SYSTEM AND METHOD THEREOF FOR EFFICIENT PRODUCTION OF AMMONIA

Abstract

A system and method for production of ammonia are presented. The system includes a reactor adapted to receive therein through a first input of the reactor sulfate ammonia and a reacting agent through a second input of the reactor, wherein the reactor is heated to a temperature not to exceed a predetermined temperature to create a chemical reaction between a sulfate ammonia and the reacting agent; and a purifier adapted to accept ammonia from the reactor and perform a purification process to purify the ammonia to a predetermined degree of purification.

Claims

1. A system for production of ammonia, comprising: a reactor adapted to receive therein through a first input of the reactor sulfate ammonia and a reacting agent through a second input of the reactor, wherein the reactor is heated to a temperature not to exceed a predetermined temperature to create a chemical reaction between a sulfate ammonia and the reacting agent; and a purifier adapted to accept ammonia from the reactor and perform a purification process to purify the ammonia to a predetermined degree of purification.

2. The system of claim 1, wherein the reacting agent is any one of: a metal oxide and a hydroxide.

3. The system of claim 2, wherein the metal oxide is NaCl.

4. The system of claim 2, wherein the hydroxide is at least one of: NaOH, KOH, Ca(OH)2, and Na(Al(OH)4).

5. The system of claim 1, wherein the predetermined temperature is 250° C.

6. The system of claim 1, wherein the temperature is in the range of 70° C. to 100° C.

7. The system of claim 1, wherein the reactor further contains therein water (H2O).

8. The system of claim 1, wherein the chemical reaction is one any of:
(NH4)2SO4+2NaOH.fwdarw.Na2SO4+2NH3+2H2O;
(NH4)2SO4+2KOH.fwdarw.K2SO4+2NH3+2H2O;
2(NH4)2SO4+2KOH+2NaOH.fwdarw.2Na2SO4+2K2SO4+4NH3+2H2O;
(NH4)2SO4+2NaCl.fwdarw.Na2SO4+2NH3+2HCl;
(NH4)2SO4+Ca(OH)2.fwdarw.CaSO4+2NH3+2H2O; and
(NH4)2SO4+2Na(Al(OH)4).fwdarw.2l1(OH)3+Na2SO4+2NH3+4H2O.

9. The system of claim 1, wherein the system is a mobile manufacturing unit.

10. The system of claim 1, wherein the system is further adapted to provide at least one of: gas ammonia, and liquid ammonia.

11. A method for producing ammonia, comprising: providing sulfate ammonia and a reacting agent to a reactor; heating the reactor to a predetermined temperature to create a chemical reaction between the sulfate ammonia and the reacting agent; providing the ammonia produced in the reactor to an ammonia purifier; and purifying the ammonia to a predetermined level of purity.

12. The method of claim 11, wherein the reacting agent is any one of: a metal oxide and a hydroxide.

13. The method of claim 12, wherein the metal oxide is NaCl.

14. The method of claim 12, wherein the hydroxide is at least one of: NaOH, KOH, Ca(OH)2, and Na(Al(OH)4).

15. The method of claim 11, wherein the predetermined temperature is 250° C.

16. The method of claim 11, wherein the temperature is in the range of 70° C. to 100° C.

17. The method of claim 11, further comprising: adding water (H2O) to the reactor.

18. The method of claim 11, wherein the chemical reaction is any one of:
(NH4)2SO4+2NaOH.fwdarw.Na2SO4+2NH3+2H2O;
(NH4)2SO4+2KOH.fwdarw.K2SO4+2NH3+2H2O;
2(NH4)2SO4+2KOH+2NaOH.fwdarw.2Na2SO4+2K2SO4+4NH3+2H2O;
(NH4)2SO4+2NaCl.fwdarw.Na2SO4+2NH3+2HCl;
(NH4)2SO4+Ca(OH)2.fwdarw.CaSO4+2NH3+2H2O; and
(NH4)2SO4+2Na(Al(OH)4).fwdarw.2l1(OH)3+Na2SO4+2NH3+4H2O.

19. The method of claim 11, further comprising: providing gas ammonia.

20. The method of claim 11, further comprising: providing liquid ammonia.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0012] The subject matter that is regarded as the invention is particularly pointed out and distinctly claimed in the claims at the conclusion of the specification. The foregoing and other objects, features, and advantages of the invention will be apparent from the following detailed description taken in conjunction with the accompanying drawings.

[0013] FIG. 1 is a schematic diagram of a system for production of ammonia according to an embodiment.

[0014] FIG. 2 is a flowchart of an operation flow of the system, of FIG. 1, for efficient production of ammonia according to an embodiment.

DETAILED DESCRIPTION

[0015] It is important to note that the embodiments disclosed herein are only examples of the many advantageous uses of the innovative teachings herein. In general, statements made in the specification of the present application do not necessarily limit any of the various claims. Moreover, some statements may apply to some inventive features but not to others. In general, unless otherwise indicated, singular elements may be in plural and vice versa with no loss of generality.

[0016] According to an example embodiment, a method of manufacture results in efficient production of ammonia (NH3) and byproducts such as Na2SO4, HCL, CaSO4, ZnSO4, Al2SO4, K2SO4 and the like. These are produced with good purity by decomposing of ammonium sulfate under relatively mild operating conditions. The ammonium sulfate reacts with a metal oxide or hydroxide at a temperature of not more than 250° C. to form NH3 and a metal sulfate. An advantage of the methods of manufacture is that it makes it possible to provide ammonia production safely and on a continuous amount on an as needed basis, as well as mobile manufacturing units.

[0017] The term ammonium sulfate as used herein refers to starting materials that are not only to ammonium sulfate itself but also to acid ammonium sulfate, acid ammonium sulfate containing sulfuric acid, and any mixtures thereof. In one embodiment these starting materials may include impurities in a concentration of up to 10% by weight. The impurities include, for example but not by way of limitation, non-combustible carbon, ash, epsilon-caprolactam, acetonedisulfonic acid, p-toluenesulfonic acid, polymers of these and sulfur which are contained in an epsilon-caprolactam waste liquor, methyl methacrylate waste liquor from an acetone-cyanohydrin process, acrylonitrile waste liquor from ethylene-cyanohydrin process and crude oil refining waste liquor.

[0018] There are various different reactions that may be performed according to the invention. These include, but are not limited to, the following chemical reactions which would be understood by one of ordinary skill:

(NH4)2SO4+2NaOH.fwdarw.Na2SO4+2NH3+2H2O

[0019] In an example case (a), in a reactor there are mixed ammonium sulfate and sodium hydroxide, for example in the presence of water. The mix is heated to no more than 250° C., preferably in the range of 70 to 100° C. As a result of the chemical interaction, the resultant compounds are produced: sodium sulfate, ammonia, and water. Another reaction may be:

(NH4)2SO4+2KOH.fwdarw.K2SO4+2NH3+2H2O

[0020] In another example case (b), in a reactor there are mixed ammonium sulfate and potassium hydroxide, for example in the presence of water. The mix is heated to no more than 250° C., preferably in the range of 70 to 100° C. As a result of the chemical interaction, the resultant compounds are produced: potassium sulfate, ammonia, and water. Yet another reaction may be:

2(NH4)2SO4+2KOH+2NaOH.fwdarw.2Na2SO4+2K2SO4+4NH3+2H2O

[0021] In another example case (c), in a reactor there are mixed ammonium sulfate, potassium hydroxide and sodium hydroxide, for example in the presence of water. The mix is heated to no more than 250° C., preferably in the range of 70 to 100° C. As a result of the chemical interaction, the resultant compounds are produced: sodium sulfate, potassium sulfate, ammonia, and water. Yet another reaction may be:

(NH4)2SO4+2NaCl.fwdarw.Na2SO4+2NH3+2HCl

[0022] In another example case (d), in a reactor there are mixed ammonium sulfate and sodium chloride (commonly known as salt), for example in the presence of water. The mix is heated to no more than 250° C., preferably in the range of 70 to 100° C. As a result of the chemical interaction, the resultant compounds are produced: potassium sulfate, ammonia, and hydrogen chloride, when solved in water also known as hydrochloric acid. Yet another reaction may be:

(NH4)2SO4+Ca(OH)2.fwdarw.CaSO4+2NH3+2H2O

[0023] In another example case (e), in a reactor there are mixed ammonium sulfate and calcium hydroxide, for example in the presence of water. The mix is heated to no more than 250° C., preferably in the range of 70 to 100° C. As a result of the chemical interaction, the resultant compounds are produced: calcium sulfate, ammonia, and water. Yet another reaction may be:

(NH4)2SO4+2Na(Al(OH)4).fwdarw.2Al(OH)3+Na2SO4+2NH3+4H2O

[0024] In another example case (f), in a reactor there are mixed ammonium sulfate and sodium (meta) aluminate, for example in the presence of water. The mix is heated to no more than 250° C., preferably in the range of 70 to 100° C. As a result of the chemical interaction, the resultant compounds are produced: aluminum hydroxide, sodium sulfate, ammonia, and water.

[0025] FIG. 1 depicts a schematic diagram of a system 100 for efficient production of ammonia according to an embodiment. The system includes a reactor 110. At input 115 the reactor is adapted to receive sulfate ammonium and at input 113 it receives a metal oxide or hydroxide substance as described herein.

[0026] In one embodiment the reactor further contains therein also an amount of water (H2O). The reactor is heated to a temperature not to exceed 250° C., preferably in the range of 70 to 100° C. As a result, a chemical interaction occurs resulting in the chemical response as described herein which includes the output 117 to provide the ammonia purifier chamber 130. Another out 119 of reactor 110 provides to a byproduct collection chamber 120 from which by-products produced by the process as described herein may be collected and provided through output 123. In one embodiment, the byproduct collection chamber 120 may be used for decomposing the metal sulfate in the presence of a reducing agent to form a metal oxide and SO2.

[0027] The ammonia purifier chamber 130 is adapted to perform purification of the ammonia extracted by the process described herein. The ammonia purifier chamber 130 may provide ammonia as a gas through output 133 or through output 135 to a mixing chamber where the ammonia is mixed with water to provide liquid ammonia on output 145 of the mixing chamber 140. One of ordinary skill in the art would readily realize the advantages of the described system when compared to the prior art solution. Firstly, the temperatures used by the reactor 110 do not exceed 250° C., preferably in the range of 70 to 100° C., which reduces costs and is inherently safer.

[0028] Secondly, the input substances used to produce the ammonia are safe and until the production of the ammonia itself do not pose an inherent safety threat. Thirdly, the system 100 is a simple system that can produce efficiently ammonia in small quantities, on-location thereby enabling the production of ammonia on premise rather than by using large-scale manufacturing structures that, while efficient (but not more efficient than the described process herein), require the storage and transportation of relatively large quantities of ammonia thereby posing a safety hazard.

[0029] FIG. 2 describes an example flowchart 200 of an operation flow of the system 100 for efficient production of ammonia according to an embodiment. At S210 ammonium sulfate is reacted, for example in reactor 110, with the metal oxide or hydroxide. Generally, but not by way of limitation, the use of an oxide or hydroxide of a metal is selected from Ca, Na, K, Al, Fe, Zn, Cu, and like elements, and is preferred because it produces the desired effects described herein and are practicable. In an embodiment the reaction takes place in a medium such as water (H2O).

[0030] At S220 the solution is heated, for example in reactor 110, to a temperature not to exceed 250° C., and more preferably in the range of 70 to 100° C. At S230 separation of the ammonia from the byproducts takes place, for example by clearing the byproducts from the reactor 110 through output 119, and clearing the ammonia from the reactor 110 through output 107. In S240 the ammonia provided by the reaction is purified in, for example, an ammonia purification chamber 130 from which ammonia in the form of gas or in the form of liquid, i.e., ammonia and water, is provided.

[0031] In one embodiment, the system 100 is adapted to small production scale units. This allows the implementation of modular compact factories for the production of ammonia and secondary products. Moreover, this can be also produced as mobile version. These small units, due to the recovery processes discussed herein result in economically profitable solutions which are safe in the transportation and storage of ammonia compared to existing prior art solutions.

[0032] As used herein, the phrase “at least one of” followed by a listing of items means that any of the listed items can be utilized individually, or any combination of two or more of the listed items can be utilized. For example, if a system is described as including “at least one of A, B, and C,” the system can include A alone; B alone; C alone; A and B in combination; B and C in combination; A and C in combination; or A, B, and C in combination.

[0033] All examples and conditional language recited herein are intended for pedagogical purposes to aid the reader in understanding the principles of the invention and the concepts contributed by the inventor to furthering the art, and are to be construed as being without limitation to such specifically recited examples and conditions. Moreover, all statements herein reciting principles, aspects, and embodiments of the invention, as well as specific examples thereof, are intended to encompass both structural and functional equivalents thereof. Additionally, it is intended that such equivalents include both currently known equivalents as well as equivalents developed in the future, i.e., any elements developed that perform the same function, regardless of structure.