POLYSILICON RESISTORS WITH HIGH SHEET RESISTANCE
20220399434 · 2022-12-15
Inventors
Cpc classification
H01L21/32155
ELECTRICITY
H01L21/26586
ELECTRICITY
H01L29/04
ELECTRICITY
International classification
H01L29/04
ELECTRICITY
Abstract
An integrated circuit includes a dielectric isolation structure formed at a surface of a semiconductor substrate and a polysilicon resistor body formed on the dielectric isolation structure. The polysilicon resistor body includes an N-type dopant having an N-type dopant concentration, nitrogen having a nitrogen concentration, and carbon having a carbon concentration. The sheet resistance of the resistor body is greater than 5 kΩ/square.
Claims
1. An integrated circuit comprising: a resistor including a polysilicon resistor body over a semiconductor substrate; an N-type dopant in the polysilicon resistor body; and carbon and nitrogen dopants in the polysilicon resistor body.
2. The integrated circuit as recited in claim 1, wherein the N-type dopant is phosphorous.
3. The integrated circuit as recited in claim 1, wherein the resistor has a sheet resistance greater than 5 kΩ/□.
4. The integrated circuit as recited in claim 1, wherein the resistor body has an average concentration of carbon three times an average concentration of the N-type dopant, and an average concentration of nitrogen 1.5 times the average concentration of the N-type dopant.
5. The integrated circuit as recited in claim 1, wherein the resistor has a temperature coefficient of about −0.4%/° C. at 25° C.
6. The integrated circuit as recited in claim 1, wherein the resistor has a median drift no greater than about ±0.1% after 168 hours at 150° C.
7. The integrated circuit as recited in claim 1 wherein a matching coefficient for the resistor is less than about 2.5%.Math.μm.
8. The integrated circuit as recited in claim 1, wherein the polysilicon resistor body is located over a dielectric isolation structure.
9. A method of fabricating an integrated circuit, the method comprising: forming a polysilicon resistor body over a semiconductor substrate; and implanting an N-type dopant, nitrogen and carbon into the polysilicon resistor body.
10. The method as recited in claim 9, further comprising first implanting the N-type dopant, then implanting the nitrogen, and then implanting the carbon.
11. The method as recited in claim 9, wherein the N-type dopant is phosphorous.
12. The method as recited in claim 9, wherein the N-type dopant is implanted at a dose of about 6.5 E14 cm.sup.−2 and an energy of about 30 keV.
13. The method as recited in claim 9, wherein the nitrogen is implanted at a dose of about 1.0 E15 cm.sup.−2 and an energy of about 20 keV.
14. The method as recited in claim 9 wherein the carbon is implanted at a dose of about 2.0 E15 cm.sup.−2 and an energy of about 7 keV.
15. The method as recited in claim 14 wherein implanting the carbon includes a tilt angle of about nine degrees and a rotation of a long axis of the polysilicon resistor body about four degrees with respect to the tilt axis.
16. The method as recited in claim 9 wherein implanting nitrogen, carbon and the N-type dopant includes first implanting phosphorus with a dose of about 6.5 E14 cm-2 at an energy of about 30 keV with no tilt, then implanting the nitrogen with a dose of about 1.0 E15 cm-2 at an energy of about 20 keV with no tilt, and then implanted the carbon at a dose of about 2.0 E15 cm.sup.−2 and an energy of about 7 keV using a tilt angle of about nine degrees and a rotation of a long axis of the polysilicon resistor body about four degrees with respect to the tilt axis.
17. The method as recited in claim 9, wherein an implant dose of the nitrogen is about twice an implant dose of the N-type dopant, and an implant dose of the carbon is about 1.5 times the implant dose of the N-type dopant.
18. The method as recited in claim 9, wherein the polysilicon resistor body is formed on a dielectric isolation structure.
19. The method as recited in claim 18, wherein the dielectric isolation structure is a shallow trench isolation structure.
20. The method as recited in claim 9, wherein the polysilicon resistor body has a sheet resistance greater than 5 kΩ/□ after the implanting.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0005] Implementations of the present disclosure are illustrated by way of example, and not by way of limitation, in the figures of the accompanying drawings in which like references indicate similar elements. It should be noted that different references to “an” or “one” implementation in this disclosure are not necessarily to the same implementation, and such references may mean at least one. Further, when a particular feature, structure, or characteristic is described in connection with an implementation, it is submitted that it is within the knowledge of one skilled in the art to effect such feature, structure, or characteristic in connection with other implementations whether or not explicitly described. As used herein, the term “couple” or “couples” is intended to mean either an indirect or direct electrical connection unless qualified as in “communicably coupled” which may include wireless connections. Thus, if a first device couples to a second device, that connection may be through a direct electrical connection, or through an indirect electrical connection via other devices and connections.
[0006] The accompanying drawings are incorporated into and form a part of the specification to illustrate one or more exemplary implementations of the present disclosure. Various advantages and features of the disclosure will be understood from the following Detailed Description taken in connection with the appended claims and with reference to the attached drawing figures in which:
[0007]
[0008]
[0009]
[0010]
[0011]
DETAILED DESCRIPTION
[0012] Specific implementations will now be described in detail with reference to the accompanying figures. In the following detailed description of implementations, numerous specific details are set forth in order to provide a more thorough understanding of the disclosure. However, it will be apparent to one of ordinary skill in the art that other implementations may be practiced without these specific details. In other instances, well-known features have not been described in detail to avoid unnecessarily complicating the description.
[0013] Various disclosed methods and devices of the present disclosure may be beneficially applied to ultra-high sheet resistance resistors employed in integrated circuits. Various implementations may provide resistors with low drift, low matching coefficient and low temperature coefficient of resistance while providing a sheet resistance exceeding 5 kΩ/□. While such embodiments may be expected to provide stable resistors that provide a high resistance in a small device area, no particular result is a requirement unless explicitly recited in a particular claim.
[0014]
[0015] In baseline devices (e.g. integrated circuits) implementing an HSR resistor and a UHRES resistor, the HSR resistor includes an N-type dopant, e.g., phosphorus or arsenic, which has been implanted into a polysilicon resistor body. Such N-type dopants are thought to have better resistance to drift than a P-type dopant such as boron. While such dopant stability is desirable, some such phosphorus-doped UHRES resistors have been found to be unable to meet other requirements, such as a sufficiently low temperature coefficient of resistance (TCR) and a sufficiently low matching coefficient. As a result, UHRES resistors using boron have been used in some designs. Such resistors may have low TCR and matching coefficient, but may also be subject to dopant drift effects due to the relatively high mobility of boron in polysilicon.
[0016] The inventors have determined that UHRES resistors may be made that include the benefits of reduced dopant mobility and low TCR and matching coefficient by doping polysilicon with non-electrically active dopants nitrogen (N) and carbon (C). An N-type dopant such as phosphorus or arsenic in the UHRES resistor is understood to provide better resistance to drift, the nitrogen is understood to suppress hydrogen passivation that may degrade the resistor over time, and the carbon and the nitrogen are understood to reduce the TCR and the matching coefficient. Such resistors may have a sheet resistance greater than 5 kΩ/□, and even approach 10 kΩ/□, providing stable resistors with small footprint for reduced device size.
[0017] The addition of carbon and nitrogen implants to the UHRES implantation process provides the ability to add the carbon and nitrogen implants to HSR resistors or other polysilicon resistors as well by patterning mask level used for the UHRES C/N implants to provide suitable openings to additionally dope the HSR resistors with carbon and nitrogen. The carbon and nitrogen may provide the similar benefits to the HSR resistors that are described for the UHRES resistors, e.g., improved matching coefficient and improved temperature coefficient.
[0018]
[0019] As shown in
[0020]
[0021] The implantation process 126 provides an N-type dopant, nitrogen and carbon, each of which may be provided at a corresponding dosage and energy. The N-type dopant dose may establish the sheet resistance R.sub.s of the polysilicon resistor structure 118. The use of an N-type dopant rather than a P-type dopant such as boron is expected to reduce resistance drift that might otherwise occur with the smaller boron atom. In an example implementation of the implantation process 126, the N-type dopant includes phosphorus which may be implanted at a dose of about 6.5 E14 cm.sup.−2 and an energy of about 30 keV. In other examples the N-type dopant may include arsenic with suitable adjustment of dosage and energy.
[0022] The nitrogen dopant is expected to reduce possible diffusion of hydrogen into the polysilicon resistor structure 118 as might occur during an anneal at a later stage of manufacturing. In some examples nitrogen is implanted with a dose about 1.5 times the dose of the N-type dopant. In a specific example nitrogen is implanted at a dose of about 1.0 E15 cm.sup.−2 and an energy of about 20 keV. In some examples the nitrogen implant is performed with no tilt of the semiconductor substrate 102 with respect to the normal to the top surface 110.
[0023] The carbon dopant is expected to suppress diffusion of the N-type dopant that might otherwise occur in the absence of the carbon dopant, e.g. by an anneal at a later stage of manufacturing. In some examples carbon is implanted with a dose about three times the dose of the N-type dopant, or about two times the carbon. In a specific example carbon is implanted at a dose of about 2.0 E15 cm.sup.−2 and an energy of about 7 keV. In some examples the carbon implant is performed with a tilt of the semiconductor substrate 102 of about nine degrees with respect to the normal to the top surface 110, with a rotation of the tilt axis about four degrees with respect to a long axis of the polysilicon resistor structure 118. It is expected that the concentrations of the N-type dopant, the nitrogen and the carbon will scale about proportionately with the implant dose. Thus the average concentration of carbon in the polysilicon resistor structure 118 is expected to be about 3× the average concentration of the N-type dopant, and the average concentration of nitrogen in the polysilicon resistor structure 118 is expected to be about 1.5× the average concentration of the N-type dopant. Note that these ratios apply to a polysilicon resistor body 1186 described below with respect to
[0024] While examples of the disclosure are not necessarily limited to a particular order of implanting the N-type dopant, the nitrogen and the carbon, it is thought that at least for the case that the N-type dopant is phosphorous it may be advantageous to first implant the phosphorous, then implant the nitrogen, and then implant the carbon. The implant order may be relevant to passivating grain boundaries along which hydrogen may layer otherwise diffuse, and/or stabilizing the location of the phosphorous at the desired depth in the polysilicon.
[0025]
[0026]
[0027] It is generally desirable that the matching coefficient of the polysilicon resistors formed consistent with the UHRES resistor 104 be as low as possible while meeting other resistor parameter requirements, such as having a sheet resistance greater than 5 kΩ/□.
[0028] In
[0029] By these results the inventors conclude without implied limitation that 1) moving the peak phosphorous concentration closer to the top surface of the resistor body tends to reduce the mismatch coefficient, and 2) co-implanting nitrogen and carbon tends to further reduce the mismatch coefficient. It is thought that the carbon and nitrogen suppressed hydrogen passivation and suppress phosphorous diffusion, each of which may degrade the stability of the resistor. In some technology implementations matching coefficient and sheet resistance targets may be 2%.Math.μm and 5 kΩ/□, respectively. The fifth case (210) demonstrates that a sheet resistance of about 10 kΩ/□ and a matching coefficient of about 2.25%.Math.μm are achievable by the principles of the present disclosure, providing an excellent solution to the technology target.
[0030]
[0031] The temperature coefficient of resistance (TCR) is another factor of interest for the disclosed resistors and provides a measure of how the resistance changes over temperature. The TCR was determined for polysilicon resistors formed consistent with the example of
[0032] The drift of the resistance is another factor of interest for the disclosed resistors and provides a measure of how the resistance changes, or drifts, over time. Such first was determined by aging a population of resistors formed consistent with the example of
[0033]
[0034] A patterned photoresist layer (e.g., 124 in
[0035] Following the implantation of the N-type dopant, the nitrogen and the carbon, the photoresist (e.g., 124 in
[0036] Although not specifically shown in the method 400, processing of the integrated circuit may proceed with the formation of the silicide blocking layer (e.g., 142 in
[0037] Applicants have disclosed an integrated circuit that contains a UHRES resistor that uses phosphorus as a dopant, rather than boron and a method of fabricating the integrated circuit. In addition to phosphorus, the UHRES implantation process also provides nitrogen and carbon, which provide better matching across the wafer and between batches and a better temperature coefficient of resistance. Each element in the UHRES implantation process is implanted separately and at an individual dosage and energy. The UHRES implantation process may be shared with other polysilicon resistors to provide similar benefits.
[0038] Although various implementations have been shown and described in detail, the claims are not limited to any particular implementation or example. None of the above Detailed Description should be read as implying that any particular component, element, step, act, or function is essential such that it must be included in the scope of the claims. Reference to an element in the singular is not intended to mean “one and only one” unless explicitly so stated, but rather “one or more.” All structural and functional equivalents to the elements of the above-described implementations that are known to those of ordinary skill in the art are expressly incorporated herein by reference and are intended to be encompassed by the present claims. Accordingly, those skilled in the art will recognize that the exemplary implementations described herein can be practiced with various modifications and alterations within the spirit and scope of the claims appended below.