MANUFACTURING METHOD OF THERMOPLASTIC CONTINUOUS-DISCONTINUOUS FIBER COMPOSITE SHEET
20190152212 ยท 2019-05-23
Assignee
Inventors
Cpc classification
B29B17/0026
PERFORMING OPERATIONS; TRANSPORTING
B29C70/34
PERFORMING OPERATIONS; TRANSPORTING
B32B5/16
PERFORMING OPERATIONS; TRANSPORTING
Y02W30/62
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B38/0012
PERFORMING OPERATIONS; TRANSPORTING
B29C70/081
PERFORMING OPERATIONS; TRANSPORTING
B29C66/72141
PERFORMING OPERATIONS; TRANSPORTING
B32B2272/00
PERFORMING OPERATIONS; TRANSPORTING
B32B37/182
PERFORMING OPERATIONS; TRANSPORTING
B32B37/24
PERFORMING OPERATIONS; TRANSPORTING
B32B5/30
PERFORMING OPERATIONS; TRANSPORTING
B29B7/90
PERFORMING OPERATIONS; TRANSPORTING
B32B38/0004
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/54
PERFORMING OPERATIONS; TRANSPORTING
B32B37/144
PERFORMING OPERATIONS; TRANSPORTING
B29C66/72143
PERFORMING OPERATIONS; TRANSPORTING
B29K2105/08
PERFORMING OPERATIONS; TRANSPORTING
B32B2262/106
PERFORMING OPERATIONS; TRANSPORTING
B32B2037/148
PERFORMING OPERATIONS; TRANSPORTING
B29C69/001
PERFORMING OPERATIONS; TRANSPORTING
B32B2260/021
PERFORMING OPERATIONS; TRANSPORTING
B29B17/04
PERFORMING OPERATIONS; TRANSPORTING
B32B5/24
PERFORMING OPERATIONS; TRANSPORTING
B32B2250/40
PERFORMING OPERATIONS; TRANSPORTING
B29K2105/12
PERFORMING OPERATIONS; TRANSPORTING
Y02P20/582
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B27/20
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B37/18
PERFORMING OPERATIONS; TRANSPORTING
B32B27/20
PERFORMING OPERATIONS; TRANSPORTING
B29C69/00
PERFORMING OPERATIONS; TRANSPORTING
B29C65/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A manufacturing method of a thermoplastic continuous-discontinuous fiber composite sheet is provided, including providing a thermoplastic composite including a continuous fiber and a first thermoplastic resin. A mechanical treatment is performed on the thermoplastic composite to form a plurality of fragments such that the continuous fiber is changed into a discontinuous fiber. At least one thermoplastic discontinuous fiber aggregate layer is formed using the plurality of fragments as a raw material. The at least one thermoplastic discontinuous fiber aggregate layer is thermally compressed with at least one thermoplastic continuous fiber layer.
Claims
1. A manufacturing method of a thermoplastic continuous-discontinuous fiber composite sheet, comprising: providing a thermoplastic composite, wherein the thermoplastic composite comprises a continuous fiber and a first thermoplastic resin; performing a mechanical treatment on the thermoplastic composite to form a plurality of fragments such that the continuous fiber is changed into a discontinuous fiber; forming at least one thermoplastic discontinuous fiber aggregate layer using the plurality of fragments as a raw material; and thermally compressing the at least one thermoplastic discontinuous fiber aggregate layer and at least one thermoplastic continuous fiber layer.
2. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 1, wherein the step of thermally compressing the at least one thermoplastic discontinuous fiber aggregate layer and the at least one thermoplastic continuous fiber layer comprises overlapping the thermoplastic discontinuous fiber aggregate layer and the two thermoplastic continuous fiber layer and performing a thermal compression such that the thermoplastic discontinuous fiber aggregate layer is clamped between the two thermoplastic continuous fiber layers.
3. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 1, wherein the step of thermally compressing the at least one thermoplastic discontinuous fiber aggregate layer and the at least one thermoplastic continuous fiber layer comprises overlapping the thermoplastic continuous fiber layer and the two thermoplastic discontinuous fiber aggregate layer and performing a thermal compression such that the thermoplastic continuous fiber layer is clamped between the two thermoplastic discontinuous fiber aggregate layers.
4. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 1, wherein the step of thermally compressing the at least one thermoplastic discontinuous fiber aggregate layer and the at least one thermoplastic continuous fiber layer comprises alternately overlapping the thermoplastic continuous fiber layer and the thermoplastic discontinuous fiber aggregate layer and performing a thermal compression.
5. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 1, further comprising, before the step of thermally compressing the at least one thermoplastic discontinuous fiber aggregate layer and the at least one thermoplastic continuous fiber layer, forming a strengthening layer on at least one surface of the thermoplastic discontinuous fiber aggregate layer, wherein the strengthening layer is at least located between the thermoplastic discontinuous fiber aggregate layer and the thermoplastic continuous fiber layer.
6. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 5, wherein the strengthening layer comprises a single film layer or is formed by a powder.
7. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 1, wherein a method of forming the thermoplastic discontinuous fiber aggregate layer comprises thermally compressing the plurality of fragments.
8. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 7, wherein a method of thermally compressing the plurality of fragments comprises molding or stamping.
9. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 1, wherein a method of forming the thermoplastic discontinuous fiber aggregate layer comprises mixing and granulating the plurality of fragments to form a plurality of particles and performing an injection molding using the plurality of particles.
10. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 1, wherein a method of thermally compressing the thermoplastic discontinuous fiber aggregate layer and the thermoplastic continuous fiber layer comprises performing a lamination using a flat film or a flat steel sheet.
11. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 1, wherein the continuous fiber in the thermoplastic composite comprises a carbon fiber, a glass fiber, a basalt fiber, a metal fiber, a ceramic fiber, or a chemical fiber.
12. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 1, wherein the first thermoplastic resin in the thermoplastic composite comprises a polycarbonate (PC), a polypropylene (PP), a polysulfone (PS), a thermoplastic polyurethane (TPU), an acrylonitrile butadiene styrene resin (ABS), a polyethylene (PE), a thermoplastic epoxy resin, a polyurethane resin, a polyurea resin, or a combination thereof.
13. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 5, wherein the strengthening layer comprises a second thermoplastic resin.
14. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 13, wherein the second thermoplastic resin comprises a PC, a PP, a PS, a TPU, an ABS resin, a PE, a thermoplastic epoxy resin, a polyurethane resin, a polyurea resin, or a combination thereof.
15. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 13, wherein the first thermoplastic resin is different from the second thermoplastic resin.
16. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 1, wherein a length of the discontinuous fiber is 3 mm to 20 mm.
17. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 1, wherein a length of the discontinuous fiber is less than 3 mm.
18. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 1, wherein a length of the discontinuous fiber is 20 mm to 50 mm.
19. The manufacturing method of the thermoplastic continuous-discontinuous fiber composite sheet of claim 1, wherein the thermoplastic resin is a recycled thermoplastic composite.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0032] The accompanying drawings are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification. The drawings illustrate embodiments of the invention and, together with the description, serve to explain the principles of the invention.
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DESCRIPTION OF THE EMBODIMENTS
[0043] Some embodiments are provided hereinafter and described in detail with reference to figures. However, the embodiments provided are not intended to limit the scope of the invention. Moreover, the figures are only descriptive and are not drawn to scale. For ease of explanation, the same devices below are provided with the same reference numerals. Moreover, terms such as contain, include, and have used in the specification are all open terms, i.e., contains, but not limited to. Moreover, directional terms used in the specification such as up and down are only directions used in the figures. Therefore, the directional terms are used to illustrate and are not intended to limit the invention.
[0044]
[0045] Referring to
[0046] In an embodiment, the length of the discontinuous fiber in the thermoplastic discontinuous fiber aggregate layer 102 is 3 mm to 20 mm. In another embodiment, the length of the discontinuous fiber in the thermoplastic discontinuous fiber aggregate layer 102 is less than 3 mm. In yet another embodiment, the length of the discontinuous fiber in the thermoplastic discontinuous fiber aggregate layer 102 is 20 mm to 50 mm.
[0047] The thermoplastic continuous fiber layer 104 includes a continuous fiber and a second thermoplastic resin. In an embodiment, the continuous fiber in the thermoplastic continuous fiber layer 104 is, for instance, a material such as carbon fiber, glass fiber, basalt fiber, metal fiber, ceramic fiber, or other chemical fibers; the second thermoplastic resin in the thermoplastic continuous fiber layer 102 is, for instance, polycarbonate, polypropylene, polysulfone, thermoplastic polyurethane, acrylonitrile-butadiene-styrene resin, polyethylene, thermoplastic epoxy resin, polyurethane resin, polyurea resin, or a combination thereof. In an embodiment, the thermoplastic continuous fiber layer 104 is, for instance, a continuous fiber cloth impregnated by a thermoplastic resin.
[0048] The thermoplastic continuous-discontinuous fiber composite sheet 100 has a structure formed by a thermoplastic continuous fiber layer and a thermoplastic discontinuous fiber aggregate layer, and therefore has good flexural properties and formability.
[0049]
[0050] In general, the stacking between fibers may produce spaces, such that mechanical strength is reduced. In the present embodiment, since the strengthening layer 103 is formed between the thermoplastic discontinuous fiber aggregate layer 102 and the thermoplastic continuous fiber layer 104, the strengthening layer 103 can be filled to level the space between the thermoplastic discontinuous fiber aggregate layer 102 and the thermoplastic continuous fiber layer 104 to enhance the overall mechanical properties of the resulting product. Moreover, if the surface of the thermoplastic discontinuous fiber aggregate layer 102 is a smooth surface, then the surface can also be modified to increase the bonding between the thermoplastic discontinuous fiber aggregate layer and the subsequent structural layer using the thermoplastic resin different from the thermoplastic resin in the thermoplastic discontinuous fiber aggregate layer 102. Moreover, the thermoplastic fiber layer is generally bonded with a regular engineering plastic (a different type of material), but the thermoplastic fiber layer cannot satisfy the lamination of all of the different types of materials. In the present embodiment, since the strengthening layer 103 is formed on the surface of the thermoplastic discontinuous fiber aggregate layer 102, interface modification can be performed on the surface of the thermoplastic discontinuous fiber aggregate layer 102 via the strengthening layer 103 to increase the bonding of different types of materials.
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[0054]
[0055]
[0056] Referring to
[0057] Next, in step S102, a mechanical treatment is performed on the thermoplastic composite to form a plurality of fragments such that the continuous fiber is changed into a discontinuous fiber. In an embodiment, the mechanical treatment includes crushing the recycled thermoplastic composite having a fiber length less than 20 mm. In another embodiment, the mechanical treatment includes shredding the recycled thermoplastic composite having a fiber length of 20 mm or more with a shredder. The fragments from the mechanical treatment can include short fibers, long fibers, or super-long fibers. For instance, the fragments obtained from crushing are, for instance, short fibers with a fiber length of less than 5 mm or long fibers with a fiber length of 5 mm to 20 mm; and the fragments obtained from shredding are, for instance, super-long fibers with a fiber length greater than 20 mm.
[0058] Next, in step S104, at least one thermoplastic discontinuous fiber aggregate layer 102 is formed by directly using the fragments as a raw material. In an embodiment, the method of forming the thermoplastic discontinuous fiber aggregate layer 102 can include mixing and granulating the fragments to form a plurality of particles and then performing injection molding using the particles as shown in
[0059] Next, in step S106, the at least one thermoplastic discontinuous fiber aggregate layer 102 is thermally compressed with at least one thermoplastic continuous fiber layer 104. The method of thermally compressing the thermoplastic discontinuous fiber aggregate layer 102 and the thermoplastic continuous fiber layer 104 includes laminating using, for instance, a flat film or a flat steel sheet. At this point, the thermoplastic continuous-discontinuous fiber composite sheet 100 of the invention is complete.
[0060] The thermoplastic continuous-discontinuous fiber composite sheet 100 has a structure formed by a thermoplastic continuous fiber layer and a thermoplastic non-continuous fiber aggregate layer, and therefore has good flexural properties and formability.
[0061] In
[0062] Therefore, in an embodiment, before step S106 is performed, the strengthening layer 103 can be formed on at least one surface of the thermoplastic discontinuous fiber aggregate layer 102. Next, thermal compression is performed such that the strengthening layer 103 is at least located between the thermoplastic discontinuous fiber aggregate layer 102 and the thermoplastic continuous fiber layer 104. Since the strengthening layer 103 is formed between the thermoplastic discontinuous fiber aggregate layer 102 and the thermoplastic continuous fiber layer 104, the strengthening layer 103 can be filled to level the space between the thermoplastic discontinuous fiber aggregate layer 102 and the thermoplastic continuous fiber layer 104 to enhance the overall mechanical properties of the resulting product. Moreover, in the present embodiment, the strengthening layer 103 is formed on opposite surfaces (i.e., the first surface 102a and the second surface 102b) of the thermoplastic discontinuous fiber aggregate layer 102 as shown in
[0063] In an embodiment, the step of thermally compressing the at least one thermoplastic discontinuous fiber aggregate layer and the at least one thermoplastic continuous fiber layer can include first overlapping a thermoplastic discontinuous fiber aggregate layer and two thermoplastic continuous fiber layers and performing thermal compression such that the thermoplastic discontinuous fiber aggregate layer 112 of the thermoplastic continuous-discontinuous fiber composite sheet 300 is clamped between two thermoplastic continuous fiber layers 114 as shown in
[0064] In an embodiment, the step of thermally compressing the at least one thermoplastic discontinuous fiber aggregate layer and the at least one thermoplastic continuous fiber layer can include overlapping a thermoplastic continuous fiber layer and two thermoplastic discontinuous fiber aggregate layers and then performing thermal compression such that the thermoplastic continuous fiber layer 124 of the thermoplastic continuous-discontinuous fiber composite sheet 400 is clamped between two thermoplastic discontinuous fiber aggregate layers 122 as shown in
[0065] In an embodiment, the step of thermally compressing the at least one thermoplastic discontinuous fiber aggregate layer and the at least one thermoplastic continuous fiber layer includes: alternately overlapping the thermoplastic continuous fiber layer and the thermoplastic discontinuous fiber aggregate layer and performing thermal compression to obtain the thermoplastic continuous-discontinuous fiber composite sheet shown in
[0066] Moreover, in other embodiments, a thermoplastic discontinuous fiber aggregate layer 102 and a thermoplastic continuous fiber layer 104 with different sizes can be selected for thermal compression to form a thermoplastic continuous-discontinuous fiber composite sheet 700 of the complex structure of
[0067] Several experimental examples are described below to verify the efficacy of the invention. However, the invention is not limited to the following content.
Experimental Example 1
[0068] First, a thermoplastic composite having a carbon fiber with a fiber length less than 20 mm was crushed to obtain fragments with a fiber length of 3 mm to 20 mm (i.e., crushed material). Next, the crushed material was mixed and granulated, that is, fresh plastic material was added for mixing to produce particles (fiber length less than 3 mm), and then injection molding was performed using the particles to obtain a thermoplastic discontinuous fiber aggregate layer. Next, the thermoplastic discontinuous fiber aggregate layer and two layers of 3K prepreg cloth (i.e., thermoplastic continuous fiber layers) were thermally compressed, wherein the 3K prepreg cloth refers to a prepreg cloth formed by weaving a 3K carbon yarn in half warp and half weft. The resulting structure is a sandwich structure of thermoplastic continuous fiber layer/thermoplastic discontinuous fiber aggregate structure/thermoplastic continuous fiber layer with thermoplastic continuous fiber layer as the upper and lower outer layers.
Experimental Example 2
[0069] First, a thermoplastic composite having a carbon fiber with a fiber length less than 20 mm was crushed to obtain fragments with a fiber length of 3 mm to 20 mm (i.e., crushed material). Next, the crushed material was thermally compressed to form a thermoplastic discontinuous fiber aggregate layer.
Experimental Example 3
[0070] First, a thermoplastic composite having a carbon fiber with a fiber length of 20 mm or more was shredded by a shredder to obtain fragments with a fiber length of 20 mm to 50 mm (crushed material). Next, the crushed material was thermally compressed to form a thermoplastic discontinuous fiber aggregate layer.
[0071] Control Group
[0072] Three layers of unidirectional prepreg cloth and two layers of 3K prepreg cloth were thermally compressed, wherein the unidirectional prepreg cloth and the 3K prepreg cloth are both thermoplastic continuous fiber layers.
[0073] Next, a mechanical strength test and an estimate in the decline of mechanical properties and cost were respectively performed on experimental examples 1 to 3 and a control group, and the results are shown in Table 1 below. It should be mentioned that, all of the measurement data is based on the same thickness and the 3K prepreg cloth used are all the same.
TABLE-US-00001 TABLE 1 Average Average Decline in flexural flexural mechanical Cost Sheet stack Density strength modulus property reduction configuration (g/cm.sup.3) (MPa) (GPa) (%) (%) Experimental Thermoplastic 1.24 572.63 36.4 45 32 example 1 continuous fiber layer/thermoplastic discontinuous fiber aggregate layer/thermoplastic continuous fiber layer Experimental Thermoplastic 1.53 711.81 47.0 30 35 example 2 continuous fiber layer/thermoplastic discontinuous fiber aggregate layer/thermoplastic continuous fiber layer Experimental Thermoplastic 1.54 744.17 50.7 25 35 example 3 continuous fiber layer/thermoplastic discontinuous fiber aggregate layer/thermoplastic continuous fiber layer Control Thermoplastic 1.53 988.52 67.3 group continuous fiber layer
[0074] It can be seen from Table 1 that, experimental examples 1 to 3 can achieve the effects of 32% to 35% lower cost and maintaining different degrees of mechanical strengths, and material utilization is increased to 99%.
[0075] Although the invention has been described with reference to the above embodiments, it will be apparent to one of ordinary skill in the art that modifications to the described embodiments may be made without departing from the spirit of the invention. Accordingly, the scope of the invention is defined by the attached claims not by the above detailed descriptions.