Exhaust treatment apparatus and container apparatus
10315151 ยท 2019-06-11
Assignee
Inventors
Cpc classification
H01M50/24
ELECTRICITY
B01D46/0005
PERFORMING OPERATIONS; TRANSPORTING
B01D53/0407
PERFORMING OPERATIONS; TRANSPORTING
Y02E60/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M50/204
ELECTRICITY
H01M10/4207
ELECTRICITY
International classification
B01D53/02
PERFORMING OPERATIONS; TRANSPORTING
H01M10/42
ELECTRICITY
Abstract
An exhaust treatment apparatus includes a casing having an inlet port for allowing an exhaust gas to flow into the casing and an outlet port for allowing a purified exhaust gas to be discharged from the casing, an exhaust fan provided in the casing for sending the exhaust gas from the inlet port to the outlet port, and chemical filters provided in two or more stages between the exhaust fan in the casing and the outlet port.
Claims
1. An exhaust treatment apparatus comprising: a casing having a first chamber with an inlet port provided at a lower portion of the first chamber and configured to allow an exhaust gas to flow into the casing, a second chamber with an outlet port provided at a lower portion of the second chamber and configured to allow a purified exhaust gas to be discharged from the casing, and a partition plate as a partition between the first chamber and the second chamber; a communication hole provided at an upper position of the partition plate and configured to communicate the first chamber with the second chamber; an exhaust fan provided at an upper position of the first chamber, the exhaust fan being configured to send the exhaust gas from the inlet port of the first chamber to the second chamber through the communication hole; and a chemical filter provided in at least one stage in a flow path between the communication hole in the partition plate and the outlet port of the second chamber, wherein a pre-filter in at least one stage is provided in a flow path between the inlet port of the first chamber and the exhaust fan, the pre-filter having a pressure loss higher than that of the chemical filter.
2. The exhaust treatment apparatus according to claim 1, wherein the pre-filter is arranged in an oblique direction relative to flow direction of the exhaust gas.
3. The exhaust treatment apparatus according to claim 1, wherein at least one first pre-filter is provided in a preceding stage of the chemical filter, the first pre-filter having a pressure loss higher than that of the chemical filter; and a second pre-filter is provided between the chemical filter and the first pre-filter, the second pre-filter having a pressure loss higher than that of the chemical filter and lower than that of the first pre-filter.
4. The exhaust treatment apparatus according to claim 1, wherein the chemical filter comprises chemical filters in two or more stages, and among the chemical filters, adjacent chemical filters are provided in different orientations.
5. A container apparatus comprising a package having a container space surrounded by at least a roof, a front plate, and a side plate, and a content housed in the container space of the package, the container apparatus further having: an intake port and an exhaust port provided in the package; a shutter mechanism configured to close the intake port and the exhaust port when an abnormality occurs in the content and thereby confine the exhaust gas; and an exhaust treatment apparatus provided in combination with the package, wherein the exhaust treatment apparatus includes: a casing having a first chamber with an inlet port provided at a lower portion of the first chamber and configured to allow an exhaust gas to flow into the casing, a second chamber with an outlet port provided at a lower portion of the second chamber and configured to allow a purified exhaust gas to be discharged from the casing, and a partition plate as a partition between the first chamber and the second chamber; a communication hole provided at an upper position of the partition plate and configured to communicate the first chamber with the second chamber; an exhaust fan provided at an upper position of the first chamber, the exhaust fan being configured to send the exhaust gas from the inlet port of the first chamber to the second chamber through the communication hole; and chemical filters provided in two or more stages in a flow path between the communication hole in the partition plate and the outlet port of the second chamber, wherein a pre-filter in at least one stage is provided in a flow path between the inlet port of the first chamber and the exhaust fan, the pre-filter having a pressure loss higher than that of the chemical filter.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
(17)
(18)
(19)
DESCRIPTION OF THE PREFERRED EMBODIMENTS
(20) Hereinafter, embodiments of an exhaust treatment apparatus and a container apparatus according to the present invention will be described with reference to
(21) Firstly, as shown in
(22) Specifically, the casing 18 has a rectangular parallelepiped outer shape, for example. The casing 18 includes a first chamber 24A having the inlet port 14, a second chamber 24B having the outlet port 16, and a partition plate 26 as a partition between the first chamber 24A and the second chamber 24B. The partition plate 26 has a communication hole 28 for communicating the first chamber 24A with the second chamber 24B. The inlet port 14 is provided at a lower position of the first chamber 24A, and the outlet port 16 is provided at a lower position of the second chamber 24B. The communication hole 28 is provided at an upper position of the partition plate 26. An exhaust fan 20 is provided at an upper position of the first chamber 24A, and sends the exhaust gas 12 from the inlet port 14 of the first chamber 24A to the second chamber 24B through the communication hole 28.
(23) The chemical filters 22 are provided in the second chamber 24B, and the second chamber 24B has support members 30 for supporting the chemical filters 22. Any member can be used as the support member 30 as long as it does not obstruct the downward flow of the exhaust gas 12 passing through the chemical filter 22. For example, a frame body or a grid plate fixed to a rack frame provided on an inner wall of the second chamber 24B may be used as the support member 30. It is a matter of course that the rack frame itself may be used as the support member 30. It should be noted that illustration of the support member is omitted in
(24) For example, each of the chemical filters 22 is a molded structure having grid structure (including honeycomb structure) made of porous absorbing material, or a structure where porous granular absorbing material is supported on a porous structural component such as nonwoven fabric. This chemical filter 22 uses activated carbon or aluminum oxide as base material, and is formed by molding the base material while mixing with phosphoric acid, potassium carbonate, sodium thiosulfate, sodium permanganate, sulfur, etc. appropriately in correspondence with the target component removed from the exhaust gas 12 (i.e., target component to be absorbed). The target component includes formaldehyde, VOCs (volatile organic compounds), ozone, hydrogen sulfide, sulfur dioxide, chlorine, ammonia, amine, etc.
(25) Next, operation of the first exhaust treatment apparatus 10A will be described. The exhaust gas 12 produced in a fire, etc. is sent from the inlet port 14 to the second chamber 24B through the communication hole 28 by operation of the exhaust fan 20. After the exhaust gas 12 is sent to the second chamber 24B, the exhaust gas 12 flows through the chemical filters 22 provided in the second chamber 24B. Consequently, the target component contained in the exhaust gas 12 is gradually removed, and the concentration of the target component in the exhaust gas 12 is reduced, and the exhaust gas 12 is purified. As a result, the purified exhaust gas 12a is discharged from the outlet port 16 of the second chamber 24B. Since no liquid is used, no flow channel for such liquid is required. Therefore, size reduction is achieved, and the first exhaust treatment apparatus 10A can be provided easily in combination with various apparatuses which discharge gas, and management and maintenance operations can be carried out easily. It should be noted that the flow speed of the exhaust gas 12 passing through at least the chemical filters 22 by operation of the exhaust fan 20 is in a range of 0.1 to 1.5 m/sec.
(26) In particular, since the inlet port 14 is provided at the lower position of the first chamber 24A, the outlet port 16 is provided at the lower position of the second chamber 24B, and the communication hole 28 is provided at the upper position of the partition plate 26, the flow path of the exhaust gas 12 can be formed vertically in a serpentine pattern, and the size of the installation area required for providing the casing 18 can be reduced. That is, at is possible to realize size reduction of the exhaust treatment apparatus 10. Consequently, the exhaust treatment apparatus 10 can be provided in combination with a building, a container apparatus (e.g., container apparatus of secondary batteries) or the like where high concentration gas is produced in a fire, etc.
(27) Further, since the exhaust fan 20 is provided at the upper position of the first chamber 24A, the exhaust gas 12 can be sent to the second chamber 24B efficiently from the inlet port 14 provided at the lower position of the first chamber 24A through the communication hole 28 provided at the upper position of the partition plate 26.
(28) Next, an exhaust treatment apparatus according to a second embodiment of the present invention (hereinafter referred to as a second exhaust treatment apparatus 10B) will be described with reference to
(29) As shown in
(30) In some cases, clogging occurs in the chemical filters 22 due to dust, etc., produced by a fire, etc., and the purification performance of the chemical filter 22 may be degraded. In the second exhaust treatment apparatus 10B, since one or more pre-filters 32 having the higher pressure loss in comparison with the chemical filters 22 are provided in the preceding stage of the chemical filters 22, dust, etc., can be collected by the pre-filter 32. Consequently, clogging in the chemical filters 22 is suppressed, and thus, degradation of the purification performance of the chemical filters 22 is suppressed.
(31) Next, an exhaust treatment apparatus according to a third embodiment of the present invention (hereinafter referred to as a third exhaust treatment apparatus 10C) will be described with reference to
(32) As shown in
(33) Specifically, one or more first pre-filters 32A having a pressure loss higher than that of the chemical filters 22 are provided in the preceding stage of the chemical filters 22. Further, a second pre-filter 32B having a pressure loss higher than that of the chemical filters 22 and lower than that of the first pre-filter 32A is provided between the chemical filters 22 and the first pre-filter 32A. As for installation of the second pre-filter 32B, as shown in
(34) In this regard, the range of pressure loss of each of the chemical filter 22, the first pre-filter 32A and the second pre-filter 32B is shown in the following table 1. This table shows the range of the pressure loss in the case where the flow speed is 1.5 m/sec.
(35) TABLE-US-00001 TABLE 1 Pressure Loss (In the case of flow speed of 1.5 m/sec) Chemical 30 to 20 Pa Filter First 150 to 30 Pa Pre-Filter Second 25 to 15 Pa Pre-Filter
(36) In the third exhaust treatment apparatus 10C, the first pre-filter 32A is provided in the preceding stage of the chemical filters 22. Therefore, as in the case of the second exhaust treatment apparatus 10B, since dust, etc. collected by the first pre-filter 32A, clogging of the chemical filters 22 is suppressed, and thus, degradation of the purification performance of the chemical filters 22 is suppressed.
(37) Even in the case where the chemical filters 22 are provided in multiple stages, depending on the structure of the chemical filters 22, the flow of the exhaust gas 12 is aligned, and turbulence of the flow of the exhaust gas 12 does not occur easily at the surfaces of the chemical filters 22 in the second stage and the subsequent stages. This often occurs particularly in the case where a porous body having gird structure or honeycomb structure is used. In such a case, the target component is reduced effectively (removal rate of the target component is high) in the chemical filter 22 in the first stage (uppermost stage). However, in some cases, the chemical filters in the second stage and the subsequent stages hardly produce the reduction effect of the target component.
(38) In order to address the problem, in the third exhaust treatment apparatus 10C, the second pre-filter 32B is provided between the chemical filters 22 and the first pre-filter 32A. Specifically, the second pre-filter 32B is provided on the surface of each of the chemical filters 22. In the structure, since the flow of the exhaust gas 12 is disturbed by the second pre-filter 32B, turbulent flow of the exhaust gas 12 is generated easily at the surface of the chemical filter 22. Consequently, even in the case where the chemical filters 22 are provided in multiple stages, the effect of reducing concentration of the target component (effect of removing the target component) in each chemical filter 22 is obtained at a certain level or more. Further, since the pressure loss of the second pre-filter 32B is lower than that of the first pre-filter 32A, it is possible to prevent the excessive increase in the resistance.
(39) Next, an exhaust treatment apparatus according to a fourth embodiment of the present invention (hereinafter referred to as a fourth exhaust treatment apparatus 10D) will be described with reference to
(40) As shown in
(41) In the above described second exhaust treatment apparatus 10B, two pre-filters 32 are arranged in a horizontal posture. In contrast, in this fourth exhaust treatment apparatus 10D, three pre-filters 32 are arranged in an oblique posture, such that the surfaces of the pre-filters 32 are oriented, e.g., toward the second chamber 24B. Specifically, the pre-filters 32 are arranged obliquely relative to the flow direction of the exhaust gas 12. The pre-filters 32 are installed at an inclined angle in a range of 10 to 60 relative to the horizontal direction. In the structure, the surface areas of the pre-filters 32 can be increased about twice at most in comparison to the case of the horizontally-arranged pre-filters. In
(42) Further, in the fourth exhaust treatment apparatus 10D, the adjacent chemical filters 22 are provided in different orientations. Specifically, the chemical filters 22 in the first stage, third stage, and fifth stage from the top are arranged in an oblique posture such that the surfaces of the chemical filters 22 are orientated toward the first chamber 24A, for example. The chemical filters 22 in the second stage and the fourth stage are arranged in an oblique posture such that the surfaces of the chemical filters 22 are orientated in a direction opposite to the first chamber 24A. Also in this case, the chemical filters 22 are installed at an inclined angle in a range of 5 to 50, preferably, in a range of 10 to 30 relative to the horizontal direction. In
(43) In this fourth exhaust treatment apparatus 100, firstly, the pre-filter 32 is oriented in an oblique direction relative to the flow direction of the exhaust gas 12. Therefore, in the case where the pre-filter 32 has, e.g., porous structure like non-woven fabric, the surface area of the contact between the exhaust gas 12 and the pre-filter 32 is increased, so that the effect of collecting dust, etc. is increased.
(44) Further, since the adjacent chemical filters 22 are provided in different orientations, turbulence is caused in the flow of the exhaust gas 12, and the exhaust gas 12 can be agitated. Consequently, the effect of reducing concentration of the target component (effect of removing the target component) in each chemical filter 22 is obtained at a certain level or more.
(45) In particular, the chemical filters 22 in the first stage, third stage, and fifth stage from the top are arranged in an oblique direction such that the surfaces of the chemical filters 22 are oriented toward the first chambers 24A, whereas the chemical filters 22 in the second and fourth stage are arranged in an oblique direction such that the surfaces of the chemical filters 22 are oriented in a direction opposite to the first chamber 24A. In this case, by making each of the chemical filters 22 to have a grid structure or a honeycomb structure, the exhaust gas 12 can be caused to flow in a zigzag pattern. With the simple structure, it is possible to agitate the exhaust gas 12. It is not required to additionally provide an apparatus for agitating the exhaust gas 12.
(46) Next, one experimental example will be shown. In this experimental example, as the exhaust gas 12, SO.sub.2 gas was used. The removal rate of SO.sub.2 (target component) was checked for each of the first exhaust treatment apparatus 10A, the third exhaust treatment apparatus 10C, and the fourth exhaust treatment apparatus 10D. Specifically, assuming that SO.sub.2 concentration before the exhaust gas 12 passes through the chemical filters 22 is a reference concentration, the ratio of the SO.sub.2 concentration after the exhaust gas passes through each of the chemical filters 22 to the reference concentration and the overall removal rate of the target component were checked. The result is shown in the following table 2.
(47) TABLE-US-00002 TABLE 2 Ratio To Reference Concentration After After After After After Reference 1st 2nd 3rd 4th 5th Overall Concen- Stage Stage Stage Stage Stage Removal tration Filter Filter Filter Filter Filter Rate First 100% 45% 42% 43% 44% 37% 63% Exhaust Treatment Apparatus Third 100% 56% 29% 8% 4% 1% 99% Exhaust Treatment Apparatus Fourth 100% 72% 53% 46% 37% 25% 75% Exhaust Treatment Apparatus
(48) As can be seen from the table 2, even in the first exhaust treatment apparatus 10A, the removal rate of 60% or more is achieved, and thus, the first exhaust treatment apparatus 10A can be used in practical applications. Further, in the third exhaust treatment apparatus 10C and the fourth exhaust treatment apparatus 10D using the pre-filters, the removal rate of 75% or more is achieved, and thus, the third exhaust treatment apparatus 10C and the fourth exhaust treatment apparatus 10D have the excellent performance of purifying the exhaust gas 12. In particular, in the third exhaust treatment apparatus 10C using two types of pre-filters (first pre-filter 32A and second pre-filter 32B), the removal rate of 99% is achieved, and thus, the third exhaust treatment apparatus 10C is very excellent.
(49) Next, a container apparatus 50 according to an embodiment of the present invention will be described with reference to
(50) As shown in
(51) An exhaust apparatus 64 is provided at an upper position of the control chamber 62, and a control device 66 is provided at a lower position of the control chamber 62. A communication hole 68 (see
(52) As shown in
(53) Each of the first package 54A and the second package 54B has a plurality of (e.g., four) casings 78 (first casing 78A to fourth casing 78D). Each of the casings 78 has a container space 86 surrounded by at least a front plate 80, a rear plate 82, and a side plate 84. In the container space 86, a plurality of (e.g., five) module batteries 88 (containers) are stacked in stages.
(54) The casing 78 has four support columns 90 (see
(55) Further, as shown in
(56) Further, as shown in
(57) Further, as shown in
(58) In this case, in the casing 18 of the exhaust treatment apparatus 10, the first chamber 24A is provided adjacent to the first package 54A, and the inlet port 14 (not shown in
(59) As shown in
(60) The detection unit 100 detects concentration of an active material or an impurity contained in the gas (exhaust gas 12) discharged through the exhaust gas channel 70. The gas as the detection target may be a gas in the exhaust gas channel 70, or may be a gas forcibly discharged by the exhaust apparatus 64.
(61) The control unit 102 at least controls the intake port opening/closing unit 96, the exhaust apparatus 64, and the exhaust fan 20 of the exhaust treatment apparatus 10. During normal operation, an opening signal is outputted to the intake port opening/closing unit 96 to thereby place the intake port 94 in the open state at all times.
(62) Therefore, during normal operation, as shown in
(63) Further, when concentration of the active material detected by the detection unit 100 has a predetermined value or more, the control unit 102 outputs a closing signal to the intake port opening/closing unit 96, and outputs an operation stop signal to the exhaust apparatus 64 to thereby place the intake port 94 in the closed state and stop operation of the exhaust apparatus 64. When operation of the exhaust apparatus 64 is stopped, the exhaust port 74 is placed in the closed state as well by the wind pressure type shutter 76. Therefore, it is possible to prevent the gas containing active material (exhaust gas 12) from being discharged to the outside directly.
(64) Further, the control unit 102 operates the exhaust fan 20 of the exhaust treatment apparatus 10. Therefore, as shown in
(65) In the container apparatus 50 according to the embodiment of the present invention, when an abnormality occurs in the gas concentration in the event of a fire, etc. of the module battery 88, the intake port 94 and the exhaust port 74 of the container apparatus 50 are closed. Therefore, the high concentration exhaust gas 12 containing active material does not leak out. However, since the container apparatus 50 is filled with the exhaust gas 12, at the time of opening the container apparatus 50 for subsequently handling the accident, the handling of the accident may not be performed smoothly due to the high concentration exhaust gas. However, the container apparatus 50 according to the embodiment of the present invention is equipped with the exhaust treatment apparatus 10. Therefore, the high concentration exhaust gas 12 produced in a fire, etc. is sent from the inlet port 14 to the outlet port 16 by operation of the exhaust fan 20 of the exhaust treatment apparatus 10. Since the exhaust gas 12 flows through the chemical filter 22 between the inlet port 14 and the outlet port 16, concentration of the target component is reduced. Consequently, the purified exhaust gas 12a is discharged from the outlet port 16 of the exhaust treatment apparatus 10. Therefore, the accident can be handled promptly. Further, since no liquid is used, no flow channel for such liquid is required. Accordingly, size reduction of the container apparatus 50 where the exhaust treatment apparatus 10 is provided in combination with the first package 54A and the second package 54B is achieved, and management and maintenance operations can be carried out easily.
(66) Further, in the embodiment of the present invention, the exhaust apparatus 64 is provided at the upper position of the control chamber 62 provided adjacent to the exhaust gas channel 70, and the control device 66 having the detection unit 100 and the control unit 102 is provided at the lower position of the control chamber 62. Therefore, the space which otherwise would have been considered as a dead space in the control chamber 62 can be utilized for installation of the exhaust apparatus 64, and effective utilization of installation space is achieved. Accordingly, it becomes possible to suppress increase in the size.
(67) In the above examples, the exhaust treatment apparatus 10 is provided at the corner of the control chamber 62 adjacent to the first package 54A. Alternatively, the exhaust treatment apparatus 10 may be provided at the corner of the control chamber 62 adjacent to the second package 54B. Alternatively, the exhaust treatment apparatus 10 may be provided at the side closing plate 58 opposite to the control chamber 62, in a portion communicating with the exhaust gas channel 70. That is, the exhaust treatment apparatus 10 may be provided at any portion as long as the portion communicates with the exhaust gas channel 70.
(68) Further, in consideration of the case where a blackout occurs due to a fire, etc., preferably, an auxiliary power source should be provided. In the event of a blackout, using the auxiliary power source, the control device 66, the exhaust apparatus 64, and the exhaust treatment apparatus 10 are energized, and thus it is possible to purify the exhaust gas.
(69) In the above example, although a case has been described in which the container apparatus 50 according to the present invention is utilized for the package 54 formed by stacking a large number of module batteries 88 in stages, the container apparatus 50 can be suitably applied to a container, a warehouse, etc. containing a large number of objects to be kept at a certain temperature.
(70) It is a matter of course that the exhaust treatment apparatus and the container apparatus according to the present invention are not limited to the embodiments described above, and various structures can be adopted without deviating from the scope of the present invention.