may be selected from silicates, silicon oxides, calcium carbonate, barium sulphate, polytetrafluoreten.
[0126] The cohesive particles, such as fine non-pigment cohesive particles, may be selected from silicates, such as aluminium silicate, magnesium silicate or silicon oxides, preferably SiO.sub.2, preferably as fumed silica.
[0127] The cohesive particles, such as fine non-pigment cohesive particles, may be selected from calcium carbonate (CaCO.sub.3, such as MIKHART C), barium sulphate such as BaSO.sub.4 BB30EX, aluminium silicate such as POLYGLOSS 90, hydrated magnesium silicate, calcinated aluminium silicate (fired raw kaolin with reduced crystalline water content), polytetrafluoreten such as ALGOFLON and fumed silica such as HDK N20.
[0128] It shall be understood that cohesive particles are particles having cohesive attraction or cohesive force. Cohesive force is the action or property or like of particles sticking together, being mutually attractive. It is an intrinsic property of a substance that is caused by the shape and structure of at least one particle, creating electrical attraction that can maintain a microscopic structure. In other words, cohesion allows for surface energy reduction by creating a bulk-like atmosphere for the particle surface molecules.
[0129] By fine particle it is typically understood that at least 70% of the particles have a length in their largest dimension of 2.5 m or less, preferably that the particles have a length in their largest dimension of 2.5 m or less.
[0130] Fine cohesive particles, such as fine non-pigment cohesive particles, are thus particles wherein at least 70% of the particles having a size, preferably the length in their largest dimension, being between 0.1 m and 2.5 m, such that particles having a size, preferably the length in their largest dimension, being between 0.1 m and 2.5 m.
[0131] A cohesion force of the cohesive particles may exceed a cohesive force of said at least one filler, such that the cohesive particles coat the fillers. The cohesion force of the cohesive particles may be at least 0.25 kPa, such 0.25-3 kPa, as measured with standard Shear Cell Program, 50 mm shear 6 kPa (FT4 Powder Rheometer).
[0132] According to an aspect, the cohesive particles, such as fine non-pigment cohesive particles, in the first layer are present in an amount of 0.05 wt % to 9 wt % in the mixture.
[0133] Preferably, the amount of cohesive particles, such as fine non-pigment cohesive particles, in the mixture is between 0.3 wt % and 8.5 wt %, preferably between 1 wt % and 7 wt %, preferably between 2 wt % and 6 wt %, preferably between 4 wt % and 5 wt %.
[0134] In one embodiment, the amount of non-pigment cohesive particles in the mixture may be about 7.5 wt %.
[0135] In one embodiment, the amount of non-pigment cohesive particles in the mixture may be about 2.5 wt %.
[0136] In an aspect, the amount of cohesive particles, such as fine non-pigment cohesive particles, in the mixture may be between 0.2 wt % and 4.5 wt %, preferably between 0.2 wt % and 2.5 wt %.
[0137] In an aspect, the amount of cohesive particles, such as fine non-pigment cohesive particles, in the mixture may be between 0.3 wt % and 5 wt %, preferably between 0.5 wt % and 5 wt %, more preferably between 2 wt % and 4 wt %.
[0138] In one embodiment, the amount of non-pigment cohesive particles in the mixture may be about 0.1 wt %.
[0139] According to another aspect, the fine non-pigment cohesive particles are selected from silicates, such as aluminium silicate or silicon oxides, preferably SiO.sub.2, preferably as fumed silica.
[0140] In particular, if aluminium silicate is used as fine non-pigment cohesive particles, the amount of aluminium silicate in the mixture may be between 0.5 wt % and 9 wt %, such as between 0.5 wt % and 5 wt %, preferably between 2 wt % and 4 wt %. In an aspect, the amount of aluminium silicate in the mixture may be between 0.3 wt % and 5 wt %.
[0141] If fumed silica, such as SiO.sub.2, is used as fine non-pigment cohesive particles, the amount of silicon oxides in the mixture may be between 0.05 wt % and 3 wt %, preferably between 0.05 wt % and 0.7 wt % such as between 0.1 wt % and 0.7 wt %, preferably between 0.3 wt % and 0.7 wt %.
[0142] Preferably, fine non-pigment cohesive particles may be selected from calcium carbonate (CaCO.sub.3, such as MIKHART C), BaSO.sub.4 BB30EX, POLYGLOSS 90 (aluminium silicate), hydrated magnesium silicate, calcinated aluminium silicate (fired raw kaolin with reduced crystalline water content), ALGOFLON (polytetrafluoreten) and HDK N20 (fumed silica).
[0143] If calcium carbonate is used as fine non-pigment cohesive particles, the amount of calcium carbonate in the mixture may be between 0.3 wt % and 9 wt %, preferably between 0.3 wt % and 5 wt % such as between 0.5 wt % and 5 wt %, preferably between 2 wt % and 4 wt %. In an aspect, the amount of calcium carbonate in the mixture may be between 0.5 wt % and 9 wt %.
[0144] If barium sulphate is used as fine non-pigment cohesive particles, the amount of calcium carbonate in the mixture may be between 0.3 wt % and 9 wt %, preferably between 0.3 wt % and 5 wt % such as between 0.5 wt % and 5 wt %, preferably between 2 wt % and 4 wt %. In an aspect, the amount of barium sulphate in the mixture may be between 0.5 wt % and 9 wt %.
[0145] If polytetrafluoreten is used as fine non-pigment cohesive particles, the amount of calcium carbonate in the mixture may be between 0.3 wt % and 9 wt %, preferably between 0.3 wt % and 5 wt % such as between 0.5 wt % and 5 wt %, preferably between 2 wt % and 4 wt %. In an aspect, the amount of polytetrafluoreten in the mixture may be between 0.5 wt % and 9 wt %.
[0146] According to another aspect, SiO.sub.2 is a fumed silica.
[0147] In one aspect, the first layer may further comprise pigment.
[0148] In another aspect, the first layer may comprise essentially no pigment.
[0149] Preferably, cohesive particles, such as fine non-pigment cohesive particles, have a refractive index (RI) of less than 1.9, such as 1.0-1.9. When refractive index is equal to or below 1.9, the fine non-pigment cohesive particles discolour the first layer less that the particles having refractive index more than 1.9. Thereby, fine non-pigment cohesive particles in accordance with certain embodiments of the invention do not significantly affect certain properties of the first layer, such as colour.
[0150] Preferably, cohesive particles such as fine non-pigment cohesive particles have a refractive index of about 1.56, such as the cohesive particles being aluminium silicate.
[0151] Preferably, cohesive particles such as fine non-pigment cohesive particles have a refractive index of about 1.46, such as the cohesive particles being fumed silica (such as) AEROSIL.
[0152] The refractive index of cohesive pigment particles is a number that describes how fast light propagates through the material and is defines as:
[0153] Refractive Index (RI)=speed of light/phase velocity of the light in the medium. Refractive index can be measured with refractometers, such as OPTi Digital Range refractometers from Bellingham and Stanley.
[0154] The dry mixture preferably comprises between 30 wt % to 47 wt % of filler such as wood powder, preferably 33-45 wt %, more preferably 35 wt % or 44 wt %.
[0155] The dry mixture preferably comprises between 44 wt % and 70 wt % of at least one binder (or a mixture of binders), such as 49-54 wt %, or 60-75 wt %.
[0156] The dry mixture preferably comprises between 0.05 wt % and 9 wt % of cohesive particles, such as fine non-pigment cohesive particles. For example, when aluminium silicate is used, the mixture preferably comprises aluminium silicate in the amount between 2-4 wt %. For example, when fumed silica is used, it is preferably comprised in the dry mixture in the amount 0.2-0.7 wt %.
[0157] The mixture may be applied in an amount of 200-600 g/m.sup.2, preferably 300-500 g/m.sup.2, such as about 400 g/m.sup.2 thereby forming a first layer. The amount of binder in the applied mixture may be 100-300 g/m.sup.2, preferably 150-250 g/m.sup.2 such as about 200 g/m.sup.2.
[0158] The mixture of a binder, at least one filler and fine non-pigment cohesive particles may be distributed on the first surface of the substrate 2 to form a first layer 1, as shown in
[0159] It has been surprisingly discovered by the inventors that fine non-pigment cohesive particles added in the above disclosed ranges to the dry mixture comprising a binder and at least one filler increase free flow of the dry mixture of the first layer.
[0160] At the same time addition of such particles to the well-balanced composition had no material negative effect on other properties of the mixture. The process parameters for the production of the building element such as pressure, temperature and time remained largely unchanged.
[0161] It has been discovered by the inventors that fine non-pigment cohesive particles are suitable for the purpose and does not materially affect any other parameters of the mixture and the first surface layer in a negative way. Thus, a mixture comprising a binder, at least one filler and fine non-pigment cohesive particles may form a first layer of the building element as defined herein.
[0162] Including non-pigment cohesive particles in the mixture improves free flow of the first layer, thereby allowing for a better distribution of the layer. It also improves the attachment of the first layer 1 to the substrate 2 after pressing.
[0163] The first layer 1 may also have other properties such as wear-resistant properties, provided by additives such as wear resistant particles. Wear resistant particles may be aluminium oxide particles, such as corundum.
[0164] The first layer 1 may comprise further additives such as wetting agents, anti-static agents and/or heat conductive additives such as aluminium, catalysts.
[0165] Flowability of the dry mixture positively created by the addition of fine non-pigment cohesive particles that improves curing of a building element when applying heat and/or pressure, since the board coming out of press has an improved shape.
[0166] The balancing of the product is thereby improved. A balancing layer 5, if any may be thinner than is conventionally used in the art.
[0167] There may be an additional or intermediate layer arranged on the first layer 1 or on the first surface of the substrate 2, not shown on
[0168] Moisture may be applied to the first layer 1 prior to pressing. The first layer 1 may be dried and or stabilised by applying heat, for example by IR or NIR.
[0169] The mixture is applied on the substrate 2 to form the first layer 1 and pressed together by applying heat and/or pressure to the first layer 1 and/or substrate 2, as shown in
[0170] A surface layer 3 may optionally be applied on the first layer 1, preferably prior to pressing. The first layer 1 may be pre-pressed prior to applying the surface layer 3 or may be scattered onto the substrate 2, preferably prior to pressing.
[0171] A surface layer 3 may applied on the first layer 1, thereby forming a second layer above the first layer 1. The surface layer 3 may be a veneer layer as shown in
[0172] When a surface layer 3 is applied on the first layer 1, the binder, such as a thermosetting binder of the above described type, simultaneously bonds the surface layer 3 with the first layer 1 during pressing. When heat and/or pressure are applied to the first layer 1, the thermosetting binder becomes fluid before cross-linking takes place. The applied heat and pressure results in curing of the thermosetting binder of the first layer 1, simultaneously as bonding the surface layer 3 to the first layer 1.
[0173] In an embodiment, a produced building element may be 6-25 mm thick, preferably 8-15 mm thick after pressing, while the substrate may be 5-22 mm thick, preferably 7-14 mm thick. The first layer may be 0.1-2 mm thick after pressing.
[0174] Exemplary building elements 10 produced by embodiments of the above described method are shown in
[0175] In the embodiment shown in
[0176] In the embodiment shown in
[0177] In the embodiment shown in
[0178] The first layer may be applied in a powder form.
[0179] According to an aspect, the building panel is a floor panel or wall panel.
[0180] According to an aspect, a building element 10 may comprise a first layer 1 arranged on a substrate 2, the first layer comprising a mixture of a binder, at least one filler and fine non-pigment cohesive particles, wherein said building element is assembled by applying heat and/or pressure to the first layer 1 and/or substrate 2.
[0181] A building element according to the above aspects may incorporate all the advantages of the method, which previously has been discussed, whereby the previous discussion is applicable also to the building element.
[0182] It is contemplated that there are numerous modifications of the embodiments described herein, which are still within the scope of the invention as defined by the appended claims. For example, it is contemplated that more than one wear resistant foil may be arranged on a core for forming a building panel.
EXAMPLES
Example 1
[0183] Different powder formulations comprising wood fibres and melamine-formaldehyde resin were made with increasing concentration of ASP G90, a fine particle aluminium silicate, in order to investigate a connection between the powder free flow and the concentration of ASP G90 as demonstrated in Table 1. The powder formulations were placed in glass jars to approximately half their volume and visually evaluated as the powders were let flowing by adding an external force to the jars. The typical powder which was considered was flowing without forming aggregates and did not show heavy dust formation which tended to partly adsorb to the jar walls. Acceptable formulation has a more even particle size distribution (
TABLE-US-00001 TABLE 1 Free flow experiment with different concentrations of ASP G90 ASP G90 MF Wood fibres Formulation (wt %) (wt %) (wt %) A (Ref) 0 54 46 B 1 53.5 45.5 C 2 53 45 D 3 52.5 44.5 E 5 51.5 42.5
[0184] Formulation B-E showed significantly higher free flow as visually evaluated than the reference powder A (Ref). There was visually a remarkable improvement between formulation B and C but no notable difference between samples C, D and E.
Example 2
[0185] Different powder formulations comprising wood fibres and a melamine-formaldehyde resin were made with increasing concentration of AEROSIL 200, a very fine particle fumed silica, in order to investigate a connection between the powder free flow and the concentration of AEROSIL 200. The mixture compositions are shown in Table 2. The powder formulations were evaluated as described in the Example 1.
TABLE-US-00002 TABLE 2 Free flow experiment with different concentrations of AEROSIL 200. AEROSIL 200 MF Wood fibres Formulation (wt %) (wt %) (wt %) A (Ref) 0 54 46 F 0.1 53.95 46.95 G 3 52.5 44.5
[0186] Formulation F and G showed visually remarkable higher free flow than the reference A (Ref), which is further visualized in
[0187] When formulations B-E and F-G were used further in the method of manufacturing a building element the formulation was easy to distribute, did not form aggregates. The formulation provided for an even layer thereby improving properties of the first layer and binding of the first layer to the substrate.
Example 3
[0188] From four standardised formulations (A-D in Table 3 below), wherein only the additive part was switched between different inorganic non-pigment fine cohesive particles. These formulations were then run in a permeability program using a Freeman Technology FT4 Powder Rheometer where air is forced through a powder bed at different pressures. Pressure drop is directly negative proportional to permeability. A plot of Pressure drop vs. Applied normal stress was obtained where a high pressure drop is due to a low permeability, meaning higher cohesion in the powder. All powders were then visually inspected and the flowability compared using the glass jar method mentioned in Example 1.
TABLE-US-00003 TABLE 3 Standardised formulations. Recipe type A (wt %) B (wt %) C (wt %) D (wt %) Reference Wood fibre 37.5 37.5 40 41.5 42 MF resin 49 52.5 52 52.5 53 Aluminium 5 5 5 5 5 oxide Additive 8.5 5 3 1 Additives used MIKHART C (CaCO3) BaSO.sub.4 BB30EX POLYGLOSS 90/ASP G90 (aluminium silicate) Micro talc Calcinated kaolin ALGOFLON (polytetrafluoreten) HDK N20 (fumed silica)
[0189] Presented in
[0190]
[0191] When the word about or essentially is used in this specification in connection with a numerical value, it is intended that the associated numerical value include a tolerance of +/10% around the stated numerical value.
Embodiments
[0192] 1. A method of manufacturing a building element (10), comprising applying a first layer (1) on a first surface of a substrate (2), the first layer (1) comprising a mixture of a binder, at least one filler and fine non-pigment cohesive particles, wherein an amount of the fine non-pigment cohesive particles in the mixture is between 0.05 wt % and 9 wt % of the mixture,
[0193] applying heat and/or pressure to the first layer (1) and/or the substrate (2) thereby forming the building element (10).
[0194] 2. The method according to embodiment 1, wherein a cohesion force of said cohesive particles is exceeding a cohesive force of said at least one filler.
[0195] 3. The method according to embodiment 1 or 2, wherein a cohesion force of said cohesive particles is at least 0.25 kPa, as measured with standard Shear Cell Program, 50 mm shear 6 kPa (FT4 Powder Rheometer).
[0196] 4. The method according to any one of the preceding embodiments, wherein the mixture is applied in a dry form.
[0197] 5. The method according to any one of the preceding embodiments, wherein at least 70% of the fine non-pigment cohesive particles have a length in their largest dimension of 2.5 m or less, preferably a length in their largest dimension between 0.1 m and 2.5 m.
[0198] 6. The method according to any one of the preceding embodiments, wherein the fine non-pigment cohesive particles have a refractive index (RI) of less than 1.9.
[0199] 7. The method according to any one of the preceding embodiments, wherein the fine non-pigment cohesive particles are selected from silicates, such as aluminium silicate or silicon oxides, such as SiO.sub.2.
[0200] 8. The method according to embodiment 7, wherein SiO.sub.2 is provided as fumed silica.
[0201] 9. The method according to any one of embodiments 1-6, wherein the fine non-pigment cohesive particles is selected from calcium carbonate, barium sulphate, polytetrafluoreten.
[0202] 10. The method according to any one of the preceding embodiments, wherein said at least one filler comprises wood powder.
[0203] 11. The method according to any one of the preceding embodiments, wherein the binder is a thermosetting binder.
[0204] 12. The method according to any one of the preceding embodiments, wherein the first layer (1) further comprises wear resistant particles.
[0205] 13. The method according to any one of the preceding embodiments, wherein the first layer (1) further comprises pigment particles.
[0206] 14. The method according to any one of the preceding embodiments, wherein the substrate (2) is a wood-based board, a particleboard, a thermoplastic board, a plywood, a lamella core, a veneer layer.
[0207] 15. A building element (10), comprising
[0208] a first layer (1) arranged on a substrate (2), the first layer (1) formed by a mixture comprising a binder, at least one filler and fine non-pigment cohesive particles,
[0209] wherein an amount of the fine non-pigment cohesive particles in the mixture is between 0.05 wt % and 9 wt % of the mixture,
[0210] wherein said building element (10) is formed by applying heat and/or pressure.
[0211] 16. The building element according to embodiment 15, wherein a cohesion force of said cohesive particles is exceeding a cohesive force of said at least filler.
[0212] 17. The building element according to embodiment 15 or 16, wherein a cohesion force of said cohesive particles is at least 0.25 kPa, as measured with standard Shear Cell Program, 50 mm shear 6 kPa (FT4 Powder Rheometer).
[0213] 18. The building element according to any one of embodiments 15-17, wherein the mixture is applied in a dry form.
[0214] 19. The building element according to any one of embodiments 15-18, wherein at least 70% of the fine non-pigment cohesive particle has a length in its largest dimension of 2.5 m or less, preferably a length in its largest dimension between 0.1 m and 2.5 m.
[0215] 20. The building element according to any one of embodiments 15-19, wherein the fine non-pigment cohesive particles have a refractive index (RI) of less than 1.9.
[0216] 21. The building element according to any one of embodiments 15-20, wherein the fine non-pigment cohesive particles are selected from silicates, such as aluminium silicate or silicon oxides, such as SiO2.
[0217] 22. The building element according to embodiment 21, wherein SiO.sub.2 is provided as fumed silica.
[0218] 23. The building element according to any one of embodiments 15-20, wherein the fine non-pigment cohesive particles is selected from calcium carbonate, barium sulphate, polytetrafluoreten.
[0219] 24. The building element according to any one of embodiments 15-23, wherein said at least one filler comprises wood powder.
[0220] 25. The building element according to any one of embodiments 15-24, wherein the binder is a thermosetting binder.
[0221] 26. The building element according to any one of embodiments 15-25, wherein the first layer (1) further comprises wear resistant particles.
[0222] 27. The building element according to any one of embodiments 15-26, wherein the first layer (1) further comprises pigment particles.
[0223] 28. The building element according to any one of embodiments 15-27 wherein the substrate (2) is a wood-based board, a particleboard, a thermoplastic board, a plywood, a lamella core, a veneer layer.