Highly decorated tube, especially highly decorated laminate tube

Abstract

A flexible tube skirt (10) has a primary film (20) and a decorative film (30), wherein the decorative film (30) has a decoration substrate and a sealable outer layer (33) The decoration substrate is applied on all of at least one of the surfaces of the primary film (20) and is below the sealable outer layer (33). The flexible tube skirt may be used in a flexible tube.

Claims

1. A flexible tube skirt comprising a primary film and a decorative film, wherein said decorative film comprises a decoration substrate having a first surface and a second surface opposite the first surface and a sealable outer layer applied to the first surface of the decoration substrate, said primary film having a first surface and a second surface opposite the first surface, said second surface of the primary film comprising an outer sealable layer, said second surface of the decoration substrate being applied on all of the first surface of said primary film, the flexible tube skirt comprising an overlap side seam, wherein said sealable outer layer of the decorative film is sealed with the outer sealable layer of the primary film, the decoration substrate being present in the overlap side seam, said primary film being a multilayer film comprising at least one ethylene vinyl alcohol (EVOH) barrier layer.

2. A flexible tube skirt according to claim 1, wherein said decoration substrate comprises a base layer and a decoration, said decoration being applied on said base layer.

3. A flexible tube skirt according to claim 2, wherein said decoration is applied to form a metallized, holographic and/or printed surface on the base layer.

4. A flexible tube skirt according to claim 2, wherein said base layer is selected from polypropylene, polyethylene and/or polyethylene terephthalate.

5. A flexible tube skirt according to claim 2, wherein said decoration is applied to be visible through said sealable outer layer of the decorative film and/or visible through said primary film.

6. A flexible tube skirt according to claim 2, wherein said decorative film further comprises printing on the decoration and/or on the sealable outer layer.

7. A flexible tube skirt according to claim 1, wherein said sealable outer layer of said decorative film is transparent and comprises PE material.

8. A flexible tube skirt according to claim 1, wherein said primary film is a blown film.

9. A flexible tube skirt according to claim 8, wherein said primary film is a multi-layer film representing at least 70% by mass of the final flexible tube skirt.

10. A flexible tube skirt according to claim 1, wherein said primary film is printed on its first surface.

11. A flexible tube comprising a flexible tube skirt according to claim 1.

Description

(1) The invention will be better understood and other objects, details, features and advantages thereof will become more clearly apparent in the following detailed explanatory description of at least one embodiment given as an illustrative and non-limiting example with reference to the attached drawings, in which:

(2) FIG. 1 is a schematic representation of a flexible tube skirt according to the invention and showing an overlap side seam,

(3) FIG. 2 is a schematic representation of a flexible tube skirt according to a first embodiment, obtained by adhesive-lamination,

(4) FIG. 3 is a schematic representation of a flexible tube skirt according to a second embodiment, obtained by adhesive-lamination,

(5) FIG. 4 is a schematic representation of a flexible tube skirt according to a third embodiment, obtained by extrusion-lamination,

(6) FIG. 5 is a schematic representation of a flexible tube skirt according to a fourth embodiment, obtained by extrusion-lamination.

(7) In all the figures, common elements are provided with identical reference numerals.

(8) In the different FIGS. 1 to 5, the flexible tube skirt 10 comprises a primary film 20 and a decorative film 30. In each embodiment, the decorative film 30 comprises a decoration substrate and a sealable outer layer 33. According to the invention, the decoration substrate is applied on all of at least one of the surfaces of said primary film 20 and is below the sealable outer layer 33. In other words, there is no area of the primary film 20 not covered by both the decoration substrate and the sealable outer layer 33.

(9) The decoration substrate can comprise a base layer 31 and a decoration 32. The decoration 32 is applied on said base layer 31. In such embodiment, the primary film is entirely covered by said base layer 31 which is entirely covered by said decoration 32 which is entirely covered by said sealable outer layer 33.

(10) The base layer 31 can be selected from polypropylene (PP), polyethylene (PE) and/or polyethylene terephthalate (PET). Preferably, the base layer 31 has a thickness between 5 and 50 ?m, more preferably between 10 and 30 ?m.

(11) Preferably, the decoration 32 is applied on one surface of the base layer 31 so that the decoration 32 is directed toward the sealable outer layer 33 of the decorative film 30 or toward the primary film 20.

(12) In the embodiments shown in FIGS. 2 and 4, the base layer 31 is polyethylene terephthalate (PET) and the decoration 32 is directed toward the sealable outer layer 33 of the decorative film 30.

(13) In the embodiments shown in FIGS. 3 and 5, the base layer 31 is biaxially oriented polypropylene (BOPP) and the decoration 32 is directed toward the primary film 20. In this embodiment, the base layer 31 is preferably transparent, so that the decoration 32 is clearly visible.

(14) The decoration 32 can be a metallized, holographic and/or printed surface and the sealable outer layer 33 of the decorative film function as a protective layer, especially in the embodiments of FIGS. 2 and 4. In all the embodiments, the sealable outer layer 33 is preferably transparent so that the decoration is clearly visible from outside the tube. It can comprise a PE material and it can be a multilayer or a coating comprising PE. Generally, the sealable outer layer 33 of said decorative film 30 has a thickness between 5 and 90 ?m, more preferably between 10 and 80 ?m. The thickness of the sealable outer layer 33 can depend, for example, of the nature of the different layers.

(15) Once formed, the flexible tube skirt can comprise an overlap side seam 40, i.e. a seam obtained by the superposition of two opposite sides of a laminated film, as shown in FIG. 1. Preferably, the primary film 20 is a multilayer film that can comprise an outer sealable layer 21 that is sealed with the sealable outer layer 33 of the decorative film 30.

(16) The side seam can be done by method known in the tube industry. In particular, it can be obtained by heat sealing. In this case, the outer sealable layer 21 of the primary film and the sealable outer layer 33 of the decorative film 30 are heat sealable outer layers.

(17) In the present invention, the outer sealable layer 33 of the decorative film 30 allow to have the decoration 32 applied on all of at least one of the surfaces of said base layer 31 even in the region of the side seam 40, as shown in FIG. 1.

(18) To complete and enhance the decorative aspect of the tube, the decorative film 30 can be further printed on the decoration 32 and/or on the sealable outer layer 33 and/or on the primary film 20 on a surface directed toward said decorative film 30. Known surface printing methods can be used, such as UV-flexographic method.

(19) The primary film 20 can be a blown film, i.e. a film obtained by co-extruding several polymer material compositions as hot melts through a die in the form of a tube and blowing cooling air currents thereon to form a cylindrical bubble. Once the blown film bubble has cooled, it is then collapsed at a desired point by nip rollers, and a multilayer primary film is obtained with a uniform thickness. The blown film technology is well known in the art.

(20) With such technology, the different layers of the primary film have a similar molecular orientation profile and do not exhibit conflicting molecular orientation profiles and/or stress patterns. As a result, the respective layers do not exhibit competing forces or stresses and does not suffer of weakness in terms of stress cracking and/or delamination. In addition, once formed the final flexible tube does not suffer from ovality and other distortions, which can ultimately compromise the structural integrity of the final product.

(21) As said before, the primary film 20 can be a multilayer film. Preferably it comprises between three and twenty-two layers. At least one of the layers can be a barrier layer, such as an ethylene vinyl alcohol (EVOH) layer. The others layers can be selected from polyethylene, such as low density polyethylene (LDPE), linear low density polyethylene (LLDPE), medium density polyethylene (MDPE), high density polyethylene (HDPE) or their mixture, or ethylene vinyl acetate (EVA). Between the different layers, a tie layer and/or an adhesive coating can be applied to enhance the adherence for example, notably on the barrier layer surfaces. Preferably the primary film 20 has a thickness between 100 and 500 ?m, more preferably between 200 and 350 ?m.

(22) Among the layers of the skirt, the primary film 20 comprises the layers located between a lower layer in contact with the interior of the tube (for example the sealable outer layer 21 of FIG. 1) and an upper layer adjacent to an assembly layer (for example layers 51 or 53 shown in FIGS. 2 to 5) situated between the primary film 20 and the decorative film 30, and more precisely between the primary film 20 and the base layer 31, i.e. the layer on which the decoration 32 is applied.

(23) In a preferred embodiment, the primary film 20 represents at least 70% by mass of the final flexible tube skirt 10, taking into account the lower layer, the upper layer and all the layers in between.

(24) The primary film 20 and the decorative film 30 can be assembled by method known in the art. It can be with solvent adhesive, solvent free adhesive, UV adhesive-lamination or by extrusion-lamination. Generally, the decoration substrate and the outer sealable layer 33 can also be assembled using similarly methods.

(25) In the case of an adhesive-lamination process, shown in FIGS. 2 and 3, the flexible tube skirt can comprise an adhesive layer 51 mentioned before as assembly layer and delimiting the primary film and the decorative film. The adhesive layer 51 can comprise polyurethane.

(26) In the embodiment shown in FIG. 2, the sealable outer layer 33 is assembled to the decorated base layer 31 with an adhesive layer, such as the layer 52, which can comprise polyurethane.

(27) In the case of an extrusion-lamination process, shown in FIGS. 4 and 5, the flexible tube skirt can comprise an extrusion layer 53 mentioned before as assembly layer and delimiting the primary film and the decorative film. The extrusion layer can be a monolayer called tie layer or can comprise two layers, a tie layer and a PE layer, such as low density polyethylene (LDPE). The tie layer can comprise an ethylene acrylic acid copolymer (EAA).

(28) In the embodiment shown in FIG. 4, the sealable outer layer 33 is assembled to the decorated base layer 31 with an extrusion layer, such as the layer 54, which can be a monolayer called tie layer comprising an ethylene acrylic acid copolymer (EAA) or can comprise two layers, a tie layer comprising an ethylene acrylic acid copolymer (EAA) and a PE layer, such as low density polyethylene (LDPE).

(29) The sealable outer layer 33 can be assembled to the decorated base layer 31 with an adhesive layer such as the layer 52 in FIG. 2 or with an extrusion layer such as the layer 54 in FIG. 4. Alternatively, the layer 54 and the sealable outer layer 33 may be produced by co-extrusion, thereby coating the decoration 32 in FIG. 4 or the base layer 31 in FIG. 5.

(30) Coming to the specific embodiment of FIG. 2, it comprises, from the inside to the outside: the primary film 20, the adhesive layer 51, the base layer 31, the decoration 32, the adhesive layer 52, the sealable outer layer 33.

(31) Coming to the specific embodiment of FIG. 3, it comprises, from the inside to the outside: the primary film 20, the adhesive layer 51, the decoration 32, the base layer 31, the sealable outer layer 33.

(32) Coming to the specific embodiment of FIG. 4, it comprises, from the inside to the outside: the primary film 20, the extrusion layer 53, the base layer 31, the decoration 32, the extrusion layer 54, the sealable outer layer 33.

(33) Coming to the specific embodiment of FIG. 5, it comprises, from the inside to the outside: the primary film 20, the extrusion layer 53, the decoration 32, the base layer 31, the sealable outer layer 33.

(34) Here are some detailed examples of structures according to the invention.

EXAMPLE 1

(35) TABLE-US-00001 Density Thickness Correspondance with Layer Material Type (g/cm3) (?) FIGS. 1 MDPE 0.934 15 Sealable outer layer 2 MDPE 0.934 22 (33) 3 MDPE 0.934 13 4 Adhesive lamination 4 Adhesive layer (52) 5 PET film 1.417 12 Decoration (32) + base layer (31) 6 Adhesive lamination 4 Adhesive layer (51) 7 MDPE (clear) 0.934 109 Primary film (20) 8 Tie 0.91 7 9 EVOH 1.17 10 10 Tie 0.92 7 11 Adhesive layer EVA 0.941 17 ? 2 12 Tie 0.92 7 13 EVOH 1.17 10 14 Tie 0.91 7 15 MDPE (clear) 0.934 109

EXAMPLE 2

(36) TABLE-US-00002 Density Thickness Correspondance with Layer Material Type (g/cm3) (?) FIG. 2 1 MDPE 0.934 15 Sealable outer layer 2 MDPE 0.934 22 (33) 3 MDPE 0.934 13 4 Adhesive lamination 4 Adhesive layer (52) 5 PET film 1.417 12 Decoration (32) + base layer (31) 6 Adhesive lamination 4 Adhesive layer (51) 7 MDPE (clear) 0.934 59 Primary film (20) 8 MDPE (white color) 0.934 50 9 Tie 0.91 7 10 EVOH 1.17 10 11 Tie 0.92 7 12 Adhesive layer EVA 0.941 17 ? 2 13 Tie 0.92 7 14 EVOH 1.17 10 15 Tie 0.91 7 16 MDPE (white color) 0.934 50 17 MDPE (clear) 0.934 59

(37) Avantageously, the first and the last layers (layer 1 and layer 17) are composed of MDPE, for a better sealing. In other terms, the sealable outer layers of the decorative film and the primary film are composed of MDPE.

(38) The melt flow index of MDPE is in a range between 0.9 to 3.5 gm per 10 minutes (2.16 kg, 190 degrees Celsius).

(39) The melting point of MDPE is in a range between 122 and 125 degrees Celsius.

EXAMPLE 3

(40) TABLE-US-00003 Thickness Layer Material Type (?) Correspondance with FIG. 2 1 LLDPE 15 Sealable outer layer (33) 2 MDPE 22 3 LLDPE 13 4 Adhesive lamination Adhesive layer (52) 5 Metallized PET film 12 Decoration (32) + base layer with metal up (31) 6 Adhesive lamination Adhesive layer (51) 7 MDPE 72 Primary film (20) 8 Tie 7 9 EVOH 7 10 Tie 7 11 MDPE 40 12 Adhesive layer EVA 17.3 ? 2 13 MDPE 40 14 Tie 7 15 EVOH 7 16 Tie 7 17 MDPE 72