COMPOSITE LAYER STRUCTURE, DECORATED MOLDING ARTICLE AND METHOD FOR FABRICATING THE SAME
20220347985 · 2022-11-03
Assignee
Inventors
Cpc classification
B32B2307/406
PERFORMING OPERATIONS; TRANSPORTING
B29C48/21
PERFORMING OPERATIONS; TRANSPORTING
B32B27/302
PERFORMING OPERATIONS; TRANSPORTING
B32B37/02
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/4023
PERFORMING OPERATIONS; TRANSPORTING
B29C45/14688
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B2250/246
PERFORMING OPERATIONS; TRANSPORTING
B29C2045/14696
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/54
PERFORMING OPERATIONS; TRANSPORTING
B29C2045/14713
PERFORMING OPERATIONS; TRANSPORTING
B32B27/308
PERFORMING OPERATIONS; TRANSPORTING
B29C51/10
PERFORMING OPERATIONS; TRANSPORTING
B29C45/14786
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/4026
PERFORMING OPERATIONS; TRANSPORTING
B32B27/20
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/409
PERFORMING OPERATIONS; TRANSPORTING
International classification
B29C45/14
PERFORMING OPERATIONS; TRANSPORTING
B29C48/21
PERFORMING OPERATIONS; TRANSPORTING
B29C51/10
PERFORMING OPERATIONS; TRANSPORTING
B32B27/20
PERFORMING OPERATIONS; TRANSPORTING
Abstract
Provided is a composite layer structure comprising a first layer and a second layer. The second layer is disposed on the first layer. A material of the second layer is different from a material of the first layer. The composite layer structure is formed by a co-extrusion molding film process, and the composite layer structure has a thickness of between 0.01 mm and 1 mm. Further, the present invention also provides a decorated molding article and a method for fabricating the same.
Claims
1. A decorated molding article, comprising: a workpiece; a composite layer structure, attached onto an outer surface of the workpiece via an adhesive layer, comprising: a first layer; and a second layer, disposed on the first layer, wherein a material of the second layer comprising poly(methyl methacrylate) is different from a material of the first layer comprising acrylonitrile butadiene styrene copolymer, the composite layer structure is formed by a co-extrusion molding film process, and the composite layer structure has a thickness of between 0.01 mm and 1 mm, wherein the material of the first layer is 70 wt % to 80 wt %, and the material of the second layer is 20 wt % to 30 wt %, based on a total weight of the material of the first layer and the material of the second layer; and a decorative layer, disposed between the composite layer structure and the adhesive layer.
2. The decorated molding article of claim 1, wherein a material of the outer surface of the workpiece comprises plastics, resin, metal, carbon fiber, glass, or a combination thereof.
3. The decorated molding article of claim 1, wherein the workpiece comprises a housing or component of an electronic device, a housing or component of a vehicle, or a combination thereof; and the housing or component of the vehicle comprises an automotive interior decoration, an automotive exterior decoration, an automotive logo, an automotive dashboard, an intelligent key, an engine start button or a combination thereof.
4. The decorated molding article of claim 1, wherein the material of the first layer further comprises polycarbonate, polypropylene, polyurethane, acrylonitrile styrene acrylate rubber copolymer, acrylonitrile-styrene copolymer, methyl methacrylate acrylonitrile butadiene styrene copolymer, polystyrene, methyl methacrylate styrene copolymer, or a combination thereof.
5. The decorated molding article of claim 1, wherein the material of the second layer further comprises polycarbonate, polypropylene, polyurethane, acrylonitrile styrene acrylate rubber copolymer, acrylonitrile-styrene copolymer, methyl methacrylate acrylonitrile butadiene styrene copolymer, polystyrene, methyl methacrylate styrene copolymer, or a combination thereof.
6. The decorated molding article of claim 1, wherein a mixed region is included between the first layer and the second layer, the mixed region comprises both of the material of the first layer and the material of the second layer.
7. The decorated molding article of claim 1, wherein the first layer further comprises a color concentrate, a pigment, a pearl powder or a combination thereof, so that the composite layer structure has colorful, pearlescent, glossy, mirror-like or other visual effects.
8. The decorated molding article of claim 1, wherein the composite layer structure is a transparent composite layer structure.
9. A method for fabricating a decorated molding article comprising: providing a first material to a first screw of a co-extrusion blow molding machine, wherein a first material comprises acrylonitrile butadiene styrene copolymer; providing a second material to a second screw of the co-extrusion blow molding machine, wherein the second material comprises poly(methyl methacrylate); performing a co-extrusion molding film process, so that the first material and the second material are extruded to form a composite layer structure; after performing the co-extrusion molding film process, forming a decorative layer on the composite layer structure; after performing the co-extrusion molding film process, performing an in-mold decoration or an out mold decoration on the composite layer structure, so that the composite layer structure is attached onto an outer surface of a workpiece via an adhesive layer to form the decorated molding article, wherein the first material is different from the second material, the first material is 70 wt % to 80 wt %, and the second material is 20 wt % to 30 wt %, based on a total weight of the first material and the second material, wherein the composite layer structure has a thickness of between 0.01 mm and 1 mm, wherein the decorative layer is disposed between the composite layer structure and the adhesive layer.
10. The method for fabricating the decorated molding article of claim 9, wherein the first material further comprises polycarbonate, polypropylene, polyurethane, acrylonitrile styrene acrylate rubber copolymer, acrylonitrile-styrene copolymer, methyl methacrylate acrylonitrile butadiene styrene copolymer, polystyrene, methyl methacrylate styrene copolymer, or a combination thereof.
11. The method for fabricating the decorated molding article of claim 9, wherein the second material further comprises polycarbonate, polypropylene, polyurethane, acrylonitrile styrene acrylate rubber copolymer, acrylonitrile-styrene copolymer, methyl methacrylate acrylonitrile butadiene styrene copolymer, polystyrene, methyl methacrylate styrene copolymer, or a combination thereof.
12. The method for fabricating a decorated molding article of claim 9, further comprising, prior to performing the co-extrusion molding film process, providing a third material to a third screw of the co-extrusion blow molding machine, wherein the third material comprises a color concentrate, a pigment, a pearl powder, or a combination thereof.
13. The method for fabricating a decorated molding article of claim 9, further comprising, prior to performing the co-extrusion molding film process, providing a fourth material to a fourth screw of the co-extrusion blow molding machine, wherein the fourth material comprises an additive.
14. The method for fabricating a decorated molding article of claim 9, wherein a method for forming the decorative layer comprises printing, spraying, electroplating, evaporation deposition, sputtering, or a combination thereof.
15. The method for fabricating a decorated molding article of claim 9, wherein the performing the in-mold decoration on the composite layer structure comprises: disposing the composite layer structure in an in-mold decoration mold having a mold cavity, wherein the composite layer structure covers at least a portion of a surface of the mold cavity; injecting a molding material into the in-mold decoration mold, so that the molding material and the composite layer structure are combined with each other; cooling the molding material; and taking the decorated molding article out from the in-mold decoration mold.
16. The method for fabricating a decorated molding article of claim 9, wherein the performing the out mold decoration on the composite layer structure comprises: providing a workpiece; placing the workpiece and the composite layer structure in a fixture; and performing a high pressure decorative molding process, so that the composite layer structure is attached onto the outer surface of the workpiece via the adhesive layer.
17. The method for fabricating a decorated molding article of claim 16, wherein the high pressure decorative molding process comprises: performing a heating and softening step on the composite layer structure; contacting the composite layer structure with the workpiece, and performing a pressurizing step; and performing a high pressure vacuum molding step on the composite layer structure and the workpiece, so that the composite layer structure is attached onto the outer surface of the workpiece.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0030] The features and advantages of the present invention set forth above will be described in view of the following examples with reference to the accompanying drawings.
[0031]
[0032]
[0033]
[0034]
[0035]
[0036]
[0037]
DESCRIPTION OF THE EMBODIMENTS
[0038] The present invention is described more detailed hereinafter with reference to the accompanying drawings. However, the present invention may be embodied in a variety of ways and is not limited to the examples set forth herein. Spatially related terms used in the following examples, such as “upper,” “lower,” and the like, may refer to the orientations of the attached drawings, and are therefore intended for the purposes of illustration rather than limitation. Furthermore, thicknesses of layer s and regions in the drawings will be exaggerated for clarity. Same or like numeral references denote same or like elements, and the descriptions thereof will be omitted hereinafter.
[0039]
[0040] Referring to
[0041] In an embodiment, the composite layer structure 100 is formed by a co-extrusion molding film process. Thus, a mixed region 106 is included between the first layer 102 and the second layer 104. The mixed region 106 includes a portion of the first layer 102 and a portion of the second layer 104. That is to say, the mixed region 106 includes both the material of the first layer 102 and the material of the second layer 104. For example, the mixed region 106 includes acrylonitrile butadiene styrene copolymer (ABS) and poly(methyl methacrylate) (PMMA). In some embodiments, acrylonitrile butadiene styrene copolymer and poly(methyl methacrylate) in the mixed region 106 may be mixed together. In an alternate embodiment, poly(methyl methacrylate) in the mixed region 106 may be disposed on the acrylonitrile butadiene styrene copolymer as well. A method for fabricating the composite layer structure 100 will be described in more details hereinafter and thus the related descriptions will be omitted.
[0042] In an embodiment, the first layer 102 of the composite layer structure 100 further includes a color concentrate, a pigment, a pearl powder or a combination thereof, such that the composite layer structure 100 has colorful, pearlescent, glossy, mirror-like or other visual effects. For example, the composite layer structure 100 may have decorative effects such as glossy black and electroplating silver. However, the present invention is not limited thereto. In other embodiments, the second layer 104 of the composite layer structure 100 may also include a color concentrate, a pigment, a pearl powder, or a combination thereof. In an alternate embodiment, both of the first layer 102 and the second layer 104 of the composite layer structure 100 may include a color concentrate, a pigment, a pearl powder, or a combination thereof. In another embodiment, the composite layer structure 100 may be a transparent composite layer structure as well.
[0043] In an embodiment, the composite layer structure 100 has a thickness of between 0.01 mm and 1 mm. In an alternate embodiment, the apparent surface gloss (i.e., the surface gloss measured by using a surface gloss meter at an angle of 60 degrees) of the composite layer structure 100 is about 80% or more. In other embodiments, the composite layer structure 100 has a density of about 1.06 g/ml or more. However, the present invention is not limited thereto. In other embodiments, the thickness, uniformity of brightness, density, and the like of the composite layer structure 100 may be adjusted depending on different materials thereof.
[0044]
[0045] Referring to
[0046] In an embodiment, the screw is a supply unit for melting the plastics in the extrusion process, and plays an essential role in the quality of the melted plastics. That is to say, the main functions of the screw are to melt the solid plastics, transfer the melted plastics, homogenize the plastics and provide the pressure required for the melted plastics extruding out of the die head. Specifically, as shown in
[0047] In an embodiment, the feeding section 12 (also referred to as a solids transport section) is used to compress the solid plastic particles and push them forward smoothly. The conveying method in this section is transported by the drag and the guide of the screw. In other words, the difference between a frictional force of the plastics against the casing and a frictional force of the plastics against the surface of the screw is used to push the solid plastic particles (referred to the first material here) forward. The greater the difference between the frictional force of the plastics against the inner side of the casing and the frictional force of the plastics against the surface of the screw is, the greater the transportability is. In order to increase the frictional force of the plastics against the casting, the surface of the casting may be engraved with a plurality of longitudinal grooves parallel to the screw, such that the frictional force is significantly increased and the first material is pushed forward along the axial direction of the screw rather than twisted surrounding the screw, thereby improving the capability of the solids transport section.
[0048] In an embodiment, the compression section (also referred to as a melt section) 14 is located at the end of the feeding section 12 where the groove depth of the longitudinal groove gradually decreases along the direction of the screw. When the first material is transferred from the feeding section 12 to the compression section 14, the frictional heat of the solid particles of the first material and external heating cause the plastics begin to melt. The volume of the plastics is decreased while melting, so the depth of the groove needs to be reduced as well to match the decreased volume of the plastics. In addition, as the depth of the groove is reduced, the flow is constrained, so that the pressure in this area is gradually increased, thereby generating a pressurized effect on the first material.
[0049] In an embodiment, the metering section (also referred to as a melt transfer section) 16 is the last section in the first screw 10 that controls the flow. When the melt enters this section, it is thoroughly mixed and pressurized, so as to resist the back pressure of the die head at the front end of the first screw 10.
[0050] Referring back to
[0051] In this case, the composite layer structure 100a of the first embodiment may be a transparent composite layer structure. However, the present invention is not limited thereto.
[0052] In other embodiments, prior to the co-extrusion molding film process 45, the first material and a color concentrate, a pigment, a pearl powder, and additional additives may be blended to form a mixture. Next, the mixture and the second material are subjected to the co-extrusion molding film process 45 to form another composite layer structure, such that the composite layer structure has colorful, pearlescent, glossy, mirror-like, lusterless matte or other visual effects.
[0053] Further, after performing co-extrusion molding film process 45, various surface treatments (such as gloss, matt, and geometric texture) may be performed by the pressure roller in the back end of the extrusion process.
[0054]
[0055] Referring to
[0056] As shown in
[0057] Although the embodiments of
[0058]
[0059] Referring to
[0060] As shown in
[0061] In an embodiment, the decorative layer 110 may be formed by printing, spraying, electroplating, evaporation deposition, sputtering, or a combination thereof. For example, the decorative layer 110 may be composed of a printing ink or a printable material, which may be a single ink layer, multiple ink layers, or a patterned ink layer for example, so as to present a single color, multiple colors or desired patterns respectively. The decorative layer 110 may increase the diversity of patterns and colors of the composite layer structure 100, so as to enrich the visual effects of the user or the viewer. In an alternate embodiment, the decorative layer 110 may be formed by gravure printing, screen printing, offset printing, reverse printing, inkjet printing, or any suitable printing method. In other embodiments, a material of the decorative layer 110 may include polyurethane (PU), polyacrylate, polyethylene terephthalate (PET), ethylene, propylene, polymer of higher olefins (polyolefin, PO), poly(methyl methacrylate) (PMMA), acrylonitrile styrene acrylic rubber copolymer (ASA), acrylonitrile-styrene copolymer (SAN), methyl methacrylate acrylonitrile butadiene styrene copolymer (MABS), polystyrene (PS), methyl methacrylate styrene copolymer (MS), or any suitable material, which may be mixed with an inorganic material.
[0062] As shown in
[0063]
[0064]
[0065] In detail, referring to
[0066] Next, in the step S104, the composite layer structure 100 is disposed in an in-mold decoration mold. In detail, the in-mold decorative mold includes a hollow molding cavity. The molding cavity has a surface. Thereafter, the composite layer structure 100 is attached onto the surface of the molding cavity, such that the composite layer structure 100 covers at least a portion of the surface of the molding cavity. In an alternate embodiment, prior to step S106, a heating and pre-molding step may be optionally performed, and an excessive portion of the composite layer structure is removed by using die cutting, laser cutting, or water jet cutting.
[0067] Then, in the step S106, a molding material is injected into the molding cavity of the in-mold decorative mold, such that the molding material and the composite layer structure 100 are combined with each other. In an embodiment, the molding material may be a plastic material, a resin material, a metal material, a carbon fiber material, glass, or any suitable molding material.
[0068] Thereafter, in the step S108, the molding material is cooled to form the workpiece 200. Depending on the applications of the decorated molding article of the present invention, the workpiece 200 may be a housing or component of an electronic device, a housing or component of a vehicle, or a combination thereof. For example, the workpiece 200 may be a housing or component used in an electronic device, such as a mobile phone, a digital camera, a personal digital assistant (PDA), a laptop computer, a desktop computer, a touch panel, a television, a global positioning system (GPS) device, a car monitor, a navigator, a display, a digital photo frame, a DVD player, automotive interior trim panels (e.g., handles, trims, touchable front bumpers and the like), automotive exterior trim panels (e.g., exterior handles, back door trim strips and the like), an automotive dashboard, an automotive logo, an intelligent key (I-key), an engine start button, a clock, a radio, a toy, a watches, or other electronic devices that require electricity. However, the present invention is not limited to the shape and structure of the workpiece 200. Any workpiece 200 of which the shape and structure may be accomplished by IMD falls within the scope of this invention.
[0069] Next, in step S110, the decorated molding article 1 is taken out from the in-mold decorative mold. The obtained decorated molding article 1 is described above in
[0070] On the other hand, the decorated molding article 1 may also be manufactured by OMD. Referring to
[0071] Next, in step S204, a composite layer structure is provided. The composite layer structure may be the composite layer structure 100 or the composite layer structure 100′ having the decorative layer 110 as shown in
[0072] Thereafter, in step S206, the workpiece 200 and the composite layer structure 100 are placed in a fixture. It should be noted that, prior to step S206, the fixture may optionally tailored depending on the demands of the final products and manufactured accordingly.
[0073] Then, in step S208, a high pressure decorative molding process is performed to attach the composite layer structure 100 onto the outer surface 200a of the workpiece 200 via an adhesive layer 120. Accordingly, the adhesive layer 120 is disposed between the decorative layer 110 and the workpiece 200. In detail, the high pressure decorative molding process includes firstly performing a heating and softening step on the composite layer structure 100, for example. In an embodiment, the temperature for the heating and softening step ranges from 80° C. to 150° C.; the duration for the heating and softening step ranges from 30 seconds to 180 seconds. Next, the composite layer structure 100 is in contact with the workpiece 200, and a pressurizing step is performed. Thereafter, a high pressure vacuum molding step is performed on the composite layer structure 100 is subjected, so as to attach the composite layer structure 100 onto the workpiece 200. Finally, a remaining composite layer structure may be optionally removed by die cutting, laser cutting, or water jet cutting. Briefly, in this embodiment, the composite layer structure 100 is adhered tightly onto the outer surface 200a of the workpiece 200 by OMD.
[0074] In view of the foregoing, the present invention combines a first layer and a second layer which have different materials to form a composite layer structure, such that the composite layer structure has both high hardness and high tensile properties suitable for subsequent IMD or OMD. Further, the present invention provides a method for fabricating a decorated molding article, which may perform a dyeing treatment during the formation of the composite layer structure. Therefore, the composite layer structure may achieve decorative effects without an additional printing process so as to reduce the costs and improve the yields.
[0075] Although the invention is disclosed with reference to the above embodiments, it will be apparent to one of ordinary skill in the art that modifications and alterations thereof may be made without departing from the spirit and scope of the invention. Thus, the scope of the invention should be defined by the appended claims and their equivalents.