Detector comprising a variable capacitance diode
10147824 ยท 2018-12-04
Assignee
Inventors
- Heidemarie SCHMIDT (Dresden, DE)
- Ilona SKORUPA (Dresden, DE)
- Slawomir Prucnal (Dresden, DE)
- Danilo BUERGER (Dresden, DE)
- Agnieszka Bogusz (Freiberg, DE)
- Laveen Selvaraj (Chemnitz, DE)
Cpc classification
H01L31/09
ELECTRICITY
H01L31/10
ELECTRICITY
H01L28/56
ELECTRICITY
International classification
H01L27/10
ELECTRICITY
H01G7/02
ELECTRICITY
H01L31/09
ELECTRICITY
Abstract
A capacitance diode or variable capacitance diode includes first and second electrodes and a layer configuration disposed in contact-making fashion between the two electrodes. The layer configuration has, one after the other in a direction from the first electrode towards the second electrode, a layer formed of a ferroelectric material and an electrically insulating layer formed of a dielectric material having electrically charged defects. A method for producing a capacitance diode or a variable capacitance diode, a storage device and a detector including a capacitance diode or a variable capacitance diode are also provided.
Claims
1. A detector for detecting radiation, the detector, comprising: at least one variable capacitance diode as a detector element, the at least one variable capacitance diode including: a first electrode and a second electrode; and a layer configuration disposed in contact-making fashion between said first electrode and said second electrode; said layer configuration having, in succession in a direction from said first electrode to said second electrode, a layer made of a ferroelectric material and an electrically insulating layer made of a dielectric material, said layer made of said dielectric material having electrically charged impurities; and means for detecting a capacitance of said at least one variable capacitance diode and characterizing the radiation on a basis of the detected capacitance.
2. The detector according to claim 1, wherein said layer configuration has, in succession in said direction from said first electrode to said second electrode, said layer made of said ferroelectric material, said layer made of said dielectric material and a layer made of a doped semiconductor material.
3. The detector according to claim 1, wherein said layer made of said dielectric material has a thickness of at least 5 nm.
4. The detector according to claim 1, wherein: said layer made of said ferroelectric material has a polarization surface charge density at an interface thereof in a polarized state, corresponding to a state after applying a coercivity field strength of said ferroelectric material over said layer made of said ferroelectric material; said layer made of said dielectric material has a volume charge density of electrically charged defects; and said layer made of said dielectric material has a thickness causing a product of said thickness and said volume charge density of said layer made of said dielectric material, in terms of magnitude, to at most equal said polarization surface charge density of said layer made of said ferroelectric material.
5. The detector according to claim 1, wherein the radiation is particle radiation or electromagnetic radiation.
6. The detector according to claim 1, wherein: the detector is configured to apply a switching voltage between said first electrode and said second electrode; and said switching voltage has a magnitude being at least so large that: a coercivity field strength of said ferroelectric material is exceeded in said layer made of said ferroelectric material, such that: said at least one capacitance diode can be put into a predetermined storage state with a defined capacitance characteristic by applying said switching voltage.
7. The detector according to claim 6, wherein: said at least one capacitance diode has a capacitance-voltage characteristic with a minimum in said predetermined storage state; and the detector is embodied to characterize the radiation on a basis of a position of said minimum.
Description
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING
(1) Below, the invention is elucidated on the basis of exemplary embodiments, with reference being made to the attached figures, with equivalent or similar features being provided with the same reference sign; here, schematically:
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DESCRIPTION OF THE INVENTION
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(15) Moreover, the variable capacitance diode 1 has a first electrode 4 and a second electrode 5, wherein the first electrode 4 is applied in contact-making fashion at the ferroelectric layer 1F and the second electrode 5 is applied in contact-making fashion at the doped semiconductor layer 15 such that variable capacitance diode 1 has, in succession in the direction from the first electrode 4 to the second electrode 5, the ferroelectric layer 1F, the dielectric layer or insulating layer 19 and the doped semiconductor layer 15.
(16) The overall capacitance of the multilayer system is composed of the nonvolatile capacitance C.sub.I of the insulating layer 19 and the nonvolatile and irradiation-dependent capacitance C.sub.S, C.sub.S11 of the depletion region of the doped semiconductor 15 (where C.sub.S denotes the capacitance of the depletion region without incident radiation 11 and C.sub.S11 denotes the capacitance of the depletion region in the case of incident radiation 11). In the figures, the capacitances C.sub.I, C.sub.S, C.sub.S11 are visualized as an equivalent circuit diagram.
(17) When applying a voltage V1 to the front contact 4 and the associated counter contact 5, there predominantly is a change in the capacitance C.sub.S, C.sub.S11 of the depletion region of the doped semiconductor 15. The multilayer system can be applied to a substrate 3.
(18) Ferroelectric substances are always also piezoelectric. Without an externally applied voltage V1, an electric polarization forms spontaneously (not spontaneously) in the ferroelectric (piezoelectric) material 1F, but said electric polarization varies locally. In the region 2F, the ferroelectric layer 1F is contacted by the front contact 4. With an externally applied voltage V1, an electric polarization forms spontaneously (not spontaneously) in the region 2F of the ferroelectric (piezoelectric) material 1F (elucidated in the figures by the arrows, depicted using dashed lines, in the region 2F of the ferroelectric layer 1F). On account of the electric polarization in the region 2F of the ferroelectric material 1F, electric field lines 7F form in the multilayer system in the region of the ferroelectric (piezoelectric) material 2F, electric field lines 7I form in the region of the insulator 19 and electric field lines 7S form in the region of the doped semiconductor 15.
(19) When the electric field which is caused by the drop in the applied voltage V1 across the region 2F of the ferroelectric layer is less than the coercivity field strength of the ferroelectric material, the ferroelectric material 1F is not electrically polarized in a homogeneous fashion in the region 2F either and the electric field lines 7F are not directed. In this case, the electric field 7F in the ferroelectric region 2F has no influence on the distribution of the charges IC in the insulator 19. The distribution of the charges IC in the insulator 19 is stabilized in the case of sufficiently large electric polarization charges of the ferroelectric material 1F, but the charge centroid of the charges IC in the insulator 19 is displaced neither in the direction of the interface GFI between the ferroelectric layer 1F and the insulating layer 19 nor in the direction of the interface GIS between the insulating layer 19 and the doped semiconductor material 15.
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(26) If a negative voltage ?V2 is initially applied between the front side contact 4 and the rear side contact 5 (
(27) If a positive voltage +V2 is initially applied between the front side contact 4 and the rear side contact 5 (
(28) The difference in the flatband voltages for the two possible extremal distributions of the charges IC in the insulator 19 is greater, the greater the electric polarization charge of the ferroelectric material, the greater the concentration of the charges IC in the insulator 19 and the thicker the insulator 19 are. In the present case, the thickness of the insulating layer 19 is 50 nm as an example, as result of which a reliable electrical insulation and a reliably detectable geometric displacement of the charge centroid of the charged impurities IC are ensured. Moreover, the thicknesses of the ferroelectric layer 1F and of the dielectric layer 19 are selected in such a way that the product of the volume charge density of the charged impurities IC and the thickness of the dielectric layer 19, in terms of magnitude, at most equals the polarization surface charge density of the ferroelectric layer 1F in the polarized state, as a result of which a pronounced variation of the charge centroid of the charged impurities IC in the dielectric layer 19 depending on the polarization state of the ferroelectric layer 1F is made possible.
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(31) By way of example, if the write voltage pulse ?V2 is applied, the CV curve of the multilayer system has the minimum M1 and the capacitance read with a read-out voltage U.sub.read=U.sub.1,min of the minimum M1 is less than the capacitance read out with a read-out voltage U.sub.read=U.sub.2,min of the minimum M2. By contrast, if the write voltage pulse +V2 is applied, the CV curve of the multilayer system has a minimum M2 and the capacitance read with a read-out voltage U.sub.read=U.sub.2,min of the minimum M2 is less than the capacitance read out with a read-out voltage U.sub.read=U.sub.1,min of the minimum M1.
(32) Therefore, the variable capacitance diode 1 can be put into a stable first switching state by applying the first switching voltage ?V2 and it can be put into a stable second switching state by applying the second switching voltage +V2, wherein these two switching states have different capacitance characteristics. The switching voltages are also referred to as write voltages.
(33) Accordingly, the variable capacitance diode 1 can act e.g. as a storage element for storing binary information, wherein the first switching state and the second switching state act as first storage state and second storage state and wherein a read-out of the storage state can take place by detecting the capacitance of the variable capacitance diode at the voltage U.sub.1,min or U.sub.2,min.
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(35) If a positive voltage +V2 is initially applied between the front side contact 4 and the rear side contact 5 (
(36) By way of example, when using BiFeO.sub.3 as ferroelectric material, SiN as insulator with positive charges (in the form of charged impurities) and p-conducting silicon as a semiconductor material, the minimum M1 and the minimum M2 are displaced to smaller voltage values with increasing wavelength A in the case of irradiation with monochromatic light with the same intensity and different wavelengths A (
(37) By way of example, the top electrode 4 and/or the counter electrode 5 can be designed to be transparent for the radiation to be detected for improved detection of the radiation.
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(40) Charged particles can be accelerated or decelerated in the electric field 7F of the ferroelectric material 2F. Moreover, the position of the charge centroid of the impurities IC in the insulator can be influenced in a controlled manner by introducing additional charged particles in the insulator. By way of example, rare earth ions can be introduced into the insulator by ion implantation into the insulator prior to the application of the ferroelectric layer 1F. If the particles to be detected change the charge state of the rare earth ions, then there is also a change in the extremal distribution of the charges IC in the insulator 19.
(41) Accordingly, the variable capacitance diode 1 can act e.g. as a detector element for detecting radiation incident thereon, wherein the detector element can be placed into a defined state by application of the first switching voltage ?V2 or the second switching voltage +V2 and wherein the radiation incident on the variable capacitance diode is characterizable by detecting and evaluating the capacitance characteristic present (e.g. the position of the minimum of the CV characteristic).
(42) Controlling the charges IC in the insulator of the multilayer system is successful locally if both the top contact 4 and the bottom contact 5 have a structured embodiment.
(43) The depicted arrangement in each case comprises a semiconductor 15, an insulator 19 and a ferroelectric layer 1F. The ferroelectric layer 1F can be produced by thin-film growth, e.g. by means of magnetron sputtering or by means of pulsed laser plasma deposition at growth temperatures of between 350? C. and 1000? C. However, it is advantageous to produce the ferroelectric layer 1F in the amorphous phase at room temperature by means of magnetron sputtering or by means of pulsed laser plasma deposition and to subsequently recrystallize it on the timescale of milliseconds by means of FLA (flash lamp annealing). As a result, the heat influx into the doped semiconductor and into the substrate 3 is significantly reduced. A rear side electrode 5 is applied to the semiconductor and a front side electrode 4 is applied to the ferroelectric layer. The insulator 19 contains a significant number of charged impurities IC. The thickness of the insulator is at least 1 nm. The thickness of the insulator preferably lies in the range between 50 nm and 500 nm. The ferroelectric layer 1F can be electrically polarized by applying a voltage between the front side electrode 4 and the rear side electrode 5 in such a way that positive (negative) polarization charges are formed at the interface between ferroelectric layer and semiconductor and negative (positive) polarization charges are formed between ferroelectric layer and insulator. The polarization charges in the ferroelectric layer cause a drift of the charged impurities IC. The charge centroid of the drifted impurities is stable. The charge centroid is different for the two polarization states of the ferroelectric layer. The capacitance-voltage curve (C-V) of the whole arrangement is similar to the C-V curve of a metal-insulator-semiconductor structure and depends on the position of the charge centroid in the insulator. The charge state of the impurities in the interface between ferroelectric and dielectric layers GFI and in the interface between the dielectric and semiconducting layers GIS is stable in the variable capacitance diode. In the voltage range described as a flatband voltage of a metal-insulator-semiconductor structure, the difference between the two capacitance-voltage curves is particularly large. The values of the two C-V curves approach one another in the voltage region of the accumulation and inversion.
(44) In accordance with the example above, the multilayer system of the variable capacitance diode has a material sequence of electrode, BiFeO.sub.3 as ferroelectric, SiN as dielectric, p-Si as doped semiconductor, electrode. However, provision can also be made of e.g. using YMnO.sub.3 as ferroelectric instead of using BiFeO.sub.3 as ferroelectric. The electrodes can consist of e.g. aluminum or gold; in particular, provision can be made for the first electrode to consist of aluminum and for the second electrode to consist of gold.
(45) The arrangements elucidated in the figures can be used as capacitance for storing binary information. The write voltage polarizes the ferroelectric layer and stabilizes one of the two charge centroids in the insulator. The information is read by measuring the capacitance by applying a read-out voltage from the region of the flatband range. The storage state, i.e. the polarization state of the ferroelectric layer and hence also the position of the stabilized charge centroid, is not changed by measuring the capacitance at the read-out voltage.
(46) The arrangements elucidated in the figures can moreover be used in the case of irradiation with electromagnetic waves and/or particles as detector for detection of same, for example when using at least one electrode 4, 5 transparent to electromagnetic waves and/or particles. In the case of monochromatic illumination, the voltage values U.sub.1,min and U.sub.2,min of the C-V curves, at which the minima of the two C-V curves respectively occur, change when the wavelength of the electromagnetic wave changes. An increase in the light intensity in the case of an unchanging wavelength increases the value of the capacitance C.sub.1,min and C.sub.2,min at the voltage values U.sub.1,min and U.sub.2,min of the C-V curves, at which the minima of the two C-V curves respectively occur, without changing the voltage value of the respective minimum. Particles incident on the arrangement can change the polarization state of the ferroelectric layer, the concentration and distribution of the impurities in the insulating layer, and the doping of the semiconductor. It is advantageous if the polarization state of the ferroelectric layer is changed by irradiation with particles. The polarization of the ferroelectric layer can be restored after the particle detection by a repeated write pulse.
(47) What is advantageous in the case of an arrangement as an individual pixel is that, for example, the change in the photocapacitance corresponds to the spectral response and, in the case of constant luminous intensity and in comparison with the standard CCD, only depends on the wavelength of the electromagnetic wave and not on the signal integration time (accumulation of photo-generated charges in the standard CCD and measurement of the photocapacitance of the illuminated arrangement).
(48) What is advantageous in the case of the arrangement in a pixel array is that, for example, the readout of the photocapacitance of each pixel can take place simultaneously in the case of a test frequency of up to several MHz. As result, it is possible to record up to 1-10 million images per minute (whereas the line-by-line readout of the photo-generated charges in standard CCDs limits the frequency with which the information can be read). On account of the isolatability of each individual pixel from the neighboring pixel, the lateral resolution of the arrangement in the case of the parallel readout of the photocapacitance is greater than the lateral resolution of a standard CCD (in particular since pixels of a line of the pixel array need not be electrically connected). The photocapacitance of a pixel returns to the initial value after switching off the illumination by electromagnetic waves, i.e. it returns to the value of the photocapacitance of the pixel in the dark case (whereas a reset operation needs to be carried out in the case of standard CCDs in order to prevent an overflow of accumulated photo-generated charges).
LIST OF USED REFERENCE SIGNS
(49) 1 Variable capacitance diode 1F Layer of ferroelectric material 2F Portion of the ferroelectric layer covered by the first electrode 3 Substrate 4 First electrode/front contact 5 Second electrode/counter contact 7F Electric field lines in the ferroelectric layer 7I Electric field lines in the dielectric layer 7S Electric field lines in the semiconducting layer 11 Radiation 11W Radiation of electromagnetic waves 11T Radiation of particles 15 Layer made of doped semiconductor material 19 Layer made of dielectric material IC Charged impurities in the dielectric layer C.sub.I Capacitance of the dielectric layer C.sub.S Capacitance of the depletion region of the semiconductor layer without radiation C.sub.S11 Capacitance of the depletion region of the semiconductor layer with radiation GFI Interface between ferroelectric and dielectric layers GIS Interface between dielectric and semiconducting layers ?V2, ?V2.sub.j External voltage applied to the two electrodes of the variable capacitance diode with the negative terminal at the front contact and with a magnitude at which the coercivity field strength of the ferroelectric material is exceeded +V2, +V2.sub.j External voltage applied to the two electrodes of the variable capacitance diode with the positive terminal at the front contact and with a magnitude at which the coercivity field strength of the ferroelectric material is exceeded M1, M1.sub.j Minimum of the capacitance voltage characteristic of the variable capacitance diode after applying a voltage ?V2, ?V2.sub.j to the electrodes of the variable capacitance diode M2, M2.sub.j Minimum of the capacitance voltage characteristic of the variable capacitance diode after applying the voltage +V2, +V2.sub.j to the electrodes of the variable capacitance diode U.sub.1,min, U.sub.1j,min DC read-out voltage for reading the capacitance at the minimum M1, M1.sub.j of the capacitance characteristic U.sub.2,min, U.sub.2j,min DC read-out voltage for reading the capacitance at the minimum M1, M1.sub.j of the capacitance characteristic