Moulding compound based on a partially aromatic copolyamide

Abstract

A moulding composition contains at least 40 wt % of components a) and b). Based on the sum of components a) and b), there are 60-99 wt % of component a) and 40-1 wt % of component b). Component a) is a partially aromatic copolyamide containing, as polymerized monomer units, 30-90 mol % of a combination of hexamethylenediamine and terephthalic acid and 70-10 mol % of a combination of hexamethylenediamine and a linear aliphatic dicarboxylic acid having 8-19 C atoms. Component b) is an olefinic copolymer containing, as polymerized monomer units, i) 35-94.9 wt % of ethene-based monomer units, ii) 5-65 wt % of monomer units based on a 1-alkene having 4-8 C atoms, iii) 0-10 wt % of monomer units based on an olefin different from i) and ii), and iv) 0.1-2.5 wt % of monomer units based on an aliphatically unsaturated dicarboxylic acid anhydride, where the sum of wt % of i), ii), iii) and iv) is 100%.

Claims

1. A moulding composition, comprising at least 40 wt. % of the following components: a) 60 to 99 parts by wt. of a partially aromatic copolyamide which comprises as polymerized monomer units: I. 40 to 90 mol % of a combination of hexamethylenediamine and terephthalic acid; and II. 60 to 10 mol % of a combination of hexamethylenediamine and a linear aliphatic dicarboxylic acid with 8 to 19 C atoms; wherein the mol % values relate to a sum of I and II and wherein at most 20% of hexamethylenediamine is optionally replaced by an equivalent quantity of another diamine and/or wherein at most 20% of terephthalic acid is optionally replaced by an equivalent quantity of another aromatic dicarboxylic acid and/or 1,4-cyclohexanedicarboxylic acid and/or Wherein at most 20% of the repeating units of hexamethylenediamine and the linear aliphatic dicarboxylic acid are optionally replaced respectively by an equivalent number of units of a copolymerized lactam or ?-aminocarboxylic acid with 6 to 12 C atoms; and b) 40 to 1 parts by wt. of an olefinic copolymer comprising as polymerized monomer units: i) 35 to 94.9 wt. % of ethene-based monomer units, ii) 5 to 65 wt. % of monomer units based on 1-butene, iii) 0 to 10 wt. % of monomer units based on an olefin different from i) and ii), and iv) 0.1 to 2.5 wt. % of monomer units based on an aliphatically unsaturated dicarboxylic acid anhydride, wherein a sum of the wt. % values of i), iii) and iv) is 100%, wherein a sum of the parts by wt. of a) and b) is 100, and wherein polyamide fraction of the moulding composition contains less than 3 wt. % of aliphatic polyamide.

2. The moulding composition according to claim 1, wherein a crystallite melting point T.sub.m of the copolyamide a) is from 240? C. to 300? C. as determined according to ISO 11357, measured during a 2nd heating stage.

3. The moulding composition according to claim 1, wherein a ratio of amino end groups to a sum of amino and carboxyl end groups of the partially aromatic copolyamide is from 0.3 to 0.7.

4. The moulding composition according to claim 1, wherein the olefinic copolymer b) comprises the monomer unit (iii), which does not comprise an unconjugated diene.

5. The moulding composition according to claim 1, wherein the olefinic copolymer b) comprises the monomer unit (iii), which does not comprise styrene or propene.

6. The moulding composition according to claim 1, wherein the olefinic copolymer b) consists of: i) 35 to 94.9 wt. % of the ethene-based monomer units, ii) 5 to 65 wt. % of the monomer units based on 1-butene, and iv) 0.1 to 2.5 wt. % of the monomer units based on an aliphatically unsaturated dicarboxylic acid anhydride.

7. The moulding composition according to claim 1, further comprising 0.01 to 60 wt. % of an additive selected from the group consisting of a stabilizer, a polymer different from a) and b), a fibrous reinforcing material, a filler, a plasticizer, a pigment, a colorant, a flame retardant and a processing aid.

8. The moulding composition according to claim 7, wherein the moulding composition comprises a stabilizer which is a copper-containing stabilizer.

9. The moulding composition according to claim 8, wherein the copper-containing stabilizer is a copper(I) salt in combination with an alkali metal halide.

10. The moulding composition according to claim 9, wherein the copper(I) salt is selected from the group consisting of copper acetate, copper stearate, copper acetylacetonate, and a copper halide.

11. The moulding composition according to claim 9, wherein the alkali metal halide is selected from the group consisting of lithium iodide, sodium iodide, potassium iodide, lithium bromide, sodium bromide, and potassium bromide.

12. The moulding composition according to claim 8, wherein a copper content of the moulding composition is from 20 to 2000 ppm.

13. The moulding composition according to claim 7, wherein the moulding composition comprises a stabilizer which is an oxidation stabilizer.

14. A moulded article, comprising the moulding composition according to claim 1.

15. The moulded article according to claim 14, which is a monolayer pipe or a multilayer pipe.

16. The moulded article according to claim 14, which is a monolayer container or a multilayer container.

Description

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

(1) As used herein, the words a and an and the like carry the meaning of one or more. The phrases selected from the group consisting of, chosen from, and the like include mixtures of the specified materials. Terms such as contain(s) and the like are open terms meaning including at least unless otherwise specifically noted.

(2) According to the first embodiment of the present invention the moulding compound contains at least 40 wt. %, preferably at least 50 wt. %, particularly preferably at least 60 wt. %, especially preferably at least 70 wt. % and quite particularly preferably at least 80 wt. % of the following components:

(3) a) 60 to 99 parts by wt., preferably 65 to 98 parts by wt., particularly preferably 68 to 97 parts by wt. and especially preferably 70 to 96 parts by wt. of a partially aromatic copolyamide which comprises monomer units which are derived from:

(4) I. 30 to 90 mol %, preferably 40 to 85 mol %, particularly preferably 45 to 80 mol %, especially preferably 50 to 75 mol % and quite particularly preferably more than 50 to 70 mol % of a combination of hexamethylenediamine and terephthalic acid and

(5) II. 70 to 10 mol %, preferably 60 to 15 mol %, particularly preferably 55 to 20 mol %, especially preferably 50 to 25 mol % and quite particularly preferably less than 50 to 30 mol % of a combination of hexamethylenediamine and a linear aliphatic dicarboxylic acid with 8 to 19 C atoms,

(6) wherein the mol % values relate to the sum of I and II and wherein at most 20%, preferably at most 15%, particularly preferably at most 12%, especially preferably at most 8% and quite particularly preferably at most 5% or at most 4% respectively of the hexamethylenediamine can be replaced by the equivalent quantity of another diamine and/or wherein at most 20%, preferably at most 15%, particularly preferably at most 12%, especially preferably at most 8% and quite particularly preferably at most 5% or at most 4% respectively of the terephthalic acid can be replaced by the equivalent quantity of another aromatic dicarboxylic acid and/or 1,4-cyclohexanedicarboxylic acid and/or wherein at most 20%, preferably at most 15%, particularly preferably at most 12%, especially preferably at most 8% and quite particularly preferably at most 5% or at most 4% respectively of the repeating units of hexamethylenediamine and linear aliphatic dicarboxylic acid can be replaced by the equivalent quantity of units which are derived from a lactam or an ?-aminocarboxylic acid with 6 to 12 C atoms,

(7) b) 40 to 1 parts by wt., preferably 35 to 2 parts by wt., particularly preferably 32 to 3 parts by wt. and especially preferably 30 to 4 parts by wt. of an olefinic copolymer which contains the following monomer units:

(8) i) 35 to 94.9 wt. %, preferably 40 to 90 wt. % and particularly preferably 45 to 85 wt. % of ethene-based monomer units,

(9) ii) 5 to 65 wt. %, preferably 10 to 60 wt. % and particularly preferably 15 to 55 wt. % of monomer units based on a 1-alkene with 4 to 8 C atoms,

(10) iii) 0 to 10 wt. % of monomer units based on another olefin and

(11) iv) 0.1 to 2.5 wt. % of monomer units based on an aliphatically unsaturated dicarboxylic acid anhydride,

(12) wherein the individual contents are selected such that the sum of these wt. % values is 100, and wherein the sum of the parts by wt. of a) and b) is 100.

(13) Suitable linear aliphatic dicarboxylic acid with 8 to 19 C atoms include the following compounds: Octanedioic acid (suberic acid; C.sub.8), nonanedioic acid (azelaic acid; C.sub.9), decanedioic acid (sebacic acid; C.sub.10), undecanedioic acid (C.sub.11), dodecanedioic acid (C.sub.12), tridecanedioic acid (C.sub.13), tetradecanedioic acid (C.sub.14), pentadecanedioic acid (C.sub.15), hexadecanedioic acid (C.sub.16), heptadecanedioic acid (C.sub.17), octadecanedioic acid (C.sub.18) and nonadecanedioic acid (C.sub.19).

(14) According to the present invention, part of the hexamethylenediamine may optionally be replaced by another diamine. Examples of suitable diamines include but are not limited to the following compounds: 1,10-decanediamine, 1,12-dodecanediamine, m-xylylenediamine, p-xylylenediamine, bis-(4-aminocyclohexyl)-methane, 2-methyl-1,5-pentanediamine and 1,4-bis-aminomethyl-cyclohexane. Obviously, mixtures of such diamines may also be used. In one preferred embodiment the diamine consists of hexamethylenediamine, i.e., no other diamine is used.

(15) According to the present invention, part of the terephthalic acid may optionally be replaced by another aromatic dicarboxylic acid or by 1,4-cyclohexanedicarboxylic acid. Suitable aromatic dicarboxylic acids include, but are not limited to the following dicarboxylic acids: Isophthalic acid, 4,4-diphenyldicarboxylic acid, 4,4-diphenyl ether dicarboxylic acid, 2,6-naphthalenedicarboxylic acid, 1,4-naphthalenedicarboxylic acid and 1,5-naphthalenedicarboxylic acid. Obviously, mixtures of such dicarboxylic acids may also be used. In a preferred embodiment the aromatic dicarboxylic acid consists of terephthalic acid, i.e., no other aromatic dicarboxylic acid and no 1,4-cyclohexanedicarboxylic acid is used.

(16) Likewise, according to the present invention, part of the repeating units of hexamethylenediamine and linear aliphatic dicarboxylic acid may optionally be replaced by a lactam or an ?-aminocarboxylic acid with 6 to 12 C atoms. The repeating unit of hexamethylenediamine and linear aliphatic dicarboxylic acid is considered to correspond to a unit which is derived from a lactam or an ?-aminocarboxylic acid. Lactams or ?-aminocarboxylic acids with 6 to 12 C atoms include caprolactam, capryl lactam, undecanolactam, ?-aminoundecanoic acid, lauryl lactam and ?-aminododecanoic acid. In one preferred embodiment, the lactams or ?-aminocarboxylic acids have 11 or 12 C atoms.

(17) The composition of the partially aromatic copolyamide may advantageously be selected such that its crystallite melting point T.sub.m according to ISO 11357, measured during the 2nd heating, lies in the range from 240 to 300? C., preferably in the range from 250 to 295? C. and particularly preferably in the range from 260 to 290? C. If several melting peaks occur, T.sub.m is determined from the main melting peak.

(18) The copolyamide may be produced by melt polycondensation methods that are conventionally known in the art. Alternatively however, other known polyamide synthesis methods may be used.

(19) A necessarily equimolar combination of hexamethylenediamine and terephthalic acid is present when it is ensured that these monomers can react in the mol ratio 1:1. However, due to the relative volatility of hexamethylenediamine losses can occur during the polycondensation, and these losses may be compensated by increasing the initial quantity of hexamethylene weighed into the reaction. It may moreover be necessary to deviate slightly from the exact stoichiometry of 1:1 in order to establish a defined end group ratio. The same logic applies in a) II. for the combination of hexamethylenediamine and a linear aliphatic dicarboxylic acid with 8 to 19 C atoms.

(20) In a preferred embodiment, the ratio of the amino end groups to the sum of amino and carboxyl end groups in the partially aromatic polyamide is 0.3 to 0.7 and particularly preferably 0.35 to 0.65. The content of amino end groups may be adjusted by regulation of the polycondensation by methods which are known to those skilled in the art. The regulation can for example be effected by variation of the ratio of diamine used to dicarboxylic acid used by addition of a monocarboxylic acid or by addition of a monoamine. In addition, the content of amino end groups may be adjusted by mixing two copolyamides, one of which is rich in amino end groups and the other low in amino end groups, as granules or in the melt.

(21) The amino group content can be determined by titration of a solution of the copolyamide in m-cresol with perchloric acid. The determination of the carboxyl group content can be effected by titration of a solution of the copolyamide in o-cresol with KOH in ethanol. These methods are conventionally known.

(22) The 1-alkene with 4 to 8 C atoms of the olefinic copolymer includes but is not limited to the following compounds: 1-butene, 1-pentene, 1-hexene, 1-heptene and 1-octene. Obviously, the monomer units based on a 1-alkene with 4 to 8 C atoms can also be mixtures of these compounds.

(23) The nature of the iii) other olefin the monomer units up to 0 to 10 wt. % optionally contained in the olefinic copolymer is not restricted. It may be an unconjugated diene, a mono-ene such as propene, 4-methylpentene-1 or styrene or a mixture thereof.

(24) In an aspect of the first embodiment, the other olefin iii) is not an unconjugated diene.

(25) In another aspect of the first embodiment the other olefin iii) is not styrene and/or not propene.

(26) In one preferred embodiment of the present invention olefinic copolymer b) contains only i) monomer units which are derived from ethene, ii) a 1-alkene with 4 to 8 C atoms and iv) an aliphatically unsaturated dicarboxylic acid anhydride.

(27) In one aspect, the 1-alkene with 4 to 8 C atoms is 1-butene.

(28) In another aspect, the 1-alkene with 4 to 8 C atoms is 1-hexene.

(29) In a further aspect, the 1-alkene with 4 to 8 C atoms is 1-octene.

(30) These embodiments can be combined with one another without restriction.

(31) The aliphatically unsaturated dicarboxylic acid anhydride iv) may be maleic anhydride, however other similar compounds such as for example aconitic anhydride, citraconic anhydride or itaconic anhydride may also be suitable.

(32) The olefinic copolymer according to the present invention may be obtained by conventionally known methods, wherein the aliphatically unsaturated dicarboxylic acid anhydride or a precursor thereof, for example the corresponding acid or a half ester, is reacted with a preformed copolymer thermally or preferably by a radical reaction. The aliphatically unsaturated dicarboxylic acid anhydride may also be reacted in combination with other monomers, for example with dibutyl fumarate or styrene. Olefinic copolymers according to the present invention may include various commercially available types.

(33) The olefinic copolymer is generally rubber-like, although it can also have a relatively high crystalline content. This is particularly to be seen with a higher content of monomer units which are derived from ethene, and with a not completely random distribution of the individual monomer units.

(34) The moulding compound according to the invention, apart from the components a) and b), optionally contains further additives, which make up the balance to 100 wt. %, and preferably at least 0.01 wt. % thereof. These further additives include:

(35) a) stabilizers, b) other polymers, c) fibrous reinforcing materials, d) fillers, e) plasticizers, f) pigments and/or colourants, g) flame retardants and h) processing aids.

(36) In a preferred embodiment, the moulding compound contains an effective quantity of a copper-containing stabilizer. This is in particular a copper compound which is soluble in the polyamide matrix. The copper compound may be preferably combined with an alkali metal.

(37) In certain embodiments, the stabilizer is a copper(I) salt, e.g. copper acetate, copper stearate, an organic copper complex such as for example copper acetylacetonate, a copper halide or the like in combination with an alkali metal halide.

(38) In certain embodiments, the copper-containing stabilizer comprises a copper halide selected from copper iodide and copper bromide and an alkali metal halide selected from the iodides and bromides of lithium, sodium and potassium.

(39) Preferably, the copper-containing stabilizer is metered in such a way that the moulding compound contains 20 to 2000 ppm of copper, particularly preferably 30 to 1500 ppm of copper and especially preferably 40 to 1000 ppm of copper.

(40) In addition, it is preferred that the copper-containing stabilizer is constituted such that the weight ratio of alkali metal halide to copper compound lies in the range from 2.5 to 12 and particularly preferably in the range from 6 to 10. The combination of alkali metal halide and copper compound is generally contained in the moulding compound at about 0.01 wt. % to about 2.5 wt. %.

(41) The copper-containing stabilizer offers protection against long-term thermal aging, for example in applications under the hood of an automobile.

(42) In a further preferred embodiment, the moulding compound may contain an effective quantity of an oxidation stabilizer and particularly preferably an effective quantity of an oxidation stabilizer in combination with the effective quantity of a copper-containing stabilizer. Suitable oxidation stabilizers include aromatic amines, sterically hindered phenols, phosphites, phosphonites, thio synergists, hydroxylamines, benzofuranone derivatives, acryloyl modified phenols etc. Such oxidation stabilizers are commercially available in a large number of types, for example under the trade names Naugard 445, Irganox 1010, Irganox 1098, Irgafos 168, P-EPQ or Lowinox DSTDP. In general, the moulding compound contains about 0.01 to about 2 wt. % and preferably about 0.1 to about 1.5 wt. % of an oxidation stabilizer.

(43) In addition, the moulding compound may also contain a UV stabilizer or a light stabilizer of the HALS type. Suitable UV stabilizers may preferably be organic UV absorbers including benzophenone derivatives, benzotriazole derivatives, oxalanilides or phenyltriazines. Light stabilizers of the HALS type are tetramethylpiperidine derivatives; these are inhibitors which act as radical scavengers. UV stabilizers and light stabilizers may advantageously be used in combination. Both are commercially available in a large number of types; as regards the dosage, the manufacturer's instructions can be followed.

(44) The moulding compound may additionally contain a hydrolysis stabilizer such as for example a monomeric, oligomeric or polymeric carbodiimide or a bisoxazoline.

(45) Other polymers which may be contained as an additive in the moulding compound are for example aliphatic polyamides, polyether amides, polytetrafluoroethylene (PTFE) or polyphenylene ethers.

(46) Suitable aliphatic polyamides include PA46, PA66, PA68, PA610, PA612, PA613, PA410, PA412, PA810, PA1010, PA1012, PA1013, PA1014, PA1018, PA1212, PA6, PA11 and PA12 and copolyamides which are derived from these types. Preferably, the polyamide fraction of the moulding compound, which is composed of the partially aromatic copolyamide, optionally aliphatic polyamide and optionally polyether amide, contains less than 10 wt. %, particularly preferably less than 8 wt. %, especially preferably less than 5 wt. % and quite particularly preferably less than 3 wt. % of aliphatic polyamide or preferably less than 10 wt. %, particularly preferably less than 8 wt. %, especially preferably less than 5 wt. % and quite particularly preferably less than 3 wt. % of the sum of aliphatic polyamide and polyether amide.

(47) Suitable polyphenylene ethers are produced by customary methods by oxidative coupling from phenols disubstituted in the ortho position by alkyl groups. A particularly preferable polyphenylene ether is poly(2,6-dimethyl-1,4-phenylene) ether, optionally in combination with 2,3,6-trimethylphenol units. As conventionally known, the polyphenylene ether may contain functional groups for bonding to the polyamide matrix; these functional groups may for example be introduced by treatment with maleic anhydride.

(48) As the other polymer, preferably at most 4 wt. % and particularly preferably no polyhydroxy polymer selected from ethylene/vinyl alcohol copolymer and polyvinyl alcohol is contained in the moulding compound and particularly preferably at the same time also no aliphatic polyamide.

(49) The moulding composition preferably contains at most 40 wt. %, particularly preferably at most 30 wt. % and especially preferably at most 25 wt. % of other polymers.

(50) As fibrous reinforcing materials, glass fibres may be used. For this, short fibres (e.g. cut glass fibres with a length of 0.2-50 mm) or continuous fibres (rovings) may be used. The cross section of the glass fibres can be cruciform, but it can also be oval, elliptical, elliptical with constrictions (cocoon fibres), polygonal, rectangular or almost rectangular. Long fibre-reinforced moulding compounds can be produced by the known methods for production of long fibre-reinforced rod-shaped granules, in particular by pultrusion methods, in which the continuous fibre strand (roving) is completely impregnated with the polymer melt and then cooled and cut.

(51) Other suitable fibrous reinforcing materials include carbon fibres, graphite fibres, silicon carbide fibres, boron fibres, aramid fibres, fibres of stainless steel or potassium titanate whiskers.

(52) Suitable fillers include talc, mica, silicate, quartz, graphite, molybdenum disulphide, titanium dioxide, wollastonite, kaolin, amorphous silicic acids, magnesium carbonate, chalk, limestone, feldspar, barium sulphate, conductive carbon black, graphite fibrils, solid or hollow glass beads or ground glass.

(53) The content of the fibrous reinforcing materials and the fillers in the moulding compound may be at most 60 wt. %, preferably at most 50 wt. % and preferably at least 0.1 wt. %.

(54) Plasticizers and their use in polyamides are known. A general overview of plasticizers which are suitable for polyamides can be obtained from G?ehter/M?ller, Kunststoffadditive (Plastics Additives), C. Hanser Verlag, 2nd Edition, p. 296.

(55) Common compounds suitable as plasticizers include esters of p-hydroxybenzoic acid with 2 to 20 C atoms in the alcohol component or amides of arylsulphonic acids with 2 to 12 C atoms in the amine component, preferably amides of benzenesulphonic acid.

(56) Plasticizers which are suitable include ethyl p-hydroxybenzoate, octyl p-hydroxybenzoate, i-hexadecyl p-hydroxybenzoate, toluenesulphonic acid n-octylamide, benzenesulphonic acid n-butylamide or benzenesulphonic acid 2-ethylhexylamide.

(57) Suitable pigments and/or colourants include carbon black, iron oxide, zinc sulphide, ultramarine, nigrosin, pearlescent pigments and metal flakes.

(58) Suitable flame retardants include antimony trioxide, hexabromocyclododecane, tetrabromobisphenol, borates, red phosphorus, magnesium hydroxide, aluminium hydroxide, melamine cyanurate and condensation products thereof such as melam, melem and melon; melamine compounds such as melamine pyro- and polyphosphate, ammonium polyphosphate and organophosphorus compounds or salts thereof such as for example resorcinol diphenyl phosphate, phosphonate esters or metal phosphinates.

(59) Suitable processing aids include paraffins, fatty alcohols, fatty acid amides, stearates such as calcium stearate, paraffin waxes, montanates or polysiloxanes.

(60) The moulding composition is produced from the individual components in a manner known to those skilled in the art by mixing in the melt.

(61) The moulding composition according to the invention may be processed into moulded articles by injection moulding, extrusion or blow moulding. Examples of such moulded articles are casings and working parts for pumps, gears, valves and water meters, throttle valves, headlamp casings, reflectors, headlamp self-levelling systems, gearwheels, plug and socket connectors, connectors, profiles, films or layers of multilayer films, electronic components, housings for electronic components, tools, composite materials, plastic-rubber composites, connecting pieces and fittings for connecting hoses or pipes.

(62) In particular single or multilayer hollow objects may be produced from the moulding composition according to the invention, above all pipes or vessels. These include for example charge air ducts for an automobile, mono- or multilayer fluid feed pipes, which can be smooth or corrugated, such as fuel pipes, hydraulic pipes, brake pipes, coupling lines or coolant pipes, brake fluid containers or fuel containers. Further applications are for example liners for rigid or flexible pipes in the oil or gas extraction industry, anti-wear tapes on flexible pipes for offshore extraction or pipes of umbilicals in which hot liquids are conveyed.

(63) In multilayer films, multilayer pipes and multilayer containers, at least one layer consists of the moulding composition according to the invention bonded with at least one other layer which consists of another moulding composition. In case of inadequate layer adhesion, an intermediate adhesion promoter layer may be used.

(64) The moulded articles of the moulding composition according to the invention can be used everywhere where high temperatures regularly prevail, without their impact resistance and their elongation at break deteriorating to a great extent.

EXAMPLES

(65) In the examples, the following materials were used: PA6T/612: see production example 1 AMODEL A-1006: a PA6T/6I/66 from Solvay Specialty Polymers containing about 65 mol % 6T, about 25 mol % 6I and about 10 mol % 66 PA10T/TMDT: see production example 2 Colour batch: mixture of 80 wt. % PA12 and 20 wt. % carbon black TAFMER MH7010: an acid-modified ethylene-butylene rubber from Mitsui Chemicals EXXELOR VA1803: an acid-modified ethylene-propylene rubber from ExxonMobil Chemical Calcium stearate: processing aid Polyad PB201 iodide: copper-containing stabilizer based on copper iodide and alkali metal halide Naugard 445: oxidation stabilizer (aromatic amine)

Production Example 1 (PA6T/612 50:50; According to Invention):

(66) 12.621 kg of hexamethylenediamine, 9.021 kg of terephthalic acid, 13.356 kg of dodecanedioic acid, 15.000 kg distilled water and 3.53 g of a 50 weight percent aqueous solution of hypophosphorous acid were placed in a polycondensation reactor. The starting materials were melted at 180? C. and stirred for 3 hours at 225? C./22 bar. With continuous pressure release to 10 bar, the mixture was heated to 300? C. and pressure release again performed at this temperature. On attainment of 0.5 bar, the reactor was emptied and the product granulated. The granules were subjected to further condensation in a tumble dryer and thus brought up to the desired molecular weight.

(67) Crystallite melting point T.sub.m: 278? C. (main peak)

Production Example 2 (PA10T/TMDT 85:15; not According to Invention):

(68) Production was performed with the equipment shown in FIG. 2 of U.S. Pat. No. 2,361,717, in which however the items 23, 24 and 25 were replaced by a high pressure-resistant autoclave which by means of an inert gas blanket ensured a constant feed pressure through the reactors. Both reactors were operated with an oil feed of 360? C.

(69) 24.70 kg of terephthalic acid, 21.775 kg of decamethylenediamine, 3.53 kg of a mixture of 2,2,4- and 2,4,4-trimethyl-hexamethylenediamine (TMD), 14.0 kg fully deionized water (DI water) and 10.0 g of a 50 weight percent aqueous solution of hypophosphorous acid were placed in the autoclave, inertized three times with nitrogen, and the autoclave sealed and heated at an oil feed temperature of 230? C. As a result, a clear homogeneous salt solution was formed. The autoclave was adjusted with nitrogen to constant 44 bar overall pressure; this pressure fed the material through the plant. The product obtained was further condensed in a tumble dryer and thus brought up to the desired molecular weight.

(70) Crystallite melting point T.sub.m: 285? C.

(71) Production of the Moulding Compounds:

(72) The moulding compounds were produced from the individual components by melt mixing in a kneading unit, discharged as strand, granulated and dried.

(73) Next, test pieces were produced by injection moulding. One set of these test pieces was subjected to a tensile test according to ISO 527 in the freshly moulded state, one set after four hours' thermal aging at 180? C. in air and a further set after 295 hours' thermal aging at 180? C. in air. The composition and the test results are shown in Table 1.

(74) After 4 hours at 180? C. no severe thermal aging is yet to be expected. The alteration in the measured values is here mainly attributable to post-crystallization of the samples.

(75) In comparative examples 2 to 5, from the start neither yield stress nor yield strain could be measured. This is because of the only slight elongation at break.

(76) The elongation at break in the freshly moulded state and after the post-crystallization was greatest in example 1 and in particular in comparative example 1. After thermal aging, the ratios here reversed; in example 1 42% of the original elongation at break was retained, while in comparative example 1 the elongation at break declined to only 13.7% of the original value.

(77) The results showed that there is a combinatorial effect. This depends both on the selection of the correct partially aromatic polyamide and on the selection of the matching olefinic copolymer. This double selection was not previously known and was not expected based on conventional knowledge at the time of the present invention.

(78) TABLE-US-00001 TABLE 1 Example 1 and comparative examples 1 to 5; Compositions and test results Comparative Comparative Comparative Comparative Comparative Unit Example 1 example 1 example 2 example 3 example 4 example 5 PA6T/612 parts by wt. 65.38 65.38 AMODEL A-1006 parts by wt. 65.38 65.38 PA10T/TMDT parts by wt. 65.38 65.38 Colour batch parts by wt. 2.5 2.5 2.5 2.5 2.5 2.5 TAFMER MH7010 parts by wt. 30 30 30 EXXELOR VA1803 parts by wt. 30 30 30 Calcium stearate parts by wt. 0.32 0.32 0.32 0.32 0.32 0.32 Polyad PB201 iodide parts by wt. 1.2 1.2 1.2 1.2 1.2 1.2 Naugard 445 parts by wt. 0.6 0.6 0.6 0.6 0.6 0.6 Elastic modulus MPa 1260 1245 1493 1579 1352 1332 Yield stress MPa 34.4 35.1 Yield strain % 4.67 4.64 Stress at break MPa 33.6 34.4 36.9 33.9 37.9 36.1 Elongation at break % 58.23 87.99 5.16 3.29 5.82 5.27 Elastic modulus (4 hrs/180? C.) MPa 1285 1294 1511 1562 1345 1408 Yield stress (4 hrs/180? C.) MPa 35.7 36.4 Yield strain (4 hrs/180? C.) % 5.65 4.96 Stress at break (4 hrs/180? C.) MPa 36.1 37.1 36.9 34.4 38.6 31.6 Elongation at break (4 hrs/180? C.) % 45.87 87.26 4.07 3.02 4.53 3.04 Elastic modulus (295 hrs/180? C.) MPa 1298 1337 1526 1558 1390 1401 Yield stress (295 hrs/180? C.) MPa 34.9 35.9 Yield strain (295 hrs/180? C.) % 4.52 4.15 Stress at break (295 hrs/180? C.) MPa 34 34.3 33.5 30.6 26.6 22.6 Elongation at break % 24.35 12.09 3.16 2.35 2.29 1.96 (295 hrs/180? C.)

(79) The above description is presented to enable a person skilled in the art to make and use the invention, and is provided in the context of a particular application and its requirements. Various modifications to the preferred embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments and applications without departing from the spirit and scope of the invention. Thus, this invention is not intended to be limited to the embodiments shown, but is to be accorded the widest scope consistent with the principles and features disclosed herein. In this regard, certain embodiments within the invention may not show every benefit of the invention, considered broadly.