SECURITY SUBSTRATES, SECURITY DEVICES AND METHODS OF MANUFACTURE THEREOF
20180196980 ยท 2018-07-12
Assignee
Inventors
Cpc classification
B42D25/425
PERFORMING OPERATIONS; TRANSPORTING
B42D25/45
PERFORMING OPERATIONS; TRANSPORTING
B42D25/351
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
A security substrate has: a polymer substrate having first and second surfaces; array of focussing elements; an optical adjustment layer and masking layer. The array is formed of a surface relief. The optical adjustment layer is on the transparent base layer across a second region including the first. The optical adjustment layer has a first surface contacting the surface relief and an opposing second surface having a profile not operative to focus visible light. The optical adjustment layer has a first transparent material extending across a first sub-region of the array, the first transparent material having a refractive index different from that of the transparent base layer. The security substrate has a masking layer over the optical adjustment layer across a third region of the polymer substrate, the third region defining a gap in the masking layer(s), such that functional focusing elements of the array are revealed through the gap.
Claims
1-72. (canceled)
73. A security substrate, comprising: a polymer substrate having first and second surfaces; an array of focussing elements in the form of a surface relief across a first region of the polymer substrate, the surface relief being defined in the surface of a transparent base layer, wherein the transparent base layer comprises either the polymer substrate or a layer disposed thereon; an optical adjustment layer disposed on the transparent base layer across a second region of the polymer substrate, which second region includes at least the first region, the optical adjustment layer having a first surface in contact with the surface relief of the transparent base layer and an opposing second surface having a profile which is not operative to focus visible light, the optical adjustment layer comprising a first transparent material extending across a first sub-region of the array of focussing elements, the first sub-region comprising all or only part of the first region, the first transparent material having a refractive index different from that of the transparent base layer, whereby the focussing element(s) in the first sub-region of the array are functional focussing element(s); and at least one first masking layer, comprising a reflective and/or non-transparent material, disposed over the optical adjustment layer across a third region of the polymer substrate, the third region defining at least one gap in the first masking layer(s) which gap includes at least part of the first sub-region, such that functional focusing elements of the array are revealed through the at least one gap.
74. A security substrate according to claim 73, wherein the at least one gap in the first masking layer(s) reveals only a subset of the functional focusing elements of the array, other functional focusing elements of the array being substantially concealed by the first masking layer(s), at least when the security substrate is viewed in reflected light from the side of the security substrate on which the first masking layer(s) are disposed.
75. A security substrate according to claim 73, wherein the optical adjustment layer further comprises a second transparent material extending across a second sub-region of the array of focussing elements, the second transparent material having a refractive index different from that of the transparent base material and from the first transparent material such that the focussing element(s) in the second sub-region of the array are functional focussing element(s) with a focal length different from that of the focussing elements in the first sub-region of the array.
76. A security substrate according to claim 73, wherein the optical adjustment layer further comprises a third transparent material extending across a third sub-region of the array of focussing elements, the third transparent material having a refractive index substantially the same as that of the transparent base material, such that the focussing element(s) in the third sub-region are non-functional focussing element(s).
77. A security substrate according to claim 73, wherein the second region covered by the optical adjustment layer extends across substantially the whole area of the polymer substrate.
78. A security substrate according to claim 73, wherein the profile of the second surface of the optical adjustment layer is substantially planar.
79. A security substrate according to claim 73, wherein the array of focussing elements comprises a convex surface relief structure defined in the surface of the transparent base material, the transparent base material having a higher refractive index than that of the first transparent material and, if provided, the second transparent material; or wherein the array of focussing elements comprises a concave surface relief structure defined in the surface of the transparent base material, the transparent base material having a lower refractive index than that of the first transparent material and, if provided, the second transparent material.
80. A security substrate according to claim 73, further comprising an image array in at least part of the first sub-region of the polymer substrate, the image array located in a plane spaced from that of the focussing elements by a distance substantially corresponding to a focal length of the functional focusing elements in the at least part of the first sub-region, such that the functional focusing elements in the first sub-region exhibit a substantially focussed image of the image array.
81. A security substrate according to claim 80, wherein the image array is located on the second surface of the polymer substrate; or wherein the transparent base layer comprises a layer disposed on the first surface of the polymer substrate and the image array is located on the first surface of the polymer substrate.
82. A security substrate according to claim 73, wherein the security substrate is a security document, being any of a banknote, an identity document, a passport, a license, a certificate, a cheque, a visa or a stamp, and the at least one first masking layer is at least one opacifying layer comprising a non-transparent material.
83. A security substrate according to claim 73, wherein the security substrate is a security article, being a security thread, strip, patch or foil.
84. A method of manufacturing a security substrate, comprising: providing a polymer substrate having first and second surfaces; forming an array of focussing elements across a first region of the polymer substrate as a surface relief in the surface of a transparent base layer, wherein the transparent base layer comprises either the polymer substrate or a layer disposed thereon; applying an optical adjustment layer onto the transparent base layer across a second region of the polymer substrate, which second region includes at least the first region, the optical adjustment layer having a first surface in contact with the surface relief of the transparent base layer and an opposing second surface having a profile which is not operative to focus visible light, the optical adjustment layer comprising a first transparent material extending across a first sub-region of the array of focussing elements, the first sub-region comprising all or only part of the first region, the first transparent material having a refractive index different from that of the transparent base layer, whereby the focussing element(s) in the first sub-region of the array are functional focussing element(s); and applying at least one first masking layer, comprising a reflective and/or non-transparent material, over the optical adjustment layer across a third region of the polymer substrate, the third region defining at least one gap in the first masking layer(s) which gap includes at least part of the first sub-region, such that functional focusing elements of the array are revealed through the at least one gap.
85. A method according to claim 84, wherein the optical adjustment layer is formed by applying at least the first transparent material across the first sub-region region by printing or coating.
86. A security device, comprising: a polymer substrate having first and second surfaces; an array of focussing elements in the form of a surface relief across a first region of the polymer substrate, the surface relief being defined in the surface of a transparent base layer, wherein the transparent base layer comprises either the polymer substrate or a layer disposed thereon, the array of focussing elements being configured to have a uniform base focal length across the first region when the surface relief is in contact with air; an optical adjustment layer disposed on the transparent base layer across a second region of the polymer substrate, which second region includes at least a first sub-region of the array of focussing elements, the first sub-region not including the whole of the first region, the optical adjustment layer having a first surface in contact with the surface relief and an opposing second surface having a profile which is not operative to focus visible light, the optical adjustment layer comprising a first transparent material extending only across the first sub-region of the array of focussing elements, the first transparent material having a refractive index different from that of the transparent base layer, whereby the focussing element(s) in the first sub-region of the array have a first focal length which is different from the base focal length; and a first image array in at least part of the first sub-region of the substrate, the first image array being located in a plane spaced from that of the focussing elements by a distance substantially corresponding to the first focal length, such that the focusing elements in the first sub-region exhibit a substantially focussed image of the first image array and the focusing elements outside the first sub-region do not.
87. A security device according to claim 86, wherein the first image array is located on the second surface of the polymer substrate.
88. A security device according to claim 86, wherein the optical adjustment layer further comprises a second transparent material extending across a second sub-region of the array of focusing elements, the second transparent material having a refractive index different from that of the transparent base layer and different from that of the first transparent material, whereby the focussing element(s) in the second sub-region of the array have a second focal length which is different from the first and base focal lengths.
89. A security device according to claim 88, further comprising a second image array in at least part of the second sub-region of the substrate, the second image array being located in a plane spaced from that of the focussing elements by a distance substantially corresponding to the second focal length, such that the focusing elements in the second sub-region exhibit a substantially focussed image of the second image array and the focusing elements outside the second sub-region do not.
90. A security device according to claim 86, wherein the optical adjustment layer further comprises a third transparent material extending across a third sub-region of the array of focusing elements, the third transparent material having a refractive index substantially equal to that of the transparent base layer, whereby the focussing element(s) in the third sub-region of the array are non-operative.
91. A security device according to claim 90, wherein the third transparent material extends over the first transparent material and/or, if provided, the second transparent material, contacting the surface relief only in the third sub-region.
92. A security device according to claim 86, wherein the optical adjustment layer is absent across a fourth sub-region of the array of focusing elements, whereby in the fourth sub-region the focussing elements are exposed to air and have the base focal length.
93. A security device according to claim 92, further comprising a further image array in at least part of the fourth sub-region of the substrate, the further image array being located in a plane spaced from that of the focussing elements by a distance substantially corresponding to the base focal length, such that the focusing elements in the fourth sub-region exhibit a substantially focussed image of the further image array and the focusing elements outside the fourth sub-region do not.
94. A security device according to claim 86, wherein the second region covered by the optical adjustment layer extends across substantially the whole area of the polymer substrate.
95. A security device according to claim 86, wherein the array of focussing elements comprises a convex surface relief structure defined in the surface of the transparent base material, the transparent base material having a higher refractive index than that of the first transparent material and, if provided, the second transparent material; or wherein the array of focussing elements comprises a concave surface relief structure defined in the surface of the transparent base material, the transparent base material having a lower refractive index than that of the first transparent material and, if provided, the second transparent material.
96. A security device according to claim 86, wherein the profile of the second surface of the optical adjustment layer is substantially planar.
97. A security article comprising a security device according to claim 86, wherein the security article is a security thread, strip, foil, insert or patch.
98. A security document comprising a security device according to claim 86 or a security article being a security thread, strip, foil, insert or patch, wherein the security document is a banknote, an identity document, a passport, a license, a certificate, a cheque, a visa or a stamp.
99. A security document according to claim 98 wherein the polymer substrate constitutes the document substrate and the security document further comprises at least one first opacifying layer, comprising a non-transparent material, over the optical adjustment layer across a third region of the polymer substrate, the third region defining at least one gap in the first opacifying layer(s) which gap includes at least part of the first sub-region, such that a focussed image of the first image layer is exhibited through the gap.
100. A method of manufacturing a security device, comprising: providing a polymer substrate having first and second surfaces; forming an array of focussing elements as a surface relief across a first region of the polymer substrate, the surface relief being defined in the surface of a transparent base layer, wherein the transparent base layer comprises either the polymer substrate or a layer disposed thereon, the array of focussing elements being configured to have a uniform base focal length across the first region when the surface relief is in contact with air; applying an optical adjustment layer onto the transparent base layer across a second region of the polymer substrate, which second region includes at least a first sub-region of the array of focussing elements, the first sub-region not including the whole of the first region, the optical adjustment layer having a first surface in contact with the surface relief and an opposing second surface having a profile which is not operative to focus visible light, the optical adjustment layer comprising a first transparent material extending only across the first sub-region of the array of focussing elements, the first transparent material having a refractive index different from that of the transparent base layer, whereby the focussing element(s) in the first sub-region of the array have a first focal length which is different from the base focal length; and forming a first image array in at least part of the first sub-region of the substrate, the first image array being located in a plane spaced from that of the focussing elements by a distance substantially corresponding to the first focal length, such that the focusing elements in the first sub-region exhibit a substantially focussed image of the first image array and the focusing elements outside the first sub-region do not.
101. A method according to claim 100, wherein the optical adjustment layer is formed by applying at least the first transparent material across the first sub-region region by printing or coating.
Description
[0092] Examples of security devices, security substrates and methods of manufacture thereof will now be described with reference to the accompanying drawings, in which:
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[0107] The description below will focus in the main part on deployment of the disclosed security devices in security documents based on polymer document substrates, such as polymer banknotes, since the devices are particularly well suited to this application. Security documents are examples of security substrates and as discussed below it will be appreciated that the disclosed structures could instead be provided on polymer substrates forming security articles such as threads, strips or patches which can then be applied to any form of security document, including polymer-based documents but also conventional documents such as paper-based documents.
[0108] Consequentially, in the examples described below, the masking layer referred to above in connection with the first aspect of the invention is implemented as an opacifying layer. However, in other cases this may be replaced by a masking layer of another composition, such as a metal layer, a semi-transparent metal layer, metallic ink layer, iridescent ink layer or any of the other materials mentioned previously. In general, the masking layer preferably takes the form of a non-fibrous material, and may comprise multiple layers of such materials (which may or may not be the same in each layer). The masking layer(s) are preferably printed or coated layer(s) and are typically not self-supporting (that is, they are supported by the underlying substrate).
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[0110] The focussing elements could be lenses or mirrors, e.g. cylindrical, spherical, aspherical, elliptical or Fresnel structures. In the examples described below the focussing elements are lenses and hence the focussing element array may be referred to as a lens array for convenience. However it will be appreciated that the lenses could be substituted by other types of focussing elements.
[0111]
[0112] As shown in
[0113] The lens array 11 is covered by an optical adjustment layer which here comprises a first transparent material 15a disposed across the whole of the lens array 11 and beyond. In some implementations it is preferred that the optical adjustment layer covers at least the whole lens array in order to present an outer surface 15 which is smooth relative to the lens array, ideally planar, such that first opacifying layer(s) 2a can be applied thereto more readily. Most preferably the optical adjustment layer covers a region extending beyond the lens array 11, as shown, and advantageously across substantially the whole polymer substrate 3 in order to level the outer surface for application of opacifying layer(s) 2a.
[0114] The first transparent material 15a has a refractive index n which is different from that of the transparent base material 12, preferably by at least 0.1, more preferably at least 0.15, most preferably at least 0.2. In this case, since the lenses 11 are concave lenses, in order to achieve focussing in the correct direction, the first transparent material 15a will have a refractive index higher than that of the transparent base material 12. Preferably, the transparent base material 12 is a low refractive index (LRI) material having a refractive index of 1.45 or less. Examples of suitable materials will be given below. The first transparent material 15a is preferably a high refractive index (HRI) material having a refractive index of 1.55 or more. The difference in refractive index n between the transparent base material 12 and the first transparent material 15a preserves the focussing nature of the interface between the two materials at which the surface relief defining the lenses 11 is located. Hence in this case, all of the lenses 11 remain functional after application of the first transparent layer 15a.
[0115] The first surface 15 of the optical adjustment layer contacts the surface relief where it is present, and contacts the polymer substrate 3 elsewhere. The second surface 15 of the optical adjustment layer is preferably substantially planar (i.e. flat) but if any profile is present it will be non-focussing. Thus, the second surface 15 of the optical adjustment layer does not contribute to the optical effect as a result of its shaping. In preferred embodiments, the second surface of the optical adjustment layer may be smoothed, e.g. by polishing or calendaring, after application of the layer by printing, coating or another suitable method.
[0116] The focal length f.sub.1 of the lenses 11 where the first transparent material 15a makes contact with the surface relief (all over, in this case) will be different from their focal length in air (the base focal length, f.sub.B). The focal length depends on the difference in refractive index between the first transparent material 15a and the transparent base material 12, according to the expression:
where r is the radius of the focussing elements, n.sub.B is the refractive index of the transparent base material 12, n.sub.1 is the refractive index of the first transparent material 15a, and n.sub.1 is the refractive index difference between them. In air, the refractive index difference will generally be around 0.5, whereas the refractive index difference between the transparent base material 12 and a first transparent material 15a will typically be less, e.g. around 0.15, so the focal length f.sub.1 will usually be longer than the base focal length f.sub.B.
[0117] In this example, therefore, the whole of the lens array 11 is functional and can display a focussed image if an image is placed at the appropriate focal length. However, the lateral extent over which the focussed image is visible is in this case determined by the arrangement of the opacifying layer(s) 2a applied over the optical adjustment layer. In the present case, the gap 5 in the opacifying layer(s) 2a is shaped and sized so as to reveal only some and not all of the functional lenses 11. That is, some of the functional lenses are concealed under the opacifying layer 2a (at least in reflected light). As such, the lateral perimeter of the optical effect displayed by the lenses is determined solely by the extent of the opacifying layer 2a. This can be adapted such that the gap 5 has the form of any indicia, here a circle, which allows the complexity of the visual effect to be increased and also permits incorporation of the device into the rest of the banknote design more readily. Since the opacifying layers 2(a) can be applied onto a substantially flat surface 15 this enables the use of many application techniques, such as gravure printing, without encountering difficulties which would otherwise be caused by the uneven surface presented by lens array 11.
[0118] The second surface 3 of the polymer substrate is preferably provided with further opacifying layers 2b, which may correspond in extent to opacifying layers 2a (in which case the window 5 is a full window), or may continue across all or part of the gap(s) defined in opacifying layer 2a, resulting in a half window as discussed below.
[0119] The lenses 11 by themselves provide a security effect that cannot be replicated e.g. by photocopying the device. For instance, the lenses 11 could be used to view any scene therethrough or held against a suitable surface to view an item thereon. However, in most preferred embodiments, the security device 10 further includes an image array 19a located in a plane spaced from the lenses 11 by a distance substantially corresponding to the focal length f.sub.1 of the lenses (e.g. to within +/5%) so that the lenses 11 display a focused image of the image array 19a to an observer viewing the image array 19a through the lenses 11. The image array may preferably be configured to co-operate with the lenses 11 to form an optically variable effect, e.g. such that the resulting device is a moir magnifier, an integral imaging device or a lenticular device (or some combination thereof as discussed below). Examples of such devices will be described with reference to
[0120] In this example, the focal length f.sub.1 is substantially equal to the distance between the lenses 11 and the second surface 3 of the polymer substrate, as is preferred. This can be achieved through appropriate choice of the lens dimensions, the refractive indices of the transparent base material 12 and the first transparent material 15a, and of the thicknesses of the transparent base material 12 (if provided as an additional layer) and the polymer substrate 3. If necessary an additional optical spacing layer can be provided on the second surface 3 of the polymer substrate to carry the image array as discussed below. The image array 19a can be formed by various methods, including printing techniques such as gravure, lithographic or flexographic printing. However, in order to achieve good results, the elements forming the image array 19a typically need to be formed at high resolution, e.g. with dimensions of 20 microns or less, preferably 10 microns or less, most preferably 5 microns or less. Some specialist methods adapted to achieve such high resolutions are disclosed in WO-A-2014/070079, US-A-2009/0297805, WO-A-2011/102800 WO-A-2005/052650, WO-A-2015/044671, or our British patent application no. 1510073.8, and are preferred for use here. The image array can alternatively be formed as an array of recesses as will be discussed with reference to
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[0122] In contrast to the previous example, in the
[0123] The first transparent material 15a again has a refractive index different from that of the transparent base material 12 such that where it is applied (the first sub-region), the lenses remain operative and have a focal length f.sub.1. Outside the first sub-region, in the sub-regions labelled 15b, the optical adjustment layer is absent and the surface relief remains exposed to air. Hence, in the sub-regions 15b, the lenses have the base focal length f.sub.B which as discussed above is typically shorter than the first focal length f.sub.1 (in
[0124] Outside the first sub-region 15a, in the sub-regions 15b the device 10 may exhibit no focussed image. For example, in the
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[0126] The image array 19b could be formed on the first surface 3 of the polymer substrate 3 prior to application of the transparent base layer 12 and formation of the lenses 11, e.g. by cast-curing as discussed above. Alternatively the lenses 11 could be formed on a base transparent material in the form of a carrier layer on a separate component such as a patch or stripe, and then laminated onto the first surface of the polymer substrate 3. In this case it may be convenient to form the image array 19b onto the underneath surface of the separate component carrying the lenses before it is applied to the polymer substrate 3.
[0127] In this example, the second image array 19b is depicted as extending across the first sub-region 15a in addition to the sub-regions 15b, although it could be provided in the sub-regions 15b only. Provided the second image array 19b is of sufficiently low optical density, this will not significantly obstruct the view of image array 19a in the first sub-region 15a since the lenses here do not focus on the second image array 19b. Image arrays of the sort used to generate moir magnification effects or integral imaging effects are preferred for use as the second image array in this case, since they typically have a low fill factor (and hence low optical density) compared to lenticular device image arrays. Thus, in a preferred example, the second image array 19b may define a moir magnification or integral imaging effect whilst the first image array 19a may define a lenticular effect (since it is the image array furthest from the lenses 11, there is no further image array for it to obstruct).
[0128] The constructions shown in
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[0130] Outside the first sub-region 15a, the optical adjustment layer comprises a transparent material 15c with a refractive index substantially equal to that of the transparent base layer 12, e.g. with a difference of 0.1 or less. For instance, the transparent material 15c could be of the same composition as the transparent base layer 12 although this is not essential. Thus the lenses 11 in the sub-regions 15c are indexed-out, with the interface between the transparent base material and the transparent material 15c no longer operating as a focussing surface, or one with a very long focal length (tending to infinity as the difference in refractive index tends to zero). As a result, no focussed image is exhibited in the sub-region 15c.
[0131] In a variant of the
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[0133] In this example, another sub-region 15c of the lens array 11 is coated with index-matching transparent material 15c so the lenses here are non-functional as described in relation to
[0134] Any number of further transparent materials with different refractive indices (which are also different from that of the transparent base layer) could be arranged in respective sub-regions to provide additional different focal lengths if desired. A corresponding number of image arrays in the appropriate focal planes may also be formed.
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[0136] The same considerations as to the nature of image arrays 19a, 19b apply as discussed above in relation to
[0137] In all of the above embodiments, the different optical effects generated by the lenses in each distinct sub-region of the device are arranged in laterally offset areas which are distinguishable from one another by the naked eye, by virtue of their size. This enables the various different optical effects to define indicia through the shape, size and location of their peripheries. However, the principles described above can also be utilised to achieve the superposition of different optical effects, as illustrated in
[0138] In the elemental areas where the first transparent material 15a is present, the lenses have the first focal length f.sub.1 and generate a focussed image of image array 19a. In the elemental areas 15b where the lenses are exposed to the air, the lenses have the base focal length f.sub.B and generate a focussed image of image array 19b. Since the different elemental areas, and hence the focussed images exhibited by each, cannot be distinguished by the naked eye, the two optical effects appear superimposed on one another across the star-shaped region 15a,b. Outside that region, the lenses are indexed-out by material 15c and no focussed image is visible.
[0139] The same considerations as to the nature of image arrays 19a, 19b apply as discussed above in relation to
[0140] In a variant, the regions 15b could be filled-in with a second transparent material 15d with a refractive index different from that of the transparent base layer 12 and from the first transparent material 15a, as described with respect to
[0141] In some cases it may be desirable to register the application of the elemental areas 15a, 15b (or 15d) to the image arrays 19a, 19b. For example, if it is desired to superimpose two effects requiring image arrays of high optical density it may be necessary to confine each image array to the elemental areas in which it will be focussed. Since the transparent material(s) defining the optical adjustment layer and the image arrays can both be applied by printing, high register between them is achievable, e.g. by applying both simultaneously or at least as part of the same in-line process.
[0142] In all of the above embodiments, the focussing elements 11 have been formed in a layer 12 applied to the first surface of the polymer substrate 3, e.g. by cast-curing or lamination. However the focussing elements 11 can alternatively be formed in the first surface of the polymer substrate 3 itself, in which case this constitutes the transparent base material 12. An example is shown in
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[0144] In the embodiments so far, the focusing elements have been implemented as concave lenses which have a number of advantages in the disclosed overcoated system. However, the lenses could alternatively be convex lenses, i.e. formed as protrusions extending away from the body of the transparent base layer 12. This applies to all of the above examples and a further embodiment is shown in
[0145] The appearance and complexity of any of the embodiments can be yet further enhanced by arranging the or each material 15a, 15c, 15d (or some of them) forming part of the optical adjustment layer to have a optically detectable characteristic such as a visibly coloured tint, or a property such as fluorescence, phosphorescence, luminescence or the like which may be exhibited in response to certain stimuli (e.g. non-visible wavelength illumination such as UV) and emit a response which may be visible or non-visible. Thus the characteristic may be detectable by machine only, e.g. IR absorption. The various materials 15a, 15c, 15d may carry different optically detectable characteristics, e.g. colour, to further emphasise the different sub-regions already described above. Alternatively or in addition, any one of the materials 15a, 15c, 15d could be made up of more than one material with the same refractive index but different optically detectable characteristics e.g. colour. In this way, the different colours or other characteristics of the materials can be used to introduce yet further indicia or patterns to the device which are not constrained to the arrangement of the different optical effects already described.
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[0147] The transparent base layer 12 could also carry a detectable optical characteristic e.g. coloured tint or fluorescence, phosphorescence or luminescence if desired.
[0148] Examples of suitable materials for forming the transparent base layer 12 or the first or second transparent materials 15a, 15d will now be provided. In each case the transparent material 15a, 15d could be formed of just one of the material components indicated below, but more usually will comprise a mixture (co-polymer or blend) of two or more of the components listed, in order to achieve not only the required optical properties but also desirable mechanical properties. The high refractive index materials listed below have a refractive index of about 1.55 or more, and the low refractive index materials about 1.45 or less. Where available, the approximately refractive index (RI) of each component is indicated below. One or both of the materials 15a, 15d could optionally also comprise a curable component and examples of these are provided below. It will be appreciated that whether the high RI or low RI material is deployed as the transparent base layer 12 or the first or second transparent materials 15a, 15d will depend on whether the lenses are convex or concave.
[0149] Examples of High Refractive Index Components
[0150] Metal containing acrylates: [0151] zirconium acrylate (Sigma Aldrich Cat. No. 686239) [0152] hafnium acrylate (Sigma Aldrich Cat. No. R686212) [0153] zirconium carboxyethyl acrylate (Sigma Aldrich Cat. No. 686247) [0154] hafnium carboxyethyl acrylate (Sigma Aldrich Cat. No. 686220)
[0155] Fluorene acrylates based monomers [0156] (Miramer is a trade name of Miwon Chemicals, Korea) [0157] Miramer HR6040 [0158] Miramer HR6042 [0159] Miramer HR6060 [0160] Miramer HR6100
[0161] High RI Nano particulate dispersions [0162] Unidic EPC-1027 (DIC Corporation, Japan) [0163] SHR 1075 (Miwon Chemicals, Korea)
[0164] Sulfur containing acrylate [0165] Phenylthioethyl acrylate, (Dichem Korea)RI 1.560 [0166] 1-naphthylthio ethyl acrylate (Dichem Korea)RI 1.61
[0167] Standard acrylates [0168] Miramer M240 (Bisphenol A ethoxylated acrylate)RI 1.537 [0169] Miramer M2100 (Phenoxy Benzyl Acrylate)RI 1.565 [0170] Miramer M1142 (1-Ethoxylated-o-phenylphenol acrylate)RI 1.577 [0171] Miramer HR2582 (Urethane Acrylate)RI 1.595 [0172] Miramer HR2200 (Epoxy acrylate)RI 1.559 [0173] Miramer HR3000 (Urethane acrylate)RI 1.571 [0174] Miramer HR3200 (Urethane acrylate)RI 1.565 [0175] Miramer HR3700 (Urethane acrylate)RI 1.585 [0176] Miramer HR3800 (Urethane acrylate)RI 1.573 [0177] HR4000 (Urethane acrylate, RI 1.582)
[0178] Examples of Low Refractive Index Components: [0179] Fluoro-acrylate monomers from the following [0180] PDFApentadecafluorooctyl acrylateRI 1.3390 [0181] TFA=2,2,2-trifluoroethyl acrylate [0182] HFBAheptafluorobutyl acrylateRI 1.3670 [0183] HDFA=1H,1H,2H,2H-heptadecafluorodecyl acrylate, [0184] HFIPA=hexafluoroisopropy acrylate, [0185] TDFA=1H, 1H,2H,2H-tridecafluorooctyl acrylate [0186] Tetrafluoro-3-(heptafluoropropoxy)propyl acrylateRI 1.3460 [0187] Tetrafluoro-3-(pentafluoroethoxy)propyl acrylateRI 1.3480 [0188] TetrafluoroethyleneRI 1.3500 [0189] Undecafluorohexyl acrylateRI 1.3560 [0190] Nonafluoropentyl acrylateRI 1.3600 [0191] Tetrafluoro-3-(trifluoromethoxy)propyl acrylateRI 1.3600 [0192] Pentafluorovinyl propionateRI 1.3640 [0193] Trifluorovinyl acetateRI 1.3750 [0194] Octafluoropentyl acrylateRI 1.3800 [0195] Methyl 3,3,3-trifluoropropyl siloxaneRI 1.3830 [0196] Pentafluoropropyl acrylateRI 1.3850 [0197] 1H, 1H-Heptafluorobutyl(meth)acrylate, [0198] 1H, 1H,5H-octafluoropentyl(meth)acrylate, [0199] 2,2,3,4,4,4-Hexafluorobutyl(meth)acrylate, [0200] perfluorooctylethyl(meth)acrylate, [0201] trifluoroethyl(meth)acrylate, [0202] trifluoroethyl(meth)acrylate, and [0203] perfluorooctylethyl(meth)acrylate
[0204] Preferred commercially available examples include: [0205] Defensa OP-188 (from DIC Japan) [0206] Defensa OP-3801 [0207] Defensa OP-4002 [0208] Defensa OP-4003, [0209] Defensa OP-4004, [0210] Sartomer CN 4002 (from Sartomer) [0211] Viscoat 8F (from Kowa Europe GmbH) [0212] Viscoat 3F [0213] Fluorolink MD 700 (from Solvay Solexis Inc.), [0214] Fluorolink MD 500, and [0215] Fomblin MD 40
[0216] The high refractive index formulation and the low refractive index formulation may each optionally further include one or more components with higher functionality (meaning in this case a higher number of acrylic groups in the material), to increase the degree of cross-linking, which leads to reduced tackiness and improved mechanical properties. Examples of suitable higher functional acrylate components include: [0217] trimethylolpropane triacrylate, [0218] pentaerythritol triacrylate, [0219] ethoxylated (3) trimethylolpropane triacrylate, [0220] ethoxylated (3) trimethylolpropane triacrylate, [0221] propoxylated (3) trimethylolpropane triacrylate, [0222] ethoxylated (6) trimethylolpropane triacrylate, [0223] tris(2-hydroxy ethyl) isocyanurate triacrylate, [0224] dipropylene glycol diacrylate, [0225] propoxylated (3) glyceryl triacrylate, [0226] propoxylated (3) glyceryl triacrylate, [0227] pentaerythritol tetraacrylate.
[0228] A curing agent may also be included in one or both of the formulations. A range of suitable photo- and thermo-initiators are commercially available. Photo-polymerisation is preferred for the current application due to faster cure, although thermo initiation can also be used. Some examples of suitable free radical type photo-initiators are given below: [0229] 1-phenyl-2-hydroxy-2-methyl-1-propanone, [0230] 2 hydroxy 2-methyl 1-phenyl propan-1-one, [0231] 2,2-dimethoxy-1,2-di(phenyl)ethanone [0232] 1-hydroxycyclohexyl phenyl ketone, [0233] benzophenones, [0234] bis-acyl phosphine oxide (BAPO), [0235] aminoketones, [0236] thioxanthones, [0237] (2,4,6-trimethylbenzoylphenyl phosphinate), [0238] 2-Benzyl-2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-1-butanone
[0239] A preferred example formulation of a high refractive index transparent material is: [0240] 40 wt % DIC Unidic EPC 1027, [0241] 30 wt % Miramer HR 6042, [0242] 25 wt % Miramer HR3700. [0243] 5 wt % Photo-initiators and common surface active additives
[0244] A preferred example formulation of a low refractive index transparent material is: [0245] 50 wt % Defensa OP-188 [0246] 30 wt % Viscoat 8F [0247] 15 wt % Ethoxylated (3) trimethylolpropane triacrylate, [0248] 5 wt % Photo-initiators and additives
[0249] Examples of optically variable effects which can be deployed in the above security devices will now be described.
[0250] An example of a lenticular device is shown in
[0251] The strips are arranged as slices of an image, i.e. the strips A are all slices from one image, similarly for strips B and C etc. As a result, as the device is tilted a series of different images will be seen. The images could be related or unrelated. The simplest device would have two images that would flip between each other as the device is tilted. An example of the images which might be seen from two different viewing positions is shown in
[0252]
[0253] An integral imaging device would have a similar construction to that shown in
[0254] As mentioned above, focal length of the lenses is directly related to their size (radius) and for an image array 19a on the second surface of the polymer substrate to be in focus, the optical geometry must be taken into account when selecting the thickness of the transparent layer 12. In preferred examples the thickness is in the range 5 to 200 microns. Thick devices at the upper end of this range are suitable for incorporation into documents such as identification cards and drivers licences, as well as into labels and similar. For documents such as banknotes, thinner devices are desired as mentioned above. At the lower end of the range, the limit is set by diffraction effects that arise as the focusing element diameter reduces: e.g. lenses of less than 10 micron base diameter and more especially less than 5 microns will tend to suffer from such effects. Therefore the limiting thickness of such structures is believed to lie between about 5 and 10 microns.
[0255] The periodicity and therefore maximum base diameter of the focusing elements is preferably in the range 5 to 200 m, more preferably 10 to 60 m and even more preferably 20 to 40 m. The f number for the lenticular focusing elements is preferably in the range 0.1 to 16 and more preferably 0.5 to 4. The lenses could be cylindrical, spherical, aspherical or any other type as required by the application.
[0256] In all of the above examples, the image array(s) 19a, 19b etc could be formed in various different ways. For example, the image elements could be formed of ink, for example printed onto the substrate 3 or onto another layer which is then positioned adjacent to the substrate 3 or applied onto it. However, in other examples the image elements can be formed by a relief structure and a variety of different relief structure suitable for this are shown in
[0257] In another approach, the relief structures can be in the form of diffraction gratings (
[0258] Such diffraction gratings for moth eye/fine pitch gratings can also be located on recesses or bumps such as those of
[0259]
[0260] Further, in some cases the recesses of
[0261] Finally,
[0262] Additionally, image and non-image areas could be defined by combination of different element types, e.g. the image areas could be formed from moth eye structures whilst the non-image areas could be formed from gratings.
[0263] Alternatively, the image and non-image areas could even be formed by gratings of different pitch or orientation.
[0264] Where the image elements are formed solely of grating or moth-eye type structures, the relief depth will typically be in the range 0.05 microns to 0.5 microns. For structures such as those shown in
[0265] The security substrates and devices of the current invention can optionally be made machine readable by the introduction of detectable materials in any of the layers or by the introduction of separate machine-readable layers. Detectable materials that react to an external stimulus include but are not limited to fluorescent, phosphorescent, infrared absorbing, thermochromic, photochromic, magnetic, electrochromic, conductive and piezochromic materials.