METHOD AND SYSTEM FOR ZERO DISCHARGE TREATMENT OF DESULFURIZATION WASTEWATER SUITABLE FOR MULTIPLE WORKING CONDITIONS

Abstract

A desulfurization wastewater zero discharge treatment method and system suitable for multiple working conditions. A tail flue of a boiler and a bottom outlet of a wastewater drying tower are both communicated with an inlet of a dust collector; an outlet of the dust collector is communicated with flue gas inlets of a wastewater concentration tower and a desulfurization absorption tower; the wastewater concentration tower is communicated with the desulfurization absorption tower; the desulfurization absorption tower is communicated with a chimney; the desulfurization absorption tower is communicated with a gypsum cyclone; the gypsum cyclone is communicated with a filtrate water tank; the gypsum cyclone is communicated with a gypsum dewatering machine; the gypsum dewatering machine is communicated with a gas liquid separating tank; and a flue gas port of the tail flue of the boiler is communicated with the flue gas inlet of the wastewater drying tower.

Claims

1. A method for zero discharge treatment of desulfurization wastewater suitable for multiple working conditions, comprising the following steps: high-temperature flue gas generated by a boiler (1) passing through an economizer (2) and an air preheater (3) for heat recovery, then entering a dust collector (4) for dust removal, then entering a desulfurization absorption tower (6) to remove acidic pollutants, and finally being discharged through a chimney (7); gypsum slurry generated by the desulfurization absorption tower (6) entering a gypsum cyclone (9) for separation, wherein the separated overflow slurry enters a filtrate water tank (13), and the separated underflow slurry enters a gypsum dehydrator (10) for dehydration; the water in the slurry in the gypsum dehydrator (10) entering a gas-liquid separation tank (11) for gas-liquid separation after being filtered by a filter cloth of the dehydrator, and wherein the separated drainage water enters a wastewater collection tank (15); when a concentration of HCl in the flue gas is less than a preset HCl concentration value, a required amount of desulfurization wastewater is small, and when an amount of the drainage water currently output by the gas-liquid separation tank (11) is greater than the amount of the desulfurization wastewater required to be discharged, the drainage water collected by the wastewater collection tank (15) is divided into two paths one of which passes through the filtrate water tank (13) and enters the desulfurization absorption tower (6), and the other is fed into a wastewater drying tower (27) through a spray water tank (25); at the same time, the high-temperature flue gas is pumped through a flue gas port and fed into the wastewater drying tower (27), and the drainage water in the wastewater drying tower (27) is evaporated by the high-temperature flue gas so that the water in the drainage water evaporates into the flue gas, and the flue gas output from the wastewater drying tower (27) enters the dust collector (4) for dust removal; when the concentration of HCl in the flue gas is greater than or equal to the preset HCl concentration value, and a concentration ratio of SO.sub.2 to HCl in the flue gas is greater than or equal to a preset ratio, the amount of the desulfurization wastewater required to be discharged and the amount of the produced gypsum slurry are relatively large, and when the amount of the drainage water currently output by the gas-liquid separation tank (11) is greater than or equal to the amount of the desulfurization wastewater required to be discharged, part of the drainage water in the wastewater collection tank (15) is fed into the wastewater concentration tower (18), and the remaining wastewater in the wastewater collection tank (15) is fed into the filtrate water tank (13) and then into the desulfurization absorption tower (6); at the same time, a path of the flue gas output from the dust collector (4) is led out and fed into the wastewater concentration tower (18) for countercurrent contact with the desulfurization wastewater in the wastewater concentration tower (18), so that the desulfurization wastewater in the wastewater concentration tower (18) is reduced and solid content thereof is increased; the flue gas in the wastewater concentration tower (18) entering the desulfurization absorption tower (6) after being treated by a mist eliminator (19), and the slurry at the bottom of the wastewater concentration tower (18) entering a thick slurry tank (22), the slurry in the thick slurry tank (22) entering the spray water tank (25) after being clarified by a clarifier (24) and then entering the wastewater drying tower (27) for evaporation and drying treatment; and when the concentration of HCl in the flue gas is greater than or equal to the preset HCl concentration value, and the concentration ratio of SO.sub.2 to HCl in the flue gas is less than the preset ratio, the amount of the desulfurization wastewater to be discharged is large, and when the amount of the drainage water output from the gas-liquid separation tank (11) is less than the amount of the desulfurization wastewater to be discharged, all the drainage water in the wastewater collection tank (15) is transported to the wastewater concentration tower (18), and then part of the slurry in the filtrate water tank (13) is fed into the thick slurry tank (20); the two parts of the slurry are evaporated, reduced and concentrated in the wastewater concentration tower (18), and then enter the clarifier (24); the supernatant in the clarifier (24) enters the spray water tank (25), and then is fed into the wastewater drying tower (27) for evaporation.

2. The method for zero discharge treatment of desulfurization wastewater suitable for multiple working conditions according to claim 1, wherein the preset HCl concentration value is preferably 7-13 ppm.

3. The method for zero discharge treatment of desulfurization wastewater suitable for multiple working conditions according to claim 1, wherein the preset ratio of the concentration ratio of SO.sub.2 to HCl in the flue gas is 20-30.

4. The method for zero discharge treatment of desulfurization wastewater suitable for multiple working conditions according to claim 1, wherein the high-temperature flue gas pumped into the wastewater drying tower (27) is taken after the boiler economizer (2) and before the air preheater (3).

5. The method for zero discharge treatment of desulfurization wastewater suitable for multiple working conditions according to claim 1, wherein salts formed by the evaporation of the wastewater in the wastewater drying tower (27) enter the dust collector (4) with the flue gas and are collected.

6. The method for zero discharge treatment of desulfurization wastewater suitable for multiple working conditions according to claim 1, wherein the drainage water in the wastewater collection tank (15) enters the wastewater concentration tower (18) as washing water of the mist eliminator (19).

7. The method for zero discharge treatment of desulfurization wastewater suitable for multiple working conditions according to claim 1, wherein the wastewater is clarified and tempered in the clarifier (24).

8. A system for zero discharge treatment of desulfurization wastewater suitable for multiple working conditions, comprising a boiler (1), a dust collector (4), a desulfurization absorption tower (6), a chimney (7), a gypsum cyclone (9), a filtrate water tank (13), a gypsum dehydrator (10), a gas-liquid separation tank (11), a wastewater collection tank (15), a wastewater concentration tower (18), a thick slurry tank (22), a clarifier (24), a spray water tank (25) and a wastewater drying tower (27); wherein an economizer (2) and an air preheater (3) are arranged in a tail flue of the boiler (1) along a flow direction of flue gas, the tail flue of the boiler (1) and a bottom outlet of the wastewater drying tower (27) are both communicated with an inlet of a dust collector (4), an outlet of the dust collector (4) is communicated with a flue gas inlet of the wastewater concentration tower (18) and a flue gas inlet of the desulfurization absorption tower (6); a flue gas outlet of the desulfurization absorption tower (6) is communicated with the chimney (7), a bottom slurry discharge outlet of the desulfurization absorption tower (6) is communicated with an inlet of the gypsum cyclone (9) through a gypsum discharge pump (8), an overflow slurry outlet of the gypsum cyclone (9) is communicated with an inlet of the filtrate water tank (13), and an underflow slurry outlet of the gypsum cyclone (9) is connected with an inlet of the gypsum dehydrator (10); wherein an exhaust outlet of the gypsum dehydrator (10) is communicated with an inlet of the gas-liquid separation tank (11), an exhaust port of the gas-liquid separation tank (11) is connected with a vacuum pump (12), and a drain port of the gas-liquid separation tank (11) is communicated with an inlet of the wastewater collection tank (15); an outlet of the wastewater collection tank (15) is communicated with a flushing water inlet of the mist eliminator (19) in the wastewater concentration tower (18), an inlet of the spray water tank (25) and an inlet of the filtrate water tank (13) through a wastewater delivery pump (16), and an outlet of the filtrate water tank (13) is communicated with a slurry reflux port of the desulfurization absorption tower (6) and an inlet of the thick slurry tank (22) through a filtrate water pump (14); and wherein a bottom outlet of the wastewater concentration tower (18) is communicated with the inlet of the thick slurry tank (22), an outlet of the thick slurry tank (22) is communicated with an inlet of a spray layer (20) in the wastewater concentration tower (18) and an inlet of the clarifier (24), a supernatant outlet of the clarifier (24) is communicated with the inlet of the spray water tank (25), and an outlet of the spray water tank (25) is communicated with an inlet of the wastewater drying tower (27) through a spray water pump (26); and the tail flue of the boiler (1) is provided with a flue gas port, wherein the flue gas port is communicated with a flue gas inlet of the wastewater drying tower (27) and located between the economizer (2) and the air preheater (3).

9. The system for zero discharge treatment of desulfurization wastewater suitable for multiple working conditions according to claim 8, wherein the outlet of the dust collector (4) is divided into two paths after an induced draft fan (5), one of which is communicated with the flue gas inlet of the desulfurization absorption tower (6), and the other is communicated with the flue gas inlet of the wastewater concentration tower (18) through a wastewater concentration booster fan (17).

10. The system for zero discharge treatment of desulfurization wastewater suitable for multiple working conditions according to claim 8, wherein the outlet of the thick slurry tank (22) is communicated with the spray layer (20) in the wastewater concentration tower (18) through a circulating pump (21), and the outlet of the thick slurry tank (22) is communicated with the inlet of the clarifier (24) through a thick slurry pump (23).

Description

BRIEF DESCRIPTION OF DRAWINGS

[0033] FIG. 1 is a schematic structural diagram of the present disclosure.

[0034] In the FIGURE: 1—Boiler, 2—Economizer, 3—Air preheater, 4—Dust collector, 5—Induced draft fan, 6—Desulfurization absorption tower, 7—Chimney, 8—Gypsum discharge pump, 9—Gypsum cyclone, 10—Gypsum dehydrator, 11—Gas-liquid separation tank, 12—Vacuum pump, 13—Filtrate water tank and 14—Filtrate water pump, 15—Wastewater collection tank, 16—Wastewater delivery pump, 17—Wastewater concentration booster fan, 18—Wastewater concentration tower, 19—Mist eliminator, 20—Spray layer, 21—Circulating pump, 22—Thick slurry tank, 23—Thick slurry pump, 24—Clarifier, 25—Spray water tank, 26—Spray water pump, 27—Wastewater drying tower.

DESCRIPTION OF EMBODIMENTS

[0035] In order to make people in the technical field better understand the solution of the present disclosure, the technical solution in the embodiments of the present disclosure will be described clearly and completely below with reference to the drawings in the embodiments of the present disclosure. Obviously, the described embodiments are only part of the embodiments of the present disclosure, not all of them, and are not intended to limit the scope of the present disclosure. In addition, in the following description, descriptions of well-known structures and technologies are omitted to avoid unnecessarily obscuring the concepts disclosed in the present disclosure. Based on the embodiments of the present disclosure, all other embodiments obtained by those skilled in the art without creative labor should belong to the scope of the present disclosure.

[0036] Various structural schematic diagrams according to the disclosed embodiments of the present disclosure are shown in the drawings. These FIGURES are not drawn to scale, in which some details are exaggerated and may be omitted for the sake of clarity. The shapes of various regions and layers shown in the FIGURE, and their relative sizes and positional relationships are only exemplary. In practice, there may be deviations due to manufacturing tolerances or technical limitations, and those skilled in the art can additionally design regions/layers with different shapes, sizes and relative positions according to actual needs.

[0037] In the context of the present disclosure, when a layer/element is referred to as being “on” another layer/element, the layer/element may be directly on the other layer/element, or there may be an intermediate layer/element between them. In addition, if one layer/element is “on” another layer/element in one orientation, the layer/element can be “below” the other layer/element when the orientation is turned.

[0038] It should be noted that the terms “first” and “second” in the description and claims of the present disclosure and the above drawings are used to distinguish similar objects, and are not necessarily used to describe a specific order or sequence. It should be understood that the data used in this way can be interchanged under appropriate circumstances, so that the embodiments of the present disclosure described here can be implemented in a sequence other than those illustrated or described here. In addition, the terms “including” and “having” and any variations thereof are intended to cover non-exclusive inclusion. For example, a process, method, system, product or device that includes a series of steps or units is not necessarily limited to those steps or units that are clearly listed, but may include other steps or units that are not clearly listed or inherent to these processes, methods, products or devices.

[0039] The present disclosure will be further described in detail with reference to the following drawings:

[0040] Referring to FIG. 1, the system for zero discharge treatment of desulfurization wastewater suitable for multiple working conditions according to the present disclosure includes a boiler 1, a dust collector 4, a desulfurization absorption tower 6, a chimney 7, a gypsum cyclone 9, a filtrate water tank 13, a gypsum dehydrator 10, a gas-liquid separation tank 11, a wastewater collection tank 15, a wastewater concentration tower 18, a thick slurry tank 22, a clarifier 24, a spray water tank 25 and a wastewater drying tower 27. An economizer 2 and an air preheater 3 are arranged in a tail flue of the boiler 1 along a flow direction of flue gas, the tail flue of the boiler 1 and a bottom outlet of the wastewater drying tower 27 are both communicated with an inlet of a dust collector 4, an outlet of the dust collector 4 is communicated with a flue gas inlet of the wastewater concentration tower 18 and a flue gas inlet of the desulfurization absorption tower 6; a flue gas outlet of the desulfurization absorption tower 6 is communicated with the chimney 7, a bottom slurry discharge outlet of the desulfurization absorption tower 6 is communicated with an inlet of the gypsum cyclone 9 through a gypsum discharge pump 8, an overflow slurry outlet of the gypsum cyclone 9 is communicated with an inlet of the filtrate water tank 13, and an underflow slurry outlet of the gypsum cyclone 9 is connected with an inlet of the gypsum dehydrator 10; an exhaust outlet of the gypsum dehydrator 10 is communicated with an inlet of the gas-liquid separation tank 11, an exhaust port of the gas-liquid separation tank 11 is connected with a vacuum pump 12, and a drain port of the gas-liquid separation tank 11 is communicated with an inlet of the wastewater collection tank 15; an outlet of the wastewater collection tank 15 is communicated with a flushing water inlet of the mist eliminator 19 in the wastewater concentration tower 18, an inlet of the spray water tank 25 and an inlet of the filtrate water tank 13 through a wastewater delivery pump 16, and an outlet of the filtrate water tank 13 is communicated with a slurry reflux port of the desulfurization absorption tower 6 and an inlet of the thick slurry tank 22 through a filtrate water pump 14; a bottom outlet of the wastewater concentration tower 18 is communicated with the inlet of the thick slurry tank 22, an outlet of the thick slurry tank 22 is communicated with an inlet of a spray layer 20 in the wastewater concentration tower 18 and an inlet of the clarifier 24, a supernatant outlet of the clarifier 24 is communicated with the inlet of the spray water tank 25, and an outlet of the spray water tank 25 is communicated with an inlet of the wastewater drying tower 27 through a spray water pump 26; the tail flue of the boiler 1 is provided with a flue gas port. The flue gas port is communicated with a flue gas inlet of the wastewater drying tower 27 and located between the economizer 2 and the air preheater 3.

[0041] The outlet of the dust collector 4 is divided into two paths after an induced draft fan 5, one of which is communicated with the flue gas inlet of the desulfurization absorption tower 6, and the other is communicated with the flue gas inlet of the wastewater concentration tower 18 through a wastewater concentration booster fan 17.

[0042] The outlet of the thick slurry tank 22 is communicated with the spray layer 20 in the wastewater concentration tower 18 through a circulating pump 21, and the outlet of the thick slurry tank 22 is communicated with the inlet of the clarifier 24 through a thick slurry pump 23; the outlet of the spray water tank 25 is communicated with the inlet of the top of the wastewater drying tower 27 through a spray water pump 26.

[0043] The method for zero discharge treatment of desulfurization wastewater suitable for multiple working conditions is as follows:

[0044] In this embodiment, the boiler 1 used fuels from three producing areas A, B and C respectively, and the concentration of Cl.sup.− in the process water entering the desulfurization system was 150 mg/L.

[0045] The high-temperature flue gas produced by the boiler 1 passed through an economizer 2 and an air preheater 3 for heat recovery. After the flue gas temperature was reduced to about 90° C., it entered a dust collector 4 for dust removal, and then was transported to a desulfurization absorption tower 6 through induced draft fan 5 to remove acid pollutants such as sulfur dioxide SO.sub.2 and hydrogen chloride HCl. After the flue gas temperature was further reduced to about 50° C., the flue gas was discharged from chimney 7.

[0046] The gypsum slurry produced in the desulfurization absorption tower 6 was transported to the gypsum cyclone 9 by a gypsum discharge pump 8 for separation, in which the separated overflow slurry with a solid content of about 5% entered a filtrate water tank 13, and the separated underflow slurry with a solid content of about 50% entered a gypsum dehydrator 10. Through the suction effect of a vacuum pump 12, the water in the slurry in the gypsum dehydrator 10 was filtered through the filter cloth of the dehydrator, and then entered a gas-liquid separation tank 11 along with the sucked air, and the separated drainage water with a solid content of about 0.5% entered a wastewater collection tank 15.

[0047] When the fuel from the area A was burned in the boiler 1, the concentrations of HCl and SO.sub.2 in the flue gas were 7 ppm and 750 ppm respectively, the flue gas volume at the inlet of the desulfurization absorption tower 6 was 2,960,069 m.sup.3/h (in a standard state), the amount of the desulfurization wastewater required to be discharged was 2.7 m.sup.3/h, and the amount of the drainage water of the gas-liquid separation tank 11 was 11.5 m.sup.3/h; 2.7 m.sup.3/h of the drainage water collected by the wastewater collection tank 15 was directly transported to a spray water tank 25 by a wastewater delivery pump 16, and then transported to a wastewater drying tower 27 by a spray water pump 26; the flue gas of about 350° C. before the air preheater 3 was extracted to evaporate the desulfurized wastewater in the wastewater drying tower 27, and the amount of the extracted flue gas was 27,000 m.sup.3/h (in a standard state). After the water evaporates, it entered the dust collector 4 along with the flue gas. The salts formed by evaporation of wastewater entered the dust collector 4 along with the flue gas to be collected, and the excess 8.8 m.sup.3/h of the drainage water in the wastewater collection tank 15 was transported to the filtrate water tank 13, and then returned to the desulfurization absorption tower 6 through a filtrate water pump 14. In this embodiment, the amount of the desulfurization wastewater required to be discharged was small, and the collected drainage water output from the gas-liquid separation tank 11 was directly transported to the spray water tank 25 for drying, thus omitting the wastewater concentration process, and the system structure was relatively simple; moreover, the drainage water output from the gas-liquid separation tank 11 was taken as the source of desulfurization wastewater, and its solid content was as low as 0.5%, which could save the process of wastewater clarification and tempering; under this working condition, it not only saved energy, but also had high system reliability.

[0048] When the fuel from the area B was burned in the boiler 1, the concentrations of HCl and SO.sub.2 in the flue gas were 18.5 ppm and 1250 ppm respectively, and the amount of the flue gas at the inlet of the desulfurization absorption tower 6 was 2,826,051 m.sup.3/h (in a standard state); the amount of desulfurization wastewater required to be discharged was 6.0 m.sup.3/h, and the amount of the drainage water of the gas-liquid separation tank 11 was 18.0 m.sup.3/h, and 6.0 m3/h of the drainage water collected by the waste water collection tank 15 was transported by the waste water delivery pump 16, and entered the waste water concentration tower 18 as the washing water of a mist eliminator 19; the excess 12 m.sup.3/h of the drainage water in the wastewater collection tank 15 was transported to the filtrate water tank 13, and then returned to the desulfurization absorption tower 6 through the filtrate water pump 14. The desulfurization wastewater was transported to a spray layer 20 by a circulating pump 21 in the wastewater concentration tower 18 and sprayed out in the form of droplets. At the same time, the low-temperature boiler flue gas of about 90° C. was led out from an induced draft fan 5 and entered the wastewater concentration tower 18. The flue gas of 190,000 m.sup.3/h (in a standard state) was transported to the wastewater concentration tower 18 by a wastewater concentration booster fan 17, and contacted with the sprayed desulfurization wastewater droplets in countercurrent, and some water in the droplets entered the flue gas by evaporation. The amount of the desulfurized wastewater was reduced to 2.0 m.sup.3/h, with an increased solid content, and then entered a thick slurry tank 22, and was transported to a clarifier 24 by a thick slurry pump 23 for clarification and tempering. The supernatant in the clarifier 24 flows into the spray water tank 25, and then was transported to the wastewater drying tower 27 by the spray water pump 26 for evaporation. 20,000 m.sup.3/h (in a standard state) of the high-temperature flue gas of about 350° C. was taken. The flue gas contacted with the droplets in the wastewater concentration tower 18 not only contained evaporated water vapor, but also carried some desulfurization wastewater droplets. The droplets were collected by the mist eliminator 19, and the flue gas output from the top of the wastewater concentration tower 18 entered the desulfurization absorption tower 6. In this embodiment, a large amount of desulfurization wastewater was required to be discharged, the wastewater was concentrated and reduced by using low-temperature flue gas of about 90° C., and then evaporated by using high-temperature flue gas of about 350° C. The waste heat resources of low-temperature flue gas were utilized, and the overall energy consumption of the system was low. In this embodiment, the drainage water output from the gas-liquid separation tank 11 met the wastewater discharge requirements, and the drainage water output from the gas-liquid separation tank 11 was used as the source of desulfurization wastewater, so that the desulfurization wastewater had a low solid content, and the operation reliability of the wastewater concentration tower 18, the clarifier 24 and the wastewater drying tower 27 was high. Besides, the drainage water with a low solid content could be used as the washing water of the mist eliminator 19, and it was not necessary to introduce process water to wash the mist eliminator 19, so as to avoid the increase of required evaporated water due to the additional water intake of the wastewater concentration tower 18, so as to maintain the low energy consumption of the system.

[0049] When the fuel from the area C was burned in the boiler 1, the concentrations of HCl and SO.sub.2 in flue gas were 30.0 ppm and 590 ppm respectively, and amount of the flue gas at the inlet of desulfurization absorption tower 6 was 2,826,933 m.sup.3/h (standard state). The amount of desulfurization wastewater required to be discharged was 9.5 m.sup.3/h, and the amount of the drainage water in the gas-liquid separation tank 11 was 8.9 m.sup.3/h. The amount of the drainage water of the gas-liquid separation tank 11 was smaller than the amount of desulfurization wastewater required to be discharged, and 8.9 m.sup.3/h of the drainage water collected in the waste water collection tank 15 was all delivered to the waste water concentration tower 18 by the waste water delivery pump 16, and was used as the washing water of the mist eliminator 19; 0.6 m.sup.3/h of the slurry was drawn from the filtrate water tank 13 and transported to the thick slurry tank 22 by the filtrate water pump 14; these two portions of slurry were evaporated, reduced and concentrated in the wastewater concentration tower 18, and low-temperature flue gas of about 90° C. of 285,000 m.sup.3/h (in a standard state) was extracted to reduce the desulfurization wastewater to 3.5 m3/h, and then transported to the clarifier 24 by the thick slurry pump 23; the supernatant in the clarifier 24 flowed into the spray water tank 25 by itself, and was transported to the wastewater drying tower 27 by the spray water pump 26 for evaporation, and 35,000 m3/h (in a standard state) of the high-temperature flue gas of about 350° C. was taken. In this embodiment, the hydrophobic quantity of the gas-liquid separation tank 11 was smaller than that of the desulfurization wastewater required to be discharged. Two paths of desulfurization wastewater introduced from the wastewater collection tank 15 and filtrate water tank 13 were respectively led to the wastewater concentration tower 18 and the thick slurry tank 22, which not only ensured enough desulfurization wastewater discharge, but also avoided the hydrophobic pollution of the gas-liquid separation tank 11 with a low solid content caused by premature mixing of the two water sources, and ensured that the drainage water of the gas-liquid separation tank 11 could be used as the washing water of the mist eliminator 19.

[0050] The present disclosure has strong adaptability to flue gas components, and provides different zero discharge treatment methods of desulfurization wastewater for different flue gas components, which can ensure the high reliability and energy-saving and economic operation of the system under different working conditions.

[0051] The above contents are only used to illustrate the technical concept of the present disclosure, and are not intended to limit the protection scope of the present disclosure. Any changes made on the basis of the technical solution according to the technical concept put forward by the present disclosure shall fall within the protection scope of the claims of the present disclosure.