METHOD FOR PRODUCING III-N MATERIAL-BASED VERTICAL COMPONENTS
20240047201 ยท 2024-02-08
Assignee
- Commissariat A L'energie Atomique Et Aux Energies Alternatives (Paris, FR)
- Centre National De La Recherche Scientifique (Paris, FR)
Inventors
- Guy FEUILLET (Grenoble Cedex 09, FR)
- Thierry BOUCHET (Grenoble Cedex 09, FR)
- Matthew CHARLES (Grenoble Cedex 09, FR)
- Roy DAGHER (Nice, FR)
- Jesus ZUNIGA PEREZ (Biot, FR)
Cpc classification
H01L21/8252
ELECTRICITY
H01L29/66522
ELECTRICITY
H01L21/7806
ELECTRICITY
H01L29/66734
ELECTRICITY
International classification
H01L21/02
ELECTRICITY
H01L21/78
ELECTRICITY
H01L29/66
ELECTRICITY
H01L21/8252
ELECTRICITY
H01L27/08
ELECTRICITY
Abstract
A method for producing a vertical component comprising with the basis of a III-N material, comprising providing platelets made of the III-N material obtained by epitaxy on pads, the platelets comprise at least first and second layers doped and stacked on one another in a vertical direction. The method further includes the production of a first electrode and the production of a second electrode located on the platelet and configured such that a current passing from one electrode to the other passes through at least the second layer in all of its thickness, the thickness being taken in the vertical direction.
Claims
1. A method for producing a vertical microelectronic component comprising at least one layer with a basis of a III-N material, the method comprising: providing a stack comprising a plurality of pads extending from a base substrate, the pads being distributed over the base substrate so as to form several pad assemblies, at least some of the pads of the assembly comprising at least: one top intended to form a germination layer, one crystalline section, and one creeping section, formed of a material having a vitreous transition temperature the crystalline section surmounting the creeping section, epitaxially growing a crystallite made of the III-N material on at least some of tops of said pads and continuing the epitaxial growth of the crystallites until coalescence of the crystallites carried by the adjacent pads of one same assembly, so as to form on each assembly, a platelet made of the III-N material, and interrupting the epitaxial growth of the crystallites before those crystallites belonging to two distinct assemblies coalesce, such that the platelets of each assembly are distant from one another, wherein the method further comprises doping the III-N material of the platelets such that at least some of the platelets comprise at least: one first layer with the basis of the III-N material and which has a first doping taken from among the n+, n and p doping types, and one second layer with the basis of the III-N material and which has a second doping taken from among the n+, n and p doping types, the types of the first and second dopings being different, the first and second layers are stacked in the platelet, in a vertical direction, between a first face and a second face of the platelet, and the method further comprises producing a first electrode and a second electrode located on the platelet and configured such that a current passing from one electrode to the other passes through at least the second layer in a whole thickness, the thickness being taken in said vertical direction.
2. The method according to the preceding claim 1, wherein the electrodes are configured such that a current passing from one electrode to the other also passes through the first layer in all of a thickness of the first layer, the first and second layers being located between the first electrode and the second electrode.
3. The method according to the preceding claim 1, wherein one from among the first electrode and the second electrode is located on the first face of the platelet and the other from among the first electrode and the second electrode is located on the second face of the platelet.
4. The method according to claim 1, wherein one from among the first and the second electrodes is located on the first face of the platelet and the other from among the first and the second electrodes extends, in the vertical direction, from the first face and to the first layer by passing through the second layer.
5-8. (canceled)
9. The method according to claim 1, wherein said platelets only comprise said first layer and said second layer, the component preferably forming a Schottky type diode.
10. The method according to claim 1, wherein said platelets comprise said first layer, said second layer, and a third layer surmounting the second layer and having a p type doping, positioned such that the second layer is located between the first and third layers, the component forming a p-i-n type diode or a transistor.
11. The method according to claim 1, wherein the platelets only comprise said first layer, said second layer, and said third layer, the component forming a p-i-n type diode.
12. The method according to claim 10, wherein the platelets comprise said first layer, said second layer, said third layer, as well as at least one fourth layer surmounting the third layer and having an n+ type doping, the component forming a transistor.
13-14. (canceled)
15. The method according to claim 12, wherein: during the growth of the third layer, a first lateral portion epitaxially grows on the flanks of the second layer, and during the growth of the fourth layer, a second lateral portion epitaxially grows on the flanks of the second layer and on the first lateral portion, the growth and the doping level of the third layer and of the fourth layer being controlled, such that the first and second lateral portions form an electrically insulating barrier.
16. The method according to claim 1, wherein the method further comprises removing the pads.
17. The method according to claim 16, wherein the step of removing the pads is performed before the production of the first electrode and before the production of the second electrode.
18. The method according to claim 16, wherein the step of removing the pads is performed after the production of the first electrode and before the production of the second electrode.
19. The method according to claim 1, wherein the pads are preserved after the production of the first electrode and after the production of the second electrode.
20. The method according to claim 1, wherein the method further comprises, after the production of a platelet on each pad assembly, the second face being rotated facing the pads: fixing a handling substrate on the stack, such that the platelets and the pads are located between the base substrate and the handling substrate, removing the base substrate, making the second face of the platelets accessible, which comprises the removal of the pads, forming the second electrode on the second face, the second electrode preferably being a conductive substrate mounted on the second face, making at least a portion of the first face of the platelets accessible, and forming the first electrode on the first face.
21. The method according to claim 1, wherein the method further comprises, before the fixing of a handling substrate, the production of an encapsulation layer encapsulating the platelets and covering the first face.
22. The method according to claim 20, wherein the method comprises, after the removal of the pads, the production of an encapsulation layer encapsulating the platelets and covering the first face, the first electrode being formed through the encapsulation layer.
23. The method according to claim 20, wherein the making at least a portion of the first face of the platelets accessible, comprises fully stripping the first face of the platelets.
24. The method according to claim 20, wherein the first electrode is formed so as to not cover a central zone of the first face intended to receive an electrode forming a transistor gate, and to extend over a peripheral zone surrounding the central zone.
25. (canceled)
26. The method according to claim 1, wherein the method further comprises, after the production of a platelet on each pad assembly, the second face being rotated facing the pads: producing at least one opening for each platelet through the base substrate and the pads so as to make at least some of the second face of the platelets accessible, by preserving certain pads, forming the second electrode on the second face, by filling said opening by an electrically conductive material, and before or after the production of the at least one opening, forming the first electrode on the first face.
27. The method according to claim 1, wherein the method further comprises, after the production of a platelet on each pad assembly, the second face being rotated facing the pads: producing at least one hole for each platelet, the hole extending from the first face and at least to the first layer, forming the second electrode by filling the hole with an electrically conductive material, and forming the first electrode on the first face.
28-30. (canceled)
Description
BRIEF DESCRIPTION OF THE FIGURES
[0048] The aims, objectives, as well as the features and advantages of the invention will best emerge from the detailed description of an embodiment of the latter which is illustrated by the following accompanying drawings, wherein:
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[0062] The figures are given as examples and are not limiting of the invention. They are principle schematic representations intended to facilitate the understanding of the invention and are not therefore necessarily to the same scale as practical applications. In particular, the relative thicknesses of the different layers, sections, crystallites and platelets are not representative of reality.
DETAILED DESCRIPTION OF THE INVENTION
[0063] Before starting a detailed review of embodiments of the invention, optional features are stated below, which can optionally be used in association or alternatively:
[0064] According to an example, the first layer has a thickness e.sub.551 of between 1 and 5 m (10.sup.6 metres), preferably of between 1 and 3 m, preferably around 2 m. According to an example, the first layer extends from one flank to the other of the platelet. The first layer extends over the whole surface of the platelet. The surface of the platelet is projected over a parallel plane (plane xy), wherein the upper face of the substrate mainly extends.
[0065] According to an example, the first layer has a doping level greater than or equal to 5.10.sup.17 atoms per cubic centimetre (at/cm.sup.3). The first layer has a doping level, preferably of around 5.10.sup.18 at/cm.sup.3.
[0066] According to an example, the first layer has an n+ type doping. This makes it possible to ensure a good quality electrical conduction with the second electrode.
[0067] According to an example, the second layer extends from one flank to the other of the platelet. The second layer extends over the whole surface of the platelet. The surface of the platelet is projected over a parallel plane (plane xy), wherein the upper face of the substrate mainly extends.
[0068] According to an example, the second layer has a thickness e.sub.552 of at least 8 m (10.sup.6 metres) and preferably of at least 10 m.
[0069] According to an example, the second layer has a doping level greater than or equal to 1.10.sup.15 at/cm.sup.3. The second layer has a doping level, preferably of around 1.10.sup.16 at/cm.sup.3. According to an example, the second layer has an n type doping.
[0070] According to an example, the step of doping the III-N material of the platelets is carried out during the formation step, on each assembly, of a platelet by epitaxial growth.
[0071] According to an example, the electrodes are configured such that a current passing from one electrode to the other also passes through the first layer in all of its thickness. According to an example, the first and second layers are located between the first electrode and the second electrode. Thus, one from among the first and the to second electrodes is located on the first face of the platelet and the other, from among the first and the second electrodes is located on the second face of the platelet. This makes it possible that the current passing from one electrode to the other passes through the whole thickness of the first and second layers, which considerably improves the performance of the device.
[0072] According to an example, one from among the first and the second electrodes is located on the first face of the platelet, and the other from among the first and the second electrodes extends, in the vertical direction, from the first face and to the first layer by passing through the second layer.
[0073] According to an example, the platelets only comprise the following layers: said first layer and said second layer, the component preferably forming a Schottky-type diode.
[0074] According to an example, the platelets comprise the following layers: said first layer, said second layer, and a third layer surmounting the second layer and preferably having a p type doping, positioned such that the second layer is located between the first and third layers, the component preferably forming a p-i-n type diode or a transistor.
[0075] According to an example, the third layer has a thickness of at least 100 nm (10.sup.9 metres) and preferably of less than 1 m. Preferably, the thickness is of between 300 and 700 nm.
[0076] According to an example, the third layer has a chemical doping level greater than or equal to 5.10.sup.17 at/cm.sup.3.
[0077] According to an example, the third layer has a doping level, preferably of around 1.10.sup.18 at/cm.sup.3.
[0078] According to an example, the third layer has a p type doping.
[0079] According to an example, the platelets only comprise the following layers: said first layer, said second layer, and said third layer, the component preferably forming a p-i-n type diode.
[0080] According to an example, the platelets comprise the following layers: said first layer, said second layer, said third layer, as well as at least one fourth layer surmounting the third layer and preferably having an n+ type doping, the component preferably forming a transistor.
[0081] According to an example, the first electrode forms a source for the transistors, the second electrode forms a drain for the transistors.
[0082] According to an example, the method also comprises a step of producing a gate for the transistor.
[0083] According to an example, the fourth layer 554 has a thickness of at least 50 nm. Preferably, the thickness of the fourth layer is between 50 and 200 nm, and preferably around 100 nm.
[0084] According to an example, the fourth layer has a doping level greater than or equal to 5.10.sup.17 at/cm.sup.3. According to an example, the fourth layer has a doping level, preferably around 5.10.sup.18 at/cm.sup.3. According to an example, the second layer has an n+ type doping. This makes it possible to ensure a good quality electrical conduction with the first electrode. The fourth layer forms an Ohmic contact with the first layer.
[0085] According to an example, during the growth of the third layer, a first lateral portion epitaxially grows on flanks of the second layer. During the growth of the fourth layer, a second lateral portion epitaxially grows on the flanks of the second layer and on the first lateral portion. The growth and the doping level of the third layer and of the fourth layer are controlled, such that the first and second lateral portions form an electrically insulating barrier. This electrically insulating barrier is obtained by depletion, i.e. that they no longer comprise or only comprise very few free carriers. They thus form depleted layers.
[0086] According to an example, the method comprises at least one pad removal step.
[0087] According to an example, the at least one pad removal step is carried out before the production of the first electrode and before the production of the second electrode.
[0088] According to an example, the at least one pad removal step is carried out after the production of the first electrode and before the production of the second electrode.
[0089] According to another embodiment, the pads are preserved after the production of the first electrode and after the production of the second electrode.
[0090] According to an example, the method comprises, after the production of a platelet on each pad assembly, the second face being rotated facing the pads: [0091] Fixing a handling substrate on the stack, such that the platelets and the pads are located between the base substrate and the handling substrate, [0092] Removing the base substrate, [0093] Making the second face of the platelets accessible, which comprises the removal of pads, [0094] Forming the second electrode on the second face, the second electrode preferably being a conductive substrate mounted on the second face, [0095] Making at least some of the first face of the platelets accessible, [0096] Forming the first electrode on the first face.
[0097] According to an example, the method comprises, before the fixing of a handling substrate, the production of an encapsulation layer encapsulating the platelets and covering the first face.
[0098] According to an example, the method comprises, after the removal of pads, the production of an encapsulation layer encapsulating the platelets and covering the first face, the first electrode being formed through the encapsulation layer.
[0099] According to an example, making at least some of the first face of the platelets accessible, comprising completely stripping the first face of the platelets.
[0100] According to an example, the first electrode is formed so as to not cover a central zone 1 of the first face, for example intended to receive an electrode forming a transistor gate, and to extend over a peripheral zone surrounding the central zone 1.
[0101] According to an example, making at least some of the first face of the platelets accessible, comprising removing some of the encapsulation layer so as to create in the encapsulation layer, an opening making only some of the first face of the platelets accessible, the first electrode being formed through said opening.
[0102] According to an example, the method comprises, after the production of a platelet on each pad assembly, the second face B being rotated facing the pads: [0103] Producing at least one opening for each platelet through the base substrate and the pads so as to make at least some of the second face of the platelets accessible, optionally by preserving certain pads, [0104] Forming the second electrode on the second face, through said opening. [0105] Before or after the production of the at least one opening, forming the first electrode on the first face.
[0106] According to an example, the method comprises, after the production of a platelet on each pad assembly, the second face B being rotated facing the pads: [0107] Producing at least one hole for each platelet, the hole extending from the first face and at least to the first layer, [0108] Forming the second electrode by filling the hole with an electrically conductive material, [0109] Forming the first electrode on the first face.
[0110] According to an example, the epitaxial growth is carried out at a temperature T.sub.epitaxy, such that:
T.sub.epitaxyk1T.sub.vitreous transition, with k10.8.
[0111] According to an example, the III-N material is a nitride of at least one from among gallium (Ga), indium (In) and aluminium (Al).
[0112] According to an example, the III-N material is GaN-based, preferably the III-N material is GaN.
[0113] According to an example, each of these III-N material layers has a lower face and an upper face, substantially parallel to an upper face of the substrate. Each layer forms a platelet. All the lower faces of the layers are substantially comprised in one same plane. The same applies for the upper faces.
[0114] According to an example, the creeping layer is made of a viscous material. It has a viscoplastic transition. Preferably, this material is taken from among: [0115] a silicon oxide SixOy, x and y being integers, and preferably the creeping layer is made of SiO.sub.2, [0116] a glass, [0117] a glass made of borosilicate, [0118] a glass made of borophosphosilicate (BPSG).
[0119] According to an example, the epitaxial growth being carried out at a temperature T.sub.epitaxy, such that: T.sub.epitaxyk1T.sub.vitreous transition, with k10.8.
[0120] Optionally, the epitaxial growth is carried out at a temperature T.sub.epitaxy, such that: T.sub.epitaxyk1T.sub.vitreous transition, with k10.8.
[0121] According to an example, k1=1, and preferably k1=1.5. According to an example of an embodiment, k1=0.87 or k1=0.9. According to a particularly advantageous example, k1=0.92. Thus, in the case where the creeping sections are formed of SiO.sub.2, T.sub.epitaxy1104 C., T.sub.vitreous transition for SiO.sub.2 equal to 1200 C. According to an example of an even more preferable embodiment, k1=0.95. According to an example of an even more preferable embodiment, k1=1, and preferably k1=1.5.
[0122] According to an example, T.sub.epitaxyk2T.sub.min melting, T.sub.min melting being the lowest melting temperature from among the melting temperatures of the sections forming the pad, with k20.9 and preferably k20.8. According to an example of an embodiment, k2=0.9. This makes it possible to avoid a diffusion of the species of the material, the melting temperature of which is the lowest. Thus, in the case where the pad is formed of SiO.sub.2 creeping sections and of silicon crystalline sections, T.sub.epitaxy1296 C. Indeed, T.sub.min melting is equal to the melting temperature of silicon, since the melting temperature of silicon is equal to 1440 and the melting temperature of SiO.sub.2 is equal to 1970 C. Preferably, k2=0.8.
[0123] According to an example, the platelets have, projecting into a main extension plane parallel to the main faces of the platelets, i.e. parallel to an upper face of the substrate, i.e. parallel to the plane xy of the system xyz illustrated in
[0124] In the embodiment, wherein the pads are distributed over the substrate, so as to form a plurality of pad assemblies and that the epitaxial growth step is interrupted before crystallites belonging to two distinct assemblies coalesce, such that the layer formed on each assembly forms a platelet, the platelets being distant from one another, the method can have at least any one of the following features and steps which can be combined or taken separately:
[0125] According to an example, the distance D (D1 or D2) separating two adjacent pads of one same assembly, for example the tops of these two pads, is less than the distance W1 separating two adjacent pads belonging to two different assemblies. W1>D and preferably W12D.
[0126] According to an example, W1k4D, with k4=1.5, preferably k4=2. This makes it possible to have smaller size platelets and a significant integration density in the case of the production of transistors. Preferably, k4=5. W1 can be equal to 1.5 microns.
[0127] W2 being the distance separating two adjacent platelets (see W2 in
[0130] According to an example, each pad has a cross-section, the maximum dimension d.sub.pad of which is between 10 and 500 nm (10.sup.9 metres), the maximum dimension d.sub.pad being measured in a plane parallel to a plane (xy), wherein an upper face of the substrate mainly extends, preferably 20 nmd.sub.pad200 nm and preferably 50 nmd.sub.pad100 nm. d.sub.pad=d.sub.R or d.sub.S.
[0131] According to an example, each pad has a distinct continuous contour of the pad which itself is adjacent.
[0132] According to an example, each pad has a constant cross-section over all of its height H.sub.pad. Thus, the top of the pad has a cross-section which is identical or substantially identical to its base.
[0133] According to an example, each platelet has a cross-section, the maximum dimension d.sub.platelet of which is between 0.5 and 20 m (10.sup.6 metres), the maximum dimension d.sub.platelet being measured in a plane parallel to a plane (xy), wherein an upper face of the substrate mainly extends, preferably 0.8 md.sub.platelet3 m and preferably 1 md.sub.platelet2 m. The maximum dimension d.sub.platelet thus corresponds to the maximum dimension of a projection of the platelet into a plane parallel to the plane xy, wherein the upper face of the substrate mainly extends.
[0134] Alternatively, the pads of one same assembly are distributed over the non-periodic substrate. Optionally, but advantageously, the platelets are distributed over the substrate periodically.
[0135] According to an example, the pads comprise at least one buffer layer surmounting the crystalline section, and made of a material different from that of the nitride platelets. According to this example, the nitride platelets are made of gallium nitride (GaN) and the buffer layer is made of aluminium nitride (AlN). This makes it possible, to avoid the appearance of the phenomenon of melt-back etching, generated by very high reactivity between gallium and silicon.
[0136] According to an example, the buffer layer is formed by an epitaxial deposition above the crystalline section, before the step of forming pads by etching. Thus, the stack comprises, before the step of epitaxially growing nitride platelets, at least said buffer layer. The action of forming the plurality of pads by etching after the formation of the buffer layer above the crystalline layer, makes it possible to avoid that the buffer layer is not deposited between the pads, typically on the bottom of the creeping layer or is not deposited on the walls of the sections formed by the crystalline layer, which would have been the case if this step of forming the buffer layer had been carried out after etching of the stack to form the pads. Thus, the epitaxial growth of the nitride platelets from the creeping layer is avoided. Naturally, this advantage is observed when the growth of the nitride layer intended to form each platelet is carried out by selective epitaxy. This growth is indeed carried out on the material of the buffer layer, but is not carried out on the material of the creeping sections. Such is the case when the latter are made of SiO.sub.2, the buffer layer is made of AlN and the nitride platelet formed by epitaxy, for example according to an MOVPE technique (Metalorganic Vapour Phase Epitaxy), is GaN. Thus, the latter is not deposited at the foot of the pads.
[0137] According to an example, the pads comprise, before the step of epitaxially growing the nitride platelets, at least one primer layer, surmounting said buffer layer and made of gallium nitride (GaN).
[0138] According to an example, the stack comprises, before said step of forming pads by etching, at least one primer layer, surmounting the crystalline section, the primer layer being made of the same material as that of the nitride platelets. Thus, in an embodiment wherein the nitride platelets are made of GaN, the primer layer is also made of GaN. Advantageously, this primer layer makes it possible to facilitate the resumption of the epitaxial growth for the formation of crystallites. This feature is all the more advantageous than the surface area of the pads is small.
[0139] According to an example, each pad has an upper face and the epitaxial growth of the crystallites is carried out at least partially and preferably only from said upper face. Preferably, the buffer layer is disposed directly in contact with the upper face of the crystalline section or in contact with the upper face of the section formed by the primer layer.
[0140] If the top of the pad, i.e. the upper face of the uncovered pad, is formed by the crystalline section, then the crystallites are epitaxially grown directly in contact with the crystalline layer. If the top of the pad is formed by the primer layer, then the crystallites are epitaxially grown directly in contact with the damper layer. If the top of the pad is formed by the buffer layer, then the crystallites are epitaxially grown directly in contact with the buffer layer. Preferably, the damper layer is disposed directly in contact with the upper face of the crystalline section.
[0141] According to an example, at least one from among the buffer layer and the primer layer preserves a constant thickness during the epitaxial growth step.
[0142] According to an example, providing said stack comprises providing a developed substrate of the silicon-on-insulator (SOI) type comprising a base substrate surmounted successively on an oxide layer forming said creeping layer and a semiconductive layer forming said crystalline layer.
[0143] According to an example, the creeping section has a height e.sub.220 such that e.sub.2200.1d.sub.pad, d.sub.pad being the diameter of the pad, or more generally, the edge-to-edge distance of the pad taken, at the creeping section and in a direction parallel to a plane (xy) wherein an upper face of the substrate mainly extends, preferably e.sub.2201d.sub.pad. These values, make it possible to obtain a sufficient deformation to reduce the stresses at the grain boundary.
[0144] According to an example, the pads have a height H.sub.pad, and wherein two adjacent pads are distant by a distance D, such that: H.sub.pad/D<2 and preferably H.sub.pad/D1. This distance D can be taken at the tops of the adjacent pads.
[0145] According to an example, the crystalline section is silicon-based and preferably, the crystalline section is made of silicon.
[0146] The crystalline section can also be with the basis of materials other than Si and which enable the epitaxy of nitride materials. For example, the crystalline section can be SiC- or Al.sub.2O.sub.3-based. These materials are further usable in SiCOI form (SiC-on-Insulator) or SOS form (Silicon-on-Sapphire).
[0147] According to an example of an embodiment, the crystalline layer having served to form the crystalline section is a monocrystalline layer.
[0148] According to an example of an embodiment, the creeping layer is in direct contact with the substrate. The creeping layer is in direct contact with the crystalline section. According to an example of an embodiment, the nitride layer forming each platelet which is produced by coalescence of crystallites is in direct contact with the crystalline section. According to another embodiment, at least one intermediate layer is provided between the crystalline section and the nitride layer, which is produced by coalescence of crystallites and which forms a platelet. This intermediate layer typically forms the buffer layer.
[0149] Thus, the creeping layer and the crystalline layer are different. The creeping layer has a vitreous transition temperature. It is therefore made of a vitreous transition material and has the behaviour of vitreous transition materials. Thus, the creeping layer is not crystalline. It is made of a viscous or vitreous material, for example, of an oxide. The creeping layer and the crystalline layer are not made of the same material.
[0150] According to an example of an embodiment, the creeping layer has a thickness e.sub.220 less than 500 nm (10.sup.9 metres). It is preferably of between 50 nm and 500 nm, and preferably between 100 nm and 150 nm.
[0151] According to an example of an embodiment, the crystalline layer has a thickness of between 2 nm (10.sup.9 metres) and 10 m (10.sup.6 metres) and preferably between 5 nm and 500 nm, and preferably between 10 nm and 50 nm.
[0152] According to an example of an embodiment, crystals are epitaxially grown on all the pads.
[0153] According to an example of an embodiment, the V/III ratio of the flows in the deposition reactor by epitaxy (the flows being, for example, measured in sccm) of said material comprising nitride (N) and at least one from among gallium (Ga), indium (In) and aluminium (Al) is around 2000.
[0154] According to an example of an embodiment, the nitride of the platelets is a gallium nitride (GaN). According to another embodiment, the nitride of the platelets is gallium nitride (GaN)-based, and further comprises aluminium (Al) and/or indium (In).
[0155] According to another embodiment, the material forming the nitride (N) of the platelets is any one from among: gallium nitride (GaN), indium nitride (InN), aluminium nitride (AlN), aluminium gallium nitride (AlGaN), indium gallium nitride (InGaN), aluminium gallium indium nitride (AlGalnN), aluminium indium nitride (AlInN), aluminium indium gallium nitride (AlInGaN).
[0156] According to an example, the step of forming pads comprises the etching of the crystalline layer and the etching of only one portion of the creeping layer, so as to preserve a portion of the creeping layer between the pads.
[0157] According to an example, the step of forming pads is carried out, such that d.sub.crystallite/d.sub.padk3, with k3=3, d.sub.pad being the maximum dimension of the cross-section of the pad taken in a direction parallel to a plane (xy), wherein an upper face of the substrate mainly extends (pad or more generally, the edge-to-edge distance of the pad, i.e. the maximum dimension of the pad, whatever the shape of its cross-section), d.sub.crystallite corresponding to the dimension of the crystallite measured in the same direction as d.sub.pad at the time of coalescence of the crystallites.
[0158] Particularly effective results have been obtained for k3=3. According to an example, 100k33. Preferably, 50k33. Preferably, 5k33.
[0159] This feature makes it possible for the creeping sections to be deformed to particularly effectively take the mechanical stresses which occur when two adjacent crystallites start to coalesce. Thus, this feature effectively contributes to reducing the density of defects within the nitride platelets that are ultimately obtained.
[0160] Preferably, P.sub.pad/d.sub.pad4, and preferably P.sub.pad/d.sub.pad5. According to an example which gives particularly qualitative results, P.sub.pad/d.sub.pad=5.
[0161] In the description below, the terms crystals and crystallites will be considered as equivalent.
[0162] It is specified that in the scope of the present invention, the terms on, surmounts, covers or underlying or their equivalents, do not mean in contact with. Thus, for example, the deposition of a first layer on a second layer does not compulsorily mean that the two layers are directly in contact with one another, but this means that the first layer covers at least partially the second layer by being either directly in contact with it, or by being separated from it by at least one other layer or at least one other element, including air.
[0163] The steps of forming different layers and regions are meant in the broad sense: they can be made up of several substeps which are not necessarily strictly successive.
[0164] The terms substantially, about, around, mean within 10%, preferably within 5%.
[0165] Several embodiments of the invention implementing successive steps of the manufacturing method are described below. Unless explicitly mentioned otherwise, the adjective successive does not necessarily imply, even if this is generally preferred, that the steps immediately follow one another, intermediate steps being able to separate them.
[0166] Moreover, the term step means the embodiment of some of the method, and can mean a set of substeps.
[0167] Moreover, the term step does not compulsorily mean that the actions carried out during a step are simultaneous or immediately successive. Certain actions of a first step can, in particular, be followed by actions linked to a different step, and other actions of the first step can then be resumed. Thus, the term step does not necessarily mean single and inseparable actions over time and in the sequence of phases of the method.
[0168] The terms insulator or dielectric qualifies a material, the electrical conductivity of which is sufficiently low in the given application to serve as an insulator. In the present invention, a dielectric material preferably has a dielectric constant less than 7. The spacers are typically formed of a dielectric material.
[0169] Materials
[0170] By a substrate, a layer, a device with the basis of a material M, this means a substrate, a layer, a device comprising this material M only or this material M and optionally other materials, for example alloy elements, impurities or doping elements.
[0171] Thus, a nitride-based layer can be a layer made only of this nitride or be made of a nitride added with other species or dopants.
[0172] For example, a nitride layer or structure made at least partially of a nitride (N) obtained from at least one from among gallium (Ga), indium (In) and aluminium (Al), can be a GaN-, InN-, AlN-, InGaN-, AlGaN-, AlInN-based layer or a structure.
[0173] Thickness and Orientation of the Figures
[0174] It is specified that in the scope of the present invention, the thickness of a layer or of the substrate is measured in a direction perpendicular to the surface according to which this layer or this substrate has its maximum extension. In the figures, the thickness of the horizontal layers is taken along the vertical, i.e. along the axis z of the system illustrated in
[0175] When it is indicated that an element is located to the right of another element, this means that these two elements are both located on one same line perpendicular to the main plane of the substrate, that is on one same line oriented vertically in the figures.
[0176] In the description below, unless indicated on the contrary, when reference is made to absolute position qualificatives, such as the terms front, rear, top, bottom, left, right, etc. or relative, such as the terms above, below, upper, lower, etc. or to orientation qualificatives, such as the terms horizontal, vertical, lateral, etc., reference is made to the orientation of the corresponding figures, being understood that, in practice, the devices and assemblies described can be oriented differently.
[0177] Doping
[0178] In the present invention, doping types will be indicated. These dopings are non-limiting examples. The invention covers all the embodiments, wherein the dopings are reversed. Thus, if an example of an embodiment mentions for a first zone, a p type doping and for a second zone, an n type doping, the present description thus describes, implicitly at least, the opposite example wherein the first zone has an n type doping and the second zone, a p type doping.
[0179] Conventionally, an n+ doping means that this is an n type doping (doping by negative charges), and the content of doping species of which is greater than or equal to 1 atom of the doping species for less than 1000 atoms of semiconductive and preferably for less than 10 to 100 atoms of the material forming the semiconductive layer. Likewise, a doping referenced p+ means that this is a p type doping (doping by positive charges) and the content of doping species of which is greater than or equal to 1 atom of the doping species for less than 1000 atoms of the semiconductor and preferably for less than 10 to 100 atoms of the material forming the semiconductive layer.
[0180] In the present patent application, a doping referenced n includes all the dopings by negative charge carriers, whatever the content of the doping. Thus, an n doping comprises the n+ doping contents and the n doping contents less than the n+ type doping. Likewise, a doping referenced p includes all the dopings by positive charge carriers, whatever the content of the doping. Thus, a p doping comprises the p+ doping contents and the p doping contents less than the p+ type doping.
[0181] An electrode is configured to produce an Ohmic contact with the layer with which it is in contact. An electrode can, for example, be one from among a source, a drain, a gate of a transistor. The first electrode forms an anode. The second electrode forms the cathode.
[0182] In order to describe in detail, examples of implementation of the invention: [0183] an example of a method for producing platelets (also called vignettes or discs) will be described in reference to
[0185] An example of a method for forming platelets made of III-N material will now be described in reference to
[0186] As illustrated in
[0187] According to an example of an embodiment, the base substrate 100 is silicon-based, amorphous or crystalline. It ensures the mechanical strength of the stack.
[0188] The crystalline layer 300 has a lower face facing the creeping layer 200 and an upper face, the function of which is to serve as a base layer to grow nitride platelets 550, 550. For example, the layer which is ultimately sought to be obtained, is a gallium nitride GaN layer. According to an example of an embodiment, the crystalline layer 300 is monocrystalline silicon-based. Alternatively, the crystalline layer 300 can be SiC- or Al.sub.2O.sub.3-based.
[0189] Preferably, the creeping layer 200 is made of a viscous material. The creeping layer 200, has a vitreous transition temperature. It has the behaviour of vitreous transition materials. Like all materials having a vitreous transition temperature, the creeping layer 200, under the effect of a temperature increase, is deformed without breaking and without going back to its initial position after a temperature drop. On the contrary, the crystalline layer 300 does not naturally have vitreous transition. The crystalline layer is deformed, then is dislocated and can break. Consequently, the creeping layer 200 and the crystalline layer 300 are different. The creeping layer 200 is not crystalline.
[0190] The creeping 200 is made of an amorphous material such as an oxide, preferably a silicon oxide SixOy, such as SiO.sub.2. The role of this layer will be explained in the description below.
[0191] Advantageously but in a non-limiting manner, this stack comprising the base substrate 100, the creeping layer 200 and the crystalline layer 300 constitutes a substrate of the semiconductor-on-insulator type, preferably silicon-on-insulator (SOI). In this case, the creeping layer 200 is formed by the buried oxide layer (BOX) of the SOI substrate.
[0192] According to an example of an advantageous embodiment illustrated in
[0193] Typically, the thickness of the AlN layer is between 10 and 100 nanometres (10.sup.9 metres).
[0194] As illustrated in
[0195] It will be noted that the layers 400 and 500 are only optional. Thus, according to non-illustrated embodiments in
[0196] As illustrated in
[0197] To form the pads by etching, numerous etching techniques known to a person skilled in the art can be resorted to. Conventional lithographic techniques can, in particular, be used, such as photolithographic techniques comprising the formation of a mask, for example made of resin, then the transfer of patterns of the mask in the stack. E-beam lithographic techniques or nanoimprint techniques can be resorted to.
[0198] For concision and clarity, only four pads 1000A1-1000A4 are represented in the figures to support one same platelet 550. Naturally, a platelet 550 can be formed of a greater number of pads. As will be described below, the number of pads, as well as their period will be adapted according to the desired size for the microelectronic device, such as a power transistor, a p-i-n diode or a Schottky diode for example, which is sought to be produced from this platelet.
[0199] These pads 1000A1-1000B4 are of small dimensions and can be qualified as nano-pads or nano-pillars. Typically, the maximum dimension of the cross-section of the pads, taken in a plane parallel to the plane xy of the orthogonal system xyz or to the plane of the upper face of the base substrate 100, is comprised between a few tens and a few hundred nanometres. This maximum dimension of the cross-section of the pads is referenced d.sub.pad in
[0200] The pads 1000A1-1000B4 are not all regularly distributed on the surface of the base substrate 100. The pads 1000A1-1000B4 form pad assemblies 1000A, 1000B, each assembly comprising a plurality of pads. The pads 1000A1-1000A4 forming one same assembly 1000A defining a pad array distant from the pad 1000B1-1000B4 array forming another assembly 1000B.
[0201] Thus, the adjacent pads 1000A1-1000A4 of one same assembly 1000A are distant by a distance D. The adjacent pads 1000A4-1000B1 belonging to two distinct assemblies 1000A, 1000B are separated by a distance W1. The distances D and W1 are taken in planes parallel to the plane xy and are illustrated in
[0202] It will be noted that for one same platelet, the distance D can vary. Thus, the pads 1000A1-1000A4 of one same platelet 550 can be non-periodically distributed. Their distribution can thus be adapted to favour the growth of the platelet or to favour the controlled detachment of some of the platelet with respect to the base substrate 100. For example, if the arrangement of the pads 1000A1-1000A4 of a platelet 550 is not periodic, a distance D can be had, which varies for these pads 1000A1-1000A4, plus or minus 20% or plus or minus 10%, for example plus or minus 10 nm around an average value. According to an example, D can take the following values for one same platelet: 100 nm, 90 nm, 85 nm, 107 nm.
[0203] The platelets 550, 550 formed on pad 1000A, 1000B assemblies non-periodically distributed can themselves be periodically disposed on the base substrate 100.
[0204] According to an example of an embodiment, the sections of the pads 1000A1-1000B4, formed in the creeping layer 200, have a height e.sub.220 and, within one same assembly, two adjacent pads 1000A1, 1000A2 are distant by a distance D, such that: [0205] e.sub.220/D<1, and preferably, e.sub.220/D<1.5. Preferably, e220/D<2.
[0206] According to an example of an embodiment, the pads have a height H.sub.pad and two adjacent pads are distant by a distance D, such that: [0207] H.sub.pad/D<2, and preferably, H.sub.pad/D<1.5. Preferably, H.sub.pad/D1. [0208] H.sub.pad and e220 are measured in the direction z. D is measured parallel to the plane xy. H.sub.pad, e.sub.220 and D are illustrated in
[0209] As illustrated in
[0210] Moreover, it has been observed that the action of preserving a non-etched portion 210 of the creeping layer 200 makes it possible to facilitate the creeping of the section 220, in particular when the crystallites are disoriented by twisting, i.e. in main extension planes of the platelets 550, 550 which are sought to be obtained. These main extension planes of the platelets 550, 550 are parallel to the plane xy of the system xyz.
[0211] Preferably, the etched thickness e220, and therefore forming the height of the creeping section 220, is equal to at least half of the thickness of the creeping layer 200. This makes it possible to have a very good reorientation of the crystallites during the formation of grain boundaries.
[0212]
[0213] As illustrated in this
[0214] Whatever the embodiment retained, i.e. with or without primer layer 400 and with or without buffer layer 500, the epitaxial growth of the crystallites 510A1-510B4, is carried out at least partially or only from the upper face of the pad 1000A1-1000B4, also referenced top 1010 of the pad. Thus, this upper face is formed, either by the crystalline section 300A1-300B4, or by the section formed by the primer layer 400A1-400B4, or by the section formed by the buffer layer. This makes it possible, in particular, to rapidly obtain crystallites 510A1-510B4 of high thickness.
[0215] It will be noted that the upper faces of the buffer layer 400 and of the primer layer 500, i.e. the faces rotated facing the layer of the platelets 550, 550 which are sought to be grown, have polarities of the gallium (Ga), and not nitrogen (N) type, which considerably facilitates the obtaining of high quality epitaxial nitride platelets 550, 550. The growth of the crystallites 510A1-510B4 is continued and extends laterally, in particular along planes parallel to the plane xy. The crystallites 510A1-510B4 of one same pad 1000A1-1000A4 assembly 1000A are developed until coalescing and forming a unit or platelets 550, 550 as illustrated in
[0216] In other words, and as clearly emerges from the figures, each platelet 550, 550 extends between several pads 1000A1-1000A4. Each platelet 550, 550 forms a continuous III-N material layer.
[0217] This growth of the crystallites 510A1-510B4 does not extend downwards. Moreover, this growth is selective, in that it does not occur on the creeping layer 200 typically made of an oxide. In this sense, the growth of the crystallites 510A1-510B4 is carried out according to the pendeo-epitaxy principle.
[0218] It will be noted that it is particularly advantageous to etch the pads 1000A1-1000B4 after formation by epitaxy of the buffer layer 400 and of the primer layer 500 (when these layers are present). Indeed, if one of these layers 400, 500 was deposited after etching, it would be partially formed at least between the pads 1000A1-1000B4 on the upper face of the creeping layer 200. In the case where the epitaxial nitride is made of GaN, that the creeping layer 200 is made of SiO.sub.2, thus, at the temperature of the epitaxial deposition, the epitaxial growth of the nitride platelets 550, 550, but on the contrary, would also occur between the pads 1000A1-1000B4, which naturally is not desirable.
[0219] Particularly advantageously, the temperature T.sub.epitaxy at which epitaxy is carried out is greater than or around the vitreous transition temperature T.sub.vitreous transition of the creeping layer 200. Thus, during epitaxy, the creeping sections 220A1-220A4 are brought to a temperature which makes it possible for them to be deformed.
[0220] Consequently, if the crystallites 510A1-510A2 carried by two adjacent pads 1000A1-1000A2 are disoriented against one another, during the coalescence of these two crystallites, the boundary 560 formed at their interface, usually called grain boundary of coalescence boundary, will be formed without dislocation to make up for these disorientations. The approximate placement of the boundary 560 is illustrated in
[0221] Thus, from step 2E, a plurality of platelets 550, 550 is obtained, each platelet 550 being supported by the pads 1000A1-1000A4 of one same pad assembly 1000A. Two adjacent platelets 550, 550 are separated by a distance W2, W2 being the lowest distance taken between these two platelets. W2 is measured in the plane xy.
[0222] W2 depends on W1, on the duration and on the speed of the epitaxial growth. W2 is non-zero. W2<W1.
[0223] The maximum dimension .sub.platelet of a platelet measured parallel to the plane xy is noted d.sub.platelet. Thus, d.sub.platelet corresponds to the maximum dimension of a projection of the platelet in a plane parallel to the plane xy. Preferably, 0.8 md.sub.platelet1000 m and preferably, 1 md.sub.platelet200 m. d.sub.platelet depends on the speed and on the duration of the epitaxial growth, as well as on the number, on the dimension and on the step p.sub.pad of the pads of one same assembly. To produce vertical MOSFETs, d.sub.platelet will be, for example, around a few tens of m.
[0224]
[0225] As illustrated in
[0230] This example of doping is not limiting. For example, the features, steps and technical effects described above are fully applicable to layers of III-N material having only some of these layers 551-554, or having another combination of layers, or also having additional layers.
[0231] In the examples illustrated in
[0232] Examples of Features to Reduce the Dislocations at the Coalescence Boundaries
[0233] Generally, to obtain a coalescence of the crystallites without dislocation, the following parameters can be adjusted:
[0234] The mechanical rupture properties of the material forming the creeping section at a high temperature under relatively low stresses of 500 MPa.
[0235] The sufficiently small size d.sub.pad of the support pads 1000A1-1000A4 compared to the distance D between the pads of one same assembly 1000A, makes it possible to create a stress in the creeping section which is, for a given rotation torque, greater than the rupture stress.
[0236] Moreover, as indicated above, it will be ensured that the epitaxial temperature T.sub.epitaxy makes the creeping of the creeping section 220 possible. In practice, T.sub.epitaxy600 C. (in the scope of a molecular jet epitaxy), T.sub.epitaxy900 C. and preferably T.sub.epitaxy1000 C. and preferably, T.sub.epitaxy1100 C. These values make it possible to particularly effectively reduce the defects in the platelet or the epitaxial layer when the creeping layer is made of SiO.sub.2. In practice, T.sub.epitaxy1500 C.
[0237] In order to facilitate the formation of coalescence boundaries 560 without dislocation, it will be preferable to apply the following conditions: [0238] T.sub.epitaxyk1T.sub.vitreous transition, with k1=0.8, preferably, k1=1 and preferably, k1=1.5.
[0239] According to an example of an embodiment, T.sub.epitaxyk2T.sub.min melting, T.sub.min melting being the lowest melting temperature from among the melting temperatures of the sections forming the pad. This is mainly the crystalline section and the creeping section. According to an example of an embodiment, k2=0.9. This makes it possible to avoid a diffusion of the species of the material, the melting temperature of which is the lowest.
[0240] Thus, in the case where the pad is formed of creeping sections made of SiO.sub.2 and of crystalline sections made of silicon, T.sub.epitaxy1296 C. Indeed, T.sub.min melting is equal to the melting temperature of silicon, since the melting temperature of silicon is equal to 1440 C. and the melting temperature of SiO.sub.2 is equal to 1970 C.
[0241] Advantageously, the step of forming the pads 1000A1-1000A4 is carried out such that d.sub.crystallite/d.sub.padk3, d.sub.pad being the maximum dimension of the cross-section of the pad 1000A1-1000A4 taken in a direction parallel to the plane, wherein the upper face of the base substrate 100 extends. Thus, d.sub.pad corresponds to the maximum dimension of a projection of the pad into the plane xy. d.sub.crystallite corresponds to the dimension of the crystallite measured in the same direction as d.sub.pad at the time of coalescence of the crystallites 510A1-510B4.
[0242] According to an example, 100k31.1. Preferably, 50k31.5. Preferably, 5k32.
[0243] According to an example k33, preferably, 100k33. Preferably, 50k33. Preferably, 5k33.
[0244] This feature makes it possible for the creeping sections to be deformed to particularly effectively take the mechanical stresses which occur when two adjacent crystallites starting to coalesce. Thus, this feature effectively contributes to reducing the density of defects within the nitride platelets 550, 550 which are ultimately obtained.
[0245] Examples of Embodiments of a Vertical Component from Platelets Made of III-N Material
[0246] A first example of an embodiment of a vertical component from epitaxial platelets will now be described in detail, in reference to
[0247] A first step consists of providing a stack comprising the base substrate 100 supporting several platelets 550. Each of these platelets 550 comprises a layer of III-N material formed of several sublayers, each sublayer having dopings of different types. The method according to the invention is not limited to a certain number of doped layers, to certain types of doping or also to a certain combination of dopings.
[0248] As illustrated in
[0249] This encapsulation layer 600 is, for example, a dielectric layer, deposited by centrifugation. Typically, this is a SOG (Spin On Glass) layer, mainly comprising SiO.sub.2 and optionally other species.
[0250] As illustrated in
[0251] As illustrated in
[0252] The following steps aim to make the platelet 550 made of III-N material accessible, as illustrated in
[0253] For this, according to a first embodiment, the base substrate 100 is removed, as illustrated in FIG. 3D1. Then, the assembly of layers surmounting the rear face 550B of the platelet 550 can be removed. For this, one or more conventional material removal steps can be proceeded with, taken from among: a grinding step, a chemical mechanical polishing (CMP) step, an etching step.
[0254] According to another embodiment, illustrated in FIG. 3D2, a mechanical delamination can be proceeded with at the pads 1000. The application of a mechanical stress, in particular, makes it possible to break the pads 1000 at the creeping sections 220. Then, the removal of the different layers which surmount the rear face 550B of the platelet 550 is proceeded with. For this, one or more of the grinding, CMP or etching steps mentioned above can be resorted to.
[0255] As illustrated in
[0256] If, as indicated above, the platelet 550 has an initial layer 550i which results from the coalescence of the crystallites 510 on the pads 1000, and which is not the doped layer 551, thus, this initial layer 550i is also removed.
[0257] In the non-limiting example illustrated in this
[0258] Then, an electrode 20 is produced, making it possible to form an Ohmic contact with the layer 550 made of III-N material. This step is illustrated in
[0259] As illustrated in
[0260] As illustrated in
[0261] Preferably, the first zone 550A1 extends from the centre of the front face 550A of the platelets 550 and the second zone 550A2 surrounds the first zone 550A1. The mask 900 extends to the periphery of the front face 550A and also covers the flanks 550C of the platelets 550. The mask 900 also has portions 910 which extend between two adjacent platelets 550.
[0262] The mask 900 is preferably made of a dielectric material. This can be SiO.sub.2.
[0263] This mask 900 can be formed by partial etching of the encapsulation layer 600. Alternatively, this mask 900 can be formed by a deposition then a lithography, these two steps being carried out after removal of the encapsulation layer 600.
[0264] As illustrated in
[0265] The vertical component thus has a first electrode 10 and a second electrode 20. A current passing from one of these electrodes to the other thus passes through the thickness of the layer of III-N material of the platelet 550.
[0266] In the non-limiting example illustrated, the vertical component is a transistor. The electrode 10 acts as a source, the electrode 20 acts as a drain. Also, an additional and optional step is carried out to form an additional electrode 30 acting as a gate. For this, an electrically conductive layer is deposited, typically forming the gate metal. This electrode 30 is deposited between the platelets 550 and covers some of the portions 920 of the mask 900. Thus, the electrode 30 comprises: [0267] a portion 30A which covers some of the portions 920 of the mask 900, [0268] a portion 30B which covers the mask 900 on the flanks 550C of the platelets, [0269] portion 30C which covers the mask 900 between the platelets 550.
[0270] Thus, in the non-limiting embodiment described above, the gate is deposited on the vertical components, without being etched. Thus, the method proposed makes it possible to preserve the features of the gate, as it is not etched. This makes it possible to considerably improve the performance of the power components. In particular, this makes it possible to improve the threshold voltage, the mobility in the channel and to reduce the trapping in the oxide which has an impact on the threshold voltage and its reliability. Moreover, the gate can have a low thickness.
[0271] For example, the pads 1000 of one same assembly form a honeycomb structure, also called honeycomb array. For example, each pad 1000 has a hexagonal shape.
[0272] It clearly emerges from the non-limiting example described above, that the method proposed makes it possible to avoid the disadvantages associated with the delimitation etching of the different vertical components. Particularly advantageously, the platelets made of III-N material each correspond in their shape and their dimension to one of the electrodes of the vertical component, for example to the source of a vertical transistor. Moreover, due to their production method, the material of the platelets is completely relaxed and only contains very few dislocations. The dislocation rate is typically less than 1.sup.E8/cm.sup.2. Preferably, it is less than 1.sup.E7/cm.sup.2, preferably, it is around 1.sup.E6/cm.sup.2.
[0273] The method proposed thus makes it possible to obtain a vertical component, in this case, a transistor, with the basis of a III-N material having a high thickness, a great purity and a low density of dislocations.
[0274] Moreover, a considerable advantage of the method proposed is the cost price reduction and the increase in diameter of the plates, with respect to the solutions based on freestanding or bulk GaN plates, which only exist in a diameter less than or equal to 100 nm. Currently, the most known solution for manufacturing the freestanding GaN plates is the epitaxy of layers by HVPE (Hybrid Vapour Phase Epitaxy) on a substrate like sapphire. The growth is carried out so as to decrease the density of dislocations on the surface, and to have a final layer which is a few hundred m thick. With these known solutions, the sapphire substrate can therefore be removed, by leaving a GaN layer which could be used as a plate. This solution is long and expensive. Furthermore, it is difficult to implement on large diameter plates.
[0275] On the contrary, by growing platelets as indicated above in reference to
[0276]
[0277] The structures of these
[0278] The platelet 550 of
[0279]
[0282] In this example, the gate 30 is directly in contact with the layers 553 and 554. It is not in contact with the layer 552.
[0283]
[0284]
[0285] The growth on pads, mesa or islands is carried out often on all the surfaces, with a more or less high speed, according to the growth conditions and the orientation of the flanks of the layer made of III-N material. This could be problematic for the growth of the p-n junction on the surface of the platelet 550. Indeed, during the growth of these layers on the surface, the growth of a p-n junction of the flanks could also be had. Although this thickness is usually low, this junction could give uncontrolled conduction paths and generate a high leakage current, as it would thus be difficult to control it with the gate. The performance of the transistor would thus be highly deteriorated.
[0286] In the scope of the present invention, it is possible to take advantage of this aspect. Indeed, if the thicknesses e.sub.553A and e.sub.554A of the III-N material (typically p and n layers, preferably pGaN and nGaN) are well targeted, with the correct doping, it can be ensured that the junction is completely depleted. The layers 553A, 554A which cross over the flanks 552F thus have no free carriers, and will have a high resistivity. They will thus form a barrier preventing electrons from reaching the surface of the flanks of the platelet 550. This deserted p-n junction thus acts as passivation layers for the flanks of the platelet 550. This avoids having to add specific passivation layers. The method for producing the component is thus simplified and its cost price is reduced.
[0287] Preferably, the growth of the layers 553, 554 is carried out such that the lateral portions 553A and 554A cover the whole height of the flanks 552F of the second layer 552. Thus, the flanks 552F of the second layer 552 are fully protected and are no longer accessible.
[0288] In each of the embodiments described above in reference to
[0289] This embodiment is particularly interesting, if the platelet edges or mesas have too many impurities to have a very low doping. In this case, it will thus be interesting to produce large platelets with several cells for each platelet.
[0290] The paragraphs below give details, for a non-limiting example of an embodiment, of different layers forming the III-N material. In this non-limiting example, the III-N material is GaN-based. Preferably, the III-N material is GaN.
[0291] For example, the first layer 551 can have a thickness e.sub.551 of between 1 and 5 m (10.sup.6 metres), preferably of between 1 and 3 m, preferably of around 2 m. This first layer 551 has an n+ type doping. This makes it possible to ensure a good quality electrical conduction with the second electrode 20. For example, this first layer 551 has a doping level greater than or equal to 5.1017 atoms per cubic centimetre (at/cm.sup.3) and preferably around 5.1018 at/cm.sup.3. For example, the first layer has a doping level, preferably of around 5.1018 at/cm.sup.3. As illustrated in
[0292] The second layer 552 can have a thickness e.sub.552 of at least 8 m (10.sup.6 metres) and preferably of at least 10 m. Thus, this layer 552, relatively thick, fully suits power components. The second layer 552 has a doping level greater than or equal to 1.1015 at/cm.sup.3 and preferably, around 1.1016 at/cm.sup.3. The second layer 552 has an n type doping. As illustrated in
[0293] The third layer 553 can have a thickness e.sub.553 of at least 100 nm (10.sup.9 metres) and preferably of less than 1 m. Preferably, the thickness e.sub.553 is of between 300 and 700 nm. According to an example, the thickness e.sub.553 is equal to 500 nm. The third layer has a doping level greater than or equal to 5.1017 at/cm.sup.3 and preferably around 1.1018 at/cm.sup.3. It has a p type doping. As illustrated in
[0294] The fourth layer 554 can have a thickness e.sub.554 of at least 50 nm (10.sup.9 metres). Preferably, the thickness e.sub.554 is between 50 and 300 nm. Preferably, the thickness e.sub.554 is around 100 nm. The fourth layer 554 has a doping level greater than or equal to 5.1017 at/cm.sup.3 and preferably, around 1.1018 at/cm.sup.3. It has an n+ type doping. This makes it possible to ensure a good quality electrical conduction with the first electrode 10. As illustrated in
[0295]
[0296] The platelet 550 of
[0297]
[0300] According to a non-limiting example, the layers 551, 552 have the features, in terms of thickness and/or doping level, mentioned above about the embodiment illustrated in
[0301]
[0302] The platelet 550 of
[0303]
[0306] According to a non-limiting example, the layers 551, 552, 553 have the features, in terms of thickness and/or doping level, mentioned about the embodiment illustrated in
[0307] Example of an Embodiment Illustrated in
[0308] In reference to
[0309] As illustrated in
[0310] In this example, each platelet corresponds to the platelet 550 illustrated in
[0311] First steps comprise the encapsulation of platelets in an encapsulation layer 600 and the fixing of a sacrificial substrate 700. These steps, the result of which is illustrated in
[0312] The stack is then returned as illustrated in
[0313] The pads are then removed and the rear face 550B of the layer made of III-N material is stripped, as illustrated in
[0314] The second electrode 20 is then formed. For this, a conductive base 20 can, for example, be mounted on the rear face 550B. This step corresponds to that described above in reference to
[0315] The first electrode 10 is then formed. For this, for example, the encapsulation layer 600 can be opened, to make the front face 550A of the layer of III-N material accessible. This step corresponds to that described above in reference to
[0316] Example of an Embodiment Illustrated in
[0317] In reference to
[0318] As illustrated in
[0319] In this example, each platelet has the layers 551 and 552. Thus, in this example, the initial layer 550i produced by coalescence of the crystallites at the top of the pads, is directly the first functional layer 551. Naturally, the example below fully suits the use of different platelets, in particular, any one of the platelets illustrated in
[0320] A first step comprises the encapsulation of the platelets 550 in an encapsulation layer 600.
[0321] The first electrode 10 is then formed. For this, for example, the encapsulation layer 600 can be opened, to make the front face 550A of the layer of III-N material accessible. The result of this step is illustrated in
[0322] Before or after the formation of the first electrode 10, an opening 110 is produced, through the base substrate 100 and so as to make the first layer 551 of each platelet 550 accessible. This opening 110 can be produced by etching through a mask. During this etching, it can be provided to remove the pads which are located at the right of the opening 10. This step is illustrated in
[0323] As illustrated in
[0324] It will be noted that, according to an alternative embodiment, the opening 110, as well as the second electrode 20 can be produced before the formation of the first electrode 10.
[0325] Moreover, it will be noted that the encapsulation layer 600 is only optional. This embodiment can be implemented with a via opening onto the first layer 551 without necessarily providing an encapsulation layer 600.
[0326] This embodiment has the advantage of considerably reducing the number of steps. In particular, it is not necessary to perform steps intended to remove the pads. This embodiment is also interesting to ensure a thermal conductivity between the platelet and the substrate.
[0327] Thus, in the embodiments of
[0328] Example of an Embodiment Illustrated in
[0329] In reference to
[0330] As illustrated in
[0331] In this example, each platelet has the layers 550i, 551 and 552. Naturally, the example below fully suits the use of different platelets, in particular any one of the platelets illustrated in
[0332] A first step comprises the encapsulation of the platelets 550 in an encapsulation layer 600. This step is illustrated in
[0333] The first electrode 10 is then formed. For this, for example, the encapsulation layer 600 can be opened to make the front face 550A of the layer of III-N material accessible.
[0334] Before or after, or preferably simultaneously to the formation of the first electrode 10, an electrode serving as a gate 30 can be produced, if the vertical component is a transistor. As illustrated in the figures, preferably, it is provided that the first electrode 10 surrounds the gate 30. Thus, the first electrode can, for example, form on the front face 550A, a ring surrounding the gate 30. For the production of at least one gate 30, a prior etching can be provided within the second layer 552 such that the gate 30 penetrates at least partially into this second layer 552. The result of this step is illustrated in
[0335] Before or after the production of the first electrode 10 and the gate 30, the second electrode 20 is produced.
[0336] For this, a first step consists of producing a hole also called via 111, from the front face 550A of the platelet 550. This via 111 extends into the layer made of III-N material over a depth p111. p111 is considered so as to make the first layer 551 accessible. Thus, p111 is greater than the distance separating the front face 550A of the first layer 551. In this example, this distance corresponds to the thickness e.sub.552 of the second layer 552. This step is illustrated in
[0337] An electrically conductive material is then deposited inside the via 111 to produce the second electrode 20 forming an electrical contact with the first layer 551. Naturally, beforehand, the walls of the via 11 will have been electrically insulated, to avoid any electrical conduction between the second electrode 20 and the layers of III-N materials surmounting the first layer 551. In this non-limiting example, only the second layer 552 surmounts the first layer 551. The electrical insulation layer(s) of the via 111 are referenced 25 in
[0338] In this non-limiting example, the vertical component is a transistor, the first electrode 10 and the second electrode 20 thus effectively forming the drain is the source.
[0339] This vertical component structure, with a through electrode, as well as the production method, are fully applicable to vertical components, other than transistors. To produce a diode, for example, the same steps can be proceeded with, the steps of producing the gate thus being naturally removed.
[0340] This embodiment has the advantage of considerably reducing the number of steps. In particular, it is not necessary to perform steps intended to remove the pads. Moreover, it enables the contacts with the first 10 and second electrodes 20 from the same face of the component.
[0341] Example of an Embodiment Illustrated in
[0342] In reference to
[0343] The step illustrated in
[0344] A sacrificial substrate 700 is then mounted on the front face 550A of the platelet 550. This step, illustrated in
[0345] The stack is then returned. The base substrate 100 is removed. This removal can be carried out mechanically. During this removal, most of the pads are broken, in particular at their creeping portion 220. This step is illustrated in
[0346] As illustrated in
[0347] The electrode 20 is then disposed in contact with the first layer 551. For this, the platelets 550 are preferably fixed to an electrically conductive substrate, as illustrated in
[0348] The
[0349] With respect to the embodiments of
[0350] In view of the description above, it appears clearly that the present invention proposes a particularly effective solution for obtaining vertical microelectronic components with the basis of a III-N material having a great purity, a low density of dislocations and a high thickness, typically a thickness greater than 8 m.
[0351] Thus, the invention is particularly advantageous for the production of GaN diode and transistor power components, for the market of plateletrete components over ranges of a few 100V to a few kV in a range of intensity typically comprised in the range of 1 Ampere (A) to a few hundred Amperes. Other applications can naturally be considered.
[0352] The invention is not limited to the embodiments described above.
[0353] In particular, the examples above describe certain examples of layers of III-N material formed of several sublayers having different dopings. The method according to the invention is not limited to a certain number of doped layers, to certain types of doping or also to certain combinations of doped layers.
[0354] Moreover, in all the examples described above, the first electrode 10 can be produced before or after the second electrode 20.