Semiconductor bonding with compliant resin and utilizing hydrogen implantation for transfer-wafer removal
09991149 ยท 2018-06-05
Assignee
Inventors
- Damien Lambert (Los Altos, CA, US)
- John Spann (Albuquerque, NM, US)
- Stephen Krasulick (Albuquerque, NM, US)
Cpc classification
H01L2225/06593
ELECTRICITY
H01L24/95
ELECTRICITY
G02B6/4201
PHYSICS
H01L2221/6834
ELECTRICITY
H01L2224/83203
ELECTRICITY
H01L2224/83001
ELECTRICITY
H01L2221/68381
ELECTRICITY
H01L24/75
ELECTRICITY
H01L2221/68318
ELECTRICITY
H01L21/76254
ELECTRICITY
H01L24/89
ELECTRICITY
H01L2221/68368
ELECTRICITY
H01L2924/15738
ELECTRICITY
H01L2221/68313
ELECTRICITY
H01L24/94
ELECTRICITY
International classification
H01L21/762
ELECTRICITY
Abstract
A transfer substrate with a compliant resin is used to bond one or more chips to a target wafer. An implant region is formed in a transfer substrate. A portion of the transfer substrate is etched to form a riser. Compliant material is applied to the transfer substrate. A chip is secured to the compliant material, wherein the chip is secured to the compliant material above the riser. The chip is bonded to a target wafer while the chip is secured to the compliant material. The transfer substrate and compliant material are removed from the chip. The transfer substrate is opaque to UV light.
Claims
1. A method of bonding a chip to a target substrate, the method comprising: forming a compliant layer on a surface of a transfer substrate; forming a pit in the compliant layer by removing a portion of the compliant layer, the pit having a first depth from a surface of the compliant layer and a width, the first depth being less than a thickness of the chip, and the first width being greater than a width of the chip; securing the chip to a bottom of the pit, such that a portion of the chip protrudes above the surface of the compliant layer and there is a gap between a sidewall of the chip and a sidewall of the pit; forming a photoresist layer on the surface of the compliant layer, wherein the photoresist layer fills the gap between the sidewall of the chip and the sidewall of the pit; removing the portion of the chip that protrudes above the surface of the compliant layer; aligning the transfer substrate with the target substrate; bonding the chip to the target substrate while applying a pressure on the transfer substrate against the target substrate through the compliant layer; removing the transfer substrate from the compliant layer; and removing the compliant layer.
2. The method of claim 1, wherein the compliant layer comprises a resin.
3. The method of claim 1, wherein the compliant layer has a thickness ranging from about 10 microns to about 40 microns.
4. The method of claim 1, wherein: the transfer substrate comprises silicon; the target substrate comprises silicon; and the chip comprises a III-V semiconductor material.
5. The method of claim 1, wherein the transfer substrate is opaque to light in a wavelength range from 200 nm to 400 nm.
6. The method of claim 1, further comprising: before forming the compliant layer, forming an implant region in the transfer substrate; wherein removing the transfer substrate from the compliant layer comprises fracturing the transfer substrate at the implant region.
7. The method of claim 1, further comprising forming a first bond pad on a surface of the chip after removing the portion of the chip that protrudes above the surface of the compliant layer and before bonding the chip to the target substrate.
8. The method of claim 7, wherein the first bond pad is formed on the surface of the chip using photolithography.
9. The method of claim 7, wherein the target substrate comprises: a second bond pad on a surface of the target substrate; wherein the chip is bonded to the target substrate via a bond material disposed between the first bond pad and the second bond pad.
10. A method of bonding a chip to a target substrate, the method comprising: forming an implant region in a transfer substrate, the implant region being at a first depth from a surface of the transfer substrate; forming a compliant layer on the surface of the transfer substrate; securing the chip to the compliant layer, wherein a portion of the chip extends above a surface of the compliant layer; removing the portion of the chip that extends above the surface of the compliant layer; aligning the transfer substrate with the target substrate; bonding the chip to the target substrate while applying a pressure on the transfer substrate against the target substrate through the compliant layer; removing the transfer substrate from the compliant layer by fracturing the transfer substrate at the implant region; and removing the compliant layer.
11. The method of claim 10, wherein: securing the chip to the compliant material further comprises forming a pit in the compliant layer by removing a portion of the compliant layer, the pit having a depth from the surface of the compliant layer and a width, the depth of the pit being less than a thickness of the chip; and the chip is secured to a bottom of the pit.
12. The method of claim 11, wherein: the first width of the pit is greater than a width of the chip such that there is a gap between a sidewall of the chip and a sidewall of the pit after the chip is secured to the bottom of the pit; and removing the portion of the chip that extends above the surface of the compliant layer comprises: forming a photoresist layer on the surface of the compliant layer, the photoresist layer filling the gap between the sidewall of the chip and the sidewall of the pit; and performing photolithography to remove the portion of the chip that extends above the surface of the compliant layer.
13. The method of claim 10, wherein the compliant layer comprises a resin.
14. The method of claim 10, wherein the compliant layer has a thickness ranging from about 10 microns to about 40 microns.
15. The method of claim 10, the transfer substrate is opaque to light in a wavelength range from 200 nm to 400 nm.
16. The method of claim 10, wherein: the transfer substrate is silicon; and the target substrate is silicon.
17. A transfer structure for bonding a chip to a target substrate, the transfer structure comprising: a transfer substrate having an implant region at a first depth from a surface of the transfer substrate; the chip; and a compliant layer formed on the surface of the transfer substrate, wherein: the compliant layer defines a pit; the chip is secured to a bottom of the pit; the pit has a depth from a surface of the compliant layer and a width; the depth of the pit is less than a thickness of the chip so that the chip extends above the surface of the compliant layer; the width of the pit is greater than a width of the chip so that there is a gap between a sidewall of the pit and a sidewall of the chip; and the gap between the sidewall of the pit and the sidewall of the chip is filled by a photoresist material.
18. The transfer structure of claim 17, wherein: the compliant layer comprises a resin; the chip comprises III-V material; and the transfer substrate comprises silicon.
19. The transfer structure of claim 17 wherein the compliant layer has a thickness ranging from about 10 microns to about 40 microns.
20. The transfer structure of claim 17, wherein the transfer substrate is opaque to light in a wavelength range from 200 nm to 400 nm.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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(19) In the appended figures, similar components and/or features may have the same reference label. Further, various components of the same type may be distinguished by following the reference label by a dash and a second label that distinguishes among the similar components. If only the first reference label is used in the specification, the description is applicable to any one of the similar components having the same first reference label irrespective of the second reference label.
DETAILED DESCRIPTION OF THE INVENTION
(20) The ensuing description provides preferred exemplary embodiment(s) only, and is not intended to limit the scope, applicability, or configuration of the disclosure. Rather, the ensuing description of the preferred exemplary embodiment(s) will provide those skilled in the art with an enabling description for implementing a preferred exemplary embodiment. It is understood that various changes may be made in the function and arrangement of elements without departing from the spirit and scope as set forth in the appended claims.
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(22) The transfer substrate 104 further comprises a top surface 112 and a bottom surface 116. The implant region 108 forms a plane that is parallel, or substantially parallel, with the top surface 112 and/or the bottom surface 116. The implant region 108 is formed at a first depth, d.sub.1, from the top surface 112. In some embodiments, d.sub.1, is between 0.25 and 4 microns (e.g., 0.25, 0.5, 1, 2, or 4 microns). In some embodiments, the first depth, d.sub.1, is minimized to reduce etching in later steps. In some embodiments, the implant region 108 is made by ion implantation (e.g., using hydrogen, He, B, and/or Si ions).
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(24) In some embodiments, the risers 204 are positioned to correspond to (e.g., mirror image of) bonding sites (e.g., recesses formed in the target wafer). In some embodiments, a riser 204 has a surface area that is smaller or larger than a surface area of a corresponding recesses of the target wafer. For example, a smaller surface area of a riser 204 may help in alignment of chips to bonding sites in the target wafer, while a larger surface area may help to keep debris (after the riser 204 is fractured at the implant region 108) from falling into a corresponding recess of the target wafer.
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(26) A row and/or a column may be left blank for matching to a target wafer (e.g., target wafer is to be cut after bonding chips to the target wafer, and the target wafer has eight recesses per laser system: four pits for four lasers and four pits for four modulators; thus each laser system has four lasers and four modulators). Blank rows and/or columns are provided to give room for dicing the target wafer.
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(28) In some embodiments, the compliant material 404 is a resin (e.g., HD-3007 from HD MicroSystems). In some embodiments, the compliant material 404 has a thickness that is a function of height variance between a set of chips in order to apply a uniform pressure on the chips. For example, the thickness of the compliant material is such that the compliant material transfers substantially similar force to chips having an absolute height difference of up to 0.5, 1.0, 1.5, 2.0, 2.5, and/or 3 microns; wherein the absolute height is measured from the bottom surface 116 of the transfer substrate 104 to a top of the chip, while the chip is secured to the transfer wafer 408. For example, a chip having a height of 12.3 microns may be in a pit of the compliant material two microns deeper than a chip having a height of 10.1 microns; the absolute height difference would be 0.2 microns. In some embodiments, the compliant material is applied so that the compliant material forms a relatively flat surface parallel to top surfaces of the transfer substrate 104. In some embodiments, an initial thickness, t.sub.0, of the compliant material is between 1 to 50 microns, or between 10 and 40 microns (e.g., greater than or equal to 10, 15, 20, 25, 30, 35, or 40 microns).
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(33) The chips 604 comprise material that has some property that is different than material that is part of the target wafer. For example, the target wafer is silicon and the chips 604 are made of III-V material. The III-V material has a direct bandgap, which the silicon does not. Light emission is more easily accomplished with a semiconductor having direct-bandgap material. Thus the III-V material can more easily be a light source than the silicon of the target wafer. The active region 612 of the chip 604 is used for either a gain medium for a laser or for modulation of a laser beam, in this embodiment. For example, the active region 612 comprises quantum wells for gain medium of a semiconductor laser (and the mirrors, e.g., Bragg gratings, of the semiconductor laser are formed in silicon of the target wafer).
(34) The contact layer 608 is added to the chip 604 before the chip 604 is secured to the compliant material 404. In some embodiments, the contact layer 608 is a metal. In some embodiments, the contact layer 608 is a semiconductor (e.g., InGaAs or InGaP). The contact layer 608 is used to connect the chip 604 to an electrical current after the chip 604 is bonded to the target wafer. In some embodiments, the contact layer 608 is added to the chip 604 after the chip 604 is bonded to the target wafer.
(35) The etch stop 618 is used for a high selectivity chemical etch to remove the substrate portion 620. The etch stop 618 is made of different material than the substrate portion 620, and the etch stop 618 is epitaxially connected to the substrate portion 620. Examples of material for the etch stop 618 include InGaAs and InGaAsP for chips 604 having a substrate portion 620 made of InP. A person skilled in the art will recognize that other materials could be used for the substrate portion 620 and/or the etch stop 618 (e.g., using GaAs for the substrate portion 620). In some embodiments, the etch stop 618 also serves as a semiconductor layer used for making an electrical contact. Thus, in some embodiments, the etch stop 618 is highly doped and/or has a lower band-gap to enhance performance of future metal contact and/or reduce electrical current spent in the chip. In some embodiments, before the chip 604 is bonded to the target wafer 1004, the chip 604 does not have any contact layers 608 and contact layers 608 may be added later.
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(39) In some embodiments, bond material 808 is applied to the upper-bond pads 804. Examples of bond material 808 are given in U.S. application Ser. No. 12/902,621, filed on Oct. 12, 2010, which is incorporated by reference.
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(41) A first column 904-1 of the compliant material 404 extends between the first riser 204-1 and the first chip 604-1. The first column 904-1 of the compliant material 404 has a first final thickness t.sub.f-1. A second column 904-2 of the compliant material 404 extends between the second riser 204-2 and the second chip 604-2. The second column 904-2 of the compliant material 404 has a second final thickness t.sub.f-2. In some embodiments, the first final thickness t.sub.f-1 is not equal to the second final thickness t.sub.f-2. For example, the first final thickness t.sub.f-1 is greater than the second final thickness t.sub.f-2 because the first chip 604-1 is not as thick as the second chip 604-2. In another example, the first final thickness t.sub.f-1 is greater than the second final thickness t.sub.f-2 because the first chip 604-1 is to be placed in a deeper recess of the target wafer than the second chip 604-2.
(42) In some embodiments,
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(44) In some embodiments, the target wafer 1004 comprises multiple layers: a target substrate 1012, a first insulation layer 1016, a device layer 1020, and a second insulation layer 1024. The recess 1008 is formed by walls in the first insulation layer 1016, the device layer 1020, and the second insulation layer 1024. A floor 1032 of the recess 1008 is formed in the target substrate 1012. A lower-bond pad 1028 is disposed on the floor 1032 of the recess 1008. The lower-bond pad 1028 is used in UBM in bonding the chip 604 to the target substrate 1012. Pedestals 1036 are formed in the target substrate 1012. The pedestals 1036 are used for vertical alignment of the chip 604 to the target wafer 1004. In some embodiments, the target wafer 1004 is similar to the platform as described in U.S. application Ser. No. 14/509,914, filed on Oct. 8, 2014, which is incorporated by reference.
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(50) In step 1508, risers 204 are defined in the transfer substrate 104. The risers 204 are formed by using lithography to apply a hard mask (e.g., SiO2), etching the transfer substrate 104 to form the risers 204, and then stripping the hard mask. Portions of the transfer substrate 104 are etched to the second depth d.sub.2 from the top surface 112 of the transfer substrate 104. In some embodiments, the second depth d.sub.2 is greater than the first depth d.sub.1, such that the implant region 108 is within the risers 204. An example of risers 204 formed in the transfer substrate 104 is given in
(51) In step 1512, the compliant material 404 (e.g., a resin; HD-3007 from HD MicroSystems) is applied to coat the transfer substrate 104. In some embodiments, the compliant material 404 is used in applying a uniform pressure to chips 604 during bonding to the target wafer 1004. An example of compliant material 404 coating the transfer substrate 104 is given in
(52) In step 1516, an optional step, pits 504 are formed in the compliant material 404. In some embodiments, the transfer substrate 104 is made of a material having a thermal expansion coefficient similar to a thermal expansion coefficient of the target substrate 1012. For example, the thermal expansion coefficient of the transfer substrate 104 and the thermal expansion coefficient of the target wafer 1004 are sufficiently similar that a chip 604 secured to the transfer wafer 408 and aligned to the target substrate 1012 has an offset movement (of a point on the transfer substrate 104 substrate compared to a point on the target wafer 1004) of no more than 1, 3, 5, 7, and/or 10 microns when heated to 300 degrees Celsius. In some embodiments, different pits 504 formed in the compliant material 404 have different depths. In some embodiments, a dry etch using an O2 plasma forms the pits 504. An example of pits 504 formed in the compliant material 404 is given in
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(54) In step 1608, an optional step, the pits 504 are filled with material (e.g., photoresist and/or a polymer) to protect sides of chips 604. An example of pits 504 filled with photoresist is given in
(55) In step 1616, the upper-bond pads 804 are patterned on the chips 604. In some embodiments, photolithography is used to pattern the upper-bond pads 804 on the chips 604. In some embodiments, the upper-bond pads 804 are a metal alloy deposited using a liftoff process. In some embodiments, bond material 808 is also applied to upper-bond pads 804 of the chips 604. In some embodiments, the bond material 808 is applied to the lower-bond pads 1028 instead of, or in addition to, the upper-bond pads 804 before the chip 604 is bonded to the target wafer 1004. For example, bond material 808 is easier to clean before bonding if the bond material 808 is applied to the lower-bond pads 1028. Some cleaning materials used in cleaning the bond material 808 may harm III-V material in the chip 604. Thus if the bond material 808 is on the target wafer 1004 when cleaned, the chip 604, which is on the transfer 408, is not exposed to the cleaning materials. An example of upper-bond pads 804 and bond material 808 applied to the chips 604 is given in
(56) In step 1620, excess of the compliant material 404 is removed, leaving the columns 904 of compliant material 404 between the risers 204 and the chips 604. In some embodiments, a plasma etch (e.g., O2 dry etch) is used to remove the excess of the compliant material 404. An example of the excess of the compliant material 404 removed is given in
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(58) In step 1708, the transfer substrate 104 is removed. During bonding, the transfer substrate 104 fractures at the implant region 108 because of heat applied to the transfer substrate 104. In some embodiments, the riser 204 has a width that is greater than a width of the recess 1008 to reduce debris from falling in the recess 1008 when the transfer substrate 104 fractures at the implant region 108 (the width being measured in a direction orthogonal to the second depth, d.sub.2). After the chip 604 is bonded to the target wafer 1004, and the transfer substrate 104 fractures at the implant region 108, the transfer substrate 104 is removed (e.g., simply lifted) leaving the residual portion 1204 of the riser 204 secured to the column 904 of the compliant material 404. An example of removing the transfer substrate 104 and leaving the residual portion 1204 is given in
(59) In step 1712, the residual portion 1204 is removed using a selective dry etch. In some embodiments, the residual portion 1204 is silicon and the second insulation layer 1024 of the target wafer 1004 is silicon-dioxide. Thus a selective dry etch of silicon can remove the residual portion 1204. An example of the chip 604 bonded to the target wafer 1004 with the residual portion 1204 removed is given in
(60) In step 1716, the column 904 of the compliant material 404 is removed. In some embodiments, the column 904 of the compliant material 404 is removed with solvent. In some embodiments, the chip 604 does not need protection from the solvent used to remove the column 904 of the compliant material 404. In some embodiments, the chip 604 is further cleaned and further processed. An example of the chip 604 bonded to the target wafer 1004 with the column 904 of the compliant material 404 removed is given in
(61) The specific details of particular embodiments may be combined in any suitable manner without departing from the spirit and scope of embodiments of the invention. However, other embodiments of the invention may be directed to specific embodiments relating to each individual aspect, or specific combinations of these individual aspects.
(62) The above description of exemplary embodiments of the invention has been presented for the purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form described, and many modifications and variations are possible in light of the teaching above. For example, in some embodiments, 3200 chips 604 are secured to a transfer wafer 408 and then bonded into 3200 recesses 1008 of the target wafer 1004. The target wafer 1004 is then divided into 400 devices, each device having eight chips 604. Of the eight chips 604 in each device, four chips 604 are used as gain mediums for lasers and four chips 604 are used for modulators. Thus each device has four lasers and four modulators. But more or fewer lasers and/or modulators could be in each device. Additionally, steps of processes can be optional. For example, in process 1600 of placing chips 604 on the transfer wafer 408, step 1612 of removing portions of substrates of the chips 604 is optional. For example, in some embodiments, the substrates of chips 604 are removed before placing chips 604 in pits 504.
(63) The embodiments were chosen and described in order to explain the principles of the invention and practical applications to thereby enable others skilled in the art to best utilize the invention in various embodiments and with various modifications as are suited to the particular use contemplated.
(64) Also, it is noted that the embodiments may be described as a process which is depicted as a flowchart, a flow diagram, a data flow diagram, a structure diagram, or a block diagram. Although a flowchart may describe the operations as a sequential process, many of the operations can be performed in parallel or concurrently. In addition, the order of the operations may be re-arranged. A process is terminated when its operations are completed, but could have additional steps not included in the figure. A process may correspond to a method, a function, a procedure, a subroutine, a subprogram, etc.
(65) A recitation of a, an, or the is intended to mean one or more unless specifically indicated to the contrary.
(66) All patents, patent applications, publications, and descriptions mentioned here are incorporated by reference in their entirety for all purposes. None is admitted to be prior art.