LANTHANIDE DOUBLE PEROVSKITE NANOCRYSTALS
20240059964 ยท 2024-02-22
Inventors
Cpc classification
C01P2002/76
CHEMISTRY; METALLURGY
C01P2002/77
CHEMISTRY; METALLURGY
C01P2006/60
CHEMISTRY; METALLURGY
C01P2002/72
CHEMISTRY; METALLURGY
International classification
Abstract
Lanthanide double perovskite nanocrystals are described. The nanocrystals display high energy luminescence, making them useful in a variety of light-emitting materials and devices. Methods of preparing the lanthanide double perovskite nanocrystals using a hot injection method are also described.
Claims
1. Double perovskite nanocrystals represented by the formula Cs.sub.2ABX.sub.6, wherein: A is an alkali metal; B is one or more lanthanide selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb; and X is a halide selected from Br, Cl, or I.
2. The double perovskite nanomaterial of claim 1, wherein X is Cl.
3. The double perovskite nanomaterial of claim 1, wherein the alkali metal is Na.
4. The double perovskite nanomaterial of claim 1, wherein the nanocrystals have a cuboid morphology and an edge length from about 5 to about 20 nm.
5. The double perovskite nanomaterial of claim 4, wherein the edge length is from about 7.5 to about 15 nm.
6. The double perovskite nanomaterial of claim 1, wherein the nanomaterial is an alloy comprising a plurality of lanthanides.
7. A light emitting material comprising a material comprising double perovskite nanocrystals represented by the formula Cs.sub.2ABX.sub.6, wherein: A is an alkali metal; B is one or more lanthanide selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb; and X is a halide selected from Br, Cl, or I.
8. The light emitting material of claim 7, wherein the material luminesces at a wavelength ranging from 260 to 1550 nm.
9. The light emitting material of claim 7, wherein B is Pr, and the material has a peak emission from about 260 nm to about 270 nm.
10. The light emitting material of claim 7, wherein B is Tb, and the material has a peak emission from about 540 nm to about 560 nm.
11. The light emitting material of claim 7, wherein B is Sm, and the material has a peak emission from about 590 nm to about 610 nm.
12. The light emitting material of claim 7, wherein B is Yb, and the material has a peak emission from about 990 nm to about 1000 nm.
13. The light emitting material of claim 7, wherein B is Eu, and the material has a peak emission from about 600 nm to about 620 nm.
14. The light emitting material of claim 7, wherein the double perovskite nanocrystals are alloys comprising a plurality of lanthanides.
15. A light emitting device comprising a light emitting material comprising double perovskite nanocrystals represented by the formula Cs.sub.2ABX.sub.6, wherein: A is an alkali metal; B is one or more lanthanide selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb; and X is a halide selected from Br, Cl, or I.
16. The light emitting device of claim 15, wherein the device is a light emitting diode.
17. The light emitting device of claim 15, wherein the device is a solar concentrator.
18. The light emitting device of claim 15, wherein the device is a laser.
19. The light emitting device of claim 15, wherein the double perovskite nanocrystals are alloys comprising a plurality of lanthanides.
20. A method of preparing double perovskite nanocrystals represented by the formula Cs.sub.2ABX.sub.6, wherein: A is an alkali metal; B is one or more lanthanide selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb; and X is a halide selected from Br, Cl, or I; comprising the steps of: 1) adding cesium salt, an alkali metal salt, and a lanthanide salt or acetylacetonate to a mixture of a non-polar organic solvent, oleic acid, and oleylamine; 2) degassing the mixture for about 30 minutes to about 2 hours at a temperature ranging from about 60 C. to about 120 C. to remove oxygen and water; 3) injecting chloromethylsilane at a temperature from about 150 C. to about 200 C.; 4) rapidly cooling the mixture to about room temperature; and 5) collecting double perovskite nanocrystals from the mixture.
21. The method of claim 20, wherein the non-polar organic solvent is octadecene.
22. The method of claim 20, wherein the cesium salt is cesium carbonate.
23. The method of claim 20, wherein the alkali metal salt is alkali metal acetate, and the lanthanide salt is lanthanide acetate.
24. The method of claim 20, wherein the step of degassing the mixture is carried out for about one hour at about 110 C.
25. The method of claim 20, wherein the chloromethylsilane is injected at about 180 C.
26. The method of claim 20, wherein B comprises a plurality of different lanthanides to provide a double perovskite nanocrystal alloy.
Description
BRIEF DESCRIPTION OF THE FIGURES
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DETAILED DESCRIPTION OF THE INVENTION
[0018] The present invention provides lanthanide double perovskite nanocrystals. The nanocrystals display high energy luminescence, making them useful in a variety of light-emitting materials and devices. Methods of preparing the lanthanide double perovskite nanocrystals using a hot injection method are also provided.
Definitions
[0019] The terminology as set forth herein is for description of the embodiments only and should not be construed as limiting of the invention as a whole. Unless otherwise specified, a, an, the, and at least one are used interchangeably. Furthermore, as used in the description of the invention and the appended claims, the singular forms a, an, and the are inclusive of their plural forms, unless contraindicated by the context surrounding such.
[0020] Also herein, the recitations of numerical ranges by endpoints include all numbers subsumed within that range (e.g., 1 to 5 includes 1, 1.5, 2, 2.75, 3, 3.80, 4, 5, etc.).
[0021] As used herein, the term about refers to +/10% deviation from the basic value.
[0022] Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.
Double Perovskite Nanocrystals
[0023] In one aspect, the present invention provides double perovskite nanocrystals represented by the formula Cs.sub.2ABX.sub.6, wherein: A is an alkali metal; B is one or more lanthanide selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb; and X is a halide (i.e., a halogen bearing a negative charge) selected from Br, Cl, or I. In some embodiments, the alkali metal is Na, while in further embodiments X is Br or Cl, or Cl. A perovskite is any material with a crystal structure following the formula ABX.sub.3. The nanocrystals can also be referred to as lanthanide double perovskite nanocrystals. Cs of the formula refers to the alkali metal cesium.
[0024] Alkali metals include lithium, sodium, potassium, rubidium, cesium, and francium. It is preferable to avoid the use of francium, which is significantly radioactive. In some embodiments, the alkali metals can be replaced with organic ions like methylammonium cation and formamidium cation. Similarly silver cations can be used, as long as the silver is monovalent.
[0025] The term nanocrystal and the like refer, in the usual and customary sense, to a polycrystalline material having a crystallite size (e.g., edge length) less than a micrometer (e.g., 1-10, 1-20, 1-30, 1-40, 1-50, 1-100, 1-200-, or even 1-500 nm). In some embodiments, the nanocrystals have a cuboid morphology and an edge length from about 5 to about 20 nm, from about 5 to about 15 nm, or from about 7.5 to about 15 nm.
Light Emitting Material
[0026] Another aspect of the invention provides a light emitting material comprising a material comprising double perovskite nanocrystals represented by the formula Cs.sub.2ABX.sub.6, wherein: A is an alkali metal; B is one or more lanthanide selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb; and X is a halide selected from Br, Cl, or I. Preferably, the material luminesces at a wavelength ranging from 260 to 1550 nm.
[0027] Examples of a light emitting material include a semiconductor material or a high energy x-ray or gamma-ray scintillator. Semiconductor materials are nominally small band gap insulators, and the most commonly used semiconductor materials are crystalline inorganic solids. In many cases, and as shown in the art, the conductivity or light emission efficiency of semiconductor material can be improved by doping, i.e., by adding an impurity element.
[0028] Scintillators are materials that are able to convert high energy radiation such as X-rays or gamma-rays to a near visible or visible light. They are widely used as detectors in medical diagnostics, high energy physics and geophysical exploration. Scintillators can be gaseous, liquid or solid, organic or inorganic (glass, single crystal, ceramics). Detectors based on scintillators are essentially composed of a scintillator material, and a photodetector that can be either a photomultiplier tube (PMT) or a photodiode. The role of the photodetector is to convert the outcoming light of the scintillator to an electrical signal.
[0029] The cerium and praseodymium materials emit UV light, making them useful for the fabrication of UV LEDs. The terbium, europium and ytterbium materials absorb high-energy UV light, and down-convert it to visible light, making them ideal for many applications.
[0030] In some embodiments, the lanthanide (B) is Pr, and the material has a peak emission from about 260 nm to about 270 nm. In other embodiments, B is Tb, and the material has a peak emission from about 540 nm to about 560 nm. In additional embodiments, B is Sm, and the material has a peak emission from about 590 nm to about 610 nm. In a further embodiment, B is Yb, and the material has a peak emission from about 990 nm to about 1000 nm. In a yet further embodiment, B is Eu, and the material has a peak emission from about 600 nm to about 620 nm.
[0031] The Praseodymium material displays the highest energy luminescence currently known for a perovskite material, enabling the fabrication of higher energy LEDs than any other similar material. The Terbium, Europium and Ytterbium materials are ideal for luminescent solar concentrators. They absorb UV light and down-convert it to visible or near-IR light that commercial solar cells can utilize better than UV light. They also do not absorb visible light, making them completely transparent.
Light Emitting Devices
[0032] An additional aspect of the invention provides a light emitting device comprising a light emitting material comprising double perovskite nanocrystals represented by the formula Cs.sub.2ABX.sub.6, wherein: A is an alkali metal; B is one or more lanthanide selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb; and X is a halide selected from Br, Cl, or I.
[0033] Examples of light emitting devices including a light emitting material comprising double perovskite nanocrystals include solar cells, luminescent solar concentrators, photocatalysts, fluorescence imaging probes, displays, solid-state lighting, and UV-protecting window coatings.
[0034] In some embodiments, the device is a light emitting diode. Non-limiting examples of electronic, optic-, or optoelectronic devices include a light emitting diode (LED) such as white LED, display device, light detector, X-ray detector, gamma-ray detector, and imaging detector such as a medical imaging detector.
[0035] An LED is a semiconductor light source that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (corresponding to the energy of the photons) is determined by the energy required for electrons to cross the band gap of the semiconductor. Due to their high photoluminescence quantum efficiencies, double perovskite nanocrystals are useful in light-emitting diodes (LEDs)
[0036] A display device is an output device for presentation of information in visual or tactile form. When the input information that is supplied has an electrical signal the display is called an electronic display.
[0037] A light detector is a device used in an optical transmission system to detect an optical signal generated by a light source and propagating through a medium. A light detector essentially is an optical receiver that is paired with an optical transmitter, both of which are connected to electrically based devices or systems. So, the source converts electrons to photons and the detector converts photons to electrons. Different types of light detectors include light dependent resistors (LDRs), photo diodes, photo transistors, and the like, and they are called photoelectric devices since they convert light energy to electric energy. The light detectors can detect different types of light such as visible light, ultraviolet light, infrared light, and the like.
[0038] X-ray detectors are devices used to measure the flux, spatial distribution, spectrum, and/or other properties of x-rays. Some of the common x-ray detectors include proportional counters, microchannel plates, and semiconductor detectors.
[0039] Gamma-ray detectors measure electromagnetic radiation through the process of the counting and measuring the energy of individual photons emitted from elements. Different types of detectors are used for detecting gamma rays, the most common are scintillation detectors and semiconductors.
[0040] Imaging detector (also referred to as image sensor or imager) is a sensor that detects and conveys information used to make an image by converting variable attenuation of light waves (as they pass through or reflect off objects) into signals, small bursts of current that convey the information. Imaging detectors, such as x-ray detectors, can be used in medical imaging equipment.
[0041] In other embodiments the device is a solar concentrator. A luminescent solar concentrator is a device for concentrating radiation, solar radiation in particular, to produce electricity. Luminescent solar concentrators operate on the principle of collecting radiation over a large area, converting it by luminescence (specifically by fluorescence) and directing the generated radiation into a relatively small output target. Double perovskite nanocrystals can be used for photovoltaic cells such as those used in solar concentrators or collectors. Perovskite cells possess many optoelectrical properties that benefit their use in solar cells. Min et al., Nature. 598 (7881): 444-450 (2021).
[0042] In a further embodiment, the device is a laser. Double perovskite nanocrystals can be used to generate laser light. A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. A laser differs from other sources of light in that it emits light that is coherent, both spatially and temporally
[0043] Lasers are used in optical disc drives, laser printers, barcode scanners, DNA sequencing instruments, fiber-optic, and free-space optical communication, semiconducting chip manufacturing (photolithography), laser surgery and skin treatments, cutting and welding materials, and a wide range of other applications. Perovskite nanocrystal semiconductors can be used for highly efficient two-photon absorption in laser designs. Xu et al., J. Am. Chem. Soc., 138, 11, 3761 (2016).
[0044] Lanthanide double perovskite nanocrystals are colloidal nanocrystals. This enables easy utilization and integration in device fabrication, which is not possible using bulk materials. The perovskite nanomaterials developed by the inventors can readily be dispersed in different solvents without structural change, which is important for the aforementioned applications and processing. Bulk materials, on the other hand either, do not disperse at all in organic solvents, or they do so without maintaining their crystalline integrityboth of which are highly undesirable.
Methods for Preparing Lanthanide Double Perovskite Nanocrystals
[0045] The inventors have prepared lanthanide double perovskite nanocrystals using a colloidal hot-injection method, which involves the injection of a cold (i.e., room temperature) solution of chlorotrimethylsilane into a hot liquid containing the metal cations and organic ligands, leading to the formation of lanthanide double perovskite nanocrystals.
[0046] Accordingly, a further aspect of the invention provides a method of preparing double perovskite nanocrystals represented by the formula Cs.sub.2ABX.sub.6, wherein: A is an alkali metal; B is a lanthanide selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb; and X is a halide selected from Br, Cl, or I. The method includes the steps of: 1) adding cesium salt, an alkali metal salt, and a lanthanide salt or acetylacetonate to a mixture of a non-polar organic solvent, oleic acid, and oleylamine; 2) degassing the mixture for about 30 minutes to about 2 hours at a temperature ranging from about 60 C. to about 120 C. to remove oxygen and water; 3) injecting chloromethylsilane at a temperature from about 150 C. to about 200 C.; 4) rapidly cooling the mixture to about room temperature; and 5) collecting double perovskite nanocrystals from the mixture.
[0047] Examples of non-polar organic solvent include o-xylene, m-xylene, p-xylene, toluene, hexane, heptane, ethylbenzene, benzene, octadecene, and a combinations thereof. In particular embodiments such as those exemplified herein, the solvent is octadecene.
[0048] The method makes use of cesium salt, an alkali metal salt, and a lanthanide salt, each of which is independently an acetate, chloride, bromide, nitrate, mesylate, maleate, fumarate, tartrate, p-toluenesulfonate, benzenesulfonate, benzoate, phosphate, sulfate, citrate, carbonate, or succinate salt. In some embodiments, the cesium salt is carbonate. In further embodiments, the alkali metal salt is alkali metal acetate, and the lanthanide salt is lanthanide acetate.
[0049] The method encompasses reasonable variation in the time and temperature of reaction conditions. In some embodiments, the method comprises degassing the mixture for about 30 minutes to about 2 hours at a temperature ranging from about 60 C. to about 120 C. to remove oxygen and water. Generally, a higher temperature will result in a decreased reaction time. Accordingly, in some embodiments, the step of degassing the mixture is carried out for about one hour at about 110 C. Likewise, the method comprises injecting chloromethylsilane at a temperature from about 150 C. to about 200 C. However, in some embodiments, the chlormethylsilane is injected at a temperature from about 165 C. to about 190 C., while in further embodiments, the chloromethylsilane is injected at about 180 C.
[0050] Those skilled in the art will appreciate that other synthetic routes may be used to synthesize the compounds of the invention. Although specific starting materials and reagents are depicted in the reaction schemes and discussed below, other starting materials and reagents can be easily substituted to provide a variety of derivatives and/or reaction conditions. In addition, many of the compounds prepared by the methods described below can be further modified in light of this disclosure using conventional methods well known to those skilled in the art.
[0051] The present invention is illustrated by the following example. It is to be understood that the particular example, materials, amounts, and procedures are to be interpreted broadly in accordance with the scope and spirit of the invention as set forth herein.
Example
Lanthanide Double Perovskite Nanocrystals with Emissions Covering the UV-C to NIR Spectral Range
[0052] Herein, we present a versatile colloidal method for the synthesis of Cs.sub.2NaLnCl.sub.6 DP NCs for all Lns except for lutetium and promethium. The as-synthesized Ln-DP NCs (Ln=LaNd, Sm Yb) display uniform size and cubic shape with a pure DP crystal phase. In addition to the already reported Cs2NaErCl6 DP NCs, we found that six additional Ln-DP NCs (Ln=Ce, Pr, Sm, Eu, Tb, and Yb) exhibit characteristic emission features covering a wide spectral window from UV-C to NIR (i.e., 260-995 nm). In particular, the Cs.sub.2NaPrCl.sub.6 DP NCs display rarely accessible UVC emission with a PLQY of 14%, the highest QY value reported for any UV-C emitting perovskite NCs. The Cs.sub.2NaTbCl.sub.6 DP NCs show bright green emission with a PLQY of 45%, the highest value of any pure Ln-DP NCs known so far. By analyzing the optical behaviors of these materials with the aid of density functional theory (DFT) calculations, fundamental origins of the absorption and emission electronic transitions were identified and understood. Furthermore, taking advantage of high miscibility of different Lns, we have successfully demonstrated the possibility of fabricating alloyed Cs.sub.2NaLnCl.sub.6 DP NCs simultaneously containing multiple different Ln components. The resulting alloyed Ln-DP NCs possess optical properties that are inaccessible to the single Ln counterparts. Our study provides fundamental insight into electronic structure and optical properties of Ln-based perovskite materials, which will enable further development of Ln-DP NCs. The synthesized Ln-DP NCs are potentially suitable materials for a wide range of applications, including ultra-high energy LEDs, high-security anti-counterfeiting, efficient luminescent solar concentrators, as well as low-threshold lasers.
Results and Discussion
Synthesis, Morphology, and Crystal Phase of Ln-DP NCs
[0053] Ln-DP NCs were synthesized using a modified colloidal hot injection approach. C. Murray, et al., Annu. Rev. Mater. Sci. 2000, 30, 545. Briefly, cesium carbonate, sodium acetate, and Ln-acetate or acetylacetonate salts were added to a solution mixture of octadecene, oleic acid, and oleylamine. After oxygen and water were removed by degassing under vacuum for 1 hour at 110 C., the solution was heated to 180 C. Chlorotrimethylsilane was injected into the reaction solution, followed by rapid cooling to room temperature after 2 min. After purification, the obtained Ln-DP NCs can be redispersed in hexane to form a stable suspension. Powder X-ray diffraction (XRD) patterns of all the samples showed a cubic DP crystal phase (space group: Fm3m) with no indication of impurity presence (
[0054] Transmission electron microscopy (TEM) measurements revealed a cuboidal morphology for the synthesized Ln-DP NCs (
Optical Properties of Ln-DP NCs
[0055] Six of the 12 newly synthesized Ln-DP NCs (i.e., Cs.sub.2NaLnCl.sub.6 DP NCs, Ln=Ce, Pr, Sm, Eu, Tb, and Yb) showed measurable emission with the PL peaks covering a wide spectral range from UV (Ln=Pr and Ce) through visible (Ln=Tb, Eu, and Sm) to NIR (Ln=Yb and the previously reported Er) (R. Wu, et al., Laser Photonics Rev. 2021, 15, 2100218) (
[0056] Cs.sub.2NaPrCl.sub.6 DP NCs displayed the highest energy emission peaks of the Cs.sub.2NaLnCl.sub.6 DP NCs, with three major emission peaks observed at 265, 276, and 302 nm (4.68, 4.49, and 4.11 eV, respectively). Each of the emission peaks correspond to Pr-based electronic transitions from the 4f.sup.15d.sup.1 excited state (term symbol .sup.3H.sub.4) to 4f.sup.2 levels (term symbols .sup.3H.sub.J, where J=4-6) (
[0057] Cs.sub.2NaCeCl.sub.6 DP NCs displayed UV-A/violet emission with a main peak at 370 nm (3.35 eV) and a shoulder at 410 nm (3.02 eV) (
[0058] Cs.sub.2NaTbCl.sub.6 DP NCs exhibited a strong green emission originating from the Tb .sup.5D.sub.4.fwdarw..sup.7F.sub.J (J=2-6) transitions, where the most intense peak was located at 550 nm (2.25 eV) (
[0059] Cs.sub.2NaSmCl.sub.6 DP NCs possessed three extremely weak, yet characteristic emission peaks at 569 (2.18 eV), 607 (2.04 eV), and 655 nm (1.89 eV) (
[0060] Cs.sub.2NaEuCl.sub.6 DP NCs emitted in the red part of the spectrum, with several narrow emission peaks located between 590-710 nm (
[0061] Cs.sub.2NaYbCl.sub.6 DP NCs displayed a weak characteristic Yb .sup.2F.sub.5/2.fwdarw..sup.2F.sub.7/2 emission at 995 nm (1.25 eV) (
Absorption Features and their Origins
[0062] Due to the contracted nature of the 4f orbitals, lanthanides in the trivalent oxidation state display characteristic optical transitions that are often minimally perturbed by changes in ligand field. J. C. G. Bunzli, et al., Chem. Soc. Rev. 2005, 34, 1048. It is well established that emission from Ln.sup.III materials requires effective sensitization; however, f-f absorption eventsthat are often the lowest energy electronic transitionsare ineffective in this regard due to their Laporte- and spin-forbidden nature (: 0.1-10 m.sup.1 cm.sup.1). B. G. Wybourne, et al., Optical Spectroscopy of Lanthanides: Magnetic and Hyperfine Interactions, Taylor and Francis, London 2007. Only Cs.sub.2NaLnCl.sub.6 DP NCs displaying pronounced absorption features emitted with considerable intensity, there-fore identification and assignment of their electronic absorption features are crucial to understanding and controlling their resulting optical properties. The six emissive Ln-DP NC samples (i.e., the Cs.sub.2NaLnCl.sub.6 NCs with Ln=Ce, Pr, Sm, Eu, Tb, and Yb) can be divided into two groups depending on the nature of their absorption features: i) narrow atomic f-d absorption for the Pr, Ce, and Tb-based Ln-DP NCs; and ii) broad Cl-to-Ln LMCT absorption for the Eu, Sm-, and Yb-containing ones. J. L. Ryan, et al., J. Phys. Chem. 1966, 70, 2845. The absorption features observed in Ln-DP NCs are very close in energy to the absorption features of corresponding molecular analogs, and they show minimal quantum confinement effects because of the highly localized valence orbitals. A similar lack of dimensional confinement was previously described for Bi-based layered DPs. M. Pantaler, et al., JACS Au 2021, 2, 136.
[0063] In the case of f-d absorptions, a 4f-electron is promoted to a high energy unoccupied 5d-orbital, representing a direct transition with negligible spatial charge separation (
[0064] In the case of Cl 3p to Ln 4f LMCT absorption events, an electron is promoted from a filled Cl 3p-orbital to an empty Ln 4f-orbital to generate a transient charge-separated species featuring a divalent Ln.sup.II ion and a hole on one of the Cl ligands (
[0065] Analogies of the electronic transitions can also be drawn to the extended nanocrystalline solids for their absorptive bandgap transitions. Like direct bandgap transitions, atomic f-d transitions keep the excited electron and the hole localized on the same atom upon excitation, enabling direct radiative recombination without spatial separation (
Computational Analysis
[0066] To gain a deeper understanding of the electronic structures of Cs.sub.2NaLnCl.sub.6 DPs, DFT (P. Kratzer, et al., Front. Chem. 2019, 7, 106) calculations were employed. Band structures and density of states (DOS) DFT calculations for the six emissive materials (i.e., Cs.sub.2NaLnCl.sub.6 with Ln=Ce, Pr, Sm, Eu, Tb, and Yb) were carried out using the common plane wave approach, (M. Topsakal, et al., Comput. Mater. Sci. 2014, 95, 263) employing the Perdew-Burke-Ernzerhof (PBE, generalized gradient approximation) (J. P. Perdew, et al., Phys. Rev. Lett. 1996, 77, 3865) functional with non-linear core corrections and scalar relativistic effects. Calculated lattice constants of the six selected Cs.sub.2NaLnCl.sub.6 were in good agreement with reported values, with computed values being systematically overestimated by 0.2 . G. Meyer, Prog. Solid State Chem. 1982, 14, 141. Across all these six systems, the valence band maximum was dominated by Cl 3p character with varying contributions from Ln 4f-orbitals, while the conduction band minimum is primarily composed of Ln 4f and 5d orbitals (
[0067] Calculations for the Ce, Pr, and Tb Cs.sub.2NaLnCl.sub.6 DP NCs successfully predicted energetically accessible, direct bandgap transitions corresponding to Laporte- and spin-allowed Ln-centered 4f.fwdarw.5d transitions at 2.29, 2.77, and 3.83 eV (
[0068] While our plane-wave calculations reproduced some general properties of Cs.sub.2NaLnCl.sub.6 DP NCs, they incorrectly predicted the nature of the bandgap for Yb and featured relatively large energy differences for calculated and experimental bandgap transitions within the series. Due to the highly correlated nature of 4f states, the band structures of Ln-containing materials can be non-trivial to reproduce by single determinant methods. M. Ferbinteanu, et al., Inorg. Chem. 2017, 56, 9474. While multi-configurational approaches, such as complete active space self-consistent field, can be used to model multi-reference character, these methods scale poorly with active space size and can be cost-prohibitive for large active spaces. P. G. Szalay, et al., Chem. Rev. 2012, 112, 108. Given these restrictions, and the striking similarities in the optical properties of Cs.sub.2NaLnCl.sub.6 DPs NCs and [LnCl.sub.6].sup.3- molecular analogs, we also interrogated the electronic structure of previously studied small molecule models, [Na.sub.6LnCl.sub.6].sup.3+ (Ln=CeYb), by DFT. D. Aravena, et al., Inorg. Chem. 2016, 55, 4457. All calculations were carried out using the hybrid PBE functional and property-optimized def2-tzvpp(d) basis sets for Ln reported by Rappoport. D. Rappoport, J. Chem. Phys. 2021, 155, 124102. Geometry-optimized structures of [Na.sub.6LnCl.sub.6].sup.3+ were in good agreement with the crystal structures of Cs.sub.2NaLnCl.sub.6, where calculated and experimentally determined Ln-Cl bond distances were within 0.04 of one another. Energies of the highest occupied Cl 3p and Ln 4f orbitals as well as the lowest unoccupied Ln 4f and 5d orbitals (Ln=CeYb) were calculated in the ground state, but this simple model was also insufficient to correctly predict the nature of observed absorption features. However, time-dependent DFT (TD-DFT) calculations carried out on the optimized structures of [Na.sub.6LnCl.sub.6].sup.3+ at the same level of theory effectively captured the main sensitization transitions for Cs.sub.2NaLnCl.sub.6 DPs NCs. Ce.sup.III, Pr.sup.III, and Tb.sup.III clearly featured 4f.fwdarw.5d transitions at 4.16, 5.16, and 2.47 eV, respectively, while Sm.sup.III, Eu.sup.III, and Yb.sup.III featured Cl 3p to Ln 4f LMCT transitions at 2.48, 1.59, and 2.66 eV, respectively. Even with the observed discrepancies in transition energies, TD-DFT was able to correctly predict the lowest energy allowed electronic transitions of all six Ln-DP NCs showing features in the UV-vis spectrum. The calculated transition energies differed significantly from experimentally obtained results, highlighting the challenges and limitations in the calculation of lanthanide 4f electronic states.
[0069] With both experimental and computational data in hand, we set out to construct a semi-empirical energy diagram capable of summarizing the electronic structure and optical properties of Cs.sub.2NaLnCl.sub.6 DP NCs. In order to construct a diagram with relative orbital energies of sufficient accuracy, the highest occupied and unoccupied 4f orbital energies were corrected by using experimentally determined values for the lowest energy 4f.fwdarw.5d or LMCT transitions, where Cl 3p and Ln 5d orbital energies were taken from DFT calculations of the molecular analogs, [Na.sub.3LnCl.sub.6].sup.3+. LMCT transitions were used to adjust the DFT-calculated energies of unoccupied 4f orbitals relative to Cl 3p orbitals, while 4f.fwdarw.5d transitions were used to correct occupied 4f orbital energies with respect to Ln 5d orbitals. Select sections of the excited Ln.sup.III 4f manifold were constructed using previously reported, 4f orbital energies experimentally determined for bulk Cs.sub.2NaLnCl.sub.6 (
Alloyed Ln-DP NCs with Enhanced Optical Properties
[0070] Alloying and doping have been used extensively in the past to enhance optical properties of NCs, as alloyed nanomaterials can deliver properties inaccessible to physical mixtures of different components. G. Pan, et al., Nano Lett. 2017, 17, 8005. The successful synthesis of alloyed perovskite materials can be challenging, as stable combinations require appropriate matching of the introduced cation's size with the host material's tolerance factor while keeping charge balance in mind. Z. Li, et al., Chem. Mater. 2016, 28, 284. Given the similar ionic radii of Ln.sup.III ions, R. D. Shannon, Acta Crystallogr., Sect. A: Found. Adv. 1976, 32, 751, a large range of alloyed DP NCs should be accessible. To demonstrate this possibility, two representative examples of alloyed Cs.sub.2NaLnCl.sub.6 DP NCs were synthesized.
Cs.sub.2NaCe.sub.0.90Tb.sub.0.09Yb.sub.0.01Cl.sub.6 DP NCs
[0071] Ternary alloys showing emission across the UV, visible, and NIR range are interesting synthetic targets for light emission purposes, for multiplex imaging in biological setups, or for the synthesis of advanced anti-counterfeit materials. [J. Eng, et al., Commun. Biol. 2022, 5, 438] Using the hot injection methodology described for Ln-pure DP NCs, Cs.sub.2NaCe.sub.0.90Tb.sub.0.09Yb.sub.0.01Cl.sub.6 alloyed Ln-DP NCs were successfully synthesized. Under 340 nm excitation, the Cs.sub.2NaCe.sub.0.90Tb.sub.0.09Yb.sub.0.01Cl.sub.6 DP NCs displayed PL peaks from all three Ln components: Ce.sup.III emission at 365 nm, Tb.sup.III emission at 550 nm, and Yb.sup.III emission at 995 nm (
Cs.sub.2NaPr.sub.0.99Ce.sub.0.01Cl.sub.6 DP NCs
[0072] UV-emissive perovskite nanomaterials are exceedingly rare and highly sought after, and such materials hold the potential to be utilized in biomedical settings as disinfecting light sources, (F. Chiappa, et al., J. Hosp. Infect. 2021, 114, 63) or in fabrications of high-energy LEDs as the UV-emissive component. Y. Muramoto, et al., Semicond. Sci. Technol. 2014, 29, 084004. Given our discovery of Cs.sub.2NaCeCl.sub.6 and Cs.sub.2NaPrCl.sub.6 DP NCs capable of emitting in the UV-C and UV-A region, we synthesized Cs.sub.2NaPr.sub.0.99Ce.sub.0.01Cl.sub.6 DP NCs using an appropriate mixture of Ce(OAc).sub.3 and Pr(OAc).sub.3 precursors. The obtained Cs.sub.2NaPr.sub.0.99Ce.sub.0.01Cl.sub.6 DP NCs emit across the UV-C to UV-A, and into the visible blue spectral range, representing the first example of a broad UV-emitting perovskite nanomaterial (
[0073] In summary, we demonstrate the colloidal synthesis of Cs.sub.2NaLnCl.sub.6 (Ln=LaNd, SmYb) Ln-DP NCs using a hot injection approach. The obtained Ln-DP NCs display emissions covering a wide wavelength range from deep UV to NIR. The Cs.sub.2NaPrCl.sub.6 and Cs.sub.2NaCeCl.sub.6 DP NCs display strong UV emission, with the Cs.sub.2NaPrCl.sub.6 DP NCs being the only UV-C emitting halide perovskite nanomaterial known to date. Using the combination of molecular analogs and DFT calculations, a comprehensive understanding of energy levels and electronic transitions in the Cs.sub.2NaLnCl.sub.6 DP systems was achieved. Due to the similar ionic sizes and high miscibility of Ln elements, we have successfully synthesized alloyed Ln-DP NCs simultaneously containing multiple Ln components, which show unique optical properties that are inaccessible by their pure-Ln counterparts. Our study not only provides important fundamental understandings on the Ln-DP materials, but also offers a family of new DP nanomaterials promising for a spectrum of applications ranging from high-energy LEDs and secure anti-counterfeiting paints to biomedical disinfections.
Experimental Procedures
Chemicals
[0074] Cesium carbonate (99.9%), sodium acetate (anhydrous, 99%), cerium acetylacetonate hydrate, cerium acetate hydrate (99.9%), terbium acetate hydrate (99.9%), erbium acetate hydrate (99.9%), thulium acetate hydrate (99.9%), ytterbium acetate tetrahydrate (99.9%), chlorotrimethylsilane (TMS-Cl, 99%), 1-octadecene (ODE, technical grade 90%), oleylamine (OAm, technical grade 70%) and oleic acid (OA, technical grade 90%) were purchased from Aldrich. Lanthanum acetate sesquihydrate (99.9%), praseodymium acetate hydrate (99.9%) and europium acetate hydrate (99.9%) were purchased from Alfa Aesar. Neodymium acetate hydrate (99.9%), samarium acetate hydrate (99.9%), gadolinium acetate tetrahydrate (99.9%), dysprosium acetate hydrate (99.9%) and holmium acetate monohydrate (99.9%) were obtained from Strem Chemicals. Hexane, ethyl acetate and toluene for use in ambient air were obtained from Fisher. Hexane (anhydrous), ethyl acetate (anhydrous) and toluene (anhydrous) used in the glovebox were obtained from Aldrich. All chemicals were used as received without further purification.
Syntheses
[0075] Cs.sub.2NaLaCl.sub.6 Double Perovskite (DP) Nanocrystals (NCs):
[0076] Cesium carbonate (53 mg, 0.16 mmol), sodium acetate (18 mg, 0.22 mmol) and lanthanum acetate sesquihydrate (85 mg, 0.25 mmol) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMS-Cl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-based DP (Ln-DP) NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox.
[0077] Cs.sub.2NaCeCl.sub.6 DP NCs:
[0078] Cesium carbonate (53 mg, 0.16 mmol), sodium acetate (18 mg, 0.22 mmol) and cerium acetylacetonate hydrate (105 mg, 0.25 mmolanhydrous basis) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMS-Cl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-DP NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox. The synthesis can be carried out using an equimolar amount of cerium(III) acetate hydrate instead of cerium(III) acetylacetonate hydrate as well.
[0079] Cs.sub.2NaPrCl.sub.6 DP NCs:
[0080] Cesium carbonate (53 mg, 0.16 mmol), sodium acetate (18 mg, 0.22 mmol) and praseodymium acetate hydrate (85 mg, 0.27 mmol, anhydrous basis) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMS-Cl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-DP NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox.
[0081] Cs.sub.2NaNdCl.sub.6 DP NCs:
[0082] Cesium carbonate (53 mg, 0.16 mmol), sodium acetate (18 mg, 0.22 mmol) and neodymium acetate hydrate (80 mg, 0.25 mmol, anhydrous basis) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMS-Cl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-DP NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox.
[0083] Cs.sub.2NaSmCl.sub.6 DP NCs:
[0084] Cesium carbonate (53 mg, 0.16 mmol), sodium acetate (18 mg, 0.22 mmol) and samarium acetate hydrate (82 mg, 0.25 mmol, anhydrous basis) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMS-Cl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-DP NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox.
[0085] Cs.sub.2NaEuCl.sub.6 DP NCs:
[0086] Cesium carbonate (53 mg, 0.16 mmol), sodium acetate (18 mg, 0.22 mmol) and europium acetate hydrate (82 mg, 0.25 mmol, anhydrous basis) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMS-Cl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-DP NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox.
[0087] Cs.sub.2NaGdCl.sub.6 DP NCs:
[0088] Cesium carbonate (37 mg, 0.11 mmol), sodium acetate (18 mg, 0.22 mmol) and gadolinium acetate tetrahydrate (101 mg, 0.25 mmol) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMS-Cl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-DP NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox.
[0089] Cs.sub.2NaTbCl.sub.6 DP NCs:
[0090] Cesium carbonate (53 mg, 0.16 mmol), sodium acetate (18 mg, 0.22 mmol) and terbium acetate hydrate (84 mg, 0.25 mmol, anhydrous basis) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMS-Cl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-DP NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox.
[0091] Cs.sub.2NaDyCl.sub.6 DP NCs:
[0092] Cesium carbonate (53 mg, 0.16 mmol), sodium acetate (18 mg, 0.22 mmol) and dysprosium acetate hydrate (90 mg, 0.27 mmol, anhydrous basis) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMS-Cl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-DP NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox.
[0093] Cs.sub.2NaHoCl.sub.6 DP NCs:
[0094] Cesium carbonate (37 mg, 0.11 mmol), sodium acetate (18 mg, 0.22 mmol) and holmium acetate monohydrate (90 mg, 0.25 mmol) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMS-Cl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-DP NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox.
[0095] Cs.sub.2NaErCl.sub.6 DP NCs:
[0096] Cesium carbonate (53 mg, 0.16 mmol), sodium acetate (18 mg, 0.22 mmol) and erbium acetate hydrate (86 mg, 0.25 mmol, anhydrous basis) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMS-Cl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-DP NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox.
[0097] Cs.sub.2NaTmCl.sub.6 DP NCs:
[0098] Cesium carbonate (53 mg, 0.16 mmol), sodium acetate (18 mg, 0.22 mmol) and thulium acetate hydrate (86 mg, 0.25 mmol, anhydrous basis) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMS-Cl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-DP NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox.
[0099] Cs.sub.2NaYbCl.sub.6 DP NCs:
[0100] Cesium carbonate (53 mg, 0.16 mmol), sodium acetate (18 mg, 0.22 mmol) and ytterbium acetate tetrahydrate (105 mg, 0.25 mmol) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMSCl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-DP NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox.
[0101] Cs.sub.2NaPr.sub.0.99Ce.sub.0.01Cl.sub.6 DP NCs:
[0102] Cesium carbonate (53 mg, 0.16 mmol), sodium acetate (18 mg, 0.22 mmol) cerium acetate hydrate (1.5 mg, 4 mol, anhydrous basis), praseodymium acetate hydrate (80 mg, 0.25 mmol, anhydrous basis) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMS-Cl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-DP NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox.
[0103] Cs2NaCe0.90Tb0.09Yb0.01Cl.sub.6 DP NCs: Cesium carbonate (53 mg, 0.16 mmol), sodium acetate (18 mg, 0.22 mmol) cerium acetate hydrate (75 mg, 0.22 mmolanhydrous basis), terbium acetate hydrate (9 mg, 30 mol, anhydrous basis) and ytterbium acetate tetrahydrate (1.5 mg, 4 mol) were added to ODE (5.0 mL). To this suspension, OA (1.25 mL) and OAm (330 L) were added with stirring. The mixture was degassed under vacuum at 110 C. for one hour, after which the mixture was heated to 180 C. under nitrogen. TMS-Cl (200 L, 1.58 mmol) was injected at once and the temperature was kept between 180 C.2 C. for two minutes. The reaction was then quenched with ice water and the particles were isolated by centrifugation at 6000 RPM for 10 minutes, discarding the liquid phase. The obtained Ln-DP NC solids were redispersed in hexane (4 mL) and the suspension was centrifuged at 7000 RPM for 5 minutes. The precipitates were discarded, and ethyl acetate (10 mL) was added to the liquid phase. The mixture was then centrifuged again at 7000 RPM for 10 minutes, followed by discarding the supernatant. The precipitated DP NCs were then dispersed in hexane (3 mL) and the suspension was centrifuged one final time at 7000 RPM for 5 minutes, followed by discarding the precipitates. The resulting NC hexane suspension can be stored under dry air protection or inside a glovebox. Cs.sub.2NaCe.sub.0.99Yb.sub.0.01Cl.sub.6 DP NCs were synthesized using the same procedure by adjusting the molar ratio of Ce to Yb in the starting mixture appropriately.
[0104] NC Storage
[0105] While Ln-DP NCs were found to be stable towards oxygen, some moisture-sensitivity was noted. For storage, Ln-DP NC suspensions in hexane were added to glass vials, which were sealed under a gentle flow of dry compressed air or nitrogen. The particles can be stored this way for at least 4 weeks in air. Alternatively, the particle suspensions can be stored under inert conditions inside a drybox for extended periods of time.
[0106] Ultraviolet-Visible (UV-Vis) Absorption Spectroscopy Measurements
[0107] Absorption spectra were collected using an Agilent Cary 8454 UV-Vis Spectrometer. Samples were dispersed in hexane for the measurement and spectra were collected in ambient air. f-f absorption spectra of Cs.sub.2NaYbCl.sub.6 DP NCs were collected using a Varian Cary 50 Bio spectrometer.
[0108] Photoluminescence (PL), PL Excitation (PLE) Spectroscopy and PL Quantum Yield (PLOY) Measurements
[0109] PL and PLE spectra were measured using an Edinburgh Instruments FS5 Spectrofluorometer. NCs were dispersed in hexane and PL spectra were collected while irradiating the samples at the first absorption peak wavelength. All PLE measurements were carried out monitoring PL intensity at the PL peak wavelengths. PLQYs were determined using a built-in integrating sphere on the Edinburgh Instruments FS5 Spectrofluorometer. The detectors used for measuring the PL include a visible range signal detector (a UV enhanced silicon photodiode) with spectral coverage from 200 nm to 870 nm and a NIR signal detector (a thermoelectric cooled InGaAs photodiode) with spectral coverage from 850 nm to 1650 nm. The full PL spectra were obtained by connecting two spectra collected by the visible signal detector and NIR signal detector with a scaling factor using CuInS2/ZnS core/shell nanocrystal (emitting at 880 nm with a peak width of 170 nm) solution as a calibration sample for the responsivity of the two detectors under the same measurement conditions. All measurements were collected in ambient air.
[0110] X-Ray Diffraction (XRD) Measurements
[0111] Powder XRD patterns were obtained on a Bruker D8 Discovery 2D X-ray Diffractometer equipped with a Vantec 500 2D area detector working on Cu K radiation. NC samples were drop-cast on a glass slide inside the glovebox followed by slow evaporation of the solvent. The glass slides were then sealed in air-tight containers under nitrogen and the samples were transported to the XRD machine. The XRD spectra were collected in air over the course of 10 minutes to avoid absorption of moisture.
[0112] Transmission Electron Microscopy (TEM) and High-Resolution TEM (HR-TEM) Measurements
[0113] TEM measurements were carried out using a JEOL-2100F TEM operating at 200 kV. Samples were drop-cast on a 300-mesh TEM grid and allowed to dry under nitrogen inside the glovebox. The grids were then sealed in air-tight containers under nitrogen and the samples were transported to the electron microscope. The grids were quickly mounted in air to minimize moisture exposure.
[0114] X-Ray Photoelectron Spectroscopy (XPS) Measurements
[0115] XPS spectra were measured on a Thermo Scientific KAlpha+ instrument operating on Al K.sub.=1486.6 eV radiation with a spot size of 400 m. Samples dispersions were drop-casted on silicon wafers and allowed to evaporate with gentle heating. The samples were transported to the XPS machine under vacuum using a Thermo Scientific 831-57-100-2 vacuum transfer vessel. All XPS spectra were calibrated by setting the adventitious carbon is signal to 284.8 eV. Samples were ion etched using Ar+ ions for 30 seconds before data collection unless otherwise indicated.
[0116] The complete disclosure of all patents, patent applications, and publications, and electronically available materials cited herein are incorporated by reference. The foregoing detailed description and examples have been given for clarity of understanding only. No unnecessary limitations are to be understood therefrom. The invention is not limited to the exact details shown and described, for variations obvious to one skilled in the art will be included within the invention defined by the claims.