III-NITRIDE VERTICAL TRANSISTOR WITH APERTURE REGION FORMED USING ION IMPLANTATION
20190115448 ยท 2019-04-18
Assignee
Inventors
Cpc classification
H01L29/41766
ELECTRICITY
H01L29/66462
ELECTRICITY
H01L29/7781
ELECTRICITY
H01L29/66977
ELECTRICITY
H01L29/205
ELECTRICITY
H01L21/0262
ELECTRICITY
H01L29/4236
ELECTRICITY
International classification
H01L29/66
ELECTRICITY
H01L29/778
ELECTRICITY
H01L29/08
ELECTRICITY
H01L29/06
ELECTRICITY
Abstract
III-nitride vertical transistors and methods of making the same are disclosed. The transistors can include aperture regions that are formed using ion implantation. The resulting transistors can have improved properties.
Claims
1. A method for fabricating a semiconductor device, the method comprising: obtaining, growing, or forming a GaN substrate, which includes a p-type current-blocking layer; implanting Si, O, or H into the p-type current-blocking layer to form a current-aperture region for the semiconductor device; and high-temperature annealing the substrate with the layers grown on top and implanted, thereby removing implantation-induced damage and electrically reactivating the current-aperture region.
2. The method of claim 1, wherein the current-blocking layer is exposed during the implanting.
3. The method of claim 1, wherein the current-blocking layer is buried by other III-Nitride layers during the implanting.
4. The method of claim 1, wherein the current-blocking layer is buried by a sacrificial mask layer during the implanting.
5. The method of claim 1, wherein the method further comprises forming (Al, Ga, In) N layers above the current-aperture region through regrowth in a growth chamber.
6. The method of claim 5, wherein the (Al, Ga, In) N layers are formed during an initial growth, which occurs before the implantation of the current-aperture region.
7. The method of claim 5, wherein the (Al, Ga, In) N layers are formed by regrowth through Molecular Beam Epitaxy (MBE) or Metal organic chemical vapor deposition (MOCVD).
8. The method of claim 5, wherein (Al, In, Ga) N structures in the semiconductor device are grown Nitrogen-polar.
9. The method of claim 5, wherein (Al, In, Ga) N structures in the semiconductor device are grown Ga-polar.
10. The method of claim 1, wherein growth of the semiconductor device structure is achieved by Molecular Beam Epitaxy (MBE) under a plasma or nitrogen-rich environment.
11. The method of claim 1, wherein growth of the semiconductor device structure is achieved by metal organic chemical vapor deposition.
12. The method of claim 1, wherein the method further comprises forming one or more source contacts on the GaN substrate.
13. The method of claim 12, wherein the one or more source contacts are formed through an annealing process.
14. The method of claim 12, wherein the one or more source contacts are formed through an implantation process.
15. The method of claim 1, wherein the semiconductor device comprises a lateral channel vertical junction field-effect transistor.
16. The method of claim 1, wherein the semiconductor device comprises a vertical electron transistor having at least one gate formed on an etched sidewall.
17. The method of claim 1, wherein the semiconductor device includes a dielectric layer comprised of an oxide-based dielectric.
18. The method of claim 1, wherein the semiconductor device includes a dielectric layer comprised of a non-oxide-based dielectric.
19. The method of claim 1, wherein the method further comprises: creating one or more vias to expose at least a portion of the p-doped current-blocking layer positioned outside the current-aperture region; and annealing the semiconductor device structure in the absence of hydrogen gas at a temperature above 600 C., thereby reactivating the at least a portion of the p-type current-blocking layer positioned outside the current-aperture region.
20. The method of claim 1, wherein the semiconductor device comprises a diode.
21. The method of claim 1, wherein the semiconductor device comprises a transistor.
22. The method of claim 21, wherein a field-plated structure comprises part of a gate of the transistor for electric field management.
23. The method of claim 21, wherein a field-plated structure comprises part of a source of the transistor for electric field management.
24. The method of claim 1, wherein a field-termination region resides in the vicinity of a high electric field region in the semiconductor device during off-state semiconductor device operation.
25. The method of claim 25, wherein the field-termination region is formed by implantation or diffusion of dopants, or regrowth of p-type wells.
26. The method of claim 25, wherein the field-termination region may or may not be active.
27. The method of claim 1, wherein a drain contact for the semiconductor device is located on a back of the wafer or substrate.
28. The method of claim 1, wherein a drain contact for the semiconductor device is located on a side surface formed by etching away top layers of the semiconductor device to form a via.
29. A semiconductor device fabricated by performing the following operations: obtaining, growing, or forming a GaN substrate, which includes a p-type current-blocking layer; implanting Si, O, or H into the p-type current-blocking layer to form a current-aperture region for the semiconductor device; and high-temperature annealing the substrate with the layers grown on top and implanted, thereby removing implantation-induced damage and electrically reactivating the current-aperture region.
30. The semiconductor device of claim 19, wherein the operations further include forming (Al, Ga, In) N layers above the current-aperture region through regrowth in a growth chamber.
31. The semiconductor device of claim 29, wherein the semiconductor device comprises a lateral channel vertical junction field-effect transistor.
32. The semiconductor device of claim 29, wherein the semiconductor device comprises a vertical electron transistor having at least one gate formed on an etched sidewall.
33. The semiconductor device of claim 29, wherein the semiconductor device comprises a diode.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE INVENTION
[0099] Before the present invention is described in further detail, it is to be understood that the invention is not limited to the particular embodiments described. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments only, and is not intended to be limiting. The scope of the present invention will be limited only by the claims.
[0100] As used herein, the singular forms a, an, and the include plural embodiments unless the context clearly dictates otherwise.
[0101] Specific structures, devices, transistors, and methods relating to III-nitride vertical transistors have been disclosed. It should be apparent to those skilled in the art that many additional modifications beside those already described are possible without departing from the inventive concepts. In interpreting this disclosure, all terms should be interpreted in the broadest possible manner consistent with the context. Variations of the term comprising should be interpreted as referring to elements, components, or steps in a non-exclusive manner, so the referenced elements, components, or steps may be combined with other elements, components, or steps that are not expressly referenced. Embodiments referenced as comprising certain elements are also contemplated as consisting essentially of and consisting of those elements.
[0102] The terms (AlInGaN) (In,Al)GaN, or GaN as used herein (as well as the terms III-nitride, Group-III nitride, or nitride, used generally) refer to any alloy composition of the (Ga,Al,In,B)N semiconductors having the formula Ga.sub.wAl.sub.xIn.sub.yB.sub.zN where 0w1, 0x1, 0y1, 0z1, and w+x+y+z=1. These terms are intended to be broadly construed to include respective nitrides of the single species, Ga, Al, In and B, as well as binary, ternary and quaternary compositions of such Group III metal species. Accordingly, it will be appreciated that the discussion of the disclosure hereinafter in reference to GaN and AlGaN materials is applicable to the formation of various other (Ga,Al,In,B)N material species. Further, (Ga,Al,In,B)N materials within the scope of the disclosure may further include minor quantities of dopants and/or other impurity or inclusional materials, unless otherwise explicitly stated.
[0103] This disclosure provides semiconductor structures, devices, III-nitride vertical transistors, and methods of making and using the same.
[0104] Referring to
[0105] The device 12 or III-nitride vertical transistor 12 may further comprise a source connected field plate (SCFP). The SCFP may provide an electronic environment that enables a 2DEG to be formed at an appropriate place within the device 12 or transistor 12. Referring to
[0106] The device 12 or III-nitride vertical transistor 12 may further comprise a tunneling control electrode (TCE) 32. The TCE 32 can be used to control tunneling by manipulating the energy bands of surrounding materials or layers. An aspect of the device 12 or III-nitride vertical transistor 12 of the disclosure having a TCE 32 is shown in
[0107] A drain 14 may serve as the base of the semiconductor structure 10, device 12, or III-nitride vertical transistor 12 of the present disclosure. The drain 14 is the target for the flow of electrons through the device 12 or III-nitride vertical transistor 12. A drain 14 may comprise a drain material. In principle, any material that functions suitably as a drain and allows growth of a layer coupled to and disposed adjacent to the drain in the vertical direction may be used with the present disclosure.
[0108] In certain aspects, the drain 14 may have a thickness ranging from about 1 nm to about 2.0 mm.
[0109] A substrate may be coupled to the drain 14 and disposed adjacent to the drain 14 in the vertical direction. Alternatively, the drain 14 may be coupled to the substrate and disposed adjacent to the substrate in the vertical direction. In certain aspects, a single material serves as both the drain 14 and the substrate.
[0110] A substrate may comprise a substrate material. Examples of suitable substrate materials include, but are not limited to, GaN, (Al,In,Ga)N, sapphire, silicon, silicon carbide, glass, polymers, metal, quartz, diamond, and the like.
[0111] In certain aspects, the substrate may have a thickness ranging from about 1 nm to about 2.0 mm. In aspects where the substrate is on the thin end of the aforementioned range, the substrate may be bonded to a carrier wafer. Without wishing to be bound by any particular theory, it is believed that substrates thicker than about 150 m do not require bonding to a carrier wafer.
[0112] A current spreading layer 16 may be coupled to the drain 14 or the substrate and disposed adjacent to the respective drain 14 or substrate in the vertical direction.
[0113] The current spreading layer 16 may comprise a current spreading material. Examples of suitable current spreading material include, but are not limited to, n+ GaN, (Al,In,Ga)N, and the like.
[0114] In certain aspects, the current spreading layer 16 may have a thickness ranging from about 1 nm to about 2 mm.
[0115] The current spreading material may comprise a current spreading dopant. In certain aspects, the current spreading dopant may comprise silicon, oxygen, germanium, and the like. In certain aspects, the current spreading material may comprise current spreading dopant in an amount ranging from about 110.sup.17 cm.sup.3 to about 510.sup.20 cm.sup.3. In certain aspects, the current spreading material may have an electron mobility ranging from about 10 cm.sup.2/V.Math.s to about 1500 cm.sup.2/V.Math.s.
[0116] A drift region may be coupled to the drain 14, the substrate, or the current spreading layer 16, and disposed adjacent to the respective drain 14, substrate, or current spreading layer 16 in the vertical direction.
[0117] The drift region may comprise a drift region material. Example of suitable drift region materials include, but are not limited to, n GaN, n (Al,Ga,In)N, and the like.
[0118] In certain aspects, the drift region may have a thickness of at least about 500 nm. Depending on the range of power and associated voltage required for the application, the thickness can be between 10 nm-10 m (corresponding approximately to 3V-3000V).
[0119] The drift region material may comprise a drift region dopant. In certain aspects, the drift region dopant may comprise silicon, oxygen, germanium, and the like. In certain aspects, the drift region material may comprise drift region dopant in an amount ranging from about 110.sup.14 cm.sup.3 to about 510.sup.17 cm.sup.3. In certain aspects, the drift region material may have an electron mobility ranging from about 100 cm.sup.2/V.Math.s to about 1500 cm.sup.2/V.Math.s.
[0120] The semiconductor structures 10, devices 12, or III-nitride vertical transistors 12 may comprise one or more functional bilayers 20. The one or more functional bilayers 20 may be produced by a method that does not involve regrowth. Without wishing to be bound by any particular theory, it is believed that a regrowth process produces a physical difference at an interface when compared with a process that does not involve regrowth. Implantation processes are believed to damage the crystal structure and contaminate interfaces with impurities such as silicon. Performing Secondary Ion Mass Spectroscopy (SIMS) on material at the interface or taking a Transmission Electron Microscopy (TEM) image of a cross-section of the interface would identify the difference between an interface that was produced from a regrowth process and an interface that was not produced from a regrowth process. A person having ordinary skill in the art would be able to distinguish between an interface that was produced from a regrowth process and an interface that was not produced from a regrowth process.
[0121] In certain aspects, the functional bilayer 20 may have a thickness ranging from about 2 nm to about 20 nm.
[0122] Referring to
[0123] The barrier layer 26 may comprise a barrier material. The character of the barrier material may be impacted by the character of the materials immediately adjacent to the barrier material, in particular, the 2DEG-containing material. In other words, a barrier material may exhibit current blocking properties under some conditions and may lack current blocking properties under other conditions. Examples of suitable barrier materials include, but are not limited to, AlGaN, (Al,In,Ga)N, and the like.
[0124] The barrier layer 26 may comprise a current blocking layer and an aperture region. The channel in the aperture region may be formed by the presence of a trench, the application of a gate voltage in excess of a threshold voltage, or a combination thereof. In certain aspects, the aperture region may have an electron density ranging from about 110.sup.12 cm.sup.2 to about 2.510.sup.13 cm.sup.2 when a gate voltage exceeds the threshold voltage. In certain aspects, the aperture region may have an electron mobility ranging from about 300 cm.sup.2/V.Math.s to about 2200 cm.sup.2/V.Math.s when a gate voltage exceeds the threshold voltage.
[0125] In certain aspects, the current blocking layer and aperture region are comprised of the same material. In preferred aspects, the current blocking layer and aperture region are formed by polarization engineering. In certain aspects, the current blocking layer and aperture region are not formed by doping or implantation. In preferred aspects, the current blocking layer and aperture region are not formed by a regrowth process.
[0126] In certain aspects, the barrier layer 26 may have a thickness ranging from about 1 nm to about 20 nm.
[0127] In certain aspects, the barrier layer 26 may have an electron density ranging from about 110.sup.13 cm.sup.3 to about 110.sup.17 cm.sup.3. In certain aspects, the barrier layer 26 may have an electron mobility ranging from about 10 cm.sup.2/V.Math.s to about 2000 cm.sup.2/V.Math.s.
[0128] Electrons may pass through the barrier layer 26 via tunneling.
[0129] In certain aspects, the 2DEG-containing layer 28 may comprise a 2DEG. The 2DEG may have an electron density ranging from about 110.sup.12 cm.sup.2 to about 2.510.sup.13 cm.sup.2, or from about 510.sup.12 cm.sup.2 to about 210.sup.13 cm.sup.2. The 2DEG may have an electron mobility ranging from about 300 cm.sup.2/V.Math.s to about 2200 cm.sup.2/V.Math.s.
[0130] The 2DEG-containing layer 28 may comprise a 2DEG-containing material. The character of the 2DEG-containing material and corresponding 2DEG may be impacted by the character of the materials immediately adjacent to the 2DEG-containing material, in particular, the barrier material. In other words, a 2DEG-containing material may contain a 2DEG under some conditions and may lack a 2DEG under other conditions. Examples of suitable 2DEG-containing materials include, but are not limited to, GaN, (Al,In,Ga)N, and the like.
[0131] In certain aspects, the 2DEG-containing layer 28 may have a thickness ranging from about 0.1 nm to about 10 nm. In certain aspects, the 2DEG-containing layer 28 contains the 2DEG, but is not comprised exclusively of the 2DEG. In certain aspects, the 2DEG-containing layer 28 consists of a material and a portion of that layer or material contains the 2DEG.
[0132] In preferred aspects, the functional bilayer 20 may comprise a barrier layer 26 that is an AlGaN layer and a 2DEG-containing layer 28 that is a GaN layer coupled to the AlGaN layer and disposed adjacent to the AlGaN layer along a vertical direction.
[0133] In certain aspects, the semiconductor structure 10, device 12, or III-nitride vertical transistor 12 may comprise one or more trenches. The trench or trenches may be formed by etching and may optionally be further processed to contain a gate 22 or SCFP. The trench or trenches may extend partially through the 2DEG-containing layer 28, fully through the 2DEG-containing layer 28, partially through the barrier layer 26, fully through the barrier layer 26, partially through the drift region, or a combination thereof. In certain aspects, the trench or trenches may have vertical side walls or tapering side walls.
[0134] The gate 22 may be positioned above or within the aperture region. In preferred aspects, the flow of electrons through the aperture may be modulated by the gate 22.
[0135] The gate 22 may comprise a gate material. In principle, any material that functions as a gate 22 is suitable for use in the present disclosure as a gate material. The gate material is preferably an electrical conductor. Examples of suitable gate materials include, but are not limited to, a metal (e.g., nickel, titanium, gold, copper, molybdenum, tungsten, tantalum, ruthenium, rhodium, palladium, platinum, etc.), a metal-containing compound (e.g., tantalum nitride, titanium nitride, etc.) polysilicon, polycrystalline silicon-germanium, and the like.
[0136] The gate 22 may have a portion within a trench having an aperture length (L.sub.ap) and a portion outside of the trench and located above the functional bilayer 20 having a full gate length (L.sub.g).
[0137] The gate 22 may be placed on top of the aperture and have an aperture length ranging from about 0.1 m to about 30 m. The gate 22 may have a full gate length ranging from about 0.1 m to about 50 m.
[0138] The source 24 may be coupled to the 2DEG-containing layer 28. In preferred aspects, the source 24 may be coupled to the 2DEG.
[0139] The source 24 may comprise a source material. In principle, any material that functions as a source 24 is suitable for use in the present disclosure as a source material. The source material is preferably an electrical conductor. Examples of suitable source materials include, but are not limited to, silicon-, oxygen-, or germanium-doped or implanted regions of (Al,Ga,In)N, and the like.
[0140] The device 12 or III-nitride vertical transistor 12 may further comprise a drain contact coupled to the drain 14, a gate contact coupled to the gate 22, a source contact coupled to the source 24, or a combination thereof.
[0141] The drain contact may comprise a drain contact material. The gate contact may comprise a gate contact material. The source contact may comprise a source contact material. The drain contact material, gate contact material, or source contact material is preferably an electrical conductor. Examples of suitable drain, gate, or source contact materials include, but are not limited to, a metal (e.g., nickel, titanium, gold, copper, molybdenum, tungsten, tantalum, ruthenium, rhodium, palladium, platinum, etc.), a metal-containing compound (e.g., tantalum nitride, titanium nitride, etc.) polysilicon, polycrystalline silicon-germanium, silicide regions as is known in the art, combinations thereof, and the like.
[0142] The devices 12 and III-nitride vertical transistors 12 of the present disclosure may comprise a dielectric layer 30 adapted and positioned to provide electrical insulation between one or more of the gate 22, the SCFP, and the TCE and one or more of the functional bilayer 20, the 2DEG-containing layer 28, the barrier layer 26, and the drift layer 18.
[0143] In certain aspects, the device 12 or III-nitride vertical transistor 12 may be an enhancement mode (i.e., normally ON) or a depletion mode (i.e., normally OFF) device 12 or transistor 12.
[0144] There are 2 different modulation mechanisms that determine the normally-off or normally on operation of the device 12: 1) tunneling probability in the sidewall and the associated tunneling region overlapping the aperture region; and 2) the field-effect transport under the gate 22.
[0145] Normally off operation in these devices 12 can be ensured by appropriately choosing the layer thickness for the barrier layer 26 and 2DEG-containing layer 28. For example, making the 2DEG-containing layer 28 thinner (5 -2 nm) and the barrier layer 26 in the device 12 shown in
[0146] Normally ON: if the density of available states is increased in the sidewall region and the associated aperture region to ensure high tunneling probability at 0 V or lower bias voltages applied to gate, conduction could be achieved like in a normally ON operation device.
[0147] The number of states along the sidewall of the trenched region and associated tunneling region overlapping the aperture region can be controlled by selective implantation and/or doping of the region, or by biasing the TCE at a bias voltage >0 (separate from the gate biases) to ensure there is available states to favor tunneling.
[0148] The III-nitride materials of the present disclosure may be N-polar. Without wishing to be bound by any particular theory, it is believed that a functional bilayer 20 consisting of an N-polar AlGaN layer and an N-polar GaN layer coupled to the N-polar AlGaN layer and disposed adjacent to the N-polar AlGaN layer in the vertical direction will provide a barrier layer 26 within or coextensive with the N-polar AlGaN layer and a 2DEG within or coextensive with the N-polar GaN layer.
[0149] In certain aspects, the functional bilayer 20 may be grown in a single crystal growth process. In certain aspects, the drift layer 18 and functional bilayer 20 may be grown in a single crystal growth process. In certain aspects, the current spreading layer 16, drift layer 18, and functional bilayer 20 may be grown in a single crystal growth process. In preferred aspects, the drain 14, current spreading layer 16, drift layer 18, and functional bilayer 20 may be grown in a single crystal growth process.
[0150] The semiconductor structures 10, devices 12, and III-nitride vertical transistors 12 of the present disclosure may have a height in the vertical direction ranging from about 55 m to about 2.0 mm. The semiconductor structures 10, devices 12, and III-nitride vertical transistors 12 of the present disclosure may have a length in a direction perpendicular to the vertical direction ranging from about 10.0 m to about 100.0 m. In certain aspects, the semiconductor structures 10, devices 12, and III-nitride vertical transistors 12 may be scaled to create a multiplexed system (for example, in a multiple finger geometry) having larger physical dimensions in a direction perpendicular to the vertical direction. In such aspects, the multiplexed system can have a length in a direction perpendicular to the vertical direction of up to about 10.0 mm.
[0151] The devices 12 and III-nitride vertical transistors 12 of the present disclosure may perform closer to an ideal switch than currently-available devices and transistors. In certain aspects, the devices 12 and III-nitride vertical transistors 12 may have a resistance in the OFF-state of at least 10 /cm.sup.2 or at least about 1000 /cm.sup.2. In certain aspects, the devices 12 and III-nitride vertical transistors 12 may have a resistance in the ON-state of at most about 10 m/cm.sup.2 or at most about 10 /cm.sup.2.
[0152] In certain aspects, the devices 12 and III-nitride vertical transistors 12 may have an On/Off current ratio ranging from about 10.sup.2 to about 10.sup.10.
[0153] The devices 12 and III-nitride vertical transistors 12 of the present disclosure may have improved breakdown voltage when compared with conventional devices and transistors.
[0154] The devices 12 and III-nitride vertical transistors 12 of the present disclosure may have improved leakage current. In certain aspects, the devices 12 and III-nitride vertical transistors 12 may have a current density of less than about 0.4 A/cm.sup.2 when the device or transistor is biased in the OFF state.
[0155] A person having ordinary skill in the art should appreciate that a threshold voltage can be determined using techniques known in the art. The threshold voltage may vary based on the thickness and composition of the layers of the devices 12 or III-nitride vertical transistors 12. The devices 12 and III-nitride vertical transistors 12 of the present disclosure may have a threshold voltage (V.sub.t) of at least about 0.001 mV.
[0156] The semiconductor structures 10, devices 12, and III-nitride vertical transistors 12 of the present disclosure may exhibit nondispersive transport properties. In certain aspects, the drain 14, current spreading layer 16, drift layer 18, functional bilayer 20, 2DEG-containing layer 28, and barrier layer 26 may exhibit nondispersive transport properties.
[0157] This disclosure also provides methods of making a semiconductor structure 10, device 12, or III-nitride vertical transistor 12.
[0158] Referring to
[0159] The methods of the present disclosure may also include the following steps.
[0160] The methods may comprise obtaining, growing, or forming a substrate. The methods may comprise obtaining, growing, or forming a drain 14. In certain aspects, the methods may comprise growing or forming a drain 14 coupled to the substrate and disposed adjacent to the substrate in the vertical direction. In certain aspects, the methods may comprise growing or forming a substrate coupled to the drain 14 and disposed adjacent to the substrate in the vertical direction.
[0161] The methods may comprise obtaining, growing, or forming a current spreading layer 16. In aspects where the current spreading layer 16 is grown or formed, the methods may comprise growing or forming a current spreading layer 16 coupled to the drain 14 or substrate and disposed adjacent to the drain 14 or substrate in the vertical direction.
[0162] The methods may comprise obtaining, growing, or forming a drift layer 18. In aspects where the drift layer 18 is grown or formed, the methods may comprise growing or forming a drift layer 18 coupled to the current spreading layer 16 and disposed adjacent to the current spreading layer 16 in the vertical direction.
[0163] The methods may comprise obtaining, growing, or forming a functional bilayer 20. In aspects where the functional bilayer 20 is grown or formed, the methods may comprise growing or forming a functional bilayer 20 coupled to the drift layer 18 and disposed adjacent to the drift layer 18 in the vertical direction.
[0164] The methods may comprise obtaining, growing, or forming a barrier layer 26. In aspects where the barrier layer 26 is grown or formed, the methods may comprise growing or forming a barrier layer 26 coupled to the drift layer 18 and disposed adjacent to the drift layer 18 in the vertical direction.
[0165] The methods may comprise obtaining, growing, or forming a 2DEG-containing layer 28. In aspects where the 2DEG-containing layer 28 is grown or formed, the methods may comprise growing or forming a 2DEG-containing layer 28 coupled to the barrier layer 26 and disposed adjacent to the barrier layer 26 in the vertical direction.
[0166] The methods may comprise forming a gate region 34 or trench. The purpose of the trench may be to contain a gate 22 or a SCFP. Forming the trench may comprise etching or other processes that produce the same result as etching. In certain aspects, the gate region 34 or trench extends throughout the 2DEG-containing layer 28 and the barrier layer 26 to expose the drift layer 18.
[0167] The methods may comprise depositing a dielectric material to the interior of the trench, and optionally to the top surface of the functional bilayer 20.
[0168] The methods may comprise growing or forming a gate 22 or SCFP, optionally in the trench, and optionally on the top surface of the functional bilayer 20.
[0169] The methods may comprise growing or forming a source 24 coupled to the 2DEG-containing layer 28, and optionally coupled to the 2DEG. Forming the source 24 can be achieved by methods known to those having ordinary skill in the art. For example, a source metal can be deposited in the source regions 36, followed by an annealing step, for example, at about 900 C. for 30 seconds. As another example, Si implantation can be performed within the 2DEG-containing layer 28 beneath the source regions 36, followed by deposition of source contacts atop the Si-implanted regions. As yet another example, the 2DEG containing layer 28 can be etched beneath the source regions 36, and n+GaN can be regrown in the etched region, followed by deposition of source contacts atop the regrown n+GaN. It should be appreciated that the particular way that the source contacts are form is not intended to be limiting to the present disclosure, and any satisfactory process that forms the desired ohmic contact can be used.
[0170] Obtaining, growing or forming may comprise molecular beam epitaxy (MBE), chemical vapor deposition (CVD), metal organic CVD (MOCVD), hydride vapor pressure epitaxy (HVPE), or combinations thereof. Obtaining may further comprise simply acquiring the target of the obtaining step. An example of obtaining includes, but is not limited to, purchasing from a vendor.
[0171] In certain aspects, the method may not include a regrowth step. In certain aspects, the method may include regrowth steps in the forming of ohmic contact, but otherwise may not include a regrowth step. In certain aspects, the obtaining, growing, or forming a barrier layer may not include a regrowth step.
[0172] This disclosure also provides uses of the semiconductor structures 10, devices 12, and III-nitride vertical transistors 12 described herein. Examples of uses include, but are not limited to, use as a switch in an electronic application, in particular, in medium- and high-power (including, but not limited to 10 W-100 kW) electronic applications, in DC to DC, DC to AC, AC to DC, and AC to AC power converters, and the like. It should be appreciated that the semiconductor structures 10, devices 12, and III-nitride vertical transistors 12 of this disclosure are also suitable for low-power electronic applications, such as use in an S-band device, a radio-frequency device, or a combination thereof.
[0173] The present disclosure includes an active buried current blocking layer and aperture that can be grown in situ and formed by polarization manipulation without the need of a regrowth process. This represents a significant improvement over the prior art.
[0174] Vertical GaN transistors, CAVETs, LC-VJFETs, VMOSFETs, and other similar structures can include an n-type drift region to hold the voltage, a horizontal channel to carry electrons flowing from the source horizontally under a planar gate, and an aperture through which electrons flow vertically. In some existing technology, the aperture was first defined by MOCVD growth, and then the CBL was defined by implantation or regrowth. However, neither regrown CBL nor implanted CBL can hold a high voltage when compared with a CBL that is achieved by doping in situ during growth in a MOCVD reactor. According to one aspect, the present disclosure provides systems and methods for achieving the CBL by doping in sity during growth by MOCVD and forming an aperture region by ion implantation to selectively compensate for the acceptor in the CBL in the aperture region. Aperture region ion implantation can enable an in situ doped CBL, which can have better current blocking capabilities, thus enabling methods of regrowth free GaN vertical transistors, such as CAVET, LC-VJFET, and VMOSFET.
[0175] This disclosure provides a method including implanting Si, O, or H into an aperture region in a current blocking layer (CBL). The CBL can be exposed or buried during the implanting. Following the implanting, two annealing steps can be performed. A first high-temperature annealing can be performed to remove implantation-induced damage and electrically reactivate the material. A second annealing can reactivate the buried CBL by way of a via. The second annealing can be performed in the absence of hydrogen. The second annealing can be performed at a temperature above 700 C.
[0176] This disclosure also provides a method including implanting Si into portions of the CBL outside the aperture region. An additional high-temperature annealing can be performed to remove implantation-induced damage and electrically reactivate the material. The implanted portions can be used as source regions and source ohmic contacts can be electrically connected to the source regions.
[0177] Referring to
[0178] At process block 204, the method 200 can include applying an implantation mask to the surface of the p-type GaN layer. The implantation mask can define a designated aperture area in the CBL. The mask can be a metal mask, a dielectric mask, a photoresist mask, or the like.
[0179] At process block 206, the method 200 can include ion implanting the designated aperture area. The ion implanting can provide a well-defined impurity concentration in regions not covered by the implantation mask (i.e., the designated aperture area). In certain aspects, the ion implanting can utilize multiple energies in order to form a box profile donor concentration.
[0180] At process block 208, the method 200 can include removing the implantation mask. The implantation mask can be removed by methods known to those having ordinary skill in the art. At process block 210, the method 200 can include annealing the substrate. The annealing can be a high temperature annealing. The annealing can remove the implantation-induced damage and to enable the material to become electrically active. The annealing temperature is dependent on the properties of the implanted material, as will be appreciated by a person having ordinary skill in the art. As one example, the annealing temperature for Si implantation can be about 1280 C.
[0181] At process block 212, the method 200 can include growing one or more layers atop the p-type GaN layer including the aperture region. The one or two layers can include two III-nitride layers. The two III-nitride layers can form a lateral channel to carry current flow horizontally. The two layers can be formed of materials capable of forming a 2DEG, such as an AlGaN/GaN bilayer, where the 2DEG is located at the AlGaN/GaN interface. The two layers can also be formed of materials capable of forming a junction gate field-effect transistor (JFET) lateral channel, such as a p-GaN/n-GaN bilayer.
[0182] At process block 214, the method 200 can include creating a via, for example by etching, to expose part of the buried CBL to expose that part to the atmosphere. At process block 216, the method 200 can include annealing to cause a reaction in the buried p-type GaN CBL. The annealing of process block 216 can be at a temperature above 700 C.
[0183] At process block 218, the method 200 can include forming one or more source electrodes, a gate dielectric, a gate electrode, and a drain. The one or more source electrodes can be formed by alloyed contact or non-alloyed contact with source area implantation. The alloyed contact can be formed by Ti/Al or Ti/Al/Ni/Au with an annealing at a temperature of above 800 C. The non-alloyed contact with source implantation can be performed using Si implantation.
[0184] Referring to
[0185] Referring to
[0186] At process block 304, the method 300 can include applying an implantation mask to the surface of the one or more layers. The implantation mask can define a designated aperture area in the CBL. The mask can have properties described elsewhere herein.
[0187] At process block 306, the method 300 can include ion implanting the designated aperture area. The ion implanting can have similar properties as the ion implanting in the method 200.
[0188] At process block 308, the method 300 can include removing the implantation mask. At process block 310, the method 300 can include annealing the substrate. The annealing can have properties similar to those described with respect to method 200.
[0189] Referring to
[0190] At process block 412, the method 400 can include applying a source implantation mask to the surface of the p-type GaN layer. The source implantation mask can define a heavily doped source region of the CBL. The mask can have the properties described elsewhere herein.
[0191] At process block 414, the method 400 can include ion implanting the heavily doped source region of the CBL. The ion implanting can have the properties described elsewhere herein.
[0192] Referring to
[0193] The methods 100, 200, 300, 400 can each include one or more steps disclosed in the other methods, can exclude one or more steps disclosed, can include features described with respect to the systems, and can include other processing steps known to those having ordinary skill in the art. The materials illustrated in the various Figs. showing the progression of the methods 200, 300, 400 are exemplary only and can be replaced with other materials that allow the same function, as can be appreciated by a person having ordinary skill in the art, including but not limited to, materials described elsewhere herein.
[0194] The present disclosure can be further understood by way of the following non-limiting examples.
EXAMPLES
Example 1
Enhancement Mode, Low R.SUB.ON .III-Nitride Vertical Transistor
[0195] A computer simulation was performed to simulate the performance of a GaN-based enhancement mode (i.e., normally off), low R.sub.ON N-polar vertical device as shown in
[0196]
[0197] The energy band diagrams of routes 1 and 2 of
[0198]
[0199]
Example 2
A Two-Channel Depletion Mode III-Nitride Vertical Transistor
[0200] A computer simulation was performed to simulate the performance of a two-channel depletion mode (i.e., normally on) device shown in
[0201]
[0202] A person having ordinary skill in the art should appreciate that the functionality of this device was achieved by polarization engineering and not by way of doping or implantation. As a result, the fabrication of this device can be achieved in a single growth process, which maintains the as-grown material quality throughout the fabrication process. The breakdown field in these devices is expected to be close to the theoretical predicted values since the material quality was not compromised and the CBL was formed of a high quality, wider bandgap AlGaN material.
Example 3
[0203] A computer simulation was performed to simulate the performance of an AlGaN/GaN CAVET, as illustrated in
Example 4
[0204] A computer simulation was performed to simulate the performance of a regrowth-free AlGaN/GaN CAVET, as illustrated in