Colored Resin Composition Exhibiting Pleochroism, and Molded Plastics Manufactured Using Same

Abstract

The present invention relates to a coloring resin composition exhibiting pleochroism comprising 100 parts by weight of a transparent thermoplastic resin (A); 0.01 to 0.03 parts by weight of a dye for coloring a resin (B) which is one selected from the group consisting of an azo-based dye (b1), an anthraquinone-based dye (b2), and a methine dye (b3); and 0.1 to 0.3 parts by weight of a functional black dye (C) obtained by mixing an anthraquinone-based dye (c1) and a perinone-based dye (c2). A resin molded article manufactured by the coloring resin composition exhibiting pleochroism of the present invention is characterized by exhibiting different colors of light according to thicknesses although the resin molded article is irradiated with light sources in a single wavelength.

Claims

1. A resin molded article exhibiting pleochrosim wherein light transmitted through the molded article has different exhibited colors depending on the thickness of the molded article so that the molded article satisfies the following Mathematical Formula 1 or Mathematical Formula 2 in case of irradiation with a light source in a single wavelength:
Abs(X)=|X.sub.1X.sub.2|>0.05[Mathematical formula 1] X.sub.1= value of a CIE 1931 color space for the resin molded article with a thickness of 1.0 mm and X.sub.2= value of a CIE 1931 color space for the resin molded article with a thickness of 1.5 mm,
Abs(Y)=|Y.sub.1Y.sub.2|>0.05[Mathematical Formula 2] Y.sub.1=y value of a CIE 1931 color space for the resin molded article with a thickness of 1.0 mm and Y.sub.2=y value of a CIE 1931 color space for the resin molded article with a thickness of 1.5 mm.

2. The resin molded article of claim 1, wherein the resin molded article is prepared by a coloring resin composition comprising: a transparent thermoplastic resin; a dye for coloring a resin (B); and a functional black dye (C), wherein the functional black dye is a mixture of an anthraquinone-based dye (c1) and a perinone-based dye (c2).

3. The resin molded article of claim 2, wherein the coloring resin composition comprises: 0.01 to 0.10 parts by weight of the dye for coloring a resin (B); and 0.1 to 1.0 parts by weight of the functional black dye (C), each based on 100 parts by weight of the transparent thermoplastic resin.

4. The resin molded article of claim 2, wherein the transparent thermoplastic resin has transmissivity of 85% or more.

5. The resin molded article of claim 2, wherein the dye for coloring a resin (B) is selected from the group consisting of an azo-based dye (b1), an anthraquinone-based dye (b2), and a methine-based dye (b3).

6. The resin molded article of claim 5, wherein the azo-based dye (b1) is a compound comprising a chemical structure of the following Chemical Formula 1, the anthraquinone-based dye (b2) is a compound comprising a chemical structure of the following Chemical Formula 2, and the methine-based dye (b3) is a compound comprising a chemical structure of the following Chemical Formula 3: ##STR00010##

7. The resin molded article of claim 2, wherein the functional black dye (C) is a mixture of 20 to 70% by weight of the anthraquinone-based dye (c1) and 30 to 80% by weight of the perinone-based dye (c2).

8. The resin molded article of claim 7, wherein the anthraquinone-based dye (c1) is a compound comprising a chemical structure of the following Chemical Formula 4, and the perinone-based dye (c2) is a compound comprising a chemical structure of the following ##STR00011##

9. The resin molded article of claim 1, wherein the resin molded article is characterized in that the thicknesses of the molded article vary in a stepwise manner by forming one or more stepped parts on the molded article.

10. The resin molded article of claim 1, wherein the molded article is characterized in that a width between one side and the opposite side of the molded article continuously varies.

11. The resin molded article of claim 5, wherein the dye for coloring a resin (B) selected from the group consisting of an azo-based dye (b1), an anthraquinone-based dye (b2), and a methine-based dye (b3) imparts a color other than black.

12. The resin molded article of claim 11, wherein the dye for coloring a resin (B) is an azo-based dye (b1) having a chemical structure of Chemical Formula 1: ##STR00012##

13. The resin molded article of claim 11, wherein the dye for coloring a resin (B) is an anthraquinone-based dye (b2) having a chemical structure of Chemical Formula 2: ##STR00013##

14. The resin molded article of claim 11, wherein the dye for coloring a resin (B) is a methine-based dye (b3) having a chemical structure of Chemical Formula 3: ##STR00014##

Description

BRIEF DESCRIPTION OF DRAWINGS

[0031] FIG. 1 is an image showing that the exhibited figure of pleochroism according to thicknesses of molded articles manufactured by a coloring resin composition of the present invention.

[0032] FIGS. 2A, 2B, and 2C are images showing that the figures of a resin molded article exhibiting a variety of colors from light sources in a single wavelength when an azo-based dye, an anthraquinone-based dye, and a methine-based dye are respectively used as a dye for coloring a resin.

[0033] FIG. 3A shows a CIE 1931 XYZ color space (or CIE 1931 color space), and FIG. 3B shows the color coordinate of transmitted light through specimens of Examples 1 to 4 on the CIE 1931 color space.

[0034] FIG. 4 is one specific embodiment of a resin molded article manufactured by a coloring resin composition of the present invention and shows a perspective view of a molded article whose cross section forms a wave pattern by forming one or more curved parts on one side of the molded article.

DETAILED DESCRIPTION OF THE INVENTION

[0035] The present invention relates to a coloring resin composition exhibiting pleochroism comprising 100 parts by weight of a transparent thermoplastic resin (A); 0.01 to 0.10 parts by weight of a dye for coloring a resin (B) which is one selected from the group consisting of an azo-based dye (b1), an anthraquinone-based dye (b2), and a methine-based dye (b3); and 0.1 to 1.0 parts by weight of a functional black dye (C) obtained by mixing an anthraquinone-based dye (c1) and a perinone-based dye (c2).

[0036] A resin molded article manufactured by a coloring resin composition for exhibiting pleochroism of the present invention is characterized in that exhibited colors of light are different according to thicknesses of the molded article in case of irradiation with light sources in a single wavelength. Referring to the FIG. 1, the FIG. 1 successively shows 5 kinds of resin molded articles with different thicknesses. Although the thicknesses of the resin molded articles are different, they are manufactured by the same resin composition. Physical properties thereof are the same, but, for optical properties, exhibited colors of transmitted lights are drastically different according to the thicknesses of the resin molded articles in case of irradiation with the same LED light source (750 mA, 1/T time: 500 ms.sup.1) as shown on the FIG. 1.

[0037] Hereinafter, the present invention will be specifically described.

[0038] (A) Transparent Thermoplastic Resin

[0039] A transparent thermoplastic resin can be used as a base resin for the coloring resin composition exhibiting pleochroism of the present invention. As the transparent thermoplastic resin, acrylonitrile-butadiene-styrene (ABS), acrylonitrile-styrene (SAN), polycarbonate, polymethyl methacrylate, and the likes can be exemplified. Further, a coloring dye and a function black dye, used together with the base resin, do not influence on the original properties of the base resin, and thus a thermoplastic resin adequate for securing the desired properties of a resin molded article can be selected and variously used.

[0040] As an example, polyethylene terephthalate (PET) can be selected and used as a transparent thermoplastic resin for a display filter such as a perfectly flat computer monitor, a cathode ray tube (CRT) display, a liquid crystal display (LCD), a plasma display panel (PDP), and the likes in order to secure heat-resistance and electrical properties. Further, a variety of thermoplastic resins can be selected to secure the glossiness, wear properties, and scratch resistance of a molded article, but the selected thermoplastic resins are preferably transparent thermoplastic resins with transmissivity of 85% or more. When the transmissivity thereof is less than or equal to 85%, a problem which is difficult to exhibit pleochroism, the objective of the present invention, can be encountered.

[0041] (B) Dye for Coloring a Resin

[0042] As the dye for coloring a resin of the present invention, approximately, an azo-based dye (b1), an anthraquinone-based dye (b2), and a methine-based dye (b3) can be used.

[0043] The azo-based dye (b1) is preferably a compound comprising the chemical structure of the following Chemical Formula 1.

##STR00006##

[0044] The anthraquinone-based dye (b2) is preferably a compound comprising the chemical structure of the following Chemical Formula 2.

##STR00007##

[0045] The methine-based dye (b3) is preferably a compound comprising the chemical structure of the following Chemical Formula 3.

##STR00008##

[0046] The FIGS. 2A, 2B, and 2C show figures of a resin molded article exhibiting a variety of colors based on light sources in a single wavelength when the azo-based dye (b1), the anthraquinone-based dye (b2), and the methine-based dye (b3) are respectively used as a dye for coloring a resin.

[0047] The amount of the dye for coloring a resin (B) is 0.01 to 0.10 parts by weight, preferably 0.01 to 0.03 parts by weight, more preferably 0.015 to 0.025 parts by weight based on 100 parts by weight of the transparent thermoplastic resin. When the amount of the dye for coloring a resin is out of the above range, color exhibition and pleochroism exhibition cannot be easily performed.

[0048] (C) Functional Black Dye

[0049] In the present invention, the anthraquinone-based dye (c1) and the perinone-based dye (c2) are mixed and used as the functional black dye. The composition of the functional black dye is composed by mixing 20 to 70% by weight of the anthraquinone-based dye (c1) and 30 to 80% by weight of the perinone-based dye (c2).

[0050] In the functional black dye of the present invention, the anthraquinone-based dye (c1) is preferably a compound comprising the structure of the following Chemical Formula 4, and the perinone-based dye (c2) preferably comprises the structure of the following Chemical Formula 5.

##STR00009##

[0051] The functional black dye (C) can be used in 0.1 to 1.0 parts by weight, preferably in 0.1 to 0.3 parts by weight, more preferably in 0.15 to 0.25 parts by weight based on 100 parts by weight of the transparent thermoplastic resin (A). When the amount of the functional black dye is out of the above-mentioned range according to thicknesses of resin molded articles, color exhibition and pleochroism exhibition cannot be easily performed.

[0052] The molded article manufactured by the coloring resin composition exhibiting pleochroism of the present invention exhibits a variety of colors according to thicknesses in case of irradiation with light sources in a single wavelength. The molded article satisfies the following Mathematical Formula 1 in one specific embodiment, and the molded article satisfies the following Mathematical Formula 2 in another specific embodiment. If the following Abs (X) or Abs (Y) value increases, exhibited color difference can visually highly increase. Especially, when the Abs (X) or Abs (Y) value of the following Mathematical Formulas 1 and 2 is more than 0.05, preferably more than or equal to 0.10, more preferably more than or equal to 0.15, pleochroism exhibition, the objective of the present invention, can be possible.

Abs(X)=|X.sub.1X.sub.2|>0.05[Mathematical Formula 1]

[0053] X.sub.1= value of a CIE 1931 color space for the molded article having a thickness of 1.0 mm

[0054] X.sub.2= value of a CIE 1931 color space for the molded article having a thickness of 1.5 mm

Abs(Y)=|Y.sub.1Y.sub.2|>0.05[Mathematical Formula 2]

[0055] Y.sub.1=y value of a CIE 1931 color space for the molded article having a thickness of 1.0 mm

[0056] Y.sub.2=y value of a CIE 1931 color space for the molded article having a thickness of 1.5 mm

[0057] The resin molded article manufactured by the coloring resin composition of the present invention can be manufactured as products with a variety of shapes according to the purpose of use. The present invention has superior economical properties in terms that colors of transmitted light can be varied according to thicknesses of molded articles, although coloring resin compositions based on the same composition are used; and can be used in a variety of fields. However, in order to vary color of transmitted light into a variety of colors based on light sources in a single wavelength, that is to perform pleochroism exhibition, molded articles are preferably manufactured to have continuous or incontinuous change in thickness.

[0058] In one specific embodiment, a resin molded article manufactured based on the coloring resin composition of the present invention can be a flat type molded article whose thickness can vary in a stepwise manner by forming one or more stepped parts. Referring to the FIG. 1, when thicknesses of the flat type molded article vary into 1.0, 1.5, 2.0, 2.5, and 3.0 mm in a stepwise manner, even the same point source makes a variety of colors exhibited according to the thicknesses. Further, when a surface light source is used instead of the point source as necessary, a variety of colors of surface light emitting effect can be obtained.

[0059] In another specific embodiment, the resin molded article of the present invention can be a molded article whose width between one side and the opposite side thereof continuously varies. Referring to the FIG. 4, when the cross section of the molded article forms a wave pattern by forming one or more curved parts on one side of the molded article, the thickness of the molded article continuously varies, and thus color change of transmitted light showing gradating effect can be obtained even though the light sources in a single wavelength are used.

[0060] Hereinafter, preferred Examples of the present invention are described. However, the following Examples are the preferred Examples of the present invention, but not limited to the following Examples.

EXAMPLES

[0061] Definition of Each Component Used for the Examples

[0062] (A) Thermoplastic Resin

[0063] A polycarbonate resin (Cheil Industries Inc. SC-1120UR) having light transmissivity of 91%, measured using a haze meter is used.

[0064] (B) Dye for Coloring a Resin

[0065] (b3) Methine-Based Dye [0066] Chemical Formula: Methyl-2-[(1,5-Dihydro-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yidene)-ehylidene]-1,3,3-trimethylindoline-5-carboxylate [0067] CAS No: 5718-26-3 [0068] Color Index: Solvent Orange 107

[0069] (C) Functional Black Dye

[0070] (c1) Anthraquinone-Based Dye [0071] Chemical Formula: 1,4-Bis(p-tolylamino)anthraquinone [0072] CAS No: 128-80-3 [0073] Color Index: Solvent Green 3

[0074] (c2) Perinone-Based Dye [0075] Chemical Formula: 14H-Benz[4,5]isoquino[2,1-a]perimidin-14-one [0076] CAS No: 6829-22-7 [0077] Color Index: Solvent Red 179

Examples 1 to 4

[0078] Each of components as above are mixed based on the composition of the following Table 1 and blended, and then the mixture is introduced into a biaxial extruder (L/D=32, =30 mm). A pellet type resin composition is manufactured based on the mixture through the extruder; specimens are manufactured using a 3 oz injector at the injection temperature of 230 C.; and then resin molded articles of Examples 1 to 4 having thickness variation by 0.5 mm unit are manufactured. Average values are obtained by irradiating the manufactured color filter with an LED light source (750 mA, 1/T time: 500 ms.sup.1) and repeatedly 5 times measuring the coordinate values of the CIE1931 color space of transmitted light through the specimens, the resin molded articles, under a CD method (actinography on a predetermined area) condition using a compact array spectrometer (CAS) machine. The average values of the color coordinates are shown on the following Table 2.

TABLE-US-00001 TABLE 1 Examples Item 1 2 3 4 Thickness of Specimen 1.0 mm 1.5 mm 2.0 mm 2.5 mm (A) Transparent Thermoplastic Resin 100 100 100 100 (B) Coloring Dye 0.02 0.02 0.02 0.02 (C) Functional Black (c1) Anthraquinone-based 0.09 0.09 0.09 0.09 Dye (c2) Perinone-based 0.11 0.11 0.11 0.11 (Unit: parts by weight)

TABLE-US-00002 TABLE 2 Red Effect Examples Thickness x Average Abs (X) y Average Abs (Y) z Average Average 1 1.0 mm 0.4015 0.5537 0.0448 11.22 2 1.5 mm 0.6982 0.2967 0.3734 0.1803 0.0716 66.72 3 2.0 mm 0.6711 0.0271 0.2768 0.0966 0.0521 84.86 4 2.5 mm 0.6621 0.0090 0.2578 0.0190 0.0801 91.00

[0079] The present inventor sets a CIE 1931 XYZ color space (or CIE 1931 color space) shown on FIG. 3A as the object standard in order to determine the pleochroism exhibition of the coloring resin composition exhibiting pleochroism of the present invention. The CIE 1931 color space is one of initial color spaces mathematically defined based on research on the color recognition of humans and shows pleochroism exhibited by the resin composition of the present invention in a numerical manner. FIG. 3B shows the color coordinates of transmitted light through the specimens of Examples 1 to 4 on the CIE 1931 color space. It is confirmed that colors on the color space of FIG. 4 corresponding the color coordinates of Example 1 (1.0 T), Example 2 (1.5 T), Example 3 (2.0 T), and Example 4 (2.5 T) are the color exhibited by transmitted light through the specimens.

[0080] Based on Examples 1 to 4, specimens manufactured based on the coloring resin composition of the present invention exhibit a variety of colors according to thicknesses of the specimens although light sources of a single wavelength and properties transmit the specimens.

[0081] Examples are one specific embodiment of the present invention, and can have plenty of number of cases based on the combination of colors exhibited according to composition of resin compositions, properties of a light source, and thicknesses of specimens; and the application thereof does not have limitation.

[0082] Since the coloring resin composition exhibiting pleochroism of the present invention has optical properties showing pleochroism as above, it can be used in a variety of any technical fields where lighting such as a computer monitor bezel, a mobile phone, a vehicle headlight, and the likes is used without limitation and have properties exhibiting a variety of colors according to thicknesses of molded articles.

[0083] Simple modification or change of the present invention can be carried out by those who skilled in the art, and it seems that those modification or change are included in the field of the present invention.