LAMINATED GLASS
20220363038 · 2022-11-17
Assignee
Inventors
- Nobutaka Kidera (Tokyo, JP)
- Kazuhiko Niwano (Tokyo, JP)
- Shoichi TAKEUCHI (Tokyo, JP)
- Tetsuo ABE (Tokyo, JP)
- Yutaka Kuroiwa (Tokyo, JP)
Cpc classification
B32B17/10614
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10449
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10036
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/42
PERFORMING OPERATIONS; TRANSPORTING
B32B7/025
PERFORMING OPERATIONS; TRANSPORTING
B32B2250/40
PERFORMING OPERATIONS; TRANSPORTING
B60J1/00
PERFORMING OPERATIONS; TRANSPORTING
B32B3/18
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10788
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B3/18
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A laminated glass according to an embodiment of the present invention includes a first glass plate, a second glass plate, and an interlayer film held between the first glass plate and the second glass plate. When a relative dielectric constant of the first glass plate is represented by ε.sub.g1; a relative dielectric constant of the second glass plate is represented by ε.sub.g2; a relative dielectric constant of a first interlayer film provided in a first region of the interlayer film is represented by ε.sub.m1; a reflection coefficient at an interface between the first glass plate and the first interlayer film is represented by Γ.sub.1; and a reflection coefficient at an interface between the second glass plate and the first interlayer film is represented by Γ.sub.2, the reflection coefficients Γ.sub.1 and Γ.sub.2 satisfy relations 0.0≤Γ.sub.1≤0.2 and 0.0≤Γ.sub.2≤0.2.
Claims
1. A laminated glass comprising: a first glass plate; a second glass plate; and an interlayer film held between the first and second glass plates, wherein when a predetermined frequency between 60 GHz and 100 GHz is represented by F [GHz]; a relative dielectric constant of the first glass plate at the frequency F is represented by ε.sub.g1; a relative dielectric constant of the second glass plate at the frequency F is represented by ε.sub.g2; a relative dielectric constant of a first interlayer film provided in a first region of the interlayer film is represented by ε.sub.m1; a reflection coefficient at an interface between the first glass plate and the first interlayer film when an electromagnetic wave having the frequency F is incident on the laminated glass is represented by Γ.sub.1; and a reflection coefficient at an interface between the second glass plate and the first interlayer film when the electromagnetic wave having the frequency F is incident on the laminated glass is represented by Γ.sub.2, below-shown relations are satisfied:
0.0≤Γ.sub.1≤0.2; and
0.0≤Γ.sub.2≤0.2.
2. The laminated glass according to claim 1, wherein in a plan view of the first glass plate of the laminated glass, the relative dielectric constant of the first interlayer film at the frequency F satisfies below-shown relations:
0.0≤|ε.sub.g1−ε.sub.m1|/ε.sub.g1≤0.6; and
0.0≤|ε.sub.g2−ε.sub.m1|/ε.sub.g2≤0.6.
3. The laminated glass according to claim 1, wherein the interlayer film includes the first region and a second region in a plan view of the first glass plate, and when a relative dielectric constant of a second interlayer film provided in the second region at the frequency F is represented by ε.sub.m2, below-shown relations are satisfied:
ε.sub.m2≠ε.sub.m1, and
|ε.sub.g1−ε.sub.m2|/ε.sub.g1>0.6; and
|ε.sub.g2−ε.sub.m2|/ε.sub.g2>0.6.
4. The laminated glass according to claim 3, wherein the relative dielectric constants ε.sub.m1 and ε.sub.m2 satisfy a below-shown relation:
ε.sub.m1>ε.sub.m2.
5. The laminated glass according to claim 3, wherein the relative dielectric constants ε.sub.m1 and ε.sub.m2 satisfy a below-shown relation:
ε.sub.m1−ε.sub.m2≥1.5.
6. The laminated glass according to claim 3, wherein the second interlayer film contains at least one type selected from the group consisting of polyvinyl butyral, ethylene vinyl acetate, a cycloolefin polymer, an urethane resin, a fluorine resin, a fluoro-rubber, a polyimide resin, a liquid-crystal polymer, a bismaleimide triazine resin, a polyphenylene ether, a polyether terephthalate, an acrylic resin such as a polymethyl methacrylate resin, a silicone resin, an ABS resin, Al.sub.2O.sub.3, and SiO.sub.2.
7. The laminated glass according to claim 1, wherein the relative dielectric constants ε.sub.g1, ε.sub.g2 and ε.sub.m1 satisfy below-shown relations:
ε.sub.g1−ε.sub.m1≤3.5; and
ε.sub.g2−ε.sub.m1≤3.5.
8. The laminated glass according to claim 1, wherein a transmittance of the first interlayer film for visible light is 70% or higher.
9. The laminated glass according to claim 1, wherein when an electromagnetic wave having the frequency F is incident on the first glass plate at an incident angle θ no smaller than 30° and no larger than 90° (30°≤θ≤90°), the relative dielectric constant ε.sub.m1 of the first interlayer film satisfies a relation 3≤ε.sub.m1≤15.
10. The laminated glass according to claim 1, wherein the frequency F is in a range of 70 GHz to 84 GHz.
11. The laminated glass according to claim 1, wherein the interlayer film contains at least one type selected from the group consisting of polyvinyl butyral, ethylene vinyl acetate, a cycloolefin polymer, a urethane resin, and a polyvinylidene fluoride resin (PVDF).
12. The laminated glass according to claim 11, wherein the first interlayer film contains at least one type selected from the group consisting of Al.sub.2O.sub.3, TiO.sub.2, SiO.sub.2, ZrO.sub.2, YSZ, SnO.sub.2, forsterite, cordierite, steatite, barium magnesium-acid niobate, barium neodymium titanate, lead zirconate titanate (PZT), borosilicate glass, non-alkali glass, glass fiber, soda lime glass, phosphate glass, BaTiO.sub.3, SrTiO.sub.3, BaSrTiO.sub.3, aluminum nitride, and MnO.sub.2.
13. The laminated glass according to claim 12, wherein the first interlayer film contains Al.sub.2O.sub.3, and a volume content of Al.sub.2O.sub.3 is larger than 1.8 vol %.
14. The laminated glass according to claim 12, wherein the first interlayer film contains TiO.sub.2, and a volume content of TiO.sub.2 is in a range of 0.15 vol % to 3.4 vol %.
15. The laminated glass according to claim 12, wherein the first interlayer film contains SiO.sub.2, and a volume content of SiO.sub.2 is 10 vol % or larger.
16. The laminated glass according to claim 12, wherein the first interlayer film contains a powdery glass, the powdery glass, when expressed by mol percentages based on oxides, satisfying: SiO.sub.2: 50%-85% B.sub.2O.sub.3: 0%-35% Al.sub.2O.sub.3: 0%-25% Li.sub.2O+Na.sub.2O+K.sub.2O: 0%-30% MgO: 0%-15% CaO: 0%-15% SrO: 0%-15% BaO: 0%-15% ZrO.sub.2: 0%-5% TiO.sub.2: 0%-10% Fe.sub.2O.sub.3: 0%-5% SnO.sub.2: 0%-5%, and a volume content of the powdery glass is not smaller than 1 vol % and not larger than 50 vol %.
17. The laminated glass according to claim 12, wherein the first interlayer film contains powdery BaTiO.sub.3, and a volume content of the BaTiO.sub.3 is not smaller than 1 vol % and not larger than 50 vol %.
Description
BRIEF DESCRIPTION OF DRAWINGS
[0040]
[0041]
[0042]
[0043]
[0044]
[0045]
[0046]
[0047]
[0048]
[0049]
[0050]
[0051]
[0052]
[0053]
DESCRIPTION OF EMBODIMENTS
[0054] Embodiments according to the present invention will be described hereinafter with reference to the drawings.
[0055]
[0056] The vehicle 100 includes an information device for ensuring the safety of traveling of the vehicle 100. Such an information device is housed in, for example, a housing (a case) 10 provided on the inner side, i.e., the vehicle-interior side, of the laminated glass (the windshield) 1. Note that although the housing (the case) 10 is disposed at the center of the upper part of the laminated glass in
[0057] Note that the information device, which is a device for detecting a vehicle, a pedestrian, an obstacle, etc. in front of the own vehicle by using a millimeter-wave radar or the like, may include, for example, in addition or instead of the millimeter-wave radar, a stereo camera, an infrared laser, or the like. Further, the information device may include a communication apparatus capable of performing high-speed and large-capacity communications such as communications in conformity with 4G, LTE or 5G. For example, an antenna(s) for communication may be housed in the housing (the case) 10.
[0058] In this embodiment, the information device is configured so as to be able to transmit and/or receive electromagnetic waves (signals) in a millimeter-wave band. Therefore, in this embodiment, it is possible to increase the transmitting property for electromagnetic waves in the millimeter-wave band at least at a part of the laminated glass 1 corresponding to the housing (the case) 10. In this embodiment, the millimeter-wave band means a band from 30 GHz to 300 GHz, and the effects of the present invention become particularly noticeable in a band from 60 GHz to 100 GHz.
[0059] Each of
[0060] The structure of the laminated glass 1 (1a or 1b) in the first region 21 thereof will be described hereinafter. Note that the first region 21 may be the entire region of the laminated glass 1 (1a or 1b) as will be described later, and in such a case, the laminated glass 1 includes no second region 22.
[0061]
[0062] The first and second glass plates 11 and 12 are manufactured by using, for example, a float method, a fusion method, or the like, but the manufacturing method is not limited to these methods. Further, the laminated glass 1 according to this embodiment is obtained, at a temperature of about 70° C. to 110° C., by stacking the first glass plate 11, the interlayer film 13, and the second glass plate 12 in this order, placing them in a vacuum bag such as a rubber bag, connecting this vacuum bag to a discharging system, and sucking the gas contained in the vacuum bag (i.e., degassing the vacuum bag) so that the pressure inside the vacuum bag decreases to a decompressed pressure of about −65 kPa to −100 kPa (an absolute pressure). Further, for example, by performing a crimping process by heating and pressurizing the laminated glass at a temperature of about 100° C. to 140° C. and at a pressure of 0.6 MPa to 1.3 MPa, a laminated glass having better durability can be obtained. Note that the manufacturing method is not limited to this method.
[0063] Further, when the laminated glass 1 is used for, for example, a head-up display (HUD), at least one of the first glass plate 11, a first interlayer film 31, and the second glass plate 12 may not have a uniform thickness, and the thickness of each part thereof may be changed as required. For example, when the laminated glass 1 is used as a windshield, either or both of the first and second glass plates 11 and 12 may have a wedge shape in cross section in which the thickness of the glass plate gradually increases from the lower side toward the upper side in the state in which the windshield is mounted in the vehicle. In such a case, when the thickness of the first interlayer film 31 is uniform, the total wedge angle of the first and second glass plates 11 and 12 may be changed, for example, within a range of larger than 0 mrad and no larger than 1.0 mrad. Further, when the laminated glass 1 is used for, for example, a HUD, the first interlayer film 31 may have a wedge shape in cross section in which the thickness of the first interlayer film 31 gradually increases from the lower side toward the upper side in the state in which the windshield is mounted in the vehicle. In such a case, when the thickness of each of the first and second glass plates 11 and 12 is uniform, the total wedge angle of the first interlayer film 31 may be changed, for example, within a range of larger than 0 mrad and no larger than 1.0 mrad.
[0064] Examples of the composition of at least one of the first and second glass plates 11 and 12 used in this embodiment include a glass of which the composition, when expressed by mol percentages based on oxides, satisfies the below-shown relation. Examples of the glass include, but are not limited to, a glass containing SiO.sub.2 in an amount of 50% to 80%, B.sub.2O.sub.3 in an amount of 0% to 10%, Al.sub.2O.sub.3 in an amount of 0.1% to 25%, at least one type of an alkali metal oxide selected from the group consisting of Li.sub.2O, Na.sub.2O and K.sub.2O in a total amount of 3% to 30%, MgO in an amount of 0% to 25%, CaO in an amount of 0% to 25%, SrO in an amount of 0% to 5%, BaO in an amount of 0% to 5%, ZrO.sub.2 in an amount of 0% to 5%, Fe.sub.2O.sub.3 in an amount of 0% to 5%, and SnO.sub.2 in an amount of 0% to 5%.
[0065] Examples of the composition of at least one of the first and second glass plates 11 and 12 used in this embodiment also include a glass of which the composition, when expressed by mol percentages based on oxides, satisfies the below-shown relation:
50≤SiO.sub.2≤85
0≤Al.sub.2O.sub.3≤20
4≤R.sub.2O≤22 (R.sub.2O represents the total amount of alkali metal oxides)
0≤RO≤20 (RO represents the total amount of MgO, CaO, SrO and BaO)
0≤Na.sub.2O/R.sub.2O≤0.8
0≤K.sub.2O/R.sub.2O≤0.7.
[0066] Further, examples of the composition of at least one of the first and second glass plates 11 and 12 used in this embodiment also include a glass of which the composition, when expressed by mol percentages based on oxides, satisfies the below-shown relation:
72≤SiO.sub.2+Al.sub.2O.sub.3+B.sub.2O.sub.3≤98
55≤SiO.sub.2≤87
0≤Al.sub.2O.sub.3≤20
0≤B.sub.2O.sub.3≤25
0≤R.sub.2O≤5 (R.sub.2O represents the total amount of alkali metal oxides)
0≤RO≤20 (RO represents the total amount of MgO, CaO, SrO and BaO).
[0067] Further, in the laminated glass 1a shown in
[0068] The first interlayer film 31 is made of a material having a relative dielectric constant ε.sub.m1, and the second interlayer film 32 is made of a material having a relative dielectric constant ε.sub.m2.
[0069] For the interlayer film 13, a material containing, for example, polyvinyl butyral (PVB), ethylene vinyl acetate (EVA), a cycloolefin polymer, a urethane resin, a polyvinylidene fluoride resin (PVDF), or the like can be used. Further, a thermosetting resin which is in a liquid state before being heated may be used. That is, the interlayer film 13 needs to be a layered state only when the laminated glass 1 is formed, and the interlayer film 13 may be, for example, in a liquid state before the first and second glass plates 11 and 12 are bonded. Note that details of the interlayer film 13 will be described later.
[0070] A specific configuration of the laminated glass 1 according to this embodiment and a result of a simulation thereof will be described hereinafter in detail.
[0071] As shown in
[0072] In this embodiment, it is possible to reduce the difference between the relative dielectric constant of the first glass plate 11 and that of the first interlayer film 31, and the difference between the relative dielectric constant of the second glass plate 12 and that of the first interlayer film 31 by adjusting the relative dielectric constant of each of elements constituting the laminated glass 1 according to the above-described relations. When the difference between the relative dielectric constants of the first and second glass plates 11 and 12 and that of the interlayer film 13 (the first interlayer film 31) is reduced, the reflection at the interface between the first and second glass plates 11 and 12 and the interlayer film 13 (the first interlayer film 31) can be suppressed (i.e., reduced), so that the transmitting property for electromagnetic waves in the millimeter-wave band can be improved. Further, the difference between the relative dielectric constant of the first glass plate 11 and that of the first interlayer film 31, and the difference between the relative dielectric constant of the second glass plate 12 and that of the first interlayer film 31 may each be 0.15 or lower, and is preferably 0.12 or lower, more preferably 0.09 or lower, still more preferably 0.06 or lower, particularly preferably 0.03 or lower, and most preferably 0.01 or lower.
[0073] Further, in this embodiment, there is no need to remove any part of each of the elements constituting the laminated glass 1, especially any part of the first and second glass plates 11 and 12, so that the strength required for the ordinary laminated glass can be satisfied. That is, since the laminated glass 1 according to this embodiment has a three-layer structure composed of the first glass plate 11, the second glass plate 12, and the interlayer film 13, the strength required for the ordinary laminated glass can be satisfied.
[0074] Note that the first region 21 corresponds to, in the plan view of the first glass plate 11, a region including at least a part corresponding to the housing 10 (see
[0075] Further, in this embodiment, the relative dielectric constant of the first interlayer film 31 at the frequency F in the first region 21 in the plan view of the first glass plate 11 may satisfy the below-shown Expressions 4 and 5. By satisfying such conditions, the transmitting property for electromagnetic waves in the millimeter-wave band can be improved.
0.0≤|ε.sub.g1−ε.sub.m1|/ε.sub.g1≤0.6 Expression 4
0.0≤ε.sub.g2−ε.sub.m1|/ε.sub.g2≤0.6 Expression 5
[0076] Further, in this embodiment, the relative dielectric constant ε.sub.g1 of the first glass plate 11, the relative dielectric constant ε.sub.g2 of the second glass plate 12, and the relative dielectric constant ε.sub.m1 of the first interlayer film 31 may satisfy the below-shown Expressions 6 and 7. By satisfying such conditions, the transmitting property for electromagnetic waves in the millimeter-wave band can be improved.
ε.sub.g1−ε.sub.m1≤3.5 Expression 6
ε.sub.g2−ε.sub.m1≤3.5 Expression 7
[0077] Further, the transmittance of the first interlayer film 31 for visible light may be 70% or higher. By satisfying such conditions, the transmitting property for electromagnetic waves in the millimeter-wave band in the first region 21 is improved and the transmittance for visible light therein is also improved. In particular, in the case where an image-pickup apparatus that takes images of the outside of the vehicle is provided inside the housing 10, it is desirable that the transmittance of the first interlayer film for visible light be high. Note that the transmittance of the first interlayer film for visible light is preferably 75% or higher, more preferably 80% or higher, still more preferably 85% or higher, and most preferably 90% or higher.
[0078] Further, the first interlayer film 31 may be made of a material of which the dielectric loss tangent (tan δ) at the frequency F is 0.01 or smaller. By the above-described configuration, the transmitting property for electromagnetic waves in the millimeter-wave band in the first region 21 can be further improved. Further, the dielectric loss tangent of the first interlayer film 31 at the frequency F is preferably 0.008 or smaller, more preferably 0.005 or smaller, still more preferably 0.003 or smaller, and particularly preferably 0.001 or smaller.
[0079] Further, the first and second glass plates 11 and 12 may be made of a material of which the dielectric loss tangent (tan δ) is at the frequency F is 0.025 or smaller. By the above-described configuration, the transmitting property for electromagnetic waves in the millimeter-wave band in the first region 21 can be further improved. Further, the dielectric loss tangent of the first and second glass plates 11 and 12 at the frequency F is preferably 0.020 or smaller, more preferably 0.018 or smaller, still more preferably 0.015 or smaller, and particularly preferably 0.012 or smaller.
[0080] Further, the first and second glass plates 11 and 12 may be made of a material of which the relative dielectric constant at the frequency F is 3.5 or higher. By the above-described configuration, the transmitting property for electromagnetic waves in the millimeter-wave band in the first region 21 can be further improved. Further, the dielectric constant of the first and second glass plates 11 and 12 at the frequency F is preferably 4.5 or higher, more preferably 5.5 or higher, and still more preferably 6.0 or higher. On the other hand, when the relative dielectric constant of the first and second glass plates 11 and 12 is too high, the reflection of electromagnetic waves having the frequency F increases and hence the transmitting property therefor decreases. Therefore, the relative dielectric constant of the first and second glass plates 11 and 12 may be 8.0 or smaller, and is preferably 7.0 or smaller, more preferably 6.5 or smaller, and still more preferably 6.1 or smaller.
[0081] In the first interlayer film 31, when an electromagnetic wave having the frequency F is incident on the first glass plate 11 at an incident angle θ (θ is in a range of 30°≤θ≤90°), the relative dielectric constant ε.sub.m1 of the first interlayer film 31 may satisfy a relation 3≤ε.sub.m1≤15. For example, when an electromagnetic wave in the millimeter-wave range travels in the horizontal direction from an apparatus that is attached to the housing 10 and emits the millimeter-wave radar, it is preferable that the relative dielectric constant ε.sub.m1 in a range in which the incident angle θ on the windshield is in a range of 30°≤θ≤90° satisfies the above-described range. Further, the relative dielectric constant ε.sub.m1 in a range in which the incident angle θ is in a range of 40°≤θ≤80° may satisfy the above-described range; the relative dielectric constant ε.sub.m1 in a range in which the incident angle θ is in a range of 50°≤θ≤75° may satisfy the above-described range; or the relative dielectric constant ε.sub.m1 in a range in which the incident angle θ is in a range of 60°≤θ≤75° may satisfy the above-described range.
[0082] Further, in this embodiment, the frequency F may be, for example, in a range of 60 GHz to 100 GHz, in a range of 70 GHz to 84 GHz, in a range of 74 GHz to 82 GHz, in a range of 77 GHz to 81 GHz, or in a range of 78.5 GHz to 79.5 GHz. More specifically, the frequency F may be 79 GHz.
[0083] Further, in this embodiment, the first interlayer film 31 may contain at least one type selected from the group consisting of, in addition to polyvinyl butyral, ethylene vinyl acetate, a cycloolefin polymer, and an urethane resin, a fluorine resin such as polytetrafluoroethylene (PTFE), ethylene tetrafluoroethylene (ETFE), perfluoroalkoxyalkane (PFA), and polyvinylidene fluoride (PVDF), a fluoro-rubber, a polyimide resin, a liquid-crystal polymer (LCP), a bismaleimide triazine resin, a polyphenylene ether (PPE), a polyether terephthalate (PET), an acrylic resin such as a polymethyl methacrylate resin, a silicone resin, an ABS resin, Al.sub.2O.sub.3, and SiO.sub.2.
[0084] Further, in this embodiment, the first interlayer film 31 may contain an adhesive or a pressure-sensitive adhesive. For example, the first interlayer film 31 may be one in which an adhesive or a pressure-sensitive adhesive is disposed on at least one of the main surfaces of the first interlayer film 31 that is brought into contact with the first glass plate 11 and the main surface thereof that is brought into contact with the second glass plate 12. For example, the adhesive layer that is included in the first interlayer film 31 and is brought into contact with at least one of the first and second glass plates 11 and 12 may be one that is obtained as a photo-curable resin composition, a thermosetting resin composition, a photo-and-thermo curable resin composition, or the like is cured. The “photo-curable resin composition” means a resin composition that can be cured by exposure to light. The “thermosetting resin composition” means a resin composition that can be cured by heating. The “photo-and-thermo curable resin composition” means a resin composition that can be cured by exposure to light and heating.
[0085] Further, the relative dielectric constant of the first interlayer film 31 may be adjusted by including (i.e., adding) a filler having a high dielectric constant in the resin material. For example, the first interlayer film 31 may be obtained by including (i.e., adding), in polyvinyl butyral, ethylenevinyl acetate or the like, as a filler, at least one type selected from the group consisting of Al.sub.2O.sub.3, TiO.sub.2, SiO.sub.2, ZrO.sub.2, YSZ (Yttria-Stabilized Zirconia), SnO.sub.2, forsterite, cordierite, steatite, barium magnesium-acid niobate, barium neodymium titanate, lead zirconate titanate (PZT), (powdery) borosilicate glass, (powdery) non-alkali glass, glass fiber (E glass, D glass, NE glass, etc.), (powdery) soda lime glass, (powdery) phosphate glass, BaTiO.sub.3, SrTiO.sub.3, BaSrTiO.sub.3, aluminum nitride, and MnO.sub.2.
[0086] For example, when the first interlayer film 31 contains powdery Al.sub.2O.sub.3, the volume content of Al.sub.2O.sub.3 may be 1.8 vol % or larger, and is preferably 2.3 vol % or larger, and more preferably 3.0 vol % or larger. Depending on the (resin) material as the main component of the first interlayer film 31, if the volume content of Al.sub.2O.sub.3 is smaller than 1.8 vol %, it is difficult to increase the relative dielectric constant ε.sub.m1 of the (filler-containing) first interlayer film 31.
[0087] Further, when the first interlayer film 31 contains powdery TiO.sub.2, the volume content of TiO.sub.2 may be 0.15 vol % or larger, and is preferably 0.20 vol % or larger, and more preferably 0.30 vol % or larger. Depending on the (resin) material as the main component of the first interlayer film 31, if the volume content of TiO.sub.2 is smaller than 0.15 vol %, it is difficult to increase the relative dielectric constant ε.sub.m1 of the (filler-containing) first interlayer film 31. Further, depending on the (resin) material as the main component of the first interlayer film 31, the volume content of TiO.sub.2 may be 3.4 vol % or smaller, and is preferably 3.0 vol % or smaller, and more preferably 2.5 vol % or smaller. If the volume content of TiO.sub.2 is larger than 3.4 vol %, the dielectric constant ε.sub.m1 of the first interlayer film 31 becomes too high, and hence there is a possibility that the reflection at the interface between the first interlayer film 31 and the glass plate 11 and/or at the interface between the first interlayer film 31 and the glass plate 12 could increase.
[0088] Further, when the first interlayer film 31 contains powdery SiO.sub.2, the volume content of SiO.sub.2 may be 10 vol % or larger, and is preferably vol % or larger, and more preferably 30 vol % or larger. Depending on the (resin) material as the main component of the first interlayer film 31, if the volume content of SiO.sub.2 is smaller than 10 vol %, it is difficult to increase the relative dielectric constant ε.sub.m1 of the (filler-containing) first interlayer film 31.
[0089] Further, when the first interlayer film 31 contains powdery glass, the first interlayer film 31, when expressed by mol percentages based on oxides, satisfies:
[0090] SiO.sub.2: 50%-85%
[0091] B.sub.2O.sub.3: 0%-35%
[0092] Al.sub.2O.sub.3: 0%-25%
[0093] Li.sub.2O+Na.sub.2O+K.sub.2O: 0%-30%
[0094] MgO: 0%-15%
[0095] CaO: 0%-15%
[0096] SrO: 0%-15%
[0097] BaO: 0%-15%
[0098] ZrO.sub.2: 0%-5%
[0099] TiO.sub.2: 0%-10%
[0100] Fe.sub.2O.sub.3: 0%-5%
[0101] SnO.sub.2: 0%-5%, and under the above-described conditions, the volume content of the powdery glass can be adjusted within a range of no smaller than 1 vol % and no larger than 50 vol %. Depending on the (resin) material as the main component of the first interlayer film 31, if the volume content of the powdery glass is smaller than 1 vol %, it is difficult to increase the relative dielectric constant ε.sub.m1 of the (filler-containing) first interlayer film 31. Further, when the volume content of the powdery glass exceeds 50 vol %, the first interlayer film 31 is likely to become brittle.
[0102] Further, when the first interlayer film 31 contains powdery glass, it may be a glass that, when expressed by mol percentages based on oxides, satisfies:
[0103] SiO.sub.2: 60%-85%
[0104] B.sub.2O.sub.3: 0%-15%
[0105] Al.sub.2O.sub.3: 0%-10%
[0106] Li.sub.2O+Na.sub.2O+K.sub.2O: 0%-20%
[0107] MgO: 0%-10%
[0108] CaO: 0%-10%
[0109] SrO: 0%-10%
[0110] BaO: 0%-10%
[0111] ZrO.sub.2: 0%-3%
[0112] TiO.sub.2: 0%-5%
[0113] Fe.sub.2O.sub.3: 0%-2%
[0114] SnO.sub.2: 0%-3%, and
under the above-described conditions, the volume content of the powdery glass can also be adjusted within a range of no smaller than 1 vol % and no larger than 50 vol %.
[0115] Further, when the first interlayer film 31 contains BaTiO.sub.3 (powder), the volume content of the powdery BaTiO.sub.3 can be adjusted within a range of no smaller than 10 vol % and no larger than 50 vol %. Depending on the (resin) material as the main component of the first interlayer film 31, if the volume content of the powdery BaTiO.sub.3 is smaller than 1 vol %, it is difficult to increase the relative dielectric constant ε.sub.m1 of the (filler-containing) first interlayer film 31. Further, when the volume content of the powdery BaTiO.sub.3 exceeds 50 vol %, the first interlayer film 31 is likely to become brittle.
[0116] Further, the shape of the above-described filler is not limited to any particular shapes, and examples of the shape include common shapes of powders, such as spherical, a crushed shape (a block shape), a flat shape, and columnar. However, the shape of the filler is not limited to the aforementioned shapes, and may be a short fibrous (chop-strand) shape, a long fibrous shape, an ultrathin fibrous shape, a hollow fibrous shape, or a glass cloth shape. For example, when the filler is spherical, its size may be 100 μmφ or smaller.
[0117] Further, when the interlayer film 13 includes the first and second regions 21 and 22 in the plan view of the first glass plate 11, the relative dielectric constant ε.sub.m2 of the second interlayer film 32 disposed in the second region 22 at the frequency F may not be equal to the relative dielectric constant ε.sub.m1 (ε.sub.m2≠ε.sub.m1), and may satisfy the below-shown Expressions 8 and 9. Note that the term “plan view” means a view of the laminated glass 1 when it is viewed in the thickness direction thereof.
|ε.sub.g1−ε.sub.m2|/ε.sub.g1>0.6 Expression 8
|ε.sub.g2−ε.sub.m2|/ε.sub.g2>0.6 Expression 9
[0118] Further, in this embodiment, the relative dielectric constants ε.sub.m1 and ε.sub.m2 of the first and second interlayer films 31 and 32 may satisfy a relation ε.sub.m1>ε.sub.m2. Further, in this embodiment, the relative dielectric constants ε.sub.m1 and ε.sub.m2 of the first and second interlayer films 31 and 32 may satisfy a relation ε.sub.m1−ε.sub.m2≥1.5, a relation ε.sub.m1−ε.sub.m2≥2.0, a relation ε.sub.m1−ε.sub.m2≥2.5, a relation ε.sub.m1−ε.sub.m2≥3.0, or a relation ε.sub.m1−ε.sub.m2≥3.5. By adjusting the relative dielectric constants ε.sub.m1 and ε.sub.m2 of the first and second interlayer films 31 and 32 so as to satisfy the above-described conditions as described above, it is possible to selectively increase the transmitting property for electromagnetic waves in the millimeter-wave band in the first region of the laminated glass.
[0119] In this embodiment, the second interlayer film 32 may contain at least one type selected from the group consisting of polyvinyl butyral, ethylene vinyl acetate, a cycloolefin polymer, a urethane resin, and a polyvinylidene fluoride resin (PVDF).
[0120] Note that, in this embodiment, as described above, the dielectric constant of the interlayer film 13 may be adjusted to the relative dielectric constant ε.sub.m1 over the entire area of the laminated glass (the windshield) 1 shown in
[0121] In this embodiment, the thickness of each of the first and second glass plates 11 and 12 may be 1.1 mm or larger in order to ensure the strength thereof, and is preferably 1.5 mm or larger, and more preferably 1.8 mm or larger. Further, although the upper limit of the thickness of each of the first and second glass plates 11 and 12 is not limited to any particular thicknesses, the upper limit of the thickness is preferably 3.0 mm or smaller under the normal circumstances because the weight of the glass plate increases as it becomes thicker.
[0122] Further, for the easiness of handling, the thickness of the interlayer film 13 is preferably 0.3 mm or larger, more preferably 0.5 mm or larger, and still more preferably 0.7 mm or larger. Further, for reducing the weight, the thickness of the interlayer film 13 is preferably 2.3 mm or smaller, more preferably 2.0 mm or smaller, and still more preferably 1.0 mm or smaller.
[0123] (Results of Simulations)
[0124] Next, results of simulations of laminated glasses 1 according to this embodiment will be described.
[0125] In an Example 1, the relative dielectric constant of the first interlayer film 31 in
[0126] In the conditions of the simulations shown in
[0127]
[0128] As shown in
[0129] That is, when the relative dielectric constant of the first interlayer film 31 is 6.15 (ε.sub.m1=6.15), the relative dielectric constant of the first interlayer film 31 is close to those of the first and second glass plates 11 and 12 (ε.sub.g1, ε.sub.g2: 6.72). Therefore, it is possible to reduce the reflection at the interfaces between the first and second glass plates 11 and 12 and the first interlayer film 31, and thereby to improve the transmitting property for electromagnetic waves in the millimeter-wave band. Note that, in the Comparative Example 2 in which the incident angle θ was 0° (θ=0°), the electromagnetic wave transmission characteristic fluctuated according to the frequency of the electromagnetic wave, and the electromagnetic wave transmission characteristic was −4 dB or lower in the range of 70 GHz to 77 GHz.
[0130] Next, the electromagnetic wave transmission characteristics of the laminated glasses 1 were measured in order to verify the relation between the results of the simulations shown in
[0131] The relative dielectric constant of the first interlayer film 31 was set to 6.15 and 2.45 (ε.sub.m1=6.15, ε.sub.m1=2.45). The relative dielectric constant of the first glass plate 11 was set to 6.72 (ε.sub.g1=6.72), and the relative dielectric constant of the second glass plate 12 was set to 6.72 (ε.sub.g2=6.72). Note that each of the relative dielectric constants is a relative dielectric constant at a frequency F of 79 GHz (F=79 GHz).
[0132] Note that, for each of the first and second glass plates 11 and 12, a glass containing, when expressed by mol percentages based on oxides, SiO.sub.2: 69.7%, Al.sub.2O.sub.3: 0.9%, MgO: 7%, CaO: 9%, TiO.sub.2: 0.05%, Na.sub.2O: 12.6%, K.sub.2O: 0.6%, and Fe.sub.2O.sub.3: 0.2% was used. Note that each of the first and second glass plates 11 and 12 was a glass corresponding to a “Composition Example 1” in a Table 1.
TABLE-US-00001 TABLE 1 Composition Composition Composition Composition Composition Example 1 Example 2 Example 3 Example 4 Example 5 Composition SiO.sub.2 69.7 73.7 80 65.9 75.5 (mol %) Al.sub.2O.sub.3 0.9 0.1 2 11 0.3 B.sub.2O.sub.3 0 0 13 7 0 MgO 7 0.1 0 6 0 CaO 9 11.5 0 5 6 SrO 0 0 0 5 0 BaO 0 0 0 0 0 TiO.sub.2 0 0.05 0 0 0.05 ZrO.sub.2 0 0 0 0 0 Li.sub.2O 0 0 0 0 6 Na.sub.2O 12.6 7.2 4 0 6 K.sub.2O 0.6 7.2 1 0 6 Fe.sub.2O.sub.3 0.2 0.15 0 0.1 0.15 Relative 6.70 6.50 4.40 5.20 6.10 Dielectric Constant (ε.sub.g1, ε.sub.g2)@79 GHz Dielectric 0.032 0.02 0.012 0.011 0.015 Loss Tangent (tanδ)@79 GHz
[0133] Further, for the first interlayer film 31, a material containing PTFE as a main component (RF-60TC (manufactured by KOREA TACONIC): relative dielectric constant=6.40 at 10 GHz, tan δ=0.002 at 10 GHz) was used as the Example 1, and polyvinyl butyral (PVB) (relative dielectric constant at 10 GHz=2.60) was used as the Comparative Example 1. Note that values of the relative dielectric constant and the dielectric loss tangent (tan δ) of the first interlayer film 31 at 10 GHz were those measured under an environment in which the temperature was in a range of 23° C.±2° C., and the humidity was in a range of 50±5% RH by an SPDR (Split-Post Dielectric Resonator) method.
[0134] Note that there is a tendency that the relative dielectric constant of each material of the Example 1 and the Comparative Example 1 decreases as the frequency band increases. Therefore, in the first interlayer film 31 containing PTFE as the main component in the Example 1, the relative dielectric constant at 79 GHz was set to 6.15 (ε.sub.m1=6.15) based on the measurement value 6.40 of the relative dielectric constant at 10 GHz. Further, in the first interlayer film 31 (PVB) in the Comparative Example 1, the relative dielectric constant was set to 2.45 (ε.sub.m1=2.45) at 79 GHz based on the measurement value 2.60 of the relative dielectric constant at 10 GHz. Further, the thickness of each of the first and second glass plates 11 and 12 was set to 2 mm, and the thickness of the first interlayer film 31 was set to 0.76 mm. The frequency of electromagnetic waves used for the measurement was in a range of 70 GHz to 84 GHz. The incident angle θ of the electromagnetic wave was set to 67.5° (θ=67.5°).
[0135] As shown in
[0136] Further, when the results of the simulations shown in
[0137] Next, a relation between the relative dielectric constant ε.sub.m1 of the first interlayer film 31 and the electromagnetic wave transmission characteristic (S21) thereof will be described.
[0138] The conditions of the simulations shown in
[0139] In the simulations shown in
[0140] Firstly, the results of the simulations shown in
[0141] That is, as the relative dielectric constant of the first interlayer film 31 approaches to 6.72 (ε.sub.m1=6.72), the relative dielectric constant of the first interlayer film 31 gets closer to the relative dielectric constant (6.72) of the first and second glass plates 11 and 12. As described above, when the relative dielectric constant of the first interlayer film 31 approaches 6.72 (ε.sub.m1=6.72), the difference between the relative dielectric constants of the first glass plate 11 and the first interlayer film 31, and the difference between the relative dielectric constants of the second glass plate 12 and the first interlayer film 31 both decrease, so that the reflection of the electromagnetic wave at the interfaces between the first and second glass plates 11 and 12 and the first interlayer film 31 can be suppressed (i.e., reduced). Therefore, it is possible to improve the transmitting property for electromagnetic waves in the millimeter-wave band. Note that, in the Comparative Example 1 in which the incident angle θ was 0° (θ=0°), the electromagnetic wave transmission characteristic fluctuated according to the frequency of the electromagnetic wave, and the electromagnetic wave transmission characteristic was −3.5 dB or lower in the range of 70 GHz to 78 GHz.
[0142] Here, when values of the reflection coefficients Γ.sub.1 and Γ.sub.2 are obtained by using the above-shown Expression 1, the below-shown values are obtained. Note that since the relative dielectric constants ε.sub.g1 and ε.sub.g2 are both 6.72 (ε.sub.gi=ε.sub.g2=6.72) under the above-described conditions of the simulations, the values of reflection coefficients Γ.sub.1 and Γ.sub.2 become equal to each other.
[0143] When the relative dielectric constant ε.sub.m1 of the first interlayer film 31 was 2.8, the reflection coefficients Γ.sub.1 and Γ.sub.2 were both 0.215 (Γ.sub.1, Γ.sub.2=0.215).
[0144] When the relative dielectric constant ε.sub.m1 of the first interlayer film 31 was 3, the reflection coefficients Γ.sub.1 and Γ.sub.2 were both 0.199 (Γ.sub.1, Γ.sub.2=0.199).
[0145] When the relative dielectric constant ε.sub.m1 of the first interlayer film 31 was 3.5, the reflection coefficients Γ.sub.1 and Γ.sub.2 were both 0.162 (Γ.sub.1, Γ.sub.2=0.162).
[0146] When the relative dielectric constant ε.sub.m1 of the first interlayer film 31 was 4.5, the reflection coefficients Γ.sub.1 and Γ.sub.2 were both 0.100 (Γ.sub.1, Γ.sub.2=0.100).
[0147] When the relative dielectric constant ε.sub.m1 of the first interlayer film 31 was 5.5, the reflection coefficients Γ.sub.1 and Γ.sub.2 were both 0.050 (Γ.sub.1, Γ.sub.2=0.050).
[0148] When the relative dielectric constant ε.sub.m1 of the first interlayer film 31 was 6.15, the reflection coefficients Γ.sub.1 and Γ.sub.2 were both 0.022 (Γ.sub.1, Γ.sub.2=0.022).
[0149] When the relative dielectric constant ε.sub.m1 of the first interlayer film 31 was 6.72, the reflection coefficients Γ.sub.1 and Γ.sub.2 were both 0 (Γ.sub.1, Γ.sub.2=0).
[0150] From the above-described results, the conditions of the above-shown Expressions 2 and 3 are satisfied when the relative dielectric constant ε.sub.m1 of the first interlayer film 31 is 3.0 or higher.
[0151] Further, based on the above-described results of the simulations, the preferred range of the relative dielectric constant ε.sub.m1 of the first interlayer film 31 is 3.5 or higher, and the ranges of the above-shown Expressions 2 and 3 are expressed as 0.0≤Γ.sub.1≤0.162 and 0.0≤Γ.sub.2≤0.162, respectively. Further, based on the above-described results of the simulations, the more preferred range of the relative dielectric constant ε.sub.m1 of the first interlayer film 31 is 4.5 or higher, and the ranges of the above-shown Expressions 2 and 3 are expressed as 0.0≤Γ.sub.1≤0.100 and 0.0≤Γ.sub.2≤0.100, respectively. Further, based on the above-described results of the simulations, the still more preferred range of the relative dielectric constant ε.sub.m1 of the first interlayer film 31 is 5.5 or higher, and the ranges of the above-shown Expressions 2 and 3 are expressed as 0.0≤Γ.sub.1≤0.050 and 0.0≤Γ.sub.2≤0.050, respectively.
[0152] Next, the results of the simulations shown in
[0153] That is, as the relative dielectric constant of the first interlayer film 31 approaches to 6.72 (ε.sub.m1=6.72), the relative dielectric constant of the first interlayer film 31 gets closer to the relative dielectric constant (6.72) of the first and second glass plates 11 and 12. As described above, when the relative dielectric constant of the first interlayer film 31 approaches 6.72 (ε.sub.m1=6.72), the difference between the relative dielectric constants of the first glass plate 11 and the first interlayer film 31, and the difference between the relative dielectric constants of the second glass plate 12 and the first interlayer film 31 both decrease, so that the reflection of the electromagnetic wave at the interfaces between the first and second glass plates 11 and 12 and the first interlayer film 31 can be suppressed (i.e., reduced). Therefore, it is possible to improve the transmitting property for electromagnetic waves in the millimeter-wave band. Note that, in the Comparative Example 1 in which the incident angle θ was 0° (θ=0°), the electromagnetic wave transmission characteristic fluctuated according to the frequency of the electromagnetic wave, and the electromagnetic wave transmission characteristic was −3.5 dB or lower in the range of 70 GHz to 78 GHz.
[0154] Here, when values of the reflection coefficients Γ.sub.1 and Γ.sub.2 are obtained by using the above-shown Expression 1, the below-shown values are obtained. Note that since the relative dielectric constants ε.sub.g1 and ε.sub.g2 are both 6.72 (ε.sub.g1=ε.sub.g2=6.72) under the above-described conditions of the simulations, the values of reflection coefficients Γ.sub.1 and Γ.sub.2 become equal to each other.
[0155] When the relative dielectric constant ε.sub.m1 of the first interlayer film 31 was 20, the reflection coefficients Γ.sub.1 and Γ.sub.2 were both 0.266 (Γ.sub.1, Γ.sub.2=0.266).
[0156] When the relative dielectric constant ε.sub.m1 of the first interlayer film 31 was 18, the reflection coefficients Γ.sub.1 and Γ.sub.2 were both 0.241 (Γ.sub.1, Γ.sub.2=0.241).
[0157] When the relative dielectric constant ε.sub.m1 of the first interlayer film 31 was 15, the reflection coefficients Γ.sub.1 and Γ.sub.2 were both 0.198 (Γ.sub.1, Γ.sub.2=0.198).
[0158] When the relative dielectric constant ε.sub.m1 of the first interlayer film 31 was 13, the reflection coefficients Γ.sub.1 and Γ.sub.2 were both 0.163 (Γ.sub.1, Γ.sub.2=0.163).
[0159] When the relative dielectric constant ε.sub.m1 of the first interlayer film 31 was 10, the reflection coefficients Γ.sub.1 and Γ.sub.2 were both 0.099 (Γ.sub.1, Γ.sub.2=0.099).
[0160] When the relative dielectric constant ε.sub.m1 of the first interlayer film 31 was 8, the reflection coefficients Γ.sub.1 and Γ.sub.2 were both 0.046 (Γ.sub.1, Γ.sub.2=0.046).
[0161] When the relative dielectric constant ε.sub.m1 of the first interlayer film 31 was 6.72, the reflection coefficients Γ.sub.1 and Γ.sub.2 were both 0 (11, Γ.sub.2=0).
[0162] From the above-described results, the conditions of the above-shown Expressions 2 and 3 are satisfied when the relative dielectric constant ε.sub.m1 of the first interlayer film 31 is 15 or lower.
[0163] Further, based on the above-described results of the simulations, the preferred range of the relative dielectric constant ε.sub.m1 of the first interlayer film 31 is 13 or lower, and the ranges of the above-shown Expressions 2 and 3 are expressed as 0.0≤Γ.sub.1≤0.163 and 0.0≤Γ.sub.2≤0.163, respectively. Further, based on the above-described results of the simulations, the more preferred range of the relative dielectric constant ε.sub.m1 of the first interlayer film 31 is 10 or lower, and the ranges of the above-shown Expressions 2 and 3 are expressed as 0.0≤Γ.sub.1≤0.099 and 0.0≤Γ.sub.2≤0.099, respectively. Further, based on the above-described results of the simulations, the still more preferred range of the relative dielectric constant ε.sub.m1 of the first interlayer film 31 is 8 or lower, and the ranges of the above-shown Expressions 2 and 3 are expressed as 0.0≤Γ.sub.1≤0.046 and 0.0≤Γ.sub.2≤0.046, respectively.
[0164] From the results of the simulations shown in
[0165] Next, a relation between the relative dielectric constant of the first interlayer film 31 and the electromagnetic wave reflection characteristic thereof will be described.
[0166] The conditions of the simulations shown in
[0167] In the simulations shown in
[0168] Firstly, the results of the simulations shown in
[0169] That is, as the relative dielectric constant of the first interlayer film 31 approaches to 6.72 (ε.sub.m1=6.72), the relative dielectric constant of the first interlayer film 31 gets closer to the relative dielectric constant (6.72) of the first and second glass plates 11 and 12. As described above, when the relative dielectric constant of the first interlayer film 31 approaches 6.72 (ε.sub.m1=6.72), the difference between the relative dielectric constants of the first glass plate 11 and the first interlayer film 31, and the difference between the relative dielectric constants of the second glass plate 12 and the first interlayer film 31 both decrease, so that the reflection of the electromagnetic wave at the interfaces between the first and second glass plates 11 and 12 and the first interlayer film 31 can be suppressed (i.e., reduced). Note that the values of the reflection coefficients Γ.sub.1 and Γ.sub.2 in the above-described simulations were equal to or close to those in the simulation shown in
[0170] Next, the results of the simulation shown in
[0171] Further, when the relative dielectric constant of the first interlayer film 31 was 6.72 (ε.sub.m1=6.72), the electromagnetic wave reflection characteristic was the lowest.
[0172] That is, as the relative dielectric constant of the first interlayer film 31 approaches to 6.72 (ε.sub.m1=6.72), the relative dielectric constant of the first interlayer film 31 gets closer to the relative dielectric constant (6.72) of the first and second glass plates 11 and 12. As described above, when the relative dielectric constant of the first interlayer film 31 approaches 6.72 (ε.sub.m1=6.72), the difference between the relative dielectric constants of the first glass plate 11 and the first interlayer film 31, and the difference between the relative dielectric constants of the second glass plate 12 and the first interlayer film 31 both decrease, so that the reflection of the electromagnetic wave at the interfaces between the first and second glass plates 11 and 12 and the first interlayer film 31 can be suppressed (i.e., reduced). Note that the values of the reflection coefficients Γ.sub.1 and Γ.sub.2 in the above-described simulations were equal to or close to those in the simulation shown in
[0173] Based on the results of the simulations of electromagnetic wave transmission characteristics shown in
[0174] Further, based on the results of the simulations of electromagnetic wave transmission characteristics shown in
[0175]
[0176] In the simulations shown in
[0177] Further, the incident angle θ of the electromagnetic wave on the laminated glass 1 was 0°, 30°, 45° and 60°.
[0178] As shown in
[0179] In the case where the incident angle θ of the electromagnetic wave on the laminated glass 1 was 45°, the electromagnetic wave transmission characteristic exhibited high values when the relative dielectric constant of the first interlayer film 31 was in a range of 5 to 16 (ε.sub.m1=5 to 16). Meanwhile, when the relative dielectric constant of the first interlayer film 31 was set to 2.45 and 18 (ε.sub.m1=2.45, ε.sub.m1=18), the electromagnetic wave transmission characteristic has low values. In the case where the incident angle θ of the electromagnetic wave on the laminated glass 1 was 60°, the electromagnetic wave transmission characteristic exhibited high values when the relative dielectric constant of the first interlayer film 31 was in a range of 5 to 16 (ε.sub.m1=5 to 16). Meanwhile, when the relative dielectric constant of the first interlayer film 31 was set to 2.45 and 18 (ε.sub.m1=2.45, ε.sub.m1=18), the electromagnetic wave transmission characteristic has low values.
[0180] In the results of the simulations shown in
[0181] Each of
[0182] In the simulations shown in
[0183] As shown in
Examples 2 to 13, Comparative Examples 1 to 4
[0184] Next, for glasses having the Composition Examples 1 to 5 shown in Table 1, five combinations of the first and second glass plates 11 and 12, and three types of materials for the first interlayer film 31 were prepared, and 15 types of laminated glasses were examined in total. Specifically, for each of the examples and each of the comparative examples, a result of a simulation in which an electromagnetic wave having a frequency of 79 GHz was made incident (i.e., was applied) at an incident angle θ of 67.5° (θ=67.5°) was obtained. Note that the thickness of each of the first and second glass plates 11 and 12 was set to 2 mm, and the thickness of the first interlayer film 31 was set to 0.76 mm. Note that the laminated glasses according to the Comparative Examples 1 to 2 were the same as those of the above-described Comparative Examples 1 to 2. Further, for the first interlayer film 31 in each of the examples and each of the comparative examples, the relative dielectric constant ε.sub.m1 at 79 GHz was calculated based on the measurement value of the relative dielectric constant at 10 GHz.
TABLE-US-00002 TABLE 2 Electro- magnetic- Wave Transmitting Property (S21) Lower than −2.8 dB: X First εg1 −2.8 dB Glass (@79 or larger: Δ Plate 11 GHz) −l.6 dB Second εg2 First ε.sub.m1 Γ.sub.2 ε.sub.g1-ε.sub.m1 or larger: ◯ Glass (@79 Interlayer (@79 (@79 (@79 −1.2 dB Plate 12 GHz) Film 31 GHz) GHz) GHz) or larger: ⊚ Com- Com- 6.72 PVB 2.45 0.247 4.27 X parative position Example Example 1, 2 1 Com- Com- 6.50 PVB 2.45 0.239 4.05 X parative position Example Example 3 2 Example Com- 4.40 PVB 2.45 0.145 1.95 ◯ 2 position Example 3 Example Com- 5.20 PVB 2.45 0.186 2.75 ◯ 3 position Example 4 Com- Com- 6.10 PVB 2.45 0.224 3.65 X parative position Example Example 4 5 Example Com- 6.72 PVB + 3.50 0.162 3.22 Δ 4 position Glass Example 1 Powder (Compo- sition Example 1) Example Com- 6.50 PVB + 3.50 0.154 3.00 Δ 5 position Glass Example Powder 2 (Compo- sition Example 1) Example Com- 4.40 PVB + 3.50 0.057 0.90 Δ 6 position Glass Example Powder 3 (Compo- sition Example 1) Example Com- 5.20 PVB + 3.50 0.099 1.70 ◯ 7 position Glass Example Powder 4 (Compo- sition Example 1) Example Com- 6.10 PVB + 3.50 0.138 2.60 Δ 8 position Glass Example Powder 5 (Compo- sition Example 1) Example Com- 6.72 PVB + 6.60 0.005 0.12 Δ 9 position BaTiO.sub.3 Example 1 Example Com- 6.50 PVB + 6.60 −0.004 −0.10 Δ 10 position BaTiO.sub.3 Example 2 Example Com- 4.40 PVB + 6.60 −0.101 −2.20 Δ 11 position BaTiO.sub.3 Example 3 Example Com- 5.20 PVB + 6.60 −0.060 −1.40 ◯ 12 position BaTiO.sub.3 Example 4 Example Com- 6.10 PVB + 6.60 −0.020 −0.50 ⊚ 13 position BaTiO.sub.3 Example 5
[0185] PVB (ε.sub.m1=2.45) was used for the first interlayer film 31 in the laminated glass of each of the Comparative Examples 1 to 4 and each of the Examples 2 and 3. In the first interlayer film 31 of the laminated glass of each of the Examples 4 to 8, a powder of the glass (the particle diameter was 100 μm or smaller) shown in the “Composition Example 1” in the Table 1 was mixed (dry-blended) in the PVB, which was the matrix resin, while adjusting the volume content thereof so as to be within a range of 1 vol % to 50 vol %. Further, in the first interlayer film 31 of the laminated glass of each of the Examples 9 to 13, a powder of barium titanate (BaTiO.sub.3) having a particle diameter of 1 μm or smaller was mixed (dry-blended) in the PVB, which was the matrix resin, while adjusting the volume content thereof so as to be within a range of 1 vol % to 50 vol %. Then, this mixture was charged into a resin melting biaxial kneader (Labo Plastomill manufactured by Toyo Seiki Seisaku-sho, Ltd.), and melted and kneaded at a screw rotation speed of 50 rpm at a kneading temperature of 160° C. for a kneading time of 3 minutes, and as a result, a composite sample was obtained. This composite sample was press-molded at 160° C. by a thermal press (Mini Test Press manufactured by Toyo Seiki Seisaku-sho, Ltd.), and as a result, a sheet having a thickness of 0.4 mm was obtained. Then, the relative dielectric constant and the dielectric loss tangent of the sheet were measured by the above-described SPDR method.
[0186] From the results shown in a Table 2, it was confirmed that, in the Examples 2 to 13, the smaller the reflection coefficient Γ.sub.1 was, the larger the transmission characteristic S21 became, and hence the better the transmitting property for electromagnetic waves became. Further, the Example 13, in which: the reflection coefficient Γ.sub.1 was 0.05 or smaller; the relative dielectric constants of the first glass plate 11, the second glass plate 12, and the first interlayer film 31 (ε.sub.g1, ε.sub.g2 and ε.sub.m1) were 5.5 or higher; and the dielectric loss tangents (tan δ at 79 GHz) of the first and second glass plates 11 and 12 were 0.018 or smaller, exhibited the best transmission characteristic S21.
[0187] In the above-described embodiment, cases where the first interlayer film 31 has a one-layer structure have been described. However, in the present invention, the first interlayer film 31 may further include another layer(s). For example, in the present invention, the interlayer film 13 (the first interlayer film 31, or the first and second interlayer films 31 and 32) may further include a sound insulation layer. The sound insulation layer has, for example, a three-layer structure including a first skin layer and a second skin layer on each of both sides of a core layer. It is possible to maintain the sound insulation property by making the elastic modulus of the core layer smaller than those of the first and second skin layers. Note that the elastic modulus is a value of a storage elastic modulus when frequency dispersion measurement is performed at a strain of 0.05% by using a dynamic mechanical analysis (DMA) device. In this manner, it is possible to improve the sound insulation property of the laminated glass by including the sound insulation layer therein.
[0188] Further, in the present invention, a black ceramic film may be printed on a part(s) (for example, a peripheral part(s)) of the first and second glass plates 11 and 12. Further, the laminated glass 1 according to the present invention may be used as a radome of a millimeter-wave radar device.
[0189] While the present invention has been described in view of the above-described embodiments, the present invention is not limited to the configurations of the above-described embodiments. Further, needless to say, the present invention includes various changes, modifications, and combinations that may be made by one skilled in the art within the scope of the claims of the present application.