Simulated integrated computational elements and their applications
10481087 ยท 2019-11-19
Assignee
Inventors
- Li Gao (Katy, TX)
- David L. Perkins (The Woodlands, TX)
- Michael T. Pelletier (Houston, TX)
- Christopher Michael Jones (Houston, TX)
Cpc classification
G01N21/314
PHYSICS
G01N21/31
PHYSICS
International classification
G01N33/00
PHYSICS
Abstract
A downhole system in which an agile light source is used to simulate an integrated optical element to measure one or more characteristics of a fluid in a wellbore.
Claims
1. An optical measurement system comprising: a light source to provide an input light, the light source having a source controller circuit; a sample containment area; a detector configured to detect a sample light and produce a detector signal; a spectral profile for an integrated computational element; and a detector controller circuit configured to synchronize the input light and the detector and configured to implement the spectral profile, wherein the detector controller circuit is configured to provide and adjust in-situ a light signal to simulate the integrated computational element in a period of time with the input light, wherein the light signal is adjusted in-situ by way of the light source.
2. The optical measurement system of claim 1 further comprising an analysis unit configured to integrate a signal from the detector over the period of time and provide a value of a measurable property of the sample.
3. The optical system of claim 1, wherein the detector signal comprises a difference between a signal from a first spectral curve and a signal from a second spectral curve.
4. The optical system of claim 1, wherein the detector signal comprises a ratio of a signal from a first spectral curve and a sum of the signal from the first spectral curve spectrum and a signal from a second spectral curve.
5. A light source for use in an optical measurement system, the light source comprising: a light emitting circuit having a pre-selected center wavelength, a pre-selected amplitude, and a bandwidth; and a controller circuit configured to provide and adjust in-situ a signal to the light emitting circuit to simulate an integrated computational element in a period of time with an input light; wherein the controller circuit comprises a memory circuit, the memory circuit comprising a spectral profile having a first spectral curve and a second spectral curve associated with the simulated integrated computational element.
6. The light source of claim 5 wherein the spectral profile comprises a wavelength range greater than the bandwidth of the light emitting circuit; and the signal provided to the light emitting circuit comprises the pre-selected center wavelength and the pre-selected amplitude.
7. The light source of claim 6 wherein the wavelength range comprises the pre-selected center wavelength within at least the bandwidth of the light emitting circuit.
8. The light source of claim 5 or 6 wherein the light emitting circuit can provide input light with the pre-selected amplitude for the first spectral curve at a first time, and can provide input light with the pre-selected amplitude for the second spectral curve at a second time.
9. The light source of claim 8 wherein the first time is included in a first period of time and the second time is included in a second period of time.
10. The light source of claim 9 wherein the first period of time overlaps at least a portion of the second period of time.
11. The light source of claim 9 or 10 wherein the first period of time and the second period of time are interleaved so that the second time is subsequent to the first time.
12. The light source of claim 5, wherein a weighted difference between the first spectral curve and the second spectral curve is proportional to a regression vector associated to a measurable property of a sample.
13. The light source of claim 5, wherein a ratio of the first spectral curve to a sum of the first spectral curve and the second spectral curve is proportional to a regression vector associated to a measurable property of a sample.
14. A method for measuring a desired property of a sample, the method comprising: selecting at least one an integrated computational element (ICE) spectral profile to measure the desired property; providing a driving signal with the ICE spectral profile to a light source, wherein the driving signal and light source are adjustable in-situ; providing an illumination light from the light source to the sample based on the ICE spectral profile; collecting a sample light in a detector; and processing the detector signal using a collection signal with the spectral profile.
15. The method of claim 14 wherein processing the detector signal further comprises synchronizing the collection signal with the driving signal.
16. The method of claim 14 wherein selecting an ICE spectral profile comprises selecting a plurality of spectral profiles to measure a plurality of desired properties.
17. The method of claim 16 further comprising measuring at least one property of the group consisting of an octane rating, a gas-oil-ratio (GOR), a hydrocarbon composition, a carbon dioxide (CO.sub.2) composition, and a water (H.sub.2O) composition.
18. The method of claim 17 wherein measuring the hydrocarbon composition comprises measuring any one of the group consisting of a C.sub.1 hydrocarbon molecule, a C.sub.2 hydrocarbon molecule, a C.sub.3 hydrocarbon molecule, a C.sub.4 hydrocarbon molecule, a C.sub.5 hydrocarbon molecule, and a C.sub.6 hydrocarbon molecule.
19. An optical measurement system comprising: an alternative integrated computational element (ALICE) configured to provide an input light, the ALICE comprising a spectrally tunable light emitter and a spectral profile for an integrated computational element (ICE); a sample containment area; a detector configured to detect a sample light; and a detector controller circuit configured to synchronize the input light and the detector and further configured to implement the spectral profile such that the input light from the ALICE is adjustable in-situ and simulates an integrated computational element=wherein the input light from the ALICE is adjusted in-situ by way of the ALICE.
20. The system of claim 19, wherein the spectrally tunable light emitter is a laser.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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(9) Wherever possible, the same reference numbers are used throughout the drawings to refer to the same or like elements.
DETAILED DESCRIPTION
(10) Embodiments disclosed herein provide a rugged and compact optical measurement system that simulates a traditional integrated computational element (ICE) using an alternative integrated computational element (ALICE). As used herein, ICE will be used to refer to a traditional or conventional integrated computational element, while ALICE will be used to refer to a system that simulates an ICE. To provide detailed compositional information of a sample, some embodiments may use the ALICE to simulate a plurality of ICEs covering an entire optical spectrum of interest, including the UV, VIS, NIR, and MIR spectral regions. Accordingly, in some embodiments a single optical element simulates the plurality of ICEs used in an optical measurement. Thus, embodiments as disclosed herein significantly reduce the complexity of the system, simplifying alignment of different optical components, and boosting reliability of the sensor's mechanical, electrical and electronic components by reducing the number of moving parts.
(11) In some embodiments, a programmable agile light source functions as the ALICE and is the optical element used to simulate a plurality of traditional ICEs by utilizing one or more profiles of the traditional ICEs in conjunction with a spectrally tunable light emitter. A programmable agile light source provides an input light to a sample, the input light having a desired spectral profile by electronic control of the light source power and spectral emission. For example, by scanning an optical signal having a bandwidth across a spectral band and modulating the amplitude of the optical signal utilizing the agile light source, a first ICE may be simulated in an optical system during a first period of time, .sub.1. Moreover, by synchronizing a detector in the optical system with the agile light source, a precise measurement using the ALICE system may be completed during or after period .sub.1. Likewise, the agile light source may simulate a second ICE during a second period of time .sub.2, the detector synchronized for a precise measurement for the second simulated ICE during or after period .sub.2. As used herein, agile light source refers to a system including spectrally tunable light sources. One example of a spectrally tunable light source is a wavelength-agile, or equivalently thereto frequency-agile laser, in which the light source provides a spectrally narrowband radiation, and various wavelengths or wavelength ranges of the partial radiation are settable in a rapid and controllable manner.
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(13) In some embodiments, sample 120 may be a fluid flowing in a direction, with certain speed. In such configurations, sample area 125 may have an input opening and an output opening, allowing fluid flow through a cavity. In some embodiments, sample 120 may be a static fluid. Further according to some embodiments sample 120 may include a liquid, a solid, a powder, a mud, a colloidal suspension, an oil, a gas, a hydrocarbon, or any combination of the above. Sample 120 may further include a plurality of analytes of interest for an optical measurement. For each of the plurality of analytes in sample 120, an ICE for an analyte may be simulated using an ALICE so that detector 130 determines the analyte composition in sample 120 when input light 150 is modulated to simulate the ICE for an analyte.
(14) Light source 110 may include an emitter 115 providing input light 150, and a source controller circuit 112. As mentioned above, emitter 115 is a spectrally tunable light source such as a wavelength-agile, or equivalently thereto frequency-agile, laser. Source controller circuit 112 may provide electronic signals to emitter 115 so that input light 150 has an amplitude, a bandwidth, and a wavelength. Accordingly, source controller circuit 112 may determine the amplitude, bandwidth and wavelength of input light 150 so that in a selected period of time input light scans a spectral profile corresponding to one of a plurality of conventional ICEs 101-1, 101-2, 101-3, . . . , 101-n (hereinafter collectively referred to as ICEs 101). In that regard, source controller circuit 112 may include a memory circuit 114 to store conventional ICE profiles 101, and a processor circuit 113 to provide the control signal for emitter 115, and to provide a synchronization signal to detector controller 140. Processor circuit 113 performs operations upon executing commands stored in memory circuit 114. One of ordinary skill in the art will recognize that n may be any integer value, such as 3, 4, 10, 20, or even more. In fact, memory circuit 114 may store hundreds or thousands of conventional ICE profiles 101, depending on the desirable use of light source 110. Accordingly, in some embodiments, source controller 112 replaces the physical conventional ICEs and the filter wheel used in the prior art with desired spectral patterns. Processor circuit 113 and memory circuit 114 may include a microprocessor, a field-programmable gate array (FPGA) or an Application-specific Integrated Circuit (ASIC).
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(16) ICE curves 210 are selected such that sample light 151 for ICE profile 101-n when collected by detector 130 produces an electric signal related to a measurable characteristic of sample 120. For example, the measurable characteristic of sample 120 may be an analyte concentration in the sample. Other examples of measurable characteristics of a sample may be an octane rating of a gasoline sample. A measurable characteristic of a sample may be a component concentration in a powder; or a grain size in a powder. In some embodiments a measurable characteristic of a sample may be a Gas-Oil ratio (GOR) in a crude oil sample. Crude oil is a liquid containing a mixture of hydrocarbons forming oil, and dissolved gases such as methane CH.sub.4, carbon dioxide, CO.sub.2, and others. Hydrocarbons of interest in embodiments consistent with the present disclosure may be any one of the group including a C.sub.1 hydrocarbon molecule (e.g., methane), a C.sub.2 hydrocarbon molecule (e.g., ethanol), a C.sub.3 hydrocarbon molecule (e.g., propane), a C.sub.4 hydrocarbon molecule, a C.sub.5 hydrocarbon molecule, and a C.sub.6 hydrocarbon molecule (e.g., a hexane). The dissolved gases will form a gaseous phase at atmospheric conditions. Thus, when crude oil is released into the atmosphere it contains two main phases, a liquid phase which is the commonly known oil, and a gas phase containing natural gas, including methane and other gases. Accordingly, the GOR of a downhole crude oil sample may indicate the value and potential use of a prospective reservoir. Other samples may comprise solids, liquids, gases or a combination of any of the foregoing, formed of one or more substances mixed together.
(17) In some embodiments, it is desirable that the electric signal from detector 130 be linearly correlated to the measurable characteristic of sample 120. In some embodiments, the electric signal may be related to the measurable characteristic by a functional relation including nonlinear terms. The relation between the signal collected by detector 130 for a simulated ICE 101 and the measurable characteristic related to the simulated ICE 101 may be stored in memory circuit 147, in analysis unit 145.
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(20) Equation (1) is a linear multivariate problem targeting a measurable property .sub.i, of sample 120. For example, in some embodiments .sub.i may be the concentration of an analyte of interest in sample 120. In some embodiments, .sub.i may be an octane rating in a gasoline sample, or a GOR in a crude oil sample. In Eq. (1), is a proportionality constant and is a calibration offset. Values of and depend on design parameters of device 100 and not on sample 120. Eq. (1) shows a linear relation between the product A.Math.L.sub.i and measurable property .sub.i. The dot product of vectors A and Li includes a summation over the product of each wavelength component of vectors A and L (cf. summation in Eq. (1)). One of ordinary skill will recognize that a more general functional relation including non-linear terms in the product A.Math.L.sub.i may be used, according to embodiments consistent with the present disclosure.
(21) In some embodiments, spectral curves S.sub.a and S.sub.b in
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(23) Where .sub.1 and .sub.1 are constants independent of wavelength, suitably chosen to satisfy Eqs. (1) and (2) for measurable property .sub.i, of sample 120.
(24) In some embodiments, spectral curves S.sub.a and S.sub.b in
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(26) Where .sub.ai and .sub.bi, are constants independent of wavelength, suitably chosen to satisfy Eq. (1) for measurable property .sub.i, of sample 120.
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(28) Center wavelength 420 may be scanned across a broad wavelength band covering totally or partially the UV, VIS, NIR, and even the MIR spectral regions. By sweeping center wavelength 420 of spectral output 450 through the desired wavelength band, and modulating amplitude 430 at predetermined levels, any desired conventional ICE, such as ICE simulation 410 may be simulated. In that regard, the scanning of center wavelength 420 across the wavelength range of ICE simulation 410 may take a period of time, . In such configurations, the signal provided by detector 130 (cf.
(29) In some embodiments, ICE simulation 410 may include two spectral curves, S.sub.a collected during time period .sub.a, and S.sub.b collected during time period .sub.b, as discussed in detail above in relation to
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(31) Likewise, when a linear regression vector Li is obtained using Eq. (3), processor circuit 146 may integrate the signal from detector 130 as follows:
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(33) Accordingly, analysis unit 145 may obtain a value for measurement property .sub.i using Eq. (1) and the value d.sub.i from either Eq. (4) or Eq. (5), as follows:
.sub.i=.Math.d.sub.i+(6)
(34) While the summation (or integral) in Eqs. (4) and (5) is performed relative to wavelength, it is understood that each value A.sub.a() and A.sub.b() is collected at a specific time, which may be different for A.sub.a and for A.sub.b. For example, a value A.sub.a(.sub.j) may be collected at a time .sub.ai within interval .sub.a, and a value A.sub.b(.sub.j) may be collected at a different time .sub.bj within interval .sub.b. Accordingly, time intervals .sub.a, and .sub.b may be overlapping or non-overlapping. Furthermore, in some embodiments a portion of time interval .sub.a may occur between two portions of time interval .sub.b. For example, in some embodiments the wavelength scan of agile light source forming ICE 310a and ICE 310b (cf.
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(36) Thus, for example, agile light source 110 may provide a source light amplitude 440-1 forming ICE simulation 410 at a first time, and a source light amplitude 540-1 forming ICE simulation 510 at a second time. While source light amplitude 440-1 may be different from source light amplitude 540-1, and the times at which the amplitudes are provided to sample 120 may also be different, the center wavelength of the source light may be the same for amplitudes 440-1 and 540-1. Source controller 112 stores in memory circuit 114 the times at which signal amplitudes 440 and 540 are provided, and the corresponding wavelengths. Thus, detection controller 140 is able to correlate an amplitude of input light 150 for each signal generated in detector 130 by sample light 151, whether coming from ICE simulation 410 or from ICE simulation 510. This information may be used by analysis unit 145 to perform the signal integration and other operations shown in Eqs. (4-6) above, ultimately providing values for a plurality of measurement properties .sub.i.
(37) With reference back to
(38) Alternatively, one or more ICE profiles 101 can be downloaded into memory circuit 114 during sampling operation. For example, when a new property is requested for measurement, an ICE profile 101 associated to the new property may be downloaded into memory circuit 114 via wireless communication, or over a wired network. Once the new ICE profile 101 is stored in memory 114, processor circuit 113 may apply it in real-time to emitter circuit 115. The operational flexibility of optical measurement system 100 allows the optimization of fluid analysis on the fly, to best suit changing fluid or sampling conditions.
(39) Accordingly, light source 110 may be adapted for tool calibration. A known or recently analyzed fluid spectrum can be recast to expected conditions of an upcoming measurement to calibrate at a finer scale the response under field conditions. For example, an ICE profile 101 may be slightly modified by processor circuit 113 according to a model that accounts for different sample temperatures, pressures, or different gas, liquid or solid concentrations based on input from a sensor 116. Sensor 116 may be, for example, disposed to measure a condition of the local environment, such as temperature or pressure. The model and commands for applying the model may be stored in memory circuit 114. Accordingly, embodiments of light source 110 as disclosed herein may be adaptable and recalibrated without performing complex calibration steps which are required for manufacturing conventional multi-layer ICEs. In some embodiments, the ICE profiles 101 corresponding to traditional ICEs are digitally stored as part of agile light source 110 (e.g., in memory circuit 114), so that the ICE profile 101 in use by light source 110 may be altered or modified or changed without taking optical measurement system 100 out of a measurement setting. Such configurations accrue significant cost reduction since only a single agile light source is necessary to satisfy needs from different field operations. In that regard, some embodiments eliminate the need to design and manufacture traditional ICEs for different analytes in different fields. Cost reduction is also accrued through reduction in mechanical, electrical and electronic complexity of the sensor package due to the elimination of a rotating wheel. This leads to increase in tool robustness and lower maintenance cost due to a simpler mechanical and electrical design. Thus, by incorporating a plurality of ICE profiles 101 as part of the system, the ALICE or agile lite source 110, provides significant flexibility to be quickly adjusted in situ.
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(42) In some embodiments, optical measurement system 100 as disclosed herein may be implemented in permanent monitoring applications. For example, in an oil extraction rig similar to drilling rig 710, optical measurement system 100 may determine the chemical composition of the extracted hydrocarbons during regular operations. Further according to some embodiments, optical measurement system 100 may be used in a subsea environment of a wireline operation (cf.
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(44) To simulate an ICE as described herein in order to measure a characteristic or property of an analyte, step 810 includes selecting an ICE spectral profile to measure a desired fluid property. Step 820 includes storing the ICE spectral profile in a memory circuit or alternatively, sending the ICE spectral profile via a communication link to a light source. Step 830 includes providing a driving signal with the ICE spectral profile to a light source. Step 840 includes driving a light source with the ICE spectral profile so as to provide an illumination light from the light source to a sample. Step 850 includes collecting a sample light into a detector. Step 860 includes processing the detector signal with the spectral profile of 810. In another embodiment, a second ICE spectral profile, different from the first ICE spectral profile, may be used to drive the light source so as to measure a different characteristic or property of the analyte. It will be appreciated that the driven light may be cycled through a plurality of ICE spectral profiles in a short amount of time, thereby permitting a plurality of measurements to be made quickly. In certain embodiments, the foregoing method may be practiced during drilling of a wellbore as described above or during logging of a wellbore.
(45) In one embodiment, an optical measurement system comprises: a light source to provide an input light, the light source having a source controller circuit; a sample containment area; a detector to detect a sample light; a spectral profile for an integrated computational element; and a detector controller circuit to synchronize the input light and the detector and to implement the spectral profile in order to provide a light signal to simulate an integrated computational element in a period of time with the input light.
(46) In the practice of the foregoing, the optical measurement system may be enhanced by any one of the following, either alone or in combination with one another: An analysis unit configured to integrate a signal from the detector over the period of time and provide a value of a measurable property of the sample. A plurality of different spectral profiles for an integrated computational element. Spectral profiles for a plurality of different integrated computational elements. The sample containment area comprises one of a cavity, and open or closed container or a window adjacent a sample to be analyzed. The integrated computational element profile includes a first spectrum and a second spectrum, the first spectrum and the second spectrum selected according to a linear regression vector for a measurable property of the sample. The signal from the detector comprises a difference between a signal from the first spectrum and a signal from the second spectrum, or alternatively, the signal from the detector comprises a ratio of a signal from the first spectrum and a sum of the signal from the first spectrum and a signal from the second spectrum. A drilling system having a drilling rig, a drill string, a bottomhole assembly carried by the drill string; a drill bit carried by the bottomhole assembly, wherein at least a portion of the optical measurement system is carried by the drill string or forms part of the bottomhole assembly. The system may further include optical fiber carried by drill string connecting portions of the optical measurement system. A wellbore monitoring system having a wireline, slickline, coiled tubing or cabling deployed in a wellbore and supporting at least a portion of the optical measurement system. The system may further include optical fiber carried by the wireline, slickline, coiled tubing or cabling, connecting portions of the optical measurement system.
(47) In one embodiment, a light source for use in an optical measurement system has a light source comprising: a light emitting circuit having a pre-selected center wavelength, a pre-selected amplitude, and a bandwidth; and a controller circuit to provide a signal to the light emitting circuit to simulate an integrated computational element in a period of time with the input light; wherein the controller circuit comprises a memory circuit, the memory circuit comprising an spectral profile having a first spectrum and a second spectrum associated with the simulated integrated computational element.
(48) In the practice of the foregoing, the light source may be enhanced by any one of the following, either alone or in combination with one another: The spectral profile comprises a wavelength range greater than the bandwidth of the light emitting circuit; and the signal provided to the light emitting circuit comprises the pre-selected center wavelength and the pre-selected amplitude. The wavelength range of the light source comprises the pre-selected center wavelength within at least the bandwidth of the light emitting circuit. The light emitting circuit can provide input light with the pre-selected amplitude for the first spectrum at a first time, and can provide input light with the pre-selected amplitude for the second spectrum at a second time. The first time is included in a first period of time and the second time is included in a second period of time. The first period of time overlaps at least a portion of the second period of time. The first period of time and the second period of time are interleaved so that the second time is subsequent to the first time. A weighted difference between the first spectrum and the second spectrum is proportional to a regression vector associated to a measurable property of a sample. A ratio of the first spectrum to a sum of the first spectrum and the second spectrum is proportional to a regression vector associated to a measurable property of a sample. A plurality of different spectral profiles for an integrated computational element. Spectral profiles for a plurality of different integrated computational elements.
(49) In one embodiment, a method for measuring a desired property of a sample comprises: selecting an integrated computational element (ICE) spectral profile to measure the desired property; providing a driving signal with the ICE spectral profile to a light source; providing an illumination light from the light source to the sample based on the ICE spectral profile; collecting a sample light in a detector; and processing the detector signal using a collection signal with the spectral profile.
(50) In one embodiment, a method for measuring a desired property of a sample comprises: simulating an integrated computational element using an agile light source; and measuring a property of the sample using the simulated integrated computational element.
(51) In the practice of the foregoing, the methods for measuring a desired property of a sample may be enhanced by any one of the following, either alone or in combination with one another: Processing the detector signal further comprises synchronizing the collection signal with the driving signal. Selecting an ICE spectral profile comprises finding a linear regression vector using a first spectral profile and a second spectral profile. Selecting an ICE spectral profile comprises selecting a plurality of spectral profiles to measure a plurality of desired properties. Storing a plurality of different spectral profiles for an integrated computational element. Storing spectral profiles for a plurality of different integrated computational elements. Selecting a plurality of ICE spectral profiles to measure a plurality of desired properties comprises measuring at least one property of the group consisting of an octane rating, a gas-oil-ratio (GOR), a hydrocarbon composition, a carbon dioxide (CO2) composition, and a water (H2O) composition. Measuring the hydrocarbon composition comprises measuring any one of the group consisting of a C1 hydrocarbon molecule, a C2 hydrocarbon molecule, a C3 hydrocarbon molecule, a C4 hydrocarbon molecule, a C5 hydrocarbon molecule, and a C6 hydrocarbon molecule. Providing an illumination light in a wellbore from the light source to a sample in the wellbore, either during wireline, slickline or coiled tubing operations in the wellbore or during drilling of the wellbore
(52) Embodiments described herein are exemplary only. One skilled in the art may recognize various alternative embodiments from those specifically disclosed. Those alternative embodiments are also intended to be within the scope of this disclosure. As such, the embodiments are limited only by the following claims.