EUTECTIC BONDING WITH ALGe
20200048078 ยท 2020-02-13
Inventors
Cpc classification
H01L24/07
ELECTRICITY
H01L24/01
ELECTRICITY
B81C2203/0127
PERFORMING OPERATIONS; TRANSPORTING
H01L24/02
ELECTRICITY
B32B15/20
PERFORMING OPERATIONS; TRANSPORTING
H01L24/94
ELECTRICITY
B81C1/00269
PERFORMING OPERATIONS; TRANSPORTING
B81C1/00261
PERFORMING OPERATIONS; TRANSPORTING
International classification
B81C1/00
PERFORMING OPERATIONS; TRANSPORTING
B32B15/04
PERFORMING OPERATIONS; TRANSPORTING
B81B7/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A MEMS device formed in a first semiconductor substrate is sealed using a second semiconductor substrate. To achieve this, an Aluminum Germanium structure is formed above the first substrate, and a polysilicon layer is formed above the second substrate. The first substrate is covered with the second substrate so as to cause the polysilicon layer to contact the Aluminum Germanium structure. Thereafter, eutectic bonding is performed between the first and second substrates so as to cause the Aluminum Germanium structure to melt and form an AlGeSi sealant thereby to seal the MEMS device. Optionally, the Germanium Aluminum structure includes, in part, a layer of Germanium overlaying a layer of Aluminum.
Claims
1. A method of sealing a MEMS device formed in a first semiconductor substrate using a second semiconductor substrate, the method comprising: forming an Aluminum Germanium structure above the first substrate; forming a polysilicon layer above the second substrate; covering the first substrate with the second substrate so as to cause the polysilicon layer to contact the Aluminum Germanium structure; and performing eutectic bonding between the first and second substrates so as to cause the Aluminum Germanium structure to melt and form a AlGeSi sealant thereby to seal the MEMS device.
2. The method of claim 1 wherein said Germanium Aluminum structure comprises a layer of Germanium overlaying a layer of Aluminum.
3. The method of claim 1 further comprising: forming an adhesive layer below the Aluminum Germanium structure in the first substrate.
4. The method of claim 3 further comprising: forming an Alumina layer between the Aluminum Germanium structure and the adhesive layer.
5. The method of claim 3 wherein said adhesive layer is a Titanium Nitride layer.
6. The method of claim 1 further comprising: forming an Alumina layer below the Polysilicon layer in the second substrate.
7. The method of claim 1 further comprising: forming a Polycide layer below the Polysilicon layer in the second substrate.
8. The method of claim 6 further comprising: forming an adhesive layer below the Alumina layer in the second substrate.
9. A method of sealing a MEMS device formed in a first semiconductor substrate using a second semiconductor substrate, the method comprising: forming a Silicide layer either in or above the first substrate; forming an Aluminum Germanium structure above the Silicide layer of the first substrate; forming a Silicide layer either in or above a substrate of the second substrate; covering the first substrate with the second substrate so as to cause the Aluminum Germanium structure of the first substrate to contact the Silicide layer of the second substrate; and performing eutectic bonding between the first and second substrates so as to cause the Aluminum Germanium structure to melt and form a AlGeSi sealant thereby to seal the MEMS device.
10. The method of claim 1 wherein said Aluminum Germanium structure comprises a layer of Germanium overlaying a layer of Aluminum, wherein said Aluminum layer comprises Copper atoms.
11. The method of claim 1 wherein said Aluminum Germanium structure comprises a layer of Aluminum and Germanium that are co-deposited.
12. A method of sealing a MEMS device formed in a first semiconductor substrate using a second semiconductor substrate, the method comprising: forming a Silicide layer either in or above the first substrate; forming a Silicide layer either in or above the second substrate; forming an Aluminum Germanium structure above the Silicide layer of the second substrate; covering the first substrate with the second substrate so as to cause the Aluminum Germanium structure of the second substrate to contact the Silicide layer of the first substrate; and performing eutectic bonding between the first and second substrates so as to cause the Aluminum Germanium structure to melt and form a AlGeSi sealant thereby to seal the MEMS device.
13. A method of sealing a MEMS device formed in a first semiconductor substrate using a second semiconductor substrate, the method comprising: forming a Silicide layer either in or above a substrate of the first substrate; forming an Aluminum Germanium structure above the Silicide layer of the first substrate; forming a Silicide layer either in or above a substrate of the second substrate; forming an Aluminum Germanium structure above the Silicide layer of the second substrate; covering the first substrate with the second substrate so as to cause the Aluminum Germanium structure of the first substrate to contact the Aluminum Germanium structure of the first substrate; and performing eutectic bonding between the first and second substrates so as to cause the Aluminum Germanium structure to melt and form a AlGeSi sealant thereby to seal the MEMS device.
14. A method of sealing a MEMS device formed in a first semiconductor substrate using a second semiconductor substrate, the method comprising: forming a Silicide layer either in or above a substrate of the first substrate; forming an Aluminum Germanium structure above the Silicide layer of the first substrate; forming a Silicide layer either in or above a substrate of the second substrate; forming an Aluminum structure above the Silicide layer of the second substrate; covering the first substrate with the second substrate so as to cause the Aluminum Germanium structure of the first substrate to contact the Aluminum structure of the second substrate; and performing eutectic bonding between the first and second substrates so as to cause the Aluminum Germanium structure to melt and form a AlGeSi sealant thereby to seal the MEMS device.
15. A method of sealing a MEMS device formed in a first semiconductor substrate using a second semiconductor substrate, the method comprising: forming a Silicide layer either in or above a substrate of the first substrate; forming a Germanium structure above the Silicide layer of the first substrate; forming a Silicide layer either in or above a substrate of the second substrate; forming an Aluminum Germanium structure above the Silicide layer of the second substrate; covering the first substrate with the second substrate so as to cause the Aluminum Germanium structure of the second substrate to contact the Germanium structure of the first substrate; and performing eutectic bonding between the first and second substrates so as to cause the Aluminum Germanium structure to melt and form a AlGeSi sealant thereby to seal the MEMS device.
16. A MEMS structure comprising a first semiconductor substrate and a second semiconductor substrate, said first semiconductor substrate comprising an Aluminum Germanium structure and said second semiconductor substrate comprising a polysilicon layer, said MEMS structure further comprising a MEMS device formed in a cavity of the first semiconductor substrate, the MEMS device being sealed in an AlGeSi sealant, said AlGeSi sealant formed in response to eutectic bonding between the Aluminum Germanium structure formed in the first substrate and the polysilicon layer formed in the second substrate.
17. The MEMS structure of claim 16 wherein said Germanium Aluminum structure comprises a layer of Germanium overlaying a layer of Aluminum.
18. The MEMS structure of claim 16 wherein said MEMS structure further comprises an adhesive layer below the Aluminum Germanium structure.
19. The MEMS structure of claim 18 wherein said MEMS structure further comprises an Alumina layer disposed between the Aluminum Germanium structure and the adhesive layer.
20. The MEMS structure of claim 19 wherein said adhesive layer is a Titanium Nitride layer.
21. The MEMS structure of claim 16 wherein said MEMS structure further comprises an Alumina layer below the Polysilicon layer in the second substrate.
22. The MEMS structure of claim 16 wherein said MEMS structure further comprises a Polycide layer below the Polysilicon layer in the second substrate.
23. The MEMS structure of claim 16 wherein said MEMS structure further comprises an adhesive layer below the Alumina layer in the second substrate.
24. A MEMS structure comprising a first semiconductor substrate and a second semiconductor substrate, said first semiconductor substrate comprising an Aluminum Germanium structure and said second semiconductor substrate comprising a Silicide layer, said MEMS structure further comprising a MEMS device formed in a cavity of the first semiconductor substrate, the MEMS device being sealed in an AlGeSi sealant, said AlGeSi sealant formed in response to a eutectic bonding between the Aluminum Germanium structure formed in the first substrate and the Silicide layer formed either in or above the second semiconductor substrate.
25. A MEMS structure comprising a first semiconductor substrate and a second semiconductor substrate, said first semiconductor substrate comprising a Silicide layer and said second semiconductor substrate comprising an Aluminum Germanium structure, said MEMS structure further comprising a MEMS device formed in a cavity of the first semiconductor substrate, the MEMS device being sealed in an AlGeSi sealant, said AlGeSi sealant formed in response to a eutectic bonding between the Aluminum Germanium structure formed in the second semiconductor substrate and the Silicide layer formed either in or above the first semiconductor substrate.
26. A MEMS structure comprising a first semiconductor substrate and a second semiconductor substrate, said first semiconductor substrate comprising a first Aluminum Germanium structure and a Silicide layer, said second semiconductor substrate comprising a second Aluminum Germanium structure, said MEMS structure further comprising a MEMS device formed in a cavity of the first semiconductor substrate, the MEMS device being sealed in an AlGeSi sealant, said AlGeSi sealant formed in response to a eutectic bonding between the first Aluminum Germanium structure formed in the first semiconductor substrate, the second Aluminum Germanium structure formed in the second semiconductor substrate and the Silicide layer formed either in or above the first semiconductor substrate.
27. A MEMS structure comprising a first semiconductor substrate and a second semiconductor substrate, said first semiconductor substrate comprising a first Aluminum Germanium structure, said second semiconductor substrate comprising a second Aluminum Germanium structure and a Silicide layer, said MEMS structure further comprising a MEMS device formed in a cavity of first semiconductor substrate, the MEMS device being sealed in an AlGeSi sealant, said AlGeSi sealant formed in response to a eutectic bonding between the first Aluminum Germanium structure formed in the first semiconductor substrate, the second Aluminum Germanium structure formed in the second semiconductor substrate and the Silicide layer formed either in or above the second semiconductor substrate.
28. A MEMS structure comprising a first semiconductor substrate and a second semiconductor substrate, said first semiconductor substrate comprising an Aluminum Germanium structure and a Silicide layer, said second semiconductor substrate comprising an Aluminum structure, said MEMS structure further comprising a MEMS device formed in a cavity of a first semiconductor substrate, the MEMS device being sealed in an AlGeSi sealant, said AlGeSi sealant formed in response to a eutectic bonding between the first Aluminum Germanium structure formed in the first semiconductor substrate, the Aluminum structure formed in the second semiconductor substrate, and the Silicide layer formed either in or above the first semiconductor substrate.
29. A MEMS structure comprising a first semiconductor substrate and a second semiconductor substrate, said first semiconductor substrate comprising an Aluminum Germanium structure, said second semiconductor substrate comprising an Aluminum structure and a Silicide layer, said MEMS structure further comprising a MEMS device formed in a cavity of the first semiconductor substrate, the MEMS device being sealed in an AlGeSi sealant, said AlGeSi sealant formed by a eutectic bonding between the first Aluminum Germanium structure formed in the first semiconductor substrate, the Aluminum structure formed in the second semiconductor substrate, and the Silicide layer formed either in or above the second semiconductor substrate.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE INVENTION
[0045] In accordance with one embodiment of the present invention, A MEMS device (alternatively referred to herein as sensor) is hermetically sealed in a cavity by applying Aluminum-Germanium-Silicon (AlGeSi) eutectic wafer bonding between a first silicon wafer in which the MEMS device is formed (hereinafter referred to as device wafer) and a second silicon wafer (hereinafter referred to as lid wafer) covering the top surface of the device wafer. To achieve this, the eutectic wafer bonding is adapted to enable a structure that includes Aluminum and/or Germanium, formed on either the device wafer, the lid wafer, or both, to bond with Silicon atoms present in a structure/region of either the device wafer, the lid wafer, or both, to form a strong AlGeSi sealant sealing/encasing the MEMS device. The processing steps for forming the device wafer and the lid wafer, in accordance with a number of exemplary embodiments of the present invention, are described below.
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[0047] Device wafer 100 is also shown as including an Aluminum layer 250 overlaying Alumina layer 240, and a Germanium layer 260 overlaying Aluminum layer 250. The thicknesses of Aluminum layer 250 and Germanium layer 260 are selected so as to enable eutectic bonding to take place when the required temperature and pressure are applied. For example, Aluminum layer 250 and Germanium layer 260 may be selected to have thicknesses of 980 nm and 530 nm, respectively.
[0048] Thereafter, using conventional patterning and etching processing steps, layers 230, 240, 250, and 260 are removed to form an opening 285 having sidewalls 292, as shown in
[0049] The device structure shown in
[0050] Next, as shown in
[0051] Thereafter, using conventional patterning and etching processes, Aluminum (Al) layer 250, and Germanium (Ge) layer 260 are etched to form an AlGe structure 280 around the periphery of cavity 110.
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[0053] To prepare lid wafer 500 as a cover for device wafer 100, using conventional patterning and etching processes, layers 510, 520 and 530 are etched to form a structure 580, as shown in
[0054] To hermetically seal MEMS device 120, as seen from
[0055] Thereafter, during a eutectic bonding when the required heat and pressure are applied, Aluminum and Germanium disposed in structure 280 change their phases from solid to liquid to form an AlGe eutectic melt which subsequently reacts with the Silicon atoms present in the Polysilicon layer 530 to form a ternary AlGeSi. The AlGeSi so formed wets the undelaying Polycide or Alumina layer.
[0056] Incorporating Silicon atoms into the AlGe eutectic melt, in accordance with embodiments of the present invention, increases the eutectic point temperature thus solidifying the melt while controlling and limiting its flow. Alumina layer 240 provides a barrier against gas permeation and the highly reactive eutectic melt. The Alumina also provides a suitable adhesion layer for the eutectic melt. In embodiments in which layer 240 includes Polycide, the Polycide further acts as a barrier against the conduction diffusion and the highly reactive eutectic melt. The Silicide layer reduces the reaction speed of the AlGe eutectic melt with the silicon contained in the silicide layer. In other words, the rate of silicon incorporation into the liquid AlGe eutectic melt is made slower to provide a more controlled transformation from an AlGe eutectic melt into a tertiary AlGeSi. Any excessive uptake of Si and the resulting spike of Al or Ge into Silicon can be avoided or substantially reduced. A silicon layer (amorphous, polysilicon or any other type) on top of the silicide layer can be used as an initial, easily accessible silicon source for the AlGe eutectic melt to start the silicon incorporation into the AlGe eutectic melt at a high rate, slowing down after the layer is completely dissolved. The silicide acts as a diffusion barrier to reduce the undesirablet diffusion of Al and Ge atoms away from the liquid eutectic melt into the layers below. The silicide layer further acts as an adhesion layer for the AlGe eutectic melt A device substrate together with a lid substrate sealing a MEMS device, in accordance with the embodiments of the present invention, is alternatively referred to herein as a MEMS structure.
[0057] The device structure shown in
[0058] In accordance with one embodiment of the present invention, a Silicide layer formed and patterned on the device wafer, the lid wafer, or both, provides the Silicon atoms for the AlGe eutectic melt, as described further below.
[0059] To prepare device wafer 100 for sealing, an Aluminum layer 250 followed by a Germanium layer 260 are deposited on Silicide step structure 610. The Aluminum and Germanium layers 250, 260 are subsequently patterned and etched to form a structure 280.
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[0061] As seen from
[0062] To seal MEMS device 100, during a eutectic bonding when the required heat and pressure are applied, Aluminum and Germanium in structure 280 change their phases from solid to liquid to form an AlGe eutectic melt which subsequently reacts with the Silicon atoms present in Silicide structures 610 and/or 710 to form a ternary AlGeSi. Incorporating Silicon atoms into the AlGe eutectic melt, in accordance with embodiments of the present invention, increases the eutectic point temperature thus solidifying the melt and controlling/limiting its flow.
[0063] Although device wafer 100 of
[0064] In accordance with another embodiment of the present invention, a Silicide region formed and patterned within the substrate of the device wafer, the lid wafer, or both, provides the Silicon atoms for the AlGe eutectic melt, as described further below.
[0065] To prepare device wafer 100 for sealing, layers of Aluminum and Germanium are deposited on Silicide region 610. The Aluminum and Germanium layers are subsequently patterned and etched to form a structure.
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[0067] As seen from
[0068] To seal MEMS device 100, during a eutectic bonding when the required heat and pressure are applied, Aluminum and Germanium present in structure 280 change their phases from solid to liquid to form an AlGe eutectic melt which subsequently reacts with the Silicon atoms present in the Silicide region 610 and/or 710 to form a ternary AlGeSi. Incorporating Silicon atoms into the AlGe eutectic melt, in accordance with embodiments of the present invention, increases the eutectic point temperature thus solidifying the melt and controlling/limiting its flow.
[0069] Although device wafer 100 of
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[0071] To seal MEMS device 100, during a eutectic bonding when the required heat and pressure are applied, Aluminum and Germanium present in structure 280 change their phases from solid to liquid to form an AlGe eutectic melt which subsequently reacts with the Silicon atoms present in the Silicide region 610 and/or 710 to form a ternary AlGeSi. Incorporating Silicon atoms into the AlGe eutectic melt, in accordance with embodiments of the present invention, increases the eutectic point temperature thus solidifying the melt and controlling/limiting its flow.
[0072] Although lid wafer 700 of
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[0074] To seal MEMS device 100, during a eutectic bonding when the required heat and pressure are applied, Aluminum and Germanium change from solid to liquid so as to form an AlGe eutectic melt. The AlGe eutectic melt reacts with the Silicon atoms present in the Silicide region 610 and/or Silicide region 710 to form a ternary AlGeSi. Incorporating the Si atoms into the AlGe eutectic melt, in accordance with embodiments of the present invention, increases the eutectic point temperature thus solidifying the melt while controlling and limiting its flow.
[0075] Although not shown in
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[0077] To seal MEMS device 100, during a eutectic bonding when the required heat and pressure are applied, Aluminum and Germanium change their phases from solid to liquid to form an AlGe eutectic melt which subsequently reacts with the Silicon atoms present in the Silicide region 610 and/or 710 to form a ternary AlGeSi. Incorporating the Si atoms into the AlGe eutectic melt, in accordance with embodiments of the present invention, increases the eutectic point temperature thus solidifying the melt while controlling and limiting its flow.
[0078] Although not shown in
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[0080] To seal MEMS device 100, during a eutectic bonding when the required heat and pressure are applied, Aluminum and Germanium change their phases from solid to liquid to form an AlGe eutectic melt which subsequently reacts with the Silicon atoms present in the Silicide region 610 and/or 710 to form a ternary AlGeSi. Incorporating the Si atoms into the AlGe eutectic melt, in accordance with embodiments of the present invention, increases the eutectic point temperature thus solidifying the melt while controlling and limiting its flow.
[0081] Although not shown in
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[0084] The above embodiments of the present invention are illustrative and not limitative. Embodiments of the present invention are not limited by the type of MEMS device. Embodiments of the present invention are not limited by the type of deposition, patterning, etching, and other semiconductor processing steps required to form the various layers and structures described herein. Embodiments of the present invention are not limited to any specific thicknesses of the layers described herein. Embodiments of the present invention are not limited to the materials/layers described above. Accordingly, it is understood that other semiconductor materials may be present between the various layers described above. Other additions, subtractions or modifications are obvious in view of the present disclosure and are intended to fall within the scope of the appended claims.