Semiconductor memory devices including a memory cell array and stepped wiring portions, and manufacturing methods thereof
10186520 ยท 2019-01-22
Assignee
Inventors
Cpc classification
H10B43/27
ELECTRICITY
H10B43/50
ELECTRICITY
H01L21/4889
ELECTRICITY
International classification
B81B7/00
PERFORMING OPERATIONS; TRANSPORTING
H01L21/48
ELECTRICITY
B81C1/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A semiconductor memory device according to an embodiment includes a memory cell array that includes memory cells and a plurality of first conducting layers. The memory cells are arrayed in a three-dimensional manner. The first conducting layers are connected to the memory cells and are arrayed in a laminating direction. Stepped wiring portion includes a plurality of second conducting layers. The plurality of second conducting layers connect the first conducting layers and external circuits. At least one of the plurality of second conducting layers includes a contact formation area on a top surface thereof in the stepped wiring portion positioned on the first side portion side. Other ones of the plurality of second conducting layers includes a contact formation area on a top surface thereof in the stepped wiring portion positioned on the second side portion side.
Claims
1. A semiconductor memory device, comprising: a memory cell array that includes a plurality of memory cells and a plurality of first conducting layers, the memory cells being arrayed in a three-dimensional manner, the first conducting layers being connected to the memory cells and being arrayed in a laminating direction; a first stepped wiring portion disposed on a first side portion of the memory cell array; a second stepped wiring portion disposed on a second side portion of the memory cell array, the second side portion being opposite from the first side portion across the memory cell array in a first direction when viewed in the laminating direction; a third stepped wiring portion disposed on a third side portion of the memory cell array; and a fourth stepped wiring portion disposed on a fourth side portion of the memory cell array, the fourth side portion being opposite from the third side portion across the memory cell array in a second direction when viewed in the laminating direction, the second direction intersecting the first direction, wherein: the first stepped wiring portion to the fourth stepped wiring portion include a plurality of second conducting layers that are connected to the plurality of first conducting layers; at least one of the plurality of second conducting layers includes a contact formation area on a top surface thereof in the first stepped wiring portion; other ones of the plurality of second conducting layers include a contact formation area on a top surface thereof in the second stepped wiring portion; levels of the plurality of second conducting layers in the third stepped wiring portion are the same with levels of the plurality of the second conducting layers in the first stepped wiring portion in the laminating direction, or levels of the plurality of second conducting layers in the third stepped wiring portion are the same with levels of the plurality of the second conducting layers in the second stepped wiring portion in the laminating direction; and levels of the plurality of second conducting layers in the fourth stepped wiring portion are the same with the levels of the plurality of the second conducting layers in the first stepped wiring portion in the laminating direction, or levels of the plurality of second conducting layers in the fourth stepped wiring portion are the same with the levels of the plurality of the second conducting layers in the second stepped wiring portion in the laminating direction.
2. The semiconductor memory device according to claim 1, wherein: the first stepped wiring portion includes the contact formation area on the even-th second conducting layers counted from an upper layer side and the second stepper wiring portion includes the contact formation area on the odd-th second conducting layers counted from the upper layer side.
3. The semiconductor memory device according to claim 1, wherein: the first stepped wiring portion includes the contact formation area on the second conducting layer positioned downward of a predetermined position in the laminating direction; and the second stepped wiring portion includes the contact formation area on the second conducting layer positioned upward of the predetermined position.
4. The semiconductor memory device according to claim 1, wherein: in the first stepped wiring portion, at least the one second conducting layer is covered with the second conducting layer positioned on an upper layer side thereof; and in the second stepped wiring portion, at least the one second conducting layer is covered with the second conducting layer positioned on an upper layer side thereof.
5. The semiconductor memory device according to claim 4, wherein: the first stepped wiring portion includes the contact formation area on the even-th second conducting layers counted from an upper layer side; and the second stepper wiring portion includes the contact formation area on the odd-th second conducting layers counted from the upper layer side.
6. The semiconductor memory device according to claim 4, wherein: the first stepped wiring portion includes the contact formation area on the second conducting layer positioned downward of a predetermined position in the laminating direction; and the second stepper wiring portion includes the contact formation area on the second conducting layer positioned upward of the predetermined position.
7. The semiconductor memory device according to claim 1, further comprising: a first row decoder connected to the memory cell array via the first stepped wiring portion; and a second row decoder connected to the memory cell array via the second stepped wiring portion.
8. The semiconductor memory device according to claim 7, wherein: the first stepped wiring portion includes the contact formation area on the even-th second conducting layers counted from an upper layer side; and the second stepper wiring portion includes the contact formation area on the odd-th second conducting layers counted from the upper layer side.
9. The semiconductor memory device according to claim 7, wherein: the first stepped wiring portion includes the contact formation area on the second conducting layer positioned downward of a predetermined position in the laminating direction; and the second stepper wiring portion includes the contact formation area on the second conducting layer positioned upward of the predetermined position.
10. The semiconductor memory device according to claim 1, wherein the first stepped wiring portion to the fourth stepped wiring portion are formed so as to surround the memory cell array across a whole circumference.
11. The semiconductor memory device according to claim 10, wherein: the plurality of second conducting layers in the third stepped wiring portion are continuous with the plurality of the second conducting layers in the first stepped wiring portion, or the plurality of second conducting layers in the third stepped wiring portion are continuous with the plurality of the second conducting layers in the second stepped wiring portion; and the plurality of second conducting layers in the fourth stepped wiring portion are continuous with the plurality of the second conducting layers in the first stepped wiring portion, or the plurality of second conducting layers in the fourth stepped wiring portion are continuous with the plurality of the second conducting layers in the second stepped wiring portion.
12. The semiconductor memory device according to claim 1, wherein each of the first stepped wiring portion to the fourth stepped wiring portion is stepped downward as it goes away from the memory cell array.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
(11) A semiconductor memory device according to an embodiment includes a memory cell array and stepped wiring portions. The stepped wiring portions are disposed on a first side portion of the memory cell array and a second side portion different from the first side portion. The memory cell array includes memory cells and a plurality of first conducting layers. The memory cells are arrayed in a three-dimensional manner. The first conducting layers are connected to the memory cells and are arrayed in a laminating direction. The stepped wiring portion includes a plurality of second conducting layers. The plurality of second conducting layers connect the first conducting layers and external circuits. At least one of the plurality of second conducting layers includes a contact formation area on a top surface thereof in the stepped wiring portion positioned on the first side portion side. Other ones of the plurality of second conducting layers includes a contact formation area on a top surface thereof in the stepped wiring portion positioned on the second side portion side.
(12) The following describes semiconductor memory devices according to embodiments with reference to the accompanying drawings. Here, these embodiments are only examples. For example, the nonvolatile semiconductor memory device described below has a structure where a memory string extends in a straight line in the vertical direction with respect to a substrate. The similar structure is also applicable to the structure having a U shape where a memory string is folded back to the opposite side in the middle. The respective drawings of the nonvolatile semiconductor memory devices used in the following embodiments are schematically illustrated. The thickness, the width, the ratio, and a similar parameter of the layer are not necessarily identical to actual parameters.
(13) The following embodiments relate to a nonvolatile semiconductor memory device in a structure where a plurality of metal-oxide-nitride-oxide-semiconductor (MONOS) type memory cells (transistors) is disposed in a height direction. The MONOS type memory cell includes: a semiconductor film disposed in a columnar shape vertical to the substrate as a channel and a gate electrode film disposed on the side surface of the semiconductor film via an electric charge accumulating layer. However, a similar structure is applicable to another type, for example, a semiconductor-oxide-nitride-oxide-semiconductor (SONOS) type memory cell, a metal-aluminum oxide-nitride-oxide-semiconductor (MANOS) type memory cell, a memory cell that uses hafnium oxide (HfO.sub.x) or tantalum oxide (TaO.sub.x) as an insulating layer, or a floating-gate type memory cell.
(14) The following embodiments describe the three-dimensional NAND flash memory as an example. However, the structures of the following embodiments are also applicable to other three-dimensional semiconductor memory devices, such as a resistance change memory and a magnetic resistance memory.
(15) [First Embodiment]
(16) First, the following describes semiconductor memory devices according to the first embodiment in detail with reference to the accompanying drawings.
(17) As illustrated in
(18) As described later, the memory cell array MA is formed by arraying the memory cells in a three-dimensional manner. This memory cell array MA includes a plurality of word lines WL, a plurality of bit lines BL, and a source line SL. The plurality of word lines WL extend with the longitudinal direction in the X direction in
(19) The row decoders 2 and 3 are disposed on both sides of the memory cell array MA in the X direction. The row decoders 2 and 3 select the plurality of word lines WL to supply a voltage required for operation. Furthermore, in the Y direction of a stepped wiring portion CR, the sense amplifier circuit 4 and the column decoder 5 are disposed. The sense amplifier circuit 4 has the following functions. The sense amplifier circuit 4 is connected to the bit lines BL via a bit line connection circuit (not illustrated) to supply a voltage for writing to the bit line BL. The sense amplifier circuit 4 detects and amplifies an electric potential appeared on the bit line BL during reading. The column decoder 5 decodes column address signals provided from a control unit (not illustrated) to control the sense amplifier circuit 4. The peripheral circuit 6 includes circuits other than the above-described circuits, for example, a power supply circuit, a charge pump circuit (a step-up circuit), and a data register.
(20) Next, the following describes the schematic structure of the memory cell array MA according to the embodiment with reference to
(21) As illustrated in
(22) The conducting layer 102 is a conducting layer made of, for example, tungsten (W). The conducting layer 102 functions as the word line WL, a source side selection gate line SGS, and a drain side selection gate line SGD. An interlayer insulating film is formed between the conducting layers 102; however, for simplification,
(23) At the peripheral area of this memory cell array MA, the stepped wiring portion CR is formed. The stepped wiring portion CR is to connect the word line WL and an external circuit. This stepped wiring portion CR includes extraction wirings (second wirings). The extraction wirings are connected to the conducting layers 102 which serve as the word lines WL, the source side selection gate lines SGS and the drain side selection gate lines SGD, respectively, at the identical layers. These extraction wirings are formed into a stepped pattern on the end portion thereof. The extraction wiring has a role of electrically connecting the conducting layers 102 which serve as the word lines WL, the source side selection gate lines SGS and the drain side selection gate lines SGD, to the external circuit. By the method described later, while a slimming process is isotropically performed on a resist, the laminated conducting layers 102 and interlayer insulating films are etched. Thus, the stepped wiring portion CR is formed.
(24) This stepped wiring portion CR is at least formed on both side portions of the memory cell array MA in the X direction (a first side portion and a second side portion). Hereinafter, the stepped wiring portion CR on the right side portion of the memory cell array MA in
(25) The conducting layer 102 in the stepped wiring portion CR includes a contact formation area 102a. The contact formation area 102a is not covered with the conducting layer 102 positioned on the upper layer and is exposed. That is, the conducting layers 102 are disposed such that the end portions in the X direction differ. The conducting layers 102 form the stepped pattern, which include the contact formation areas 102a, on the different positions on the end portions (as described later, the conducting layers 102 whose end portions match are also present). On the top surface of the contact formation areas 102a, contact plugs 109 are formed. Further, wirings 110 are disposed at the upper ends of the contact plugs 109. The contact plug 109 and the wiring 110 are made of the conducting layer such as tungsten.
(26) Then, the stepped wiring portions CR1 and CR2 include the contact formation areas 102a on the respective different positions (heights). To describe specifically, in the stepped wiring portion CR1, some of the plurality of conducting layers 102 (a first group) include the contact formation areas 102a on their top surfaces. However, the conducting layers 102 other than these conducting layers 102 are covered with the other conducting layers 102 on their upper layer sides, not including a contact formation area. Meanwhile, in the stepped wiring portion CR2, the contact formation areas 102a are provided on the conducting layers 102 (a second group) where the contact formation areas 102a are not formed in the stepped wiring portion CR1. That is, in the stepped wiring portion CR2, the conducting layers 102 in the second group include the contact formation areas 102a on the top surfaces. The top surfaces of the conducting layers 102 in the first group principally have an aspect of covered with the conducting layers 102 positioned on the upper layer sides. In the example illustrated in
(27) Although the stepped wiring portions CR can be disposed not only on the side portions of the memory cell array MA in the X direction but also on the side portions of the memory cell array MA in the Y direction,
(28) As illustrated in
(29) As illustrated in
(30) The material of the conducting layer 102, as well as the above-described tungsten (W), is possibly constituted of a conducting layer such as WN, Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, TiN, WSi.sub.x, TaSi.sub.x, PdSi.sub.x, ErSi.sub.x, YSi.sub.x, PtSi.sub.x, HfSi.sub.x, NiSi.sub.x, CoSi.sub.x, TiSi.sub.x, VSi.sub.x, CrSi.sub.x, MnSi.sub.x, and FeSi.sub.x.
(31) As illustrated in
(32) Next, with reference to
(33) As illustrated in
(34) The material of the semiconductor layer 122, as well as the above-described polysilicon, is possibly constituted of a semiconductor such as SiGe, SiC, Ge, and C. On surfaces at which the semiconductor layer 122 is in contact with the substrate 101 and the conducting layers 106, silicide may be formed. As such silicide, for example, Sc, Ti, VCr, Mn, Fe, Co, Ni, Cu, Zn, Rh, Pd, Ag, Cd, In, Sn, La, Hf, Ta, W, Re, Os, Ir, Pt, and Au are possibly used. Additionally, Sc, Ti, VCr, Mn, Fe, Co, Ni, Cu, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, In, Sn, La, Hf, Ta, W, Re, Os, Ir, Pt, Au, or a similar material may be added to the silicide thus formed.
(35) The tunnel insulating layer 123 and the block insulating layer 125 are possibly consisted of a material, for example, oxide and oxynitride, in addition to the above-described silicon oxide (SiO.sub.2). The oxide constituting the tunnel insulating layer 123 and the block insulating layer 125 is possibly SiO.sub.2, Al.sub.2O.sub.3, Y.sub.2O.sub.3, La.sub.2O.sub.3, Gd.sub.2O.sub.3, Ce.sub.2O.sub.3, CeO.sub.2, Ta.sub.2O.sub.5, HfO.sub.2, ZrO.sub.2, TiO.sub.2, HfSiO, HfAlO, ZrSiO, ZrAlO, AlSiO, or a similar material. The oxide constituting the tunnel insulating layer 123 and the block insulating layer 125 may also be AB.sub.2O.sub.4. Note that A and B described here are identical or different elements and one of elements among Al, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, and Ge. For example, AB.sub.2O.sub.4 is Fe.sub.3O.sub.4, FeAl.sub.2O.sub.4, Mn.sub.1+xAl.sub.2xO.sub.4+y, Co.sub.1+xAl.sub.2xO.sub.4+y, or MnO.sub.x.
(36) The oxide constituting the tunnel insulating layer 123 and the block insulating layer 125 may also be ABO.sub.3. Note that A and B described here are identical or different elements and one of elements among Al, La, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl, Pb, Bi, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, In, and Sn. For example, ABO.sub.3 is, LaAlO.sub.3, SrHfO.sub.3, SrZrO.sub.3, or SrTiO.sub.3.
(37) The oxynitride constituting the tunnel insulating layer 123 and the block insulating layer 125 is possibly, for example, SiON, AlON, YON, LaON, GdON, CeON, TaON, Hf ON, ZrON, TiON, LaAlON, SrHfON, SrZrON, SrTiON, HfSiON, HfAlON, ZrSiON, ZrAlON, and AlSiON.
(38) The oxynitride constituting the tunnel insulating layer 123 and the block insulating layer 125 may be a material constituted by replacing some of oxygen elements of the respective materials described above as an oxide constituting the tunnel insulating layer 123 and the block insulating layer 125 with a nitrogen element.
(39) As the material for the tunnel insulating layer 123 and the block insulating layer 125, SiO.sub.2, SiN, Si.sub.3N.sub.4, Al.sub.2O.sub.3, SiON, HfO.sub.2, HfSiON, Ta.sub.2O.sub.5, TiO.sub.2, or SrTiO.sub.3 is preferable.
(40) In particular, an Si-based insulating film such as SiO.sub.2, SiN, and SiON includes an insulating film whose respective concentrations of the oxygen element and the nitrogen element are 110.sup.18 atoms/cm.sup.3 or more. Note that a barrier height of the plurality of insulating layers differ from one another.
(41) The tunnel insulating layer 123 and the block insulating layer 125 may contain impurity atoms forming defective levels or semiconductor/metal dot (a quantum dot).
(42) The connection of the memory cell MC and the selection transistors STD and STS with the above-described structure in series configures the memory unit MU as illustrated in
(43) Next, with reference to
(44) As illustrated in
(45) A large number of memory holes MH are formed in the memory cell array MA so as to penetrate the laminated body of these conducting layers 102 and interlayer insulating films 112 and 113. In this memory hole MH, the above-described memory columnar body 105 is formed via the tunnel insulating layer 123 and the electric charge accumulating layer 124. That is, the memory columnar body 105 is formed such that the peripheral area of the memory columnar body 105 is surrounded by the laminated body of the conducting layer 102 and the interlayer insulating films 112 and 113. In the example illustrated in
(46) In the peripheral circuit 6, transistors Tr, which constitute the peripheral circuits, are formed on the semiconductor substrate 101. As illustrated in
(47) The contact plugs 109 (109_1 to 109_i) are connected to the contact formation areas 102a of the respective conducting layers 102 constituting the stepped wiring portion CR. The upper ends of the contact plug 109 are connected to upper layer wirings 110. Through such upper layer wirings 110 and wiring layers (not illustrated), the contact plugs 109 are connected to the external circuits.
(48) As illustrated in
(49) The numbers of the source side selection gate lines SGS and the drain side selection gate lines SGD, which are formed on the one memory unit MU (the memory columnar body 105), are not limited to one piece as illustrated in the drawing. The plurality of the source side selection gate lines SGS and the drain side selection gate lines SGD are also possible.
(50) As described above, the stepped wiring portion CR includes the stepped wiring portion CR1 and the stepped wiring portion CR2. The stepped wiring portion CR1 is disposed on the right end portion of the memory cell array MA in the X direction. The stepped wiring portion CR2 is disposed on the left end portion. In the stepped wiring portion CR1, the contact formation areas 102a are disposed on the even-th conducting layers 102 (102_2, 102_4, . . . 102_i-2, and 102_i) counted from the above. In the stepped wiring portion CR2, the contact formation areas 102a are disposed on the odd-th conducting layers 102 (102_1, 102_3, . . . 102_i-3, and 102_i-1) counted from the above.
(51) However, on a certain conducting layer 102_k (k=1 to i), the contact formation area 102a is formed only one of the stepped wiring portions CR1 and CR2. For example, in the example of
(52) In the stepped wiring portion CR1, the contact formation areas 102a are not disposed on the top surfaces of the odd-th conducting layers 102 counted from the upper layer. Instead, the top surfaces are covered with the other conducting layers 102. The conducting layer 102 that does not include the contact formation area 102a can align the end portion in the X direction with the conducting layer 102 on the upper layer. However, all the top surfaces of the conducting layers 102 where the contact plugs 109 are not formed need not to be covered with the other conducting layers 102 on their upper layers. That is, it is only necessary that at least some of the conducting layers 102 where the contact formation areas 102a are not disposed are covered with the other conducting layers 102 on their upper layers.
(53) Similarly, in the stepped wiring portion CR2, the contact formation areas 102a are not disposed on the top surfaces of the even-th conducting layers 102 counted from the upper layer. Instead, the top surfaces are covered with the other conducting layers 102. The conducting layer 102 that does not include the contact formation area 102a can align the end portion in the X direction with the conducting layer 102 on the upper layer. However, all the top surfaces of the conducting layers 102 where the contact plugs 109 are not formed need not to be covered with the other conducting layers 102 on their upper layers. That is, it is only necessary that at least some of the conducting layers 102 where the contact formation areas 102a are not disposed be covered with the other conducting layers 102 on their upper layers.
(54) The above-described structure allows the stepped wiring portions CR1 and CR2 to be less number of steps compared with the number of laminated layers of the conducting layers 102. In view of this, the structure of this first embodiment allows decreasing the occupation areas of the stepped wiring portions CR1 and CR2, ensuring downsizing the semiconductor memory device.
(55) The above-described example describes the case where the certain conducting layer 102 includes the contact formation area 102a only either one of the right and left stepped wiring portions CR1 and CR2. However, the embodiment should not be limited to the example illustrated in the drawing. For example, some of the conducting layers 102 among the plurality of conducting layers 102 can include the contact formation areas 102a both on the right and left stepped wiring portions CR1 and CR2.
(56) [Manufacturing Method]
(57) Next, with reference to
(58) First, as illustrated in
(59) Then, as illustrated in
(60) Further, as illustrated in
(61) Then, as illustrated in
(62) Thereafter, as illustrated in
(63) In a state where the resist M1 as illustrated in
(64) After that, as illustrated in
(65) Although not illustrated hereinafter, wet etching using a hot phosphoric acid solution is performed via a slit formed on a position (not illustrated). This removes the sacrificial layer 141. After removing the sacrificial layer 141, the air gap is formed. After that, the block insulating layer 125 is formed on the wall surface of this air gap up to a predetermined film thickness using the CVD method or a similar method. After that, metal such as tungsten is embedded into the remaining air gap. This completes the laminated structure illustrated in
(66) The above-described example describes the method that laminates the sacrificial layer 141 first, removes the sacrificial layer 141 by etching, and then embeds the conducting layer 102 into the remaining void. However, the device of this embodiment is not limited to this manufacturing method. As long as the material of the conducting layer 102 is a material with which the memory holes MH can be formed at a high density, it is also possible that the sacrificial layers 141 are not laminated but the conducting layers 102 and the interlayer insulating films are laminated in alternation from the phase of
(67) [Modification of First Embodiment]
(68) The following describes modifications of the first embodiment with reference to
(69)
(70) In the stepped wiring portions CR3 and CR4 of this first modification, the entire stepped portions are formed at the height identical to the stepped wiring portion CR2. In other words, the stepped wiring portions CR2, CR3, and CR4 do not generate a level difference in the circumferential direction.
(71) Meanwhile, the stepped wiring portion CR1 and the stepped wiring portion CR3 or CR4 generate a level difference in the circumferential direction. The level difference is present, for example, at a boundary BL1 between the stepped wiring portions CR1 and CR3 or the stepped wiring portions CR1 and CR4. As illustrated in
(72)
(73)
(74) As described above, the first to the third modifications include the stepped wiring portion across the whole circumference of the memory cell array MA. The stepped wiring portion CR can be shaped so as to have the level difference in the circumferential direction at any of the positions. It is only necessary that the mask M0 at least covers the areas where the stepped wiring portion CR2 and the memory cell array MA are formed and has an end portion at any of the positions in the stepped wiring portion.
(75) [Second Embodiment]
(76) Next, the following describes a semiconductor memory device according to the second embodiment with reference to
(77)
(78) In the semiconductor memory device of this second embodiment, as illustrated in
(79) Meanwhile, in the stepped wiring portion CR2, the conducting layers 102 disposed downward of the predetermined position include the contact formation areas 102a on the end portions among the plurality of conducting layers 102. The conducting layers 102 on the layers upper than the predetermined position do not include the contact formation areas 102a. This point differs from the stepped wiring portions CR1 and CR2 of the first embodiment, which include the contact formation areas 102a on the even-th layers and the odd-th layers, respectively. This structure also allows decreasing the occupation areas of the stepped wiring portions CR1 and CR2.
(80) [Manufacturing Method]
(81) Subsequently, with reference to
(82) As illustrated in
(83) Next, as illustrated in
(84) Similar to the modification of the first embodiment, this second embodiment also allows forming the stepped wiring portions CR3 and CR4 positioned on the side surfaces of the memory cell array MA in the Y direction. This also allows appropriately setting the boundary of the level difference similar to the modification of the first embodiment.
(85) Others
(86) While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the inventions. Indeed, the novel embodiments described herein may be embodied in a variety of other forms; furthermore, various omissions, substitutions and changes in the form of the embodiments described herein maybe made without departing from the spirit of the inventions. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the inventions.
(87)
(88)