COMPACT INSERTS FOR CRYO-COMPRESSED STORAGE VESSELS
20240318785 ยท 2024-09-26
Assignee
Inventors
- David E. JARAMILLO (San Francisco, CA, US)
- Edward J. MCKLVEEN (San Francisco, CA, US)
- Anubhav Roy (San Francisco, CA, US)
- Kaushik Mallick (San Francisco, CA, US)
Cpc classification
F17C2203/0604
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2223/036
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2223/0123
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2201/054
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2221/012
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C5/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2270/0171
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2270/0168
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2203/0308
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2203/0663
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2223/0115
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2203/0391
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2201/0109
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2270/01
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C13/001
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C1/14
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2201/056
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2209/221
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2223/035
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2203/0643
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02E60/32
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F17C2201/0104
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2260/036
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C1/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2270/0189
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2205/0305
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2260/013
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2205/0367
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C3/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2223/0161
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2203/0624
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2203/0646
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F17C5/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C13/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
In one aspect, an insert including a single metal or alloy compatible with cryo-compressed tanks is disclosed. In one embodiment, the insert contains one, two, or more tubes that extend into the inner storage volume of the tank. The insert may be integrally formed with the tubes. The tubes enable the entrance and exit of hydrogen to the inner storage volume. In one embodiment, the tank includes a boss suitable to accept the insert. The boss and the insert may be the same metal. The insert may minimize the number of welds suitable for use in on-board heavy duty storage applications. Overall, this type of insert decreases the probability of hydrogen leaks, reduces the cost of the insert as only one piece is required, and leads to faster manufacturing as fewer welds are required.
Claims
1. An apparatus for use in hydrogen pressure vessels, comprising: an insert comprising: a continuous body formed of a single metal or alloy, wherein the insert is formed without welds; threads formed on the body and configured to engage with mating threads of a pressure vessel one or more ducts formed within the body and configured to provide a passage for hydrogen or fluids between opposing ends of the body; wherein, the insert is configured to be coupled to a pressure vessel with only one weld to produce a sealed inner pressure vessel.
2. The apparatus of claim 1, further comprising one or more tubes which extend the one or more ducts beyond the body, wherein the one or more tubes are formed as part of the continuous body without any additional welds coupling the one or more tubes to the body.
3. The apparatus of claim 1, wherein the single metal or alloy comprises stainless steel.
4. The apparatus of claim 1, wherein the single metal or alloy comprises aluminum.
5. The apparatus of claim 1, wherein the one or more ducts includes a mitered bend.
6. The apparatus of claim 1, further comprising one or more grooves formed in the body portion and configured to accommodate a support structure.
7. A unitary fluidic connection device comprising: a body portion including: a first end and a second end opposite the first end thereof; threads formed on an outer portion thereof; a flange portion including: a first end and a second end opposite the first end thereof, wherein the flange portion extends longitudinally and axially from the first end of the body portion, and the flange portion has a radial dimension larger than a radial dimension of the body portion; a plurality of ducts extending longitudinally through flange portion and through the body portion between the first end of the flange portion and the second end of the body portion; a respective plurality of first conduits extending longitudinally from respective first ends of each of the plurality of ducts proximate to the first end of the flange portion; a respective plurality of second conduits extending longitudinally from respective second ends of each of the plurality of ducts proximate to the second end of the body portion.
8. The unitary fluid connection device of claim 7, wherein the fluid connection device comprises stainless steel.
9. The unitary fluid connection device of claim 7, wherein the fluid connection device comprises aluminum.
10. The unitary fluid connection device of claim 7, further comprising one or more grooves configured to accommodate a support structure.
11. A pressure vessel fluid coupling comprising: an upper portion comprising: a first sub-portion including a first conduit receptacle, and a second sub-portion including a second conduit receptacle; a lower portion configured to be coupled to the upper portion; a conduit configured to be received in the first conduit receptacle and the second conduit receptacle, wherein the conduit is configured to provide a fluid pathway to an internal volume of the pressure vessel.
12. The pressure vessel fluid coupling of claim 11, further comprising: first threads formed on an outer surface of the first sub-portion; and second threads formed on an outer surface of the second sub-portion, wherein when the first sub-portion and the second sub-portion are assembled together, the first threads and the second threads form a single helix.
13. The pressure vessel fluid coupling of claim 11, wherein the upper portion is formed of a first material and the lower portion is formed of a second material different than the first material.
14. The pressure vessel fluid coupling of claim 13, wherein the first material comprises aluminum or an alloy thereof and the second material comprises steel or an alloy thereof.
15. The pressure vessel fluid coupling of claim 11, wherein: the first sub-portion includes a first flange portion; and the second sub-portion includes a second flange portion, wherein when the first sub-portion and the second sub-portion are assembled together, first flange portion and the second flange portion form a recess.
16. The pressure vessel fluid coupling of claim 15, wherein the lower portion includes a protrusion that rises proud of the main body of the lower portion.
17. The pressure vessel fluid coupling of claim 16, wherein the protrusion is receivable in the recess such that the protrusion and the recess comprise respective first and second attachment portions configured to couple the upper portion and the lower portion together.
18. The pressure vessel fluid coupling of claim 11, wherein the conduit includes a mitered bend.
19. The pressure vessel fluid coupling of claim 11, wherein the conduit is coupled to the lower portion by a weld that forms a hermetic seal.
20. A pressure vessel system comprising: a pressure vessel, comprising: a neck with neck threads formed on an inner surface thereof, an internal compartment the pressure vessel fluid coupling claim 12; a radial seal received in a gland formed in the lower portion and configured to contain a fluid within the internal compartment, wherein when the single helix is threadedly engaged with the neck threads, the radial seal prevents the leakage of a fluid from the internal compartment.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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[0042]
DETAILED DESCRIPTION
[0043] The present disclosure is directed to devices and methods to address the issues and limitations of the existing devices and methods discussed herein. In one embodiment, a tank insert is formed by additive manufacturing to produce a single, continuous, metallic and unitary threaded insert piece suitable for use with a cryogenic pressure vessel. A pressure vessel can contain a pressurized fluid (a liquid, gas, or supercritical fluid). In a preferred embodiment the pressure vessel is optimized to store cryo-compressed hydrogen. As used herein, unitary describes a device made from a single piece of material. In many embodiments, the metal or alloy used has a very low-to-undetectable permeability to hydrogen under the operating conditions, which may include large swings in temperature (e.g., 33-298 K) and pressure (e.g., 5-350 bar). Furthermore, in many embodiments, it may be desired that the metal or alloy has a fatigue life of over 11,000 discharge and refueling cycles while minimizing weight or bulk of the overall storage system. Single metallic, stainless steel alloys are promising for this use. Only recently, additive manufacturing techniques have been developed that make it possible to produce various alloys, including stainless steel, that are non-porous and feature yield strength and tensile ductility comparable to or even superior to conventionally made alloys. In particular, the application of laser powder-bed-fusion (LPBF) technique may be able to produce inserts of sufficient strength and ductility to meet the application parameters (11,000 cycles of 33-298 K and 5-350 bar swings) of on-board cryo-compressed hydrogen storage for transportation applications. This type of technique gives rise to non-equilibrium microstructures that contribute to the overall bulk material properties. Due to the contributions from these non-equilibrium microstructures, this method can impart greater yield strength and uniform elongation relative to counterparts made from standard manufacturing processes such as machining, casting, and/or forging. The laser processing parameters directly impact the peak temperature, thermal gradient, and cooling rate, which influence the resulting microstructures and bulk properties. By establishing preferred laser processing conditions, such as spot size, power, and scan speed, tank components can be constructed with the appropriate bulk properties (e.g. yield strength>200 MPa) at sufficient throughput. For example, laser spot sizes can range from 50 to 1000 ?m, laser power can range from 100 to 1000 W, and the scan speed can range from 100 to 5000 mm/s. A combination of laser-based additive manufacturing methods, including powder feed (e.g., Direct Energy Deposition or DED) and wire feed setups, can enable the production of stainless steel at the various sizes and durability traits desired. In addition to LPBF and other laser-based additive manufacturing approaches, another strategy is to cast or use metal injection modeling to construct the insert piece. However, there may be difficulties with casting the tubes of particular lengths and particular shapes (i.e. bends).
[0044] One embodiment of the present disclosure is illustrated in
[0045] The insert 200 and the threads 201 can be compatible with current type III vessels, which can serve as the inner vessel for cryo-compressed storage units. Once inserted into the neck 710, the threads 201 of the insert 200 help withstand stresses that arise when the inner volume 701 contains a pressurized fluid. Adjacent to the threads 201 and the cylindrical body portion 203, the flange portion 205 of the insert 200 may have a wider dimension than the body portion 203. The flange portion 205 may act as a collar, support base, or shoulder 202. In many embodiments, the shoulder 202 serves as support for joining the insert 200 to the inner vessel, by a joint that may be formed such as by welding, soldering, brazing, or the like. For example, as shown in
[0046] The single-piece insert 200 may contain one or more ducts 204a, 204b. As shown for example in
[0047]
[0048]
[0049]
[0050]
[0051]
[0052] With reference to
[0053] The two sub-portions 803a/b may have threads 801 formed on an outer surface thereof and configured to engage threads 201 formed in a neck 710 of a tank 700 to secure the insert 800 to the tank 700.
[0054] Each of the two portions 803a/b may have formed therein, respective conduit receptacle 806a/b. The conduit receptacle 806a/b may form a clamp structure 830 suitable to accept a conduit 810 (e.g., a fill conduit and/or a vent conduit) when the two portions are assembled, as shown for example in
[0055] This system and approach enable the conduit 810 to maximize the compactness of the insert 800 and conduit 810. The lower portion 804 of the insert 800 may be constructed as a single piece. A conduit 814 may be formed in the lower portion 804, such as by drilling, additive manufacturing or the like, and configured to accept a portion (e.g., straight portion) of the fill conduit 814. The upper portion 802 may include an attachment portion 805a configured to receive a complementary attachment portion 805b of the lower portion 804, for example after the two sub-portions 803a and 803b have been assembled with the conduit 810. The lower portion 804 may include a protrusion 816 that rises proud of the main body 818 of the lower portion 804, thereby creating the attachment portion 805b. Similarly, the upper portion 802 may include a flange portion 820 that forms a recess 822 included in the attachment portion 805a. The protrusion 816 may be receivable in the recess 822. For example, each of the two sub-portions 803a/b may include respective first and second flange portions 820 that, when the sub-portions 803a/b are assembled cooperate to form the recess 822. For example, the flange portion 820 may surround a portion of the protrusion 816. The attachment portions 805a/b may include a threaded connection, an interference fit, a conical fit for example with a keyed entry, a sealed joint, a bonded joint, or any combination thereof.
[0056] In one example, the inert 800 may be assembled by placing the conduit 810 within one of the respective conduit receptacle 806a/b of one of the two sub-portions 803a/b of the upper portion 802. The other of the two sub-portions 803a/b may be placed over the conduit 810 such that the conduit is received in the clamp structure 800 formed by the respective two conduit receptacle 806a/b. The threads formed on an outer surfaces of the two sub-portions 803a/b may, when assembled form a single helix suitable to threadedly couple the upper portion 802 with the threads 201 of the neck 710 of the pressure vessel 700. The lower portion 804 and the assembled upper portion 802 may be joined by the attachment portions 805a/b. The lower portion 804 may be placed in the neck 710 of a pressure vessel 700 until the threads 801 of the insert begin to engage the threads 201 of the neck 710 of the pressure vessel 700. The insert may be rotated such that the threads 201 and the threads 801 engage, pulling the insert 800 sufficiently far into the neck 710 for the seal 824 to engage the gland 728 (if used) of the neck 710, sealing the pressure vessel 700. The conduit 810 may provide a fluid path between the internal compartment 701 of the pressure vessel 700 and other equipment separate from the pressure vessel 700. The portions of the insert 800 may be assembled in an order other than as described. Similarly, the insert 800 may be assembled with the pressure vessel 700 in an order other than as described.
[0057] In some examples, the lower portion 804 may be made from one or more steel alloys such as stainless steel alloy 304, 316L, and others. The upper portion 802 may be made from a metal or alloy different than that of the lower portion 804, such as aluminum or an alloy thereof such as 6061-T6, a 2000 series, such as 2050, a 5000 series, such as 5083, a 7000 series, such as 7475. Different thermal expansion properties from dissimilar metals can be leveraged to ensure an effective contact between the upper portion 802 and the lower portion 804.
[0058] The lower portion 804 may include a gland 826 formed therein and configured to receive a radial seal 824 that prevents the internal pressure of the tank to egress beyond the position of the radial seal 824. The radial seal 824 may include an elastomeric sealing mechanism, spring energized sealing mechanism, o-ring, or a combination thereof. The seal 824 may be rated for cryogenic temperatures. The radial seal 824 may also be received in an appropriately configured gland 728 formed in the neck 710 of a pressure vessel 700. The radial seal 824 may prevent the internal fluid from escaping into the threads of the insert and leaking out of the pressure vessel 700. The radial seal 728 enables the construction of the insert 800 in multiple pieces as the two sub-portions 803a/b of the upper portion 802 are not subjected to the pressure from the fluid in the tank that would tend to split the two sub-portions 803a/b apart.
[0059] In some embodiments, only one weld, weld 808, may be used to provide a hermetic seal against the hydrogen in a tank into which the insert 800 is inserted. The weld 808 can be stainless steel to stainless steel. As no weld is required between the bottom and the top half of the insert, a bimetallic welding process is avoided. Furthermore, the required weld is between the fill tube and the insert piece. Both are small components, which enables serial welding. In contrast, the prior art requires welding the insert to the tank. As the tank can be a large component, it makes the welding process more challenging to accomplish in a high-throughput manner.
[0060] The description of certain embodiments included herein is merely exemplary in nature and is in no way intended to limit the scope of the disclosure or its applications or uses. In the included detailed description of embodiments of the present systems and methods, reference is made to the accompanying drawings which form a part hereof, and which are shown by way of illustration specific to embodiments in which the described systems and methods may be practiced. These embodiments are described in sufficient detail to enable those skilled in the art to practice presently disclosed systems and methods, and it is to be understood that other embodiments may be utilized, and that structural and logical changes may be made without departing from the spirit and scope of the disclosure. Moreover, for the purpose of clarity, detailed descriptions of certain features will not be discussed when they would be apparent to those with skill in the art so as not to obscure the description of embodiments of the disclosure. The included detailed description is therefore not to be taken in a limiting sense, and the scope of the disclosure is defined only by the appended claims.
[0061] From the foregoing it will be appreciated that, although specific embodiments of the invention have been described herein for purposes of illustration, various modifications may be made without deviating from the spirit and scope of the invention.
[0062] The particulars shown herein are by way of example and for purposes of illustrative discussion of the preferred embodiments of the present invention only and are presented in the cause of providing what is believed to be the most useful and readily understood description of the principles and conceptual aspects of various embodiments of the invention. In this regard, no attempt is made to show structural details of the invention in more detail than is necessary for the fundamental understanding of the invention, the description taken with the drawings and/or examples making apparent to those skilled in the art how the several forms of the invention may be embodied in practice.
[0063] As used herein and unless otherwise indicated, the terms a and an are taken to mean one, at least one or one or more. Unless otherwise required by context, singular terms used herein shall include pluralities and plural terms shall include the singular.
[0064] Unless the context clearly requires otherwise, throughout the description and the claims, the words comprise, comprising, and the like are to be construed in an inclusive sense as opposed to an exclusive or exhaustive sense; that is to say, in the sense of including, but not limited to. Words using the singular or plural number also include the plural and singular number, respectively. Additionally, the words herein, above, and below and words of similar import, when used in this application, shall refer to this application as a whole and not to any particular portions of the application.
[0065] Of course, it is to be appreciated that any one of the examples, embodiments or processes described herein may be combined with one or more other examples, embodiments and/or processes or be separated and/or performed amongst separate devices or device portions in accordance with the present systems, devices and methods.
[0066] Finally, the above discussion is intended to be merely illustrative of the present system and should not be construed as limiting the appended claims to any particular embodiment or group of embodiments. Thus, while the present system has been described in particular detail with reference to exemplary embodiments, it should also be appreciated that numerous modifications and alternative embodiments may be devised by those having ordinary skill in the art without departing from the broader and intended spirit and scope of the present system as set forth in the claims that follow. Accordingly, the specification and drawings are to be regarded in an illustrative manner and are not intended to limit the scope of the appended claims.
ADVANTAGES
From the description and accompanying drawings, several advantages for some embodiments in this disclosure are evident:
[0067] (a) An embodiment of the single-piece metal insert with tubes minimizes the number of welds used to produce a cryo-compressed tank [0068] a. There is no need to weld inlet and outlet port tubes with the threaded insert itself [0069] b. As it is all a single, unitary piece, there is no need to weld or join various components to make the insert body, as is common in the prior art.
[0070] (b) This reduction in the number of welds used may be important for meeting heavy-duty transportation application parameters, as it decreases: [0071] a. the number of leak points in the tank; [0072] b. manufacturing time; and [0073] c. tank costs.
[0074] (c) The resulting insert can be threaded into existing cylinders, presenting a path towards manufacturing at scale.
[0075] (d) The unitary insert system can contain one or multiple tubes, featuring a range of shapes [0076] a. A sharp bend in the insert duct can result in a tube that exits perpendicular to the central cylinder axis, which can mitigate heat transfer effects via the tube while maintaining high volumetric hydrogen storage densities.
[0077] (e) The insert is designed to minimize space [0078] a. Grooves exists that can interlock with support structures in the insulation layer, resulting in an overall more compact design (f) An embodiment of the multi-piece metal insert avoids bimetallic welds [0079] a. Bimetallic welds are expensive and can introduce leak points [0080] b. Some embodiments use: [0081] i. A radial seal mechanism around a bottom piece; [0082] ii. An upper portion including two sub-portions each including a respective conduit receptacle portion configured to receive a conduit; [0083] iii. An attachment portion between the upper portion and bottom portion and configured to couple the upper portion and lower portion to one another; [0084] iv. A single hermetic seal between alloys of the same kind. [0085] c. An embodiment of the multi-piece metal insert uses one weld between the fill tube and the insert body to facilitate serial welding, as these are both small components that are easily handled (relative to a tank, for example).