DEVICE AND METHOD FOR PREPARING IN-SITU MOLDED BIOCHAR WITH HIGH SPECIFIC SURFACE AREA

Abstract

A device and method for preparing in-situ molded biochar with high specific surface area. Crushed and mixed biomass and modifier are fed into a hot pressing and pyrolysis device, and hot-pressing molding and pyrolysis carbonization are completed synchronously, which solves the problem of multiple steps and complicated equipment in the existing preparation process for molded biochar material. In-situ bonding molding is realized by adhesion, bridging, cross-linking and mechanical interlocking functions of low-temperature molten & softened lignin and pyrolytic tar. No additional cross-linking agent is needed in this process, so the production cost is low. Covering and suffocating actions of trace flame retardant modifier are utilized to reduce the temperature of biomass pyrolysis carbonization, inhibit excessive ablation and accelerate polycondensation reaction, thus to improve the specific surface area and yield of a product, and improve the cost performance of the product.

Claims

1. A method for preparing in-situ molded biochar with high specific surface area, wherein a device using for preparing in-situ molded biochar with high specific surface area, the device comprising a crushing and mixing device, a hot pressing and pyrolysis device, a cleaning device, a drying device, a gas-liquid separation device, a heat exchange device, a combustible gas recovery device, a concentration reactor and a water treatment device, wherein the crushing and mixing device, the hot pressing and pyrolysis device, the cleaning device and the drying device are connected in sequence; the hot pressing and pyrolysis device is connected with the gas-liquid separation device, the gas-liquid separation device is connected with the heat exchange device, and the heat exchange device is connected with the combustible gas recovery device; the cleaning device, the concentration reactor and the water treatment device are connected in sequence; the concentration reactor is connected with the heat exchange device, and is also connected with the crushing and mixing device; the crushing and mixing device is connected with the gas-liquid separation device; a mixture of pyrolytic tar and gas at an outlet of the hot pressing and pyrolysis device is introduced into the gas-liquid separation device, and a solid is introduced into the cleaning device; liquid tar separated by the gas-liquid separation device is introduced into the crushing and mixing device, and high-temperature combustible gas is introduced into the heat exchange device; pyrolytic gas at an outlet of the heat exchange device is introduced into the combustible gas recovery device; hot air of the heat exchange device is introduced into the concentration reactor; washing liquid of the cleaning device is introduced into the concentration reactor, evaporative condensate water at an outlet of the concentration reactor is introduced into a water treatment reactor, and concentrated modifier at the outlet of the concentration reactor is introduced into the crushing and mixing device; wherein the method comprising the following steps: step (I) crushing and mixing stage: adding biomass to the crushing and mixing device, starting the crushing and mixing device, using the cutting tool set to crush the biomass into a powder of 100-200 meshes, adding modifier, starting the atomization module, adding water, then using the agitator to fully mix the biomass and the modifier, and conveying the mixture to the hot pressing and pyrolysis device through the conveying system; wherein the modifier is one or a mixture of more than one of phosphate ester, pyrophosphate, ammonium polyphosphate, phosphoramide and triammonium phosphate; and the mass ratio of the modifier to the biomass is 0.05-5; step (II) hot pressing and pyrolysis carbonization stage: after the mixture of the step (I) entering the hot pressing and pyrolysis device, starting the temperature control system and the pressure control system of the hot pressing and pyrolysis device, adjusting the pressure and temperature for hot pressing and pyrolysis carbonization, adopting continuous, stepwise or interactive pressurizing heating modes in this stage, and obtaining a three-phase product of pyrolytic tar, pyrolytic gas and pyrolytic carbon after heat preservation and pressure maintaining; introducing the mixture of pyrolytic tar and gas into the gas-liquid separation device to separate the liquid tar and the high-temperature combustible gas, circulating the liquid tar to the crushing and mixing device to be mixed with a next batch of biomass, making the high-temperature combustible gas enter the heat exchange device in the form of high-temperature pyrolytic gas, conducting indirect heat exchange between the high-temperature pyrolytic gas and the air in the heat exchange device, introducing hot air after heat exchange into the concentration reactor to provide energy for evaporation of the washing liquid, and introducing the pyrolytic gas after heat exchange into the combustible gas recovery device to be collected; step (III) separation and washing stage: cleaning and drying the solid produced by the hot pressing and pyrolysis device in the step (II) by the cleaning device and the drying device to obtain a formed biochar product, passing the washing liquid discharged by the cleaning device through the concentration reactor, providing energy for evaporation and concentration of the washing liquid by the high-temperature hot air, reusing the concentrated modifier in the crushing and mixing device, and making the residual evaporative condensate water enter the water treatment device to be treated and discharged after meeting standards.

2. The method for preparing in-situ molded biochar with high specific surface area according to claim 1, wherein the crushing and mixing device is mainly composed of a cutting tool set, a screening module, an agitator, an atomization module and a conveying system.

3. The method for preparing in-situ molded biochar with high specific surface area according to claim 1, wherein the hot pressing and pyrolysis device is mainly composed of a temperature control system, a pressure control system, a forming mold, a pressurizing module and a heating module.

4. (canceled)

5. The method for preparing in-situ molded biochar with high specific surface area according to claim 1, wherein the biomass is one or a mixture of more than one of an industrial by-product, agricultural waste and urban waste which contains lignin, cellulose and hemicellulose.

6. (canceled)

7. The method for preparing in-situ molded biochar with high specific surface area according to claim 1, wherein the heating mode is resistance heating, electromagnetic coil heating or microwave heating; and the pressurizing mode is mechanical drive or hydraulic drive.

8. (canceled)

9. (canceled)

10. (canceled)

Description

DESCRIPTION OF DRAWINGS

[0025] The Figure is a schematic diagram of a process for preparing in-situ molded biochar with high specific surface area.

DETAILED DESCRIPTION

[0026] A specific embodiment of the present invention is further described below in combination with the drawings and the technical solution.

Embodiment

[0027] Conveying 100 g of Enteromorpha to the crushing and mixing device, starting the crushing and mixing device, crushing the Enteromorpha into a powder of 200 meshes, adding 200 g of ammonium polyphosphate, starting the atomization module, adding 50 g of atomized water vapor, then using the agitator to fully mix rice husk powder and ammonium polyphosphate, and conveying the mixture to the hot pressing and pyrolysis device. Adjusting the temperature control system and pressure control system, adopting a stepwise heating and pressurizing mode, and setting heating rate to be 10° C./min, final temperature to be 400° C., pressure intensity to be 2 MPa/cm.sup.2/min, final pressure to be 80 MPa/cm.sup.2, and residence time of final temperature and final pressure to be 60 min. After pyrolysis, relieving pressure slowly, cleaning and drying the solid product to obtain a molded biochar product. Passing the washing liquid through the concentration reactor, reusing the concentrated modifier in the crushing and mixing device to be mixed with a next batch of Enteromorpha powder, and making the evaporative condensate water enter the water treatment device to be treated and discharged after meeting standards. Introducing the mixture of pyrolytic tar and gas into the gas-liquid separation device to separate liquid viscous product and gas product, circulating the liquid viscous product to the crushing and mixing device to be mixed with a next batch of Enteromorpha powder, making the gas product enter the heat exchange device in the form of high-temperature pyrolytic gas, conducting indirect heat exchange between the high-temperature pyrolytic gas and the air in the heat exchange device, introducing hot air after heat exchange into the concentration reactor to provide energy for evaporation of the washing liquid, and collecting the pyrolytic gas after heat exchange for later use.

[0028] It should be understood that the purpose of the disclosure of the embodiment is to explain, rather than limiting the present invention, and all technical solutions derived from simple replacement, combination and evolution based on the present invention shall be fallen into the protection scope of the present invention.