Semiconductor Device and Method for Manufacturing the Same
20230101293 · 2023-03-30
Inventors
Cpc classification
H01L29/1054
ELECTRICITY
H01L29/41766
ELECTRICITY
H01L29/7786
ELECTRICITY
H01L29/66462
ELECTRICITY
H01L29/66871
ELECTRICITY
H01L29/4236
ELECTRICITY
International classification
H01L29/66
ELECTRICITY
H01L29/20
ELECTRICITY
Abstract
A buffer layer formed on a substrate, a base layer formed on the buffer layer, and a channel layer formed on the base layer are provided. The base layer includes Al.sub.xGa.sub.1-xN(0<x≤1) and the composition x of Al decreases in accordance with increasing approach of the composition x to the channel layer in a thickness direction. The channel layer includes Al.sub.yGa.sub.1-yN(0<y≤1) and the composition y of Al decreases in accordance with increasing approach of the composition y to the base layer in a thickness direction.
Claims
1.-8. (canceled)
9. A semiconductor apparatus comprising: a buffer layer on a substrate, the buffer layer comprising a nitride semiconductor including Al; a base layer on the buffer layer, the base layer comprising Al.sub.xGa.sub.1-xN(0<x≤1); a channel layer on the base layer, the channel layer comprising Al.sub.yGa.sub.1-yN(0<y≤1); a source electrode and a drain electrode on the channel layer; and a gate electrode on the channel layer between the source electrode and the drain electrode; wherein the composition x of Al in the base layer decreases in accordance with an increasing approach of the composition x to the channel layer in a thickness direction; wherein the composition y of Al in the channel layer decreases in accordance with an increasing approach of the composition y to the base layer in the thickness direction; and wherein both composition ratios of Al of the base layer and the channel layer are equal at an interface between the base layer and the channel layer.
10. The semiconductor apparatus according to claim 9, wherein: the base layer comprises Al.sub.xGa.sub.1-xN(0.7<x≤1); and the channel layer comprises Al.sub.yGa.sub.1-yN(0.7<y≤1).
11. The semiconductor apparatus according to claim 9, further comprising a barrier layer on the channel layer, the barrier layer comprising a nitride semiconductor including Al.
12. The semiconductor apparatus according to claim 11, wherein the gate electrode is on the barrier layer.
13. The semiconductor apparatus according to claim 12, further comprising a recess in the channel layer, wherein the gate electrode is in the recess.
14. The semiconductor apparatus according to claim 9, further comprising: a first contact layer on the channel layer, the first contact layer comprising AlGaN; and a second contact layer on the channel layer, the second contact layer comprising AlGaN.
15. The semiconductor apparatus according to claim 14, wherein: the source electrode is on the first contact layer; the drain electrode is on the second contact layer; and the compositions of Al in the first contact layer and the second contact layer decrease in accordance with an increasing approach of the compositions to an upper layer in the thickness direction.
16. A method for producing a semiconductor apparatus, the method comprising: forming a buffer layer comprising AlN on a substrate; forming a base layer comprising Al.sub.xGa.sub.1-xN(0<x≤1) on the buffer layer; forming a channel layer comprising Al.sub.yGa.sub.1-yN(0<y≤1) on the base layer; forming a source electrode and a drain electrode on the channel layer; and forming a gate electrode on the channel layer between the source electrode and the drain electrode; wherein the composition x of Al in the base layer decreases in accordance with an increasing approach of the composition x to the channel layer in a thickness direction; wherein the composition y of Al in the channel layer decreases in accordance with an increasing approach of the composition y to the base layer in the thickness direction; and wherein both composition ratios of Al in the base layer and the channel layer are equal at an interface between the base layer and the channel layer.
17. The method according to claim 16, wherein: the base layer comprises Al.sub.xGa.sub.1-xN(0.7<x≤1); and the channel layer comprises Al.sub.yGa.sub.1-yN(0.7<y≤1).
18. The method according to claim 16, further comprising forming a barrier layer comprising AlN on the channel layer, wherein the gate electrode is formed on the barrier layer.
19. The method according to claim 18, wherein the barrier layer comprises a nitride semiconductor including Al.
20. The method according to claim 19, further comprising forming a recess in the channel layer, wherein forming the gate electrode comprises forming the gate electrode in the recess.
21. The method according to claim 16, further comprising: forming a first contact layer on the channel layer, the first contact layer comprising AlGaN; and forming a second contact layer on the channel layer, the second contact layer comprising AlGaN.
22. The method according to claim 21, wherein: the source electrode is formed on the first contact layer; the drain electrode is formed on the second contact layer; and the compositions of Al in the first contact layer and the second contact layer decrease in accordance with an increasing approach of the compositions to an upper layer in the thickness direction.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS
[0042] The semiconductor apparatus in accordance with an embodiment of the present invention is described below with reference to
[0043] The substrate 101 can be, for example, a sapphire substrate with the main surface of C face, a single crystal Si substrate, a single crystal SiC substrate, a GaN substrate, or an AlN substrate. The buffer layer 102 includes a nitride semiconductor including Al such as AlN.
[0044] The base layer 103 includes Al.sub.xGa.sub.1-xN(0<x≤1). For example, the base layer 103 includes Al.sub.xGa.sub.1-xN(0.7<x≤1). Furthermore, the base layer 103 is made such that the composition x of Al decreases in accordance with an increasing approach of the composition x to the channel layer 104 in the thickness direction. Moreover, the base layer 103 can also have a configuration doped with Si. Herein, the buffer layer 102 can include Al.sub.xGa.sub.1-xN which is the same composition as the base layer 103 the buffer layer 102 is in contact with.
[0045] The channel layer 104 includes Al.sub.yGa.sub.1-yN(0<y≤1). For example, the channel layer 104 includes Al.sub.yGa.sub.1-yN(0.7<y≤1). Furthermore, the channel layer 104 is made such that the composition y of Al decreases in accordance with an increasing approach of the composition y to the base layer 103 in the thickness direction.
[0046] Moreover, the base layer 103 and the channel layer 104 are made such that both composition ratios of Al are the same at the interface between the base layer 103 and the channel layer 104. As will be described later, the layer thickness and composition of the base layer 103 affect electrons in the channel layer 104. Also, as will be described later, the layer thickness and composition of the channel layer 104 affect electrons in the channel layer 104.
[0047] The source electrode 105 and the drain electrode 106 are in ohmic-contact with the channel layer 104. Furthermore, the gate electrode 107, for example, is Schottky-junctioned to the channel layer 104. Moreover, the gate electrode 107 can also be provided on the channel layer 104 through a gate insulating layer (not shown).
[0048] Additionally, as shown in
[0049] The barrier layer 108, for example, can include AlN. In addition, the barrier layer 108 can also include AlGaN which has a high Al composition, which is an Al composition ranging from about 0.7 to 1. As will be described later, the barrier layer 108 affects an electron concentration and electron confinement in the channel layer 104. Furthermore, the barrier layer 108 can also have a configuration doped with Si.
[0050] As the doping concentration in the barrier layer 108 increases, the free electron concentration in the channel layer 104 rises. This effect can be equally obtained even if the base layer 103 is not doped with Si. Although the doping concentration of the barrier layer 108 is adjusted according to uses, the upper limit is to be set equal to or less than a concentration which generates a self-compensation effect. For example, when the barrier layer 108 includes AlGaN which has a high Al composition, which is an Al composition ranging from about 0.7 to 1, the Si concentration as a dopant is to be set to have an upper limit of 1×10.sup.19 cm.sup.−3 or less which does not generate a self-compensation effect.
[0051] Next, the impact of the base layer 103 on the electrons in the channel layer 104 is described.
[0052] In an AlGaN layer (compositionally graded layer) in which the composition of Al is graded, as is mentioned in reference literature 1, a three-dimensional-like polarized charge is generated. Assuming that a composition difference of a compositionally graded layer is Δx and a layer thickness is d, polarization charge density (volume charge density) can be expressed as approximately 5×10.sup.13×Δx/d. As for AlGaN which grew in a group III polarity direction (+c-axis direction), in compositionally graded AlGaN in which an Al composition decreases with the growth, a negative polarization charge is generated in a +c-axis direction. Meanwhile, as for AlGaN which grew in a group III polarity direction, in compositionally graded AlGaN in which an Al composition rises with the growth, a positive polarization charge is generated in a +c-axis direction.
[0053] Therefore, in the base layer 103, a negative polarization charge is generated toward the channel layer 104, and, in the channel layer 104, a positive polarization charge is generated toward the side of the gate electrode 107. Because of the effects of these polarization charges, free electrons are induced in the channel layer 104, while free holes are generated (induced) in the base layer 103. The polarization charge density in these layers, as previously mentioned, depends on the degree of a composition gradient (Δx/d). When the degrees of the composition gradients of the channel layer 104 and the base layer 103 are the same, electrons and holes both of which have almost the same degree of the concentrations must be generated in each layer.
[0054] In embodiments of the present invention, in order to suppress free holes in the base layer 103, first of all, for example, the base layer 103 is doped with donor (such as Si) for the purpose of compensating a negative polarization charge. Additionally, doping the barrier layer 108 with donor makes it possible to improve the electron concentration of the channel layer 104. Second, such a technique is employed that the degree of the composition changes of a base layer is made to be gentler than that of a channel layer. By making the degree of the composition changes gentle, polarization charge density can be decreased. Decreasing polarization charge density makes it possible that the donor concentration with which the base layer 103 is doped is reduced.
[0055] As an example,
[0056] As an additional example,
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[0059] As explained above, by doping the base layer 103 with donor, the impact of the three-dimensional polarization charge in the base layer 103 can be mitigated and the generation of holes in the base layer 103 can be suppressed. Furthermore, the three-dimensional polarization charge density changes according to the degree of the composition gradient of the base layer 103.
[0060] In embodiments of the present invention, when the doping concentration of donor with which the base layer 103 is doped is the concentration (1×10.sup.18 cm.sup.−3) or less which does not generate a self-compensation effect, the doping concentration is effective, but it is desired that the doping concentration is the concentration (polarization charge density±1×10.sup.17 cm.sup.−3) which is nearly equal to the polarization charge density of the base layer 103.
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[0062] Next, the impact of the layer thickness and composition of the channel layer 104 on the electrons in the channel layer 104 is described.
[0063] The impact of the layer thickness and composition of the channel layer 104 also affects the electric characteristic of the channel layer 104. As previously mentioned, the positive charge density in the channel layer 104 changes according to the degree of the composition gradient (change). When the degree of the gradient becomes steep, the positive polarization charge density increases. What degree of gradient to be decided is adjusted according to the uses of a nitride semiconductor device, but whatever degree of gradient is used, the effects of embodiments of the present invention are not affected.
[0064] Moreover, while doping the channel layer 104 with donor can make the free electron concentration increase, the doping causes the electron mobility to decrease. Doping or not doping the channel layer 104 with donor and the concentration depend on the uses of a device, whereas, if the concentration is equal to or less than the concentration which generates a self-compensation effect, the effects of embodiments of the present invention are not affected.
[0065] Next, the restriction on the layer thicknesses of the base layer 103 and the channel layer 104 is described. It is important that the total layer thickness of the base layer 103 and the channel layer 104 is equal to or less than the critical layer thickness which generates lattice relaxation. This critical layer thickness is nearly equal to that of an AlGaN layer having the same composition as the average composition of the base layer 103 and the channel layer 104.
[0066] Next, the impact (electron confinement) of the barrier layer 108 is described. Providing the barrier layer 108 having a bandgap which is the same as or bigger than that of the channel layer 104 can improve the free electron concentration in the channel layer 104. This is because the polarization charge of the barrier layer 108 and the electron confinement in the channel layer 104 improve. Without the barrier layer 108, the surface side of the channel layer 104 is depleted and free electrons cannot exist. Forming the barrier layer 108 makes electrons to be distributed in the entire channel layer 104. Furthermore, the polarization effect of the barrier layer 108 also contributes to the improvement of the free electron concentration of the channel layer 104.
[0067] Moreover, forming the barrier layer 108 produces an effect of the suppression of gate leakage. The thicker the barrier layer becomes, the more effective the improvement of electron concentration and the like come to be. Herein, the change of the sheet carrier concentration is shown in
[0068] Next, another semiconductor apparatus (field effect transistor) in accordance with an embodiment of the present invention is described with reference to
[0069] For example, as shown in
[0070] Additionally, for example, as shown in
[0071] Moreover, as shown in
[0072] One of the problems of the ultra wide-bandgap semiconductor is the difficulty to lower the contact resistance of the ohmic contact. This is because it is difficult to lower a barrier height with metal as the ultra wide-bandgap semiconductor has a small electron affinity.
[0073] To cope with this, in embodiments of the present invention, the first contact layer 110 and the second contact layer in are formed in the regions of the source electrode 105 and the drain electrode 106. The first contact layer 110 and the second contact layer in each have an Al composition of AlGaN which is made to decrease in accordance with an increasing approach of the Al compositions to the electrodes, and the outermost surfaces of the layers are made to be AlGaN with a low Al composition. Thereby, the electron affinity at the contact portions with the electrodes is enhanced to achieve the lowering of the electrical contact resistance with the electrodes.
[0074] Furthermore, in the first contact layer 110 and the second contact layer 111 which each have such a graded composition, as previously mentioned, the negative polarization charge is generated. To compensate this, the first contact layer 110 and the second contact layer in are doped with the donor impurities such as Si and Ge to the extent equal to or more than the polarization charge (5×10.sup.13×Δx/d) of the first contact layer 110 and the second contact layer 111.
[0075] Additionally, as shown in
[0076] As previously mentioned, the negative polarization charge is generated in the base layer 103. By utilizing this negative polarization charge, an enhancement type field effect transistor can be produced. It is difficult to configure the enhancement type field effect transistor by a prior art of HEMT (High Electron Mobility Transistor) utilizing a heterojunction between an AlGaN layer and a GaN layer because of a two-dimensional electron gas induced at a heterointerface due to a polarization charge.
[0077] In HEMT utilizing a heterojunction between an AlGaN layer and a GaN layer, there is a recessed gate structure as one of the techniques to produce the enhancement type field effect transistor. By making the gate region of an AlGaN barrier layer thinner, the two-dimensional electron gas at the heterointerface is eliminated and an enhancement type operation is achieved. The threshold voltage becomes shallow as the depth of recess etching (etching elimination quantity) increases. In this technique, however, the control range of the threshold voltage is narrow.
[0078] Even the field effect transistor having the structure of embodiments of the present invention usually performs a depletion operation because free electrons are induced due to the polarization charge of the channel layer 104. To cope with this, the recess 109a is formed in the gate region, as mentioned above, and the gate electrode 107a is provided there, thereby, the enhancement type operation becomes possible. In addition, according to embodiments of the present invention, since the base layer 103 has a negative polarization charge, there is an advantage that the control range of the threshold voltage is wider than that of the recess structure of HEMT utilizing the heterojunction between the AlGaN layer and the GaN layer.
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[0080] Moreover, as shown in
[0081] The method for producing the semiconductor apparatus in accordance with an embodiment of the present invention is described below. First, as shown in
[0082] Next, an insulating film is formed on the barrier layer 108 by, for example, depositing silicon oxide, and a mask pattern 121 is formed on the barrier layer 108 by patterning this insulating film by a known lithography technology and a known etching technology.
[0083] Next, as shown in
[0084] Next, after the mask pattern 121 is removed, as shown in
[0085] Next, a method for producing another semiconductor apparatus in accordance with an embodiment of the present invention is described. First, as shown in
[0086] Next, an insulating film is formed on the barrier layer 108 by, for example, depositing silicon oxide, a resist pattern 124 is formed on this insulating film by a known lithography technology, and an inorganic pattern 123 is formed on the barrier layer 108 by patterning the insulating film by a known etching technology utilizing this resist pattern 124.
[0087] Next, as shown in
[0088] After that, the inorganic pattern 123 is removed, the source electrode 105 and the drain electrode 106 are formed (a second step), and the gate electrode 107 is formed (a third step). Furthermore, it is also possible that a recess is formed in the barrier layer 108 and that the gate electrode 107 is formed there. Moreover, it is also possible that before the gate electrode 107 is formed, a gate insulating layer is formed and that the gate electrode is formed on the gate insulating layer.
[0089] Next, a method for producing another semiconductor apparatus in accordance with an embodiment of the present invention is described. First, as shown in
[0090] Next, after the substrate 101 is taken out from the above-mentioned growth equipment utilized for the growth of each layer, as shown in
[0091] Next, as shown in
[0092] As explained above, according to embodiments of the present invention, since the base layer including Al.sub.xGa.sub.1-xN(0<x≤1) is made such that the composition x of Al decreases in accordance with an increasing approach of the composition x to the channel layer in the thickness direction and the channel layer which is formed on the base layer and includes Al.sub.yGa.sub.1-yN(0<y≤1) is made such that the composition y of Al decreases in accordance with an increasing approach of the composition y to the base layer in the thickness direction, the lowering of the resistance of the channel which utilizes the ultra wide-bandgap semiconductor can be achieved.
[0093] Furthermore, embodiments of the present invention should not be limited to the above-mentioned embodiments and it will be apparent that many modifications and combinations can be made by a person ordinarily skilled in the art within the spirit and scope of the invention.
REFERENCE LITERATURE
[0094] [Reference literature 1] J. Simon et al., “Polarization-Induced Hole Doping in Wide-Band-Gap Uniaxial Semiconductor Heterostructures”, SCIENCE, vol. 327, pp. 60-64, 2010. [0095] [Reference literature 2] R. People and J. C. Bean, “Calculation of critical layer thickness versus lattice mismatch for GexSi1-x/Si strained layer heterostructures”, Applied Physics Letters, vol. 47, no. 3, pp. 322-324, 1985.
REFERENCE SIGNS LIST
[0096] 101 Substrate [0097] 102 Buffer layer [0098] 103 Base layer [0099] 104 Channel layer [0100] 105 Source electrode [0101] 106 Drain electrode [0102] 107 Gate electrode