Composite film
11498319 · 2022-11-15
Assignee
Inventors
Cpc classification
B32B2307/3065
PERFORMING OPERATIONS; TRANSPORTING
B32B2262/12
PERFORMING OPERATIONS; TRANSPORTING
B32B5/245
PERFORMING OPERATIONS; TRANSPORTING
B32B27/18
PERFORMING OPERATIONS; TRANSPORTING
B32B27/12
PERFORMING OPERATIONS; TRANSPORTING
Y02A30/254
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B5/18
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/718
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/724
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B27/12
PERFORMING OPERATIONS; TRANSPORTING
B32B27/18
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B5/18
PERFORMING OPERATIONS; TRANSPORTING
B32B5/02
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The invention relates to a composite film (1), preferably intended for use in the construction industry and/or preferably for use as a construction film, having at least one functional layer (2), at least one outer protective layer (3) and at least one inner protective layer (4), the functional layer (2) being arranged between the outer protective layer (3) and the inner protective layer (4). According to the invention, it is provided that the functional layer (2) is formed as at least a single-layer membrane layer, that the outer protective layer (3) and the inner protective layer (4) are formed as a nonwoven layer comprising a polyolefin, and that the outer protective layer (3) and/or the inner protective layer (4) comprises at least one bicomponent fiber (5) having a first component (6) and a second component (7), the first component (6) comprising a first polymer and the second component (7) comprising a second polymer as constituent.
Claims
1. A composite construction film comprising: at least one functional layer, at least one outer protective layer and at least one inner protective layer, the functional layer being arranged between the outer protective layer and the inner protective layer, wherein the composite film is open to diffusion, the at least one functional layer includes thermoplastic polyurethane (TPU), the at least one functional layer is formed as at least a single-layer membrane layer, that the outer protective layer and the inner protective layer are formed as a nonwoven layer comprising polyolefin, and in that the outer protective layer and/or the inner protective layer comprises at least one bicomponent fiber with a first component and a second component, the first component comprising a first polymer and the second component comprising a second polymer.
2. The composite film according to claim 1, wherein the at least one functional layer is a monolithic membrane layer.
3. The composite film according to claim 1, wherein the at least one functional layer comprises one or more of: plastic, synthetic resin, an elastomeric material, a thermoplastic material, and/or a polyurethane plastic.
4. The composite film according to claim 1, wherein the at least one functional layer has a grammage of: less than 100 g/m.sup.2, between 1 g/m.sup.2 to 70 g/m.sup.2, between 3 g/m.sup.2 to 40 g/m.sup.2, between 4 g/m.sup.2 to 30 g/m.sup.2 or between 5 g/m.sup.2 to 25 g/m.sup.2.
5. The composite film according to claim 1, wherein the at least one functional layer comprises at least two membrane layers, wherein the at least two membrane layers are formed differently or the at least two membrane layers are formed at least substantially identically.
6. The composite film according to claim 1, wherein at least one membrane layer of the at least one functional layer, that is an outer membrane layer facing the outer protective layer and/or inner protective layer, includes thermoplastic copolyester (TPEE) and/or thermoplastic polyurethane (TPU) and/or the at least one functional layer is formed from TPEE layers and/or TPU layers.
7. The composite film according to claim 1, wherein at least one outer membrane layer and/or one inner membrane layer of the at least one functional layer comprises a foamed polymer, wherein the at least one outer membrane layer is bonded to the outer and/or inner protective layer.
8. The composite film according to claim 1, wherein the at least one outer protective layer and/or the at least one inner protective layer is formed as a nonwoven layer comprising polypropylene or as a polypropylene needlefelt layer.
9. The composite film according to claim 1, wherein the at least one outer protective layer and/or the at least one inner protective layer is formed as a spunbonded layer.
10. The composite film according to claim 1, wherein the grammage of the at least one outer protective layer and/or of the at least one inner protective layer is: less than or equal to 250 g/m.sup.2, between 1 g/m.sup.2 and 250 g/m.sup.2, between 10 g/m.sup.2 and 150 g/m.sup.2, between 20 g/m.sup.2 and 120 g/m.sup.2, or between 30 g/m.sup.2 and 100 g/m.sup.2.
11. The composite film according to claim 1, wherein the at least one outer protective layer and/or the at least one inner protective layer is formed as a mechanically, chemically and/or thermally, consolidated nonwoven layer.
12. The composite film according to claim 1, wherein the at least one functional layer is firmly bonded, or glued, to the outer protective layer and/or the inner protective layer.
13. The composite film according to claim 1, wherein the at least one outer protective layer and/or the at least one inner protective layer, comprising the at least one bicomponent fiber, and/or an outer functional layer, has an adhesion-promoting layer comprising a polymer, wherein the adhesion-promoting layer is firmly bonded to the functional layer and/or wherein the adhesion-promoting layer comprises a plastic and/or a synthetic resin, and/or a polyurethane.
14. The composite film according to claim 1, wherein the composite film is permeable to water vapor, windproof, rainproof, water-repellent and/or waterproof, and wherein the composite film has an Sd value of: less than or equal to 0.5 m, 0.008 m to 0.5 m, 0.009 m to 0.2 m, or 0.01 m to 0.1 m.
15. The composite film according to claim 1, wherein the tear strength of the composite film is: greater than 50 N/mm, between 50 N/mm to 600 N/mm, or between 100 N/mm to 400 N/mm, and/or that the tear propagation strength of the composite film is: greater than 50 N/mm, between 50 N/mm and 500 N/mm, or between 100 N/mm to 300 N/mm.
16. The composite film according to claim 1, wherein at least one reinforcing layer is arranged between the at least one functional layer and the at least one outer protective layer and/or the at least one inner protective layer, the reinforcing layer being a leno fabric, the reinforcing layer comprising a plastic and/or synthetic resin, a plastic polymer, a polypropylene (PP) and/or polyethylene terephthalate (PET).
17. The composite film according to claim 1, wherein at least one longitudinal-edge-side adhesive zone is provided on a topside and/or an underside of the composite film, the longitudinal-edge-side adhesive zone being spaced apart from a longitudinal edge of the composite film, and/or the adhesive zone being in the form of strips or as interrupted strips, and/or the adhesive zone having a width of between 2 and 10 cm.
18. The composite film according to claim 1, wherein a difference in melting points of the first component and the second component is less than or equal to 8° C., wherein the difference in the melting points of the first component and the second component is at most 6° C., between 1° C. to 8° C., or between 1° C. to 6° C.
19. The composite film according to claim 1, wherein a difference between melt flow indices of the first component and the second component is: less than or equal to 25 g/10 min, less than or equal to 20 g/10 min, or 15 g/10 min.
20. The composite film according to claim 1, wherein melt flow indices of the first component and the second component are each less than or equal to 50 g/10 min, or each less than or equal to 40 g/10 min.
21. The composite film according to claim 1, wherein the first component or the second component with a lower melting point in a cross-section of the bicomponent fiber forms an outer surface of the bicomponent fiber, and at least partially surrounds the component with a higher melting point.
22. The composite film according to claim 1, wherein the polymer of one of the first component or the second component has been polymerized with a metallocene catalyst.
23. The composite film according to claim 22, wherein the polymer of the other of the first component or the second component has been polymerized with a Ziegler-Natta catalyst and subjected to a subsequent visbreaking treatment.
24. The composite film according to claim 1, wherein the first component comprises an additive, a mass fraction of the additive in the second component being smaller than in the first component, wherein the mass fraction is: at most 66.6%, at most 50%, or at most 33.3%, of the mass fraction of the additive in the first component.
25. The composite film according to claim 24, wherein the additive is a primary or secondary antioxidant, a UV absorber, a UV stabilizer, a flame retardant, an antistatic agent, a lubricant, a metal deactivator, a hydrophilizing agent, a hydrophobizing agent, an anti-fogging additive and/or a biocide.
26. The composite film according to claim 24, wherein the additive is selected from the group of: sterically hindered phenols, aromatic secondary or tertiary amines, aminophenols, aromatic nitro or nitroso compounds, organic phosphites or phosphonates, thioethers, thioalcohols, thioesters, sulfides and sulfur-containing organic acids, dithiocarbamates, thiodipropionates, aminopyrazoles, metal-containing chelates, mercaptobenzimidazoles, hydroxybenzophenones, cinnamates, oxalanilides, salicylates, resorcinol monobenzoates, benzotriazoles, triazines, benzophenones, titanium dioxide, carbon black, metal-containing complexes of organic sulfur or phosphorus compounds, sterically hindered amines (HALS), metal hydroxides, borates, organic bromine- or chlorine-containing compounds, organic phosphorus compounds, antimony trioxide, melamine, melamine cyanurate, exfoliated graphite or other intumescent systems, quaternary ammonium salts, alkyl sulfonates, alkyl sulfates, alkyl phosphates, dithiocarbamates, (alkaline earth) metal carboxylates, polyethylene glycols and their esters and ethers, ethoxylates, mono- and diglycerides, fatty alcohols, esters of fatty alcohols, fatty acids, fatty acid esters, dicarboxylic acid esters, fatty acid amides, metal salts of fatty acids, polyolefin waxes, natural or artificial kerosenes and their derivatives, fluoropolymers and fluoroligomers, antiblocking agents, silicas, silicones, silicates, calcium carbonate, amides of mono- and dicarboxylic acids and their derivatives, cyclic amides, hydrazones and bishydrazones, hydrazides, hydrazines, melamine and its derivatives, benzotriazoles, aminotriazoles, sterically hindered phenols in combination with complexing metal compounds, benzylphosphonates, pyridithiols, thiobisphenol esters, polyglycols, ethoxylates, fluoropolymers and fluoroligomers montan waxes, stearates, 10,10′-oxybisphenoxarsine (OBPA), N-(trihalogen-methylthiol)phthalimide, tributyltin oxide, zinc dimethyldithiocarbamate, diphenylantimony-2-ethylhexanoate, copper-8-hydroxyquinoline, isothiazolones, silver and silver salts as biocides or mixtures thereof.
27. The composite film according to claim 1, the first polymer and/or the second polymer is: a polyolefin or a polyolefin copolymer, a polymer and/or copolymer of ethylene, propylene, butylene, hexene or octene and/or a blend and/or a blend thereof, and/or a polyethylene terephthalate and/or a polyethylene terephthalate copolymer.
28. The composite film according to claim 1, wherein a mass fraction of the first component or the second component with a lower melting point in the bicomponent fiber is: at most 50%, at most 25%, at most 10%, or at most 5%.
29. An open-diffusion construction film comprising: at least one functional layer; at least one outer protective layer; and at least one inner protective layer, wherein: the at least one functional layer is positioned between the at least one outer protective layer and the at least one inner protective layer, the film is open to diffusion, the at least one functional layer includes thermoplastic polyurethane, the at least one functional layer is at least a single-layer membrane layer, the at least one outer protective layer and the at least one inner protective layer are formed as a nonwoven layer comprising polyolefin, one or more of the outer protective layer and/or the inner protective layer comprises at least one bicomponent fiber including a first component and a second component, wherein the first component comprises a first polymer, and the second component comprises a second polymer.
Description
(1) Further features, advantages and possible applications of the present invention will be apparent from the following description of examples of embodiments based on the drawing and the drawing itself. In this context, all the features described and/or illustrated constitute, individually or in any combination, the subject-matter of the present invention, irrespective of their summary in the claims and their relation back.
(2) It shows:
(3)
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(7)
(8)
(9)
(10)
(11)
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(14)
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(16)
(17)
(18) The functional layer 2 shown in
(19) In particular, the outer protective layer 3 and/or the inner protective layer 4 can be firmly bonded and/or fully bonded to the functional layer 2.
(20) In another embodiment not shown, it is provided that the first polymer comprises polypropylene, in particular polymerized by a Ziegler-Natta catalyst, and the second polymer comprises polypropylene, in particular produced by metallocene catalysts, or vice versa.
(21) In the embodiment example shown in
(22) Insofar as the composite film 1 is used for weather protection of goods, the topside 12 may face the weather side or the weather, whereas the underside 13 may face the interior of a building, for example. The topside 12 is arranged on the outer side of the outer protective layer 3. The underside 13 is provided on the opposite outer side of the composite film 1. In principle, it is also possible not to expose the composite film 1 to the weather, in which case the underside 13 may face the goods, material or the like to be covered.
(23) The functional layer 2 shown in
(24) The functional layer 2 has plastic and/or synthetic resin as the material. In particular, an elastomeric material and/or a thermoplastic material is provided. In the embodiment example shown in
(25) In addition, the functional layer 2 shown in
(26)
(27) In particular, the membrane layers 8 are firmly bonded to each other, proferably via a full-surface adhesive bond.
(28)
(29) In an embodiment not shown, the outer membrane layers 9 are identical, with the topside 12 and the underside 13 being functionally identical, in particular with the outer protective layer 3 being identical and/or functionally identical to the inner protective layer 4.
(30) In another embodiment not shown, the composite film 1 has a symmetrical structure.
(31) The outer membrane layer 9 is to be understood as the membrane layer 8 directly facing the outer protective layer 3 or the inner protective layer 4.
(32) The functional layer 2 shown in
(33) It is not shown that at least one outer membrane layer 9 and/or the inner membrane layer 8 of the multilayer functional layer 2 comprises and/or is formed from a foamed polymer. The outer membrane layer 9 comprising the foamed polymer can be bonded to the protective layer facing it—that is, either the outer protective layer 3 or the inner protective layer 4—by means of bonding. In particular, the outer-side membrane layer 9 comprising the foamed polymer penetrates the surface region or the outermost surface layer of the outer protective layer 3 and/or the inner protective layer 4. The interlocking may be achieved due to the manufacturing process of the composite film 1, in particular due to the slowed cooling caused due to the foaming of the outer-side membrane layer 9. Furthermore, the outer membrane layer 9 is also firmly bonded to the immediately adjacent membrane layer 8, wherein this bonding can also be caused by interlocking.
(34) Furthermore,
(35)
(36) In the embodiments shown in
(37) In principle, various consolidation methods, such as mechanical, chemical and/or thermal consolidation, can be provided for consolidating the outer protective layer 3 and the inner protective layer 4.
(38)
(39) For bonding the functional layer 2 to the protective layers 3, 4, an adhesion-promoting layer 10 is provided, which comprises an adhesion promoter polymer.
(40)
(41)
(42) In particular, the adhesion-promoting layer 10 is provided as a component of the protective layer or protective layers 3, 4 comprising the bicomponent fibers 5. The adhesion-promoting layer 10 is firmly bonded to the functional layer 2 or the protective layers 3, 4, in particular over the entire surface. The adhesion promoter polymer or the material of the adhesion-promoting layer 10 may be a plastic and/or a synthetic resin, preferably polyurethane.
(43) The composite film 1 shown in
(44) Furthermore, in the embodiment shown in
(45)
(46)
(47) It is not shown that the adhesive zone 14 is strip-shaped. Furthermore, it is not shown that the adhesive zone 14 can also be formed as interrupted strips.
(48) The width of the adhesive zone 14 in the illustrated embodiment is between 2 to 10 cm.
(49)
(50) In
(51) The adhesive zones 14 shown in the illustrated embodiments are formed such that when adjacent composite films 1 are bonded together, wind-tight and/or airtight bonding occurs.
(52) The offset of the adhesive zones 14 shown in
(53) It is not shown that the mating surface for the adhesive zone 14 comprising the adhesive is covered with a liner and/or surface-treated. In particular, it is not shown that the adhesive zone 14 may be covered by a lacquer. The liner may serve to protect the adhesive zone 14, in particular from impurities and/or from contamination.
(54)
(55) Not shown is that the bicomponent fiber 5 may also be formed as a side-by-side fiber. Side-by-side fibers may be characterized in that both the first component 6 and the second component 7 form part of the outer surface of the bicomponent fiber 5. Circular or at least approximately circular cross-sections are also possible for side-by-side fibers, as are multilobal cross-sections. Depending on which fiber properties and/or nonwoven properties are to be achieved, the first component 6 and the second component 7 can be combined in different ratios in different spatial arrangements relative to one another.
(56) Also not shown is that the bicomponent fiber 5 may also be formed as a segmented-pie fiber. This fiber structure has a relationship to side-by-side fiber structures in that both the first component 6 and the second component 7 can form part of the outer surface of the bicomponent fiber 5.
(57) Also, a design of the bicomponent fiber 5 as an Island-In-The-Sea structure as a modification of a core-cladding fiber is not provided in the embodiments shown. In an Island-In-The-Sea structure of the bicomponent fiber 5, a plurality of cores from the second component 7 may be present. The individual cores from the second component 7 are surrounded by a common sheath from the first component 6.
(58) Furthermore, mixed forms between core-sheath fibers and side-by-side fibers are possible in principle.
(59)
(60) An exemplary spunbonded fabric may be made from bicomponent fibers 5 that have been thermally bonded by means of a calendar. In the illustrated embodiment example, the bicomponent fibers 5 are core-sheath fibers having a sheath of the first component 6 with polypropylene as the first polymer with a core of the second component 7 with a polypropylene as the second polymer. The grammage of the spunbonded web shown in
(61) Not shown is that the difference in the melting point of the first component 6 and the second component 7 is less than or equal to 8° C. In particular, the difference in the melting points of the first component 6 and the second component 7 can range from 1° C. to 6° C.
(62) Furthermore, it is not shown that the melt flow indices of the first component 6 and the second component 7 are less than or equal to 25 g/10 min. In addition, the melt flow indices of the first component 6 and the second component 7 can each be less than or equal to 50 g/10 min.
(63) In particular, the component with the low melting point in the cross-section of the bicomponent fiber 5 may form the outer surface of the bicomponent fiber 5, in particular surrounding preferably completely, the component with the higher melting point.
(64) The polymer of one of the two components 6, 7 may have been polymerized with a metallocene catalyst. The polymer of the other component may have been polymerized with a Ziegler-Natta catalyst and subsequently subjected to a visbreaking treatment.
(65) Furthermore, it is not shown that the first component 6 comprises an additive, wherein the mass fraction of the additive in the second component 7 is smaller than in the first component 6, preferably at most 66.6%.
(66) The additive may be a primary or secondary antioxidant, a UV absorber, a UV stabilizer, a flame retardant, an antistatic agent, a lubricant, a metal deactivator, a hydrophilizing agent, a hydrophobizing agent, an anti-fogging additive, and/or a biocide.
(67) Where appropriate, the additive may be selected from the group consisting of: Sterically hindered phenols, aromatic secondary or tertiary amines, aminophenols, aromatic nitro or nitroso compounds, organic phosphites or phosphonates, thioethers, thioalcohols, thioesters, sulfides and sulfur-containing organic acids, dithiocarbamates, thiodipropionates, aminopyrazoles, metal-containing chelates, mercaptobenzimidazoles, hydroxybenzophenones, cinnamates, oxalanilides, salicylates, resorcinol monobenzoates, benzotriazoles, triazines, benzophenones, titanium dioxide, carbon black, metal-containing complexes of organic sulfur or phosphorus compounds, sterically hindered amines (HALS), metal hydroxides, borates, organic bromine- or chlorine-containing compounds, organic phosphorus compounds, antimony trioxide, melamine, melamine cyanurate, expandable graphite or other intumescent systems, quaternary ammonium salts, alkyl sulfonates, alkyl sulfates, alkyl phosphates, dithiocarbamates, (alkaline earth) metal carboxylates, polyethylene glycols and their esters and ethers, ethoxylates, mono- and diglycerides, fatty alcohols, esters of fatty alcohols, fatty acids, fatty acid esters, dicarboxylic acid esters, fatty acid amides, metal salts of fatty acids, polyolefin waxes, natural or artificial kerosenes and derivatives thereof, fluoropolymers and fluoroligomers, antiblocking agents such as silicas, silicones, silicates, calcium carbonate, amides of mono- and dicarboxylic acids and their derivatives, cyclic amides, hydrazones and bishydrazones, hydrazides, hydrazines, melamine and its derivatives, benzotriazoles, aminotriazoles, sterically hindered phenols in combination with complexing metal compounds, benzylphosphonates, pyridithiols, thiobisphenol esters, polyglycols, ethoxylates, fluoropolymers and fluoroligomers montan waxes, in particular stearates, 10,10′-oxybisphenoxarsine (OBPA), N-(trihalogen-methyl-thiol)phthalimide, tributyltin oxide, zinc dimethyldithiocarbamate, diphenylantimony-2-ethylhexanoate, copper-8-hydroxyquinoline, isothiazolones, silver and silver salts as biocides or mixtures thereof.
(68) Furthermore, it is not shown that the first polymer and/or the second polymer is a polyolefin or a polyolefin copolymer, preferably a polymer and/or copolymer of ethylene, propylene, butylene, hexene or octene and/or a mixture and/or a blend thereof, and/or a polyethylene terephthalate and/or a polyethylene terephthalate copolymer.
(69) The mass fraction of the component with the low melting point in the bicomponent fiber 5 can be at most 50%.
LIST OF REFERENCE SIGNS
(70) 1 Composite film 2 Functional layer 3 outer protective layer 4 inner protective layer 5 Bicomponent fiber 6 first component 7 second component 8 Membrane layer 9 external membrane layer 10 Adhesion-promoting layer 11 Reinforcement layer 12 Topside 13 Underside 14 Adhesive zone 15 Longitudinal edge