Thin film transistors with epitaxial source/drain contact regions
10700211 ยท 2020-06-30
Assignee
Inventors
Cpc classification
B82Y40/00
PERFORMING OPERATIONS; TRANSPORTING
H01L29/78621
ELECTRICITY
H01L21/0262
ELECTRICITY
H01L29/78618
ELECTRICITY
H01L29/66757
ELECTRICITY
B82Y99/00
PERFORMING OPERATIONS; TRANSPORTING
International classification
H01L29/786
ELECTRICITY
H01L29/66
ELECTRICITY
Abstract
A method of forming a thin film transistor (TFT) that includes forming a low temperature polysilicon semiconductor layer on a substrate; and implanting first dopant regions on opposing sides of a channel region of the low temperature polysilicon semiconductor layer. The method may further include epitaxially forming second dopant regions on the first dopant regions. The concentration of the conductivity type dopant in the second dopant regions is greater than a concentration of the conductivity type dopant in the first dopant region. The second dopant regions are formed using a low temperature epitaxial deposition process at a temperature less than 350 C.
Claims
1. A transistor comprising: a first concentration doped source/drain region formed within a crystalline semiconductor region on opposing sides of a channel region within the crystalline semiconductor region; and a hydrogenated crystalline silicon (c-Si:H) source/drain regions having a second concentration dopant present on the first concentration doped source/drain region, wherein the second concentration dopant of the hydrogenated crystalline silicon (c-Si:H) source/drain regions is greater than a concentration of the first concentration doped source/drain region.
2. The transistor of claim 1, wherein a thickness of the semiconductor region is no greater than 100 nm.
3. The transistor of claim 1, further comprises an intermediately doped source/drain region between the first concentration doped source/drain regions and the hydrogenated crystalline silicon (c-Si:H) source/drain regions having the second concentration dopant.
4. The transistor of claim 1, wherein the c-Si:H containing material contains 5 atomic percent hydrogen to 40 atomic percent hydrogen.
5. The transistor of claim 1, wherein a total doping concentration of the hydrogenated crystalline silicon (c-Si:H) source/drain regions having the second concentration dopant ranges from 10.sup.20 cm.sup.3 to 10.sup.21 cm.sup.3.
6. The transistor of claim 5, wherein an active doping concentration of the hydrogenated crystalline silicon (c-Si:H) source/drain regions having the second concentration dopant ranges from 10.sup.19 cm.sup.3 to 510.sup.20 cm.sup.3.
7. The transistor of claim 1, wherein a total doping concentration of the first concentration doped source/drain region ranges from 510.sup.17 cm.sup.3 to 10.sup.19 cm.sup.3.
8. The transistor of claim 3, wherein the intermediately doped source/drain region has a total doping concentration ranging from 510.sup.18 cm.sup.3 to 10.sup.20 cm.sup.3.
9. A transistor comprising: a crystalline semiconductor region having a thickness of 100 nm or less; a first concentration doped source/drain region formed within the semiconductor region; hydrogenated crystalline silicon (c-Si:H) source/drain regions having a second concentration dopant present on the first concentration doped source/drain region, wherein the second concentration dopant of the hydrogenated crystalline silicon (c-Si:H) source/drain regions is greater than a concentration of the first concentration doped source/drain region; and a gate structure present on the crystalline semiconductor region.
10. The transistor of claim 9, further comprising spacers present on sidewalls of the gate structure.
11. The transistor of claim 9, wherein the c-Si:H containing material contains 5 atomic percent hydrogen to 40 atomic percent hydrogen.
12. The transistor of claim 9, wherein a total doping concentration of the hydrogenated crystalline silicon (c-Si:H) source/drain regions having the second concentration dopant ranges from 10.sup.20 cm.sup.3 to 10.sup.21 cm.sup.3.
13. The transistor of claim 12, wherein an active doping concentration of the hydrogenated crystalline silicon (c-Si:H) source/drain regions having the second concentration dopant ranges from 10.sup.19 cm.sup.3 to 510.sup.20 cm.sup.3.
14. The transistor of claim 9, wherein a total doping concentration of the first concentration doped source/drain region ranges from 510.sup.17 cm.sup.3 to 10.sup.19 cm.sup.3.
15. The transistor of claim 11, wherein the intermediately doped source/drain region has a total doping concentration ranging from 510.sup.18 cm.sup.3 to 10.sup.20 cm.sup.3.
16. A method of forming a transistor comprising: forming a crystalline semiconductor layer on a substrate; implanting first dopant regions on opposing sides of a channel region of the crystalline semiconductor layer; and epitaxially forming second dopant regions on the first dopant regions, wherein a concentration of the conductivity type dopant in the second dopant regions is greater than a concentration of the conductivity type dopant in the first dopant regions.
17. The method of claim 16, wherein the second dopant regions comprise epitaxial hydrogenated crystalline silicon (c-Si:H).
18. The method of claim 16, wherein a thickness of the low temperature polysilicon semiconductor layer is no greater than 100 nm.
19. The method of claim 16, wherein the epitaxial hydrogenated crystalline silicon (c-Si:H) is grown from a mixture of hydrogen (H.sub.2) containing carrier gas, a silane (SiH.sub.4) containing precursor gas, wherein the gas flow ratio [H.sub.2]/[SiH.sub.4]>5.
20. The method of claim 18, wherein the epitaxial hydrogenated crystalline silicon (c-Si:H) is grown from a mixture of hydrogen (H.sub.2) containing carrier gas, a silane (SiH.sub.4) containing precursor gas, and a phosphine (PH.sub.3) containing dopant gas, wherein the gas flow ratio of phosphine to silane [PH.sub.3]/[SiH.sub.4] is greater than 1000 ppm.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The following description will provide details of preferred embodiments with reference to the following figures wherein:
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DETAILED DESCRIPTION
(16) Detailed embodiments of the claimed structures and methods are disclosed herein; however, it is to be understood that the disclosed embodiments are merely illustrative of the claimed structures and methods that may be embodied in various forms. In addition, each of the examples given in connection with the various embodiments is intended to be illustrative, and not restrictive. Further, the figures are not necessarily to scale, some features may be exaggerated to show details of particular components. Therefore, specific structural and functional details disclosed herein are not to be interpreted as limiting, but merely as a representative basis for teaching one skilled in the art to variously employ the methods and structures of the present disclosure. For purposes of the description hereinafter, the terms upper, lower. right. left, vertical, horizontal. top, bottom, and derivatives thereof shall relate to the embodiments of the disclosure, as it is oriented in the drawing figures. The terms positioned on means that a first element, such as a first structure, is present on a second element, such as a second structure, wherein intervening elements, such as an interface structure, e.g. interface layer, may be present between the first element and the second element. The term direct contact means that a first element, such as a first structure, and a second element, such as a second structure, are connected without any intermediary conducting, insulating or semiconductor layers at the interface of the two elements.
(17) The methods and structure described herein provide thin film transistors (TFTs). A thin-film transistor (TFT) is a kind of field-effect transistor (FET) made by depositing of an active semiconductor layer as well as the dielectric layer and metallic contacts over a supporting substrate. The supporting substrate may be composed of a non-conductive material. e.g., an insulator. A common substrate for a TFT device is glass, because the primary application of TFTs is in liquid-crystal displays. This differs from the conventional transistor, where the semiconductor material typically is the substrate, such as a silicon wafer. TFTs can be made using a wide variety of semiconductor materials.
(18) Amorphous silicon TFTs have been widely used in liquid crystalline display (LCD) flat panels because of their low cost and suitability for large area deposition. However, amorphous Si TFTs suffer from low mobility and poor device stability that precludes high display resolutions and monolithic integration of the driver circuitry on the display backplane. The evolution to low temperature polycrystalline silicon thin film transistors (LTPS-TFTs) can have many benefits such as higher device performance and better device stability that enables higher display resolution (i.e. pixels per inch), and monolithic integration of the driver circuitry. XeCl Excimer-Laser Annealing (ELA) is one method to produce polycrystalline silicon (p-Si) by melting an amorphous (a-Si) material through laser irradiation, and is currently the dominant technology used in manufacturing of display panels for cell phones and other portable devices.
(19) Xenon monochloride (XeCl)-excimer laser annealing (ELA) succeeds in crystallizing amorphous silicon (-Si) for thicknesses ranging from 500 to 10,000 into polycrystalline silicon (p-Si) without substantial heating the substrates. This is because laser pulses with short durations generate local heat which may be efficiently dissipated, allowing to maintain the substrate at temperatures as low as room temperature (or even lower if substrate cooling is used). The polycrystalline form has larger grains that yield better mobility for TFTs due to reduced scattering from grain boundaries. This technique leads to the successful integration of complicated circuits in LCD displays.
(20) Low-temperature poly-Si (LTPS) thin-film transistors (TFTs) employ high voltages for driving liquid crystal displays (LCDs) and electrophoretic displays at levels ranging from 8V to 10V. and 20V to 30V, respectively. Such high voltages require drain-field relief structures, such as lightly-doped drain (LDD) regions. Conventionally, both the lightly-doped drain (LDD) regions and the highly-doped source/drain contact regions are formed by ion-implantation (or ion-shower), followed by doping activation that may include a combination of laser treatment and thermal annealing. Given the temperature limitations of the glass substrates, it has been determined that the activation of dopants is particularly challenging at high doping levels used for the source/drain contact regions, which can be close to the solid solubility limit of the material in which the dopant is being introduced. Additionally, fast diffusion of dopants along grain boundaries can reduce the effective lengths of the lightly-doped drain (LDD) regions (or eliminate), and induce non-uniformity (given the spatial variation of the grain boundaries). As a result, there can be a trade-off between low series resistance, and effective lightly-doped drain (LDD) regions/uniform device characteristics. Further, it has been determined that overall the conventional activation process is expensive and complicated.
(21) In some embodiments, the methods and structures of the present disclosure employ a low-temperature epitaxial growth of highly-doped hydrogenated crystalline silicon (c-Si:H) to form at least the highly doped source and drain contact regions of the device, in a manner that reduces dopant diffusion when compared to conventional processing. The highly-doped hydrogenated crystalline silicon (c-Si:H) provided by in-situ doped epitaxial semiconductor may replace or complement the doped source/drain contact regions that are formed by ion implantation. The disclosed devices may further include low-temperature self-aligned silicide at the source and drain regions to further reduce contact resistance and/or facilitate self-aligned device structures. The low-temperature epitaxial growth may be performed using plasma-enhanced chemical vapor deposition (PECVD) at temperatures below 450 C. In some embodiments, the plasma enhanced chemical vapor deposition (PECVD) may range from 150 C. to 350 C. While the methods and structures disclosed herein are particularly of interest to low-temperature polysilicon (LTPS) thin-film transistors, it will be appreciated that the substrate material is not limited to LTPS. For example, the substrate may include low-temperature polycrystalline silicon-germanium or high-temperature polysilicon. The methods and structures of the present disclosure are now described with greater detail with reference to
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(23) The term low-temperature polycrystalline silicon (LTPS) is polycrystalline silicon that has been synthesized at relatively low substrate temperatures, e.g., at temperatures of 650 C. and lower, compared to conventional methods for forming polysilicon crystalline, which are at substrate temperatures above 900 C. Polycrystalline silicon, also called polysilicon or poly-Si, is a high purity, polycrystalline form of silicon. In single crystal silicon, also known as monocrystalline silicon, the crystalline framework is homogenous. The entire sample is one single, continuous and unbroken crystal as its structure contains no grain boundaries. In contrast, in an amorphous structure the order in atomic positions is limited to short range. Polycrystalline and paracrystalline phases are composed of a number of smaller crystals or crystallites. Polycrystalline silicon (or semi-crystalline silicon, polysilicon, poly-Si, or simply poly) is a material consisting of multiple small silicon crystals.
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(25) The low temperature polysilicon semiconductor (LTPS) layer 10 may be formed on the dielectric substrate 5 using a chemical vapor deposition (CVD) process that employs gas precursors that can include silane, phosphine and hydrogen, which are used in the present embodiment, are SiH.sub.4, PH.sub.3 and H.sub.2, respectively. These gases can be used as the gas to deposit the LTPS layer 10. However, the material can further include other compositions. In addition, the mass ratio of silane, phosphine and hydrogen in the material gas can be adjusted according to the process requirements.
(26) In some embodiments, forming the low temperature polysilicon semiconductor (LTPS) layer 10 may include depositing an amorphous silicon (a-Si) layer, and performing a laser annealing process to convert the amorphous silicon (a-Si) layer to polysilicon. The a-Si layer may be deposited, e.g. using a plasma-enhanced chemical vapor deposition (PECVD) process that employs gas precursors that can include silane, phosphine and hydrogen, which are used in the present embodiment, are SiH.sub.4, PH.sub.3 and H.sub.2, respectively. However, the material can further include other compositions. In addition, the mass ratio of silane, phosphine and hydrogen in the material gas can be adjusted according to the process requirements. The a-Si layer may be dehydrogenated prior to laser crystallization using a furnace anneal or low-energy laser treatment to avoid explosive release of hydrogen during melting. Alternatively, a-Si may be grown using a physical vapor deposition (PVD) technique such as sputtering, e.g. from a phosphorus doped solid (sintered) silicon target. Other deposition techniques such as evaporation may also be used.
(27) In some embodiments, the aforementioned process can provide an amorphous silicon layer, e.g., a hydrogenated amorphous silicon thin film (a-Si:H), having a thickness ranging from about 5 nm to about 100 nm. In some other embodiments, the thickness of the amorphous silicon (a-Si) layer may range from 25 nm to 75 nm. It is noted that the aforementioned example for forming the amorphous silicon layer, is only one example, and the present disclosure is not intended to be limited to only this example. For example, in addition to radio frequency plasma enhanced chemical vapor deposition (RF-PECVD), the amorphous silicon layer may also be formed using any type of chemical vapor deposition, e.g., metal organic chemical vapor deposition. In yet another embodiment, the a-Si thickness is 50 nm.
(28) Still referring to
(29) Following the rapid cooling and solidification of the melted amorphous silicon layer, the layer has been converted to polysilicon. Because the polysilicon was converted from an amorphous silicon material at low substrate temperatures, the polysilicon may be referred to as low temperature polysilicon (LTPS). The laser treatment may produce a rough surface including protrusions at the locations of the grain boundaries. An optional surface planarization step, using techniques known in the art, such as chemical-mechanical polishing (CMP) may be used to substantially reduce the surface roughness of LTPS.
(30) The low temperature polysilicon layer 10 can be patterned and etched to define the dimensions extending from the end of one of the source/drain regions, e.g., the source region, across the channel region to the second of the source/drain regions, e.g., the drain region. This may be referred to as the active device region, and patterning may be performed by lithography and etching. Lithography includes forming a photoresist material (not shown) on an exposed surface of the blanket low temperature polysilicon layer 10, exposing the photoresist material to a desired pattern of radiation, and developing the photoresist material utilizing a conventional resist developer. The etching step, which transfers the pattern from the patterned photoresist into the blanket layer of crystalline semiconductor material. e.g., LTPS layer 10, can include dry etching (i.e., reactive ion etching, ion beam etching, or plasma etching), wet chemical etching, or a combination thereof. After pattern transfer, the patterned photoresist is removed from the structure utilizing a stripping process such as, for example, chemical stripping, ashing and/or selective etching.
(31) Referring to
(32) Referring to
(33) In some embodiments, the electrode portion 20 can be formed using a deposition process including, for example, chemical vapor deposition, plasma enhanced chemical vapor deposition, sputtering, chemical solution deposition, or plating. In some embodiments, the conductive material can be patterned by lithography and etching. The etch or etches that can be used in this embodiment of the present disclosure may include for example, a dry etch process such as, for example, reactive ion etching, plasma etching or ion beam etching. Alternatively, a chemical wet etch can be employed.
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(35) As used herein, the term drain means a doped region in semiconductor device located at the end of the channel, in which carriers are flowing out of the transistor through the drain. As used herein, the term source is a doped region in the semiconductor device, in which majority carriers are flowing into the channel. Because the source region and the drain region are both provided by doped regions on opposing sides of the channel of the device, and their function as a source region or a drain region is impacted by the bias applied to these regions in the final device structure, the term source/drain region is suitable for describing these doped regions in the absence of the bias that designates their type.
(36) In this step, the electrode material 20 functions as an implant mask, and the exposed portions of the LTPS layer 10 are implanted to form the source and drain regions 25a, 25b. In some embodiments, the source and drain regions 25a. 25b having a first concentration may be doped to an an-type conductivity, i.e., are doped with an n-type dopant. As used herein. n-type refers to the addition of impurities that contributes free electrons to an intrinsic semiconductor. The n-type conductivity semiconductor devices are typically produced within silicon containing substrates by doping the source and drain regions 25a, 25b with elements from group V-A of the Periodic Table of Elements. In a silicon containing substrate, examples of n-type dopants, i.e., impurities, include but are not limited to, antimony, arsenic and phosphorous.
(37) To achieve a given doping profile, a single or multiple implantation steps may be used. The implanted dopants may be activated using thermal annealing. e.g. at temperatures in the range of 450-650 C. low-energy laser anneal, or a combination thereof.
(38) In one embodiment, the n-type dopant is implanted into the source and drain regions 25a, 25b to provide a total doping concentration for the first concentration doped source/drain region that ranges from 510.sup.17 cm.sup.3 to 110.sup.19 cm.sup.3. In some embodiments, the activated doping concentration of the first concentration doped source/drain region ranges from 10.sup.18 cm.sup.3 to 510.sup.18 cm.sup.3. The activated dopant concentration is the concentration of dopants that contributes to the electrical performance, e.g., sheet resistance, of the doped region.
(39) In some embodiments, the first concentration doped source/drain region 25a, 25b may also be doped to a p-type conductivity. As used herein, p-type refers to the addition of impurities to an intrinsic semiconductor that creates deficiencies of valence electrons. The p-type conductivity semiconductor devices 100b are typically produced within silicon containing substrates by doping the source and drain regions with elements from group III-A of the Periodic Table of Elements. In a silicon containing substrate, examples of p-type dopants. i.e., impurities, include but are not limited to boron, aluminum, gallium and indium.
(40) In some embodiments, a photoresist mask may be used as an implantation mask instead of the electrode material 20. After implantation, the photoresist mask may be removed, followed by dopant activation and formation of the electrode material 20. This process sequence allows use of electrode materials that do not withstand the dopant activation process, in one or more embodiments.
(41) In some embodiments, the source region 25a and the drain region 25b having the first concentration provides a source/drain extension region, which also may be referred to as a lightly doped drain (LDD) region.
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(43) Referring to
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(45) In this example, the source and drain region having the first concentration of dopant provides a lightly doped drain (LDD)(also referred to as a source and drain extension region), and the source and drain regions having the second concentration of dopant provides intermediately doped source and drain regions. These regions are both formed using ion implantation, and have dopant concentrations less than the subsequently described epitaxial source and drain regions 35a. 35b. Therefore, the source and drain region having the first concentration of dopant provides a lightly doped drain (LDD)(also referred to as a source and drain extension region), and the source and drain regions having the second concentration of dopant provides intermediately doped source and drain regions may be collectively referred to as a first concentration region; and the epitaxial source and drain regions 35a, 35b may be collectively referred to as a second concentration region.
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(48) The epitaxially formed source and drain regions 35a, 35b is composed of a crystalline hydrogenated silicon (c-Si:H). Epitaxial growth means the material grown on a substrate follows the crystalline structure of the substrate. For example, the crystalline material of the crystalline hydrogenated silicon (c-Si:H) has a polycrystalline structure if grown epitaxially on LTPS. In another example, the crystalline hydrogenated silicon (c-Si:H) has a single crystal crystalline structure (also referred to as monocrystalline silicon) if grown on a single-crystalline substrate. e.g. a silicon-on-insulator (SOI) wafer.
(49) The Si:H material used for the epitaxial formation of source and drain regions 35a. 35b may be grown from a mixture of a precursor gas containing silane (SiH.sub.4)(or other gases of the Si.sub.xH.sub.y family), a carrier gas containing hydrogen (H.sub.2) and a dopant gas. The ratios of the carrier gas and the precursor gas may be selected such that [H.sub.2]/[SiH.sub.4]>5. For n-type doping, the dopant gas may include phosphine (PH.sub.3). For p-type doping, the dopant gas may include B.sub.2H.sub.6 or trimethylborane (TMB).
(50) The c-Si:H for the epitaxial formed source and drain regions 35a, 35b may have a hydrogen (H) content in the range of 5 atomic percent to 40 atomic percent. The H content in c-Si:H may or may not be uniform. In some embodiments, the H content has an increasing gradient towards the interface of the c-Si:H for the epitaxial formed source and drain regions 35a. 35b and the silicon (Si) of the LTPS layer 10. In some embodiments, the c-Si:H of the epitaxial formed source and drain regions 35a, 35b may further contain one or more of the following elements: deuterium (D), fluorine (F), chlorine (Cl), carbon (C), germanium (Ge), oxygen (O), nitrogen (N) and combinations thereof. In some embodiments where c-Si:H contains germanium (Ge), e.g., c-SiGe:H films, the germanium (Ge) introduced from a gas source, such as germane (GeH.sub.4), such that [H.sub.2]/([SiH.sub.4]+[GeH.sub.4])>5. In some embodiments, Ge is added for p-type films and not for n-type films. The epitaxial formed source and drain regions 35a. 35b may have a total doping concentration. e.g., n-type dopant, in the epitaxial hydrogenated crystalline silicon (c-Si:H) material that ranges from 10.sup.20 cm.sup.3 to 10.sup.21 cm.sup.3. The epitaxial formed source and drain regions 35a. 35b may have an active doping concentration in the epitaxial hydrogenated crystalline silicon (c-Si:H) material that ranges from 10.sup.19 cm.sup.3 to 510.sup.20 cm.sup.3. In one example, the epitaxial hydrogenated crystalline silicon (c-Si:H) is grown from a mixture of hydrogen (H.sub.2) containing carrier gas, a silane (SiH.sub.4) containing precursor gas, and a phosphine (PH.sub.3) containing dopant gas, wherein the gas flow ratio of phosphine to silane [PH.sub.3]/[SiH.sub.4] is greater than 1000 ppm. It is noted that the above description of the epitaxial source and drain region 35a, 35b only provides a summary type description of these regions and their formation.
(51) In one embodiment, the selective epitaxial growth of silicon for the epitaxial source and drain regions 35a. 35b is performed in a hydrogen diluted silane environment using a plasma enhanced chemical vapor deposition process (PECVD). The gas ratio of hydrogen gas to silane gas ([H.sub.2]/[SiH.sub.4]) at 150 C. is preferably between 0 to about 1000. In particularly useful embodiments, epitaxially growth of silicon begins at a gas ratio of about 5-10. The epitaxial Si quality for the epitaxial source and drain regions 35a, 35b improved by increasing the hydrogen dilution, e.g., to 5 or greater. In another embodiment, the ratio of hydrogen to source gas that can be used ranges from 5:1 to 1000:1. For example, epitaxial growth of silicon is possible at temperatures as low as 150 C. with ratios of hydrogen to silane (SiH4) ranging from 5:1 to 20:1.
(52) Epitaxial silicon for the epitaxial source and drain regions 35a, 35b can be grown using various gas sources, e.g., silane (SiH.sub.4), dichlorosilane (DCS), SiF.sub.4, SiCl.sub.4 or the like. The quality of epitaxial silicon improves by increasing the dilution of hydrogen using these or other gases. For higher hydrogen dilution, smoother interfaces were produced (epitaxial silicon to crystalline silicon) and fewer stacking faults and other defects were observed.
(53) Radio-frequency (RF) or direct current (DC) plasma enhanced chemical vapor deposition (CVD) can be performed for forming the epitaxial source and drain regions 35a, 35b at deposition temperature ranges from about room temperature (e.g., 20 C. to 25 C.) to about 500 C. In another embodiment, the deposition temperature for forming the epitaxial source and drain regions 35a, 35b ranges from about 150 C. to about 250 C. Plasma power density may range from about 2 mW/cm.sup.2 to about 2000 mW/cm.sup.2. In other examples, the power density for the PECVD process for epitaxially growing the epitaxially formed source and drain regions 35a, 35b may range from 2 mW/cm.sup.2 to 100 mW/cm.sup.2, and in one example may be in the range of 3 mW/cm.sup.2 to 10 mW/cm.sup.2. The deposition pressure range may be from about 10 mtorr to about 5 torr. In one embodiment of the present disclosure, the pressure for the PECVD process that can be used for epitaxially growing the epitaxial source and drain regions 35a. 35b can range from 10 mTorr to 5 Torr. and in one example may be in the range of 250 mtorr to 900 mTorr.
(54) The thickness of the epitaxial source and drain regions 35a, 35b, as well as the non-epitaxial material 34, may range from 2 nm to 100 nm. In another embodiment, the thickness of the epitaxial source and drain regions 35a, 35b ranges from 5 nm to 15 nm.
(55) The PECVD device can employ a parallel plate chamber configuration. In other embodiments, a hot-wire chemical vapor deposition process can be used in forming the epitaxial source and drain regions 35a, 35b.
(56) The dopant, i.e., n-type or p-type dopant is incorporated into the epitaxial source and drain regions 35a. 35b using in situ doping. By in-situ it is meant that the dopant that dictates the conductivity type of the epitaxial source and drain regions 35a, 35b is introduced during the process step, e.g., epitaxial deposition, that forms the epitaxial source and drain regions 35a, 35b. During epitaxial deposition in situ doping includes introduction of the n-type or p-type dopants through dopant gases during the epitaxial growth process. When a doped semiconductor material layer of an n-type conductivity is to be formed, e.g., n-type epitaxial source and drain regions 35a, 35b, the dopant gas includes at least one n-type dopant, e.g., phosphorus or arsenic. For example, when phosphorus is the n-type dopant, the dopant gas can be phosphine (PH.sub.3), and when arsenic is the n-type dopant, the dopant gas can be arsine (AsH.sub.3). In one example, when the conductivity type dopant is n-type, the dopant gas include phosphine gas (PH.sub.3) present in a ratio to silane (SiH.sub.4) ranging from 0.01% to 10%. In another example, when the conductivity type dopant is n-type, the dopant gas include phosphine gas (PH.sub.3) present in a ratio to silane (SiH.sub.4) ranging from 0.1% to 2%.
(57) When a doped semiconductor material of a p-type conductivity is to be formed, e.g., p-type epitaxial source and drain regions 35a, 35b, a dopant gas including at least one p-type dopant, e.g., B, is employed. For example, when boron is the p-type dopant, the dopant gas can be diborane (B.sub.2H.sub.6). In one embodiment, wherein the conductivity type dopant is p-type, the dopant gas may be diborane (B.sub.2H.sub.6) present in a ratio to silane (SiH.sub.4) ranging from 0.01% to 10%. In another embodiment, wherein the conductivity type dopant is p-type, the dopant gas may be diborane (B.sub.2H.sub.6) present in a ratio to silane (SiH.sub.4) ranging from 0.1% to 2%. In yet another embodiment, in which the conductivity type dopant is p-type, the dopant gas for may be trimethylboron (TMB) present in a ratio to silane (SiH.sub.4) ranging from 0.1% to 10%.
(58) It is noted that the above examples are provided for illustrative purposes only, and are not intended to limit the described methods and structures to only these examples.
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(61) In one example, etching is performed in-situ using a H.sub.2 plasma. In some embodiments, the hydrogen plasma etch that can be used to remove the non-crystalline (amorphous) silicon material 34 selective to the crystalline portions of the hydrogenated silicon (c-Si:H) that provides the epitaxial source and drain regions 35a, 35b can be performed in the same reactor chamber as used to form the doped semiconductor material layer without breaking the vacuum of the chamber; such an etch may be referred to herein as an in-situ hydrogen plasma etch. In other embodiments, the hydrogen plasma etch can be performed in a different reactor chamber as that used to form the doped semiconductor material layer.
(62) The hydrogen plasma etch that can be performed at a temperature of from room temperature (20 C.) to 500 C. and at a hydrogen pressure from 10 mtorr to 5 torr. In some embodiments, the hydrogen plasma etch is performed at a temperature of from 100 C. to 250 C. and at a hydrogen pressure from 10 mtorr to 1 torr. The hydrogen plasma etch can be performed utilizing one of hydrogen or HCl as a source of the hydrogen plasma. In some embodiments, the etch selectivity for removing the non-crystalline/amorphous semiconductor material layer portions 34 relative to the material for the crystalline epitaxial source and drain regions 35a. 35b is from 2:1 to 10:1. In some embodiments, the removal of the non-crystalline/amorphous semiconductor material layer portions 34 relative to the material for the crystalline epitaxial source and drain regions 35a, 35b can be performed using other types of plasmas besides hydrogen plasma including, for example. Cl.sub.2 or Ar.
(63) In this embodiment of the present disclosure and as shown in
(64) Further details regarding the epitaxial growth process and the selective etch process for forming the epitaxial source and drain regions 35a, 35b of the present disclosure are described in U.S. Patent Publication No. 2012/0210932, which is owned by the assignee of the present disclosure, and is incorporated herein by reference.
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(66) Reference is now made to
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(68) The structures identified by reference numbers 5, 10, and 15 that are depicted in
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(71) In one embodiment, the spacer 51 can be formed using a conformal deposition process in combination with an anisotropic (directional) etch process. The material for the spacer 51 can be formed by any conformal deposition process, such as chemical vapor deposition (CVD), e.g., plasma enhanced chemical vapor deposition (PECVD) and atomic layer deposition (ALD). The etch process used in the formation of the spacer 51 can be an anisotropic etch, such as reactive ion etching (RIE). In some embodiments, a portion of the spacer, e.g. an etch-stop bottom portion of the spacer which has a different composition than the top portion of the spacer, may be removed by an isotropic etch, such as a wet chemical etch.
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(75)
(76) It is noted that the dimensions in
(77) It is to be appreciated that the use of any of the following /, and/or, and at least one of, for example, in the cases of A/B, A and/or B and at least one of A and B, is intended to encompass the selection of the first listed option (A) only, or the selection of the second listed option (B) only, or the selection of both options (A and B). As a further example, in the cases of A, B, and/or C and at least one of A, B, and C, such phrasing is intended to encompass the selection of the first listed option (A) only, or the selection of the second listed option (B) only, or the selection of the third listed option (C) only, or the selection of the first and the second listed options (A and B) only, or the selection of the first and third listed options (A and C) only, or the selection of the second and third listed options (B and C) only, or the selection of all three options (A and B and C). This may be extended, as readily apparent by one of ordinary skill in this and related arts, for as many items listed.
(78) Having described preferred embodiments of thin film transistors (TFTs) with epitaxial source/drain contact regions (which are intended to be illustrative and not limiting), it is noted that modifications and variations can be made by persons skilled in the art in light of the above teachings. It is therefore to be understood that changes may be made in the particular embodiments disclosed which are within the scope of the invention as outlined by the appended claims. Having thus described aspects of the invention, with the details and particularity required by the patent laws, what is claimed and desired protected by Letters Patent is set forth in the appended claims.